• Physical Therapy Rehabilitation Science
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• v.11 no.4
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• pp.579-584
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• 2022

Objective: To identify the effect of unstable surface kettlebell exercises on muscle activity and balance in middle and high school baseball players. Design: Randomized controlled trial. Methods: The participants were 29 middle and high school baseball players (Unstable surface kettlebell exercises group, USKE: 15; Stable surface kettlebell exercise group, SSKE: 14). The players in the USKE group performed kettlebell exercises for 60 mins on a stable surface thrice a week for 6 weeks, and the return rack was solidified on a stable surface in the same way as the experimental group. Before and after the experiment, the participant's muscle activity of the tibialis anterior and soleus was measured. In addition, the participant's balance was evaluated by measuring the distance moved from the foot's center of pressure (COP). The paired t-test was used to compare groups before and after the experiment. The independent t-test was conducted to assess differences in the degree of change between the two groups before and after the experiment. Results: Compared to the SSKE group, the USKE group showed significant differences in the muscle activity of the tibialis anterior and soleus and the balance with the eyes open and closed. Conclusions: The players in the USKE group showed a significant difference in muscle activity and balance than in those in the SSKE group. Thus, effectively including an unstable surface in the kettlebell exercise program will help improve physical function in athletes and people with musculoskeletal disorders.

• Membrane and Water Treatment
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• v.15 no.3
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• pp.139-152
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• 2024

Mixed matrix membranes have gained significant recognition in the wastewater treatment industry for their effectiveness in removing dyes, proteins, and heavy metals from water sources. Researchers have developed an innovative technique to enhance properties of these membranes by incorporating amine-functionalized carbon nanotubes into the polymer matrix. This approach introduces amine functional groups onto the membrane surface, which are then modified with trimesoyl chloride and cyanuric chloride. The modified membranes are characterized by XPS to confirm successful bonding of amines with the trimesoyl chloride and cyanuric chloride. The surface charge of the modified membrane also plays a role in the modification process; the membrane modified with trimesoyl chloride has a negative surface charge, while the one modified with cyanuric chloride has a more positive charge. At the same acidic pH, the positive or negative charge of the mixed matrix membranes assists in enhancing the rejection of heavy metals. This results in improved antifouling properties for both modified membranes. The heavy metal rejection for all modified membranes is higher than for unmodified membranes, due to both adsorption and complexation abilities of the functional groups on the membrane surface with heavy metal ions. As the membrane surface functionalities increase through modification, the separation due to complexation also increases. The bulk morphology of the membrane remains unchanged, while roughness slightly increases due to the surface treatment.

• Korean Chemical Engineering Research
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• v.53 no.1
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• pp.83-90
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• 2015

In this study, we investigated optimum conditions for the introduction of a lot of free radical polymerizable methacrylate groups on the multi-walled carbon nanotube (MWCNT) surface. Carboxyl groups were introduced first on MWCNT surfaces by treating with a mixture of sulfuric acid and nitric acid with ultrasonic bath for 2 hours, and oxidized MWCNTs were reacted further with thionyl chloride followed by triethylenetetramine (TETA) to introduce amino groups on the oxidized MWCNT surface, to make MWCNT-$NH_2$. To introduce free radical polymerizable methacrylate groups on the MWCNT-$NH_2$, MWCNT-$NH_2$ was reacted with 3-(acryloyloxy)-2-hydroxypropyl methacrylate (AHM) by Michael addition reaction. We investigated progress of modification reactions for MWCNT by fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and elemental analysis (EA). We found maximum degree of Michael addition reactions between AHM and TETA grafted on MWCNT-$NH_2$ for 10:1 mol ratio and 8 hour reaction time in our reaction conditions.

• The korean journal of orthodontics
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• v.45 no.4
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• pp.164-170
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• 2015

Objective: The aim of this study was to compare the shear bond strength (SBS) of orthodontic brackets bonded to zirconia surfaces using three different zirconia primers and one silane primer, and subjected to thermocycling. Methods: We designed 10 experimental groups following the surface treatment and thermocycling. The surface was treated with one of the following method: no-primer (NP), Porcelain Conditioner (PC), Z-PRIME Plus (ZP), Monobond Plus (MP) and Zirconia Liner Premium (ZL) (n=20). Then each group was subdivided to non-thermocycled and thermocycled groups (NPT, PC, ZPT, MPT, ZLT) (n=10). Orthodontic brackets were bonded to the specimens using $Transbond^{TM}$ XT Paste and light cured for 15 s at $1,100mW/cm^2$. The SBS was measured at a 1 mm/min crosshead speed. The failure mode was assessed by examination with a stereomicroscope and the amount of bonding resin remaining on the zirconia surface was scored using the modified adhesive remnant index (ARI). Results: The SBS of all experimental groups decreased after thermocycling. Before thermocycling, the SBS was ZL, $ZP{\geq}MP{\geq}PC>NP$ but after thermocycling, the SBS was $ZLT{\geq}MPT{\geq}ZPT>PCT=NPT$ (p > 0.05). For the ARI score, both of the groups lacking primer (NP and NPT) displayed adhesive failure modes, but the groups with zirconia primers (ZP, ZPT, MP, MPT, ZL, and ZLT) were associated with mixed failure modes. Conclusions: Surface treatment with a zirconia primer increases the SBS relative to no-primer or silane primer application between orthodontic brackets and zirconia prostheses.

