• Applied Chemistry for Engineering
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• v.34 no.5
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• pp.493-500
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• 2023

In this study, we developed an impedance sensor capable of controlling electrode polarization by coating iridium oxide (IrO_x) on the surface of the screen-printed carbon electrode. IrO_x was deposited on the surface of carbon electrodes according to the number of cycles (0~50 cycles) by cyclic voltammetry. Observation of scanning electron microscope images revealed that the size and number of IrO_x particles increased as the number of cycles increased. The changes in impedance responses as a function of the NaCl concentration of the as-obtained sensors were investigated using electrochemical impedance spectroscopy. The sensors manufactured in 50 cycles exhibited the best coefficient of determination and reproducibility, attributed to the well-controlled electrode polarization. We further demonstrated the usefulness of the IrO_x-based sensor as a diagnosis sensor for dry eye syndrome by comparing the results of the commercially available osmometer and our sensor using actual solution samples.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.25 no.4
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• pp.97-103
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• 2011

The most important object of grounding systems is to protect human being from electric shock. Touch and step voltages are measured to evaluate the performances of grounding systems. Dangerous voltages have been largely studied by the power frequency fault currents, on the other hand, the ground current containing the high frequency components and surge currents haven't been considered. Many attempts about the grounding impedances reported in these days show that the performance of the grounding systems in high frequency range is very different with the ground resistance. It is necessary to analyze the dangerous voltages formed by the ground currents containing high frequency components. In this paper, the ground surface potential rises near the vertical and horizontal grounding electrodes are measured at the frequency of 100[Hz], 30[kHz], and 100[kHz]. Dangerous voltages are investigated with the frequency-dependent grounding impedance. As a result, the ground surface potential rise is increased as the grounding impedance increases. Touch and step voltages near the grounding electrode whose impedance increases with the frequency are sharply raised.

• 한국전기화학회:학술대회논문집
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• 2001.11a
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• pp.145-161
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• 2001

Novel characterization of thermal properties of a battery has been introduced by defining its frequency-dependent thermal impedance function. Thermal impedance function can be approximated as a thermal impedance spectrum by analyzing experimental temperature transient which is related to the thermal impedance function through Laplace transformation. In order to obtain temperature transient, a process has been devised to generate external heat pulse with heating wire and to measure the response of battery. This process is used to study several commercial Li-ion batteries of cylindrical type. The thermal impedance measurements have been performed using potentionstat/galvanostate controlled digital signal processor, which is more commonly available than flow-meter usually applied for thermal property measurements. Thermal impedance spectra obtained for batteries produced by different manufactures are found to differ considerably. Comparison of spectra at different states of charge indicates independence of thermal impedance on charging state of battery. It is shown that thermal impedance spectrum can be used to obtain simultaneously thermal capacity and thermal conductivity of battery by non-linear complex least-square fit of the spectrum to thermal impedance model. Obtained data is used to simulate a response of the battery to internal heating during discharge. It is found that temperature inside the battery is by one-third larger that on its surface. This observation has to be considered to prevent damage by overheating.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.6 no.4
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• pp.648-662
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• 1996

Electrode surface reaction on glassy carbon and synthesized graphite (PVDF mixed graphite) in sulfuric acid solution is investigated by impedance spectroscopy at cyclic polarization. The redox peak, which may be due to the change of chemical adsorped functional group on electrode surface or oxidation and reduction of oxygen, is represented on glassy carbon and graphite electrode in potentio-dynamic current curve. The oxidation and reduction of these surface functional group on glassy carbon and PVDF mixed graphite have a major affect on the impedance spectrum and Faraday impedance parameter at cyclic polarization.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.6 no.4
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• pp.571-583
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• 1996

The electrochemical behavior on electrographite and graphite foil electrode with porous surface in 0.5 M $K_{2}SO_{4}$ solution with 1 mM $[Fe(CN)_{6}]^{3-}/[Fe(CN)_{6}]^{4-}$ have been characterized by impedance spectroscopy. In cyclic voltammograms, relative high current according to structure of porous surface for graphite materials was represented, and indicated hgih double layer capacitance on graphite foil. The faraday-impedance and the change of impedance spectrum on both graphite materials were not remarkable during polarization by reaction of field transport. Chemical adsorption was represented on electrographite and was depended highly at anodic polarization.

