• 제목/요약/키워드: surface energy effects

검색결과 1,235건 처리시간 0.041초

Effects of Plasma Surface Treatments Using Dielectric Barrier Discharge to Improve Diamond Films

  • Kang, In-Je;Ko, Min-Guk;Rai, Suresh;Yang, Jong-Keun;Lee, Heon-Ju
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.552-552
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    • 2013
  • In our study we consider Al2O3 ceramic substrates for Plasma Surface Treatments in order to improve deposited diamond surface and increase diamond deposition rate by applying DBD (Dielectric Barrier Dischrge) system. Because Plasma Surface Treatments was used as a modification method of material surface properties like surface free energy, wettability, and adhesion. By applying Plasma Surface Treatments diamond films are deposited on the Al2O3 ceramic substrates. DC Arc Plasmatron with mathane and hydrogen gases is used. Deposited diamond films are investigated by SEM (Scanning Electron Microscopy), AFM (Atomic Force Microscopy) and XRD (X-ray Diffractometer). Then the C-H stretching of synthetic diamond films by FTIR (Fourier Transform Infrared Spectroscopy) is studied. As a result, nanocrystalline diamond films were identified by using SEM and diamond properties in XRD peaks at (111, $43.8{\Box}$, (220, $75.3{\Box}$ and (311, $90.4{\Box}$ were shown. Absorption peaks in FTIR spectrum, caused by CHx sp