• The Journal of Korean Academy of Prosthodontics
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• v.35 no.4
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• pp.719-741
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• 1997

This study was undertaken to compare by Atomic Force Microscope the effects of various finishing and polishing instruments on surface roughness of filling and veneering composite resins. Seven composite resins were studied : Silux Plus (3M Dental Products, U.S.A.), Charisma (Heraeus Kulzer, Germany), Prisma THP (L.D.Caulk, Dentsply, U.S.A.), Photoclearfil (Kuraray, Japan), Cesead (Kuraray, Japan), Thermoresin LC (GC, Japan), Artglass (Heraeus Kulzer, Germany). Samples were placed and polymerized in holes (2mm thick and 8.5mm in diameter) machined in Teflon mold under glass plate, ensuring excess of material and moulded to shape with polyester matrix strip. Except control group (Polyester matrix strip), all experimental groups were finished and polishied under manufacturer's instructions. The finishing and polishing procedure were : carbide bur (E.T carbide set 4159, Komet, Germany), diamond bur (composite resin polishing bur set, GC, Japan), aluminum-oxide disc (Sof-Lex Pop-On, 3M Dental Products, U.S.A.), diamond-particle disc (Dia-Finish, Renfert Germany), white stone bur & rubber point( composite finishing kit, EDENTA, Swiss), respectively. Each specimens were evaluated for the surface roughness with Atomic Force Microscope (AutoProbe CP, Park Scientific Instruments, U.S.A.) under contact mode and constant height mode. The results as follows : 1. Except Thermoresin LC, all experimental composite resin groups showed more rougher than control group after finishing and polishing(p<0.1). 2. A surface as smooth as control group was obtained by $Al_{2}O_{3}$ disc all filling composite resin groups except Charisma and all veneering composite resin groups except Thermoresin LC(p<0.05). 3. In case of Thermoresin LC, there were no statistically significant differences before and after finishing and polishing(p>0.1). 4. Carbide bur, diamond bur showed rough surfaces in all composite resin groups, so these were inappropriate for the final polishing instruments.

• Journal of Korean society of Dental Hygiene
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• v.16 no.1
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• pp.77-83
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• 2016

Objectives: This study was carried out to investigate the effect of fluoride application after dental prophylaxis by the type of dental floss. Methods: Artificial caries lesion was made on the surface of cow's permanent teeth having sound enamel surface and vickers hardness number(VHN) was measured. Specimens were classified into APF gel group and artificial saliva group. Each group was divided into waxed floss group and unwaxed flossed group. All specimens were immersed into the artificial saliva for one minute and dental flossing was applied to waxed or unwaxed floss. After washing and drying, APF gel groups were applied with fluoride for four minutes and artificial saliva groups were immersed into the artificial saliva for four minutes. After treatment, specimens were measured by VHN and surface conditions of enamel were confirmed by scanning electron microscopy(SEM). Results: VHN of waxed flossing and fluoride application group increased to $6.78{\pm}2.75$. VHN of unwaxed flossing and fluoride application group increased to $7.36{\pm}2.51$. There was no significant difference between waxed and unwaxed groups(p>0.05). VHN of waxed flossing and artificial saliva group increased to $1.07{\pm}2.84$. VHN of waxed flossing and artificial saliva group increased to $1.05{\pm}3.13$. There was no significant difference between waxed and unwaxed groups(p>0.05). There was significant increase in VHN between waxed/unwaxed flossing and fluoride application. However, waxed/unwaxed flossing with artificial saliva showed no significant VHN increase. SEM demonstrated no residue on the enamel surface in the waxed flossing groups. Conclusions: No difference was found in the remineralization of enamel by waxed flossing or unwaxed flossing.