• Korean Journal of Metals and Materials
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• v.47 no.10
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• pp.644-651
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• 2009

The passivation (or deactivation) of a metal surface during oxide film formation has been quantitatively explored for a ferritic stainless steel by using dynamic electrochemical impedance spectroscopy (DEIS). For this purpose, the electrochemical impedance spectra were carefully examined as a function of applied potential in the active nose region of the potentiodynamic polarization curve, to separate the charge transfer resistance and oxide film resistance. From the discrepancy in the potential dependence between the experimental charge transfer resistance and the semi-empirically expected one, the degree of passivation could be quantitatively estimated. The sensitivity of passivation of the steel surface to anodic potential, which might be the measure of the quality of the oxide film formed under unit driving force or over-potential, decreased by 31% when 3.5 wt% NaCl was added to a 5 wt% $H_2SO_4$ solution.

• Journal of Sensor Science and Technology
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• v.26 no.3
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• pp.149-154
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• 2017

Detection of rain is one of the essential weather factors that are monitored by automatic weather stations in Korea. In this work, we studied the operation standards required for impedance-based rain detectors in terms of surface temperature and sensitivity, in an effort to establish a qualification procedure for rain detectors. The surface temperature of rain detectors was measured at varying air temperatures from $-30^{\circ}C$ to $20^{\circ}C$, considering the hypothetical presence and absence of rain/snow. In addition, the sensitivity of rain detectors was studied generating artificial raindrops of regular size. The sensitivity was evaluated in terms of the critical number of droplets that triggers the activation of the rain detector. We found that the sensitivity is affected by stationary, horizontal, and vertical droplet deposition methods. The critical number of droplets for the stationary deposition is higher than that for both horizontal and vertical depositions, which provides the maximum limit of droplets required to activate the detector. Based on our experiments considering surface temperature measurements and sensitivity tests, we suggest a revised version of surface temperature and sensitivity requirements for the qualification of impedance-based rain detectors.

• The Journal of the Acoustical Society of Korea
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• v.19 no.7
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• pp.85-89
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• 2000

In this paper, by extending the previously developed self- and mutual-radiation impedance calculation method for a regular-square vibrating surface by using numerical series, we proposed a method to obtain the self-radiation impedance of a rectangular transducer with an arbitrary integer ratio of the length to width. The proposed method exhibits high accuracy and a short computation time. After investigating the accuracy and computation time as the number of elements changes, we have calculated the self-radiation impedance of several rectangular transducers, and compared the results with those in the literature.

• Journal of the Korean Society for Nondestructive Testing
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• v.31 no.1
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• pp.11-23
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• 2011

In this study, a finite element(FE) analysis on electro-mechanical impedance response of cable-anchor connection interface under various anchor force is presented. In order to achieve the objective, the following approaches are implemented. Firstly, an interface washer coupled with piezoelectric(PZT) material is designed for monitoring cable-force loss. The interface washer is a small aluminum plate on which a PZT patch is surface-bonded. Cable-force loss could be monitored by installing the interface washer between the anchor plate and the anchorage of cable-anchor connection and examining the changes of impedance of the interface washer. Secondly, a FE model for cable-anchor connection is established to examine the effect of cable-force on impedance response of interface washer. Also, the effects of geometrical and material properties of the interface washer on impedance responses under various cable-forces are investigated. Finally, validation of the FE analysis is experimentally evaluated by a lab-scale cable-anchor connection.

• 한국초전도학회:학술대회논문집
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• v.12
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• pp.18-18
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• 2002