• Journal of the Korean Applied Science and Technology
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• v.21 no.4
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• pp.345-351
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• 2004

Highly ordered pure-silica MCM-41 materials possessing well-defined morphology have been successfully prepared with surfactant used as a template. The fabrication of mesoporous silica has received considerable attention due to the need to develop more efficient materials' for catalysis, separations, and chemical sensing. The surface modified MCM-41 was used as anadsorbent for biomolecules. Silica-supported organic groups and DNA adsorption on surface modified MCM-41 were investigated by FT-IR and UV-Vis spectrometer, respectively. The use of MCM-41 as the modification of electrode surfaces were investigated electrochemical properties of metal mediators with biomolecules. The modified ITO electrodes increased peak currents for a redox process of $[Ru(bpy)_3]^{2+}$ relative to the bare electrode. The electrochemical detection of DNA by cyclic voltammetry when the current is saturated in the presence of the mediator appeared more sensitive due to a higher catalytic current on the MCM-41 supported electrodes modified by carboxylic acid functional groups. The carboxyl or amine groups on the surface of MCM-41 interact and react with the $-NH_2$ groups of guanine and backbone, respectively. Highly ordered mesoporous materials with organic groups could find applications as DNA sensors.

• Restorative Dentistry and Endodontics
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• v.12 no.1
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• pp.85-93
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• 1986

The purpose of this study was to investigate the curing effect of visible light through tooth substance, 0.5mm, 1.0mm thickness of enamel and dentin were prepared. Experimental specimen were made by Bisfil M & Silux packing into cylindrical brass mold 6.0mm in diameter, 2.0mm and 3.0mm, in height. All specimen were irradiated by visible light (Grip type) model No. SDL-50 Shofu Co.) for 30 seconds through tooth substance. Experimental groups were classified into enamel group (group 1) and dentin group (group 2) according to the thickness of tooth materials and then were divided into 2 subgroups (0.5mm group and 1.0mm group). In experimental groups, visible light irradiated to the specimen through either 0.5mm in thick or 1.0mm in think of tooth material. In Control group specimen were prepared by direct irradiation on the specimen surface of visible light without through tooth substance. The hardness was measured with a Barcol hardness tester (Barber-Colman Co. U.S.A.) for each prepared specimen. The results were as follows: 1. In control group, there were higher hardness values than those of in experimental group. 2. In experimental groups, 0.5mm groups had higher hardness values than 1.0mm groups did. 3. The hardness value at top surface of the specimen were higher than the hardness of bottom surface in each group. 4. Bisfil M had higher hardness values than Silux. 5. In all specimen of 3.0mm height polymerization effect was not occurred at bottom surface except Bisfil M in control group.

• International Journal of Naval Architecture and Ocean Engineering
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• v.9 no.2
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• pp.160-176
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• 2017

The interaction of focused wave groups with a vertical wall is investigated based on the second order potential theory. The NewWave theory, which represents the most probable surface elevation under a large crest, is adopted. The analytical solutions of the surface elevation, velocity potential and wave force exerted on the vertical wall are derived, up to the second order. Then, a parametric study is made on the interaction between nonlinear focused wave groups and a vertical wall by considering the effects of angles of incidence, wave steepness, focal positions, water depth, frequency bandwidth and the peak lifting factor. Results show that the wave force on the vertical wall for obliquely-incident wave groups is larger than that for normally-incident waves. The normalized peak crest of wave forces reduces with the increase of wave steepness. With the increase of the distance of focal positions from the vertical wall, the peak crest of surface elevation, although fluctuates, decreases gradually. Both the normalized peak crest and adjacent crest and trough of wave forces become larger for shallower water depth. For focused wave groups reflected by a vertical wall, the frequency bandwidth has little effects on the peak crest of wave elevation or forces, but the adjacent crest and trough become smaller for larger frequency bandwidth. There is no significant change of the peak crest and adjacent trough of surface elevation and wave forces for variation of the peak lifting factor. However, the adjacent crest increases with the increase of the peak lifting factor.

• Restorative Dentistry and Endodontics
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• v.16 no.2
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• pp.118-125
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• 1991

Eighty - eight recently extracted teeth were used to evaluate the leakage characteristics of the following retrofilling materials; amalgam, zinc oxide eugenol cement, glass - ionomer cement, and cermet glass - ionomer cement. Root canals were prepared with step - back method and obturated with gutta percha and zinc oxide eugenol sealer. Root apex were resected 2 mm from apex and class I cavities were prepared with 2 mm or 4 mm depth. The cavities were filled with above materials. After application of varnish on all surface except resected surface, the roots were placed in 1 % methylene blue solution for 6 days. After longitudinal polishing to expose cental parts of filled materials, penetrated depths of dye were measured. The results were as follws. 1. As retrofilling material, glass ionomer cement filling groups showed less leakage than the other groups except zinc oxide eugenol cement filling group(p<0.01). 2. Amalgam filling groups had greater leakage than zinc oxide eugenol cement filling group(p<0.01). 3. 4 mm depth of retrofilled cavity had no effect on leakage characteristics compared with 2 mm depth cavity(p>0.05). 4. Glass ionomer cement and cermet glass ionomer cement filling groups showed less apical leakage than amalgam filling groups. But there was no statistical significance(p>0.05). 5. There was no difference in apical leakage between glass ionomer cement filling groups and cermet glass ionomer cement filling groups(p>0.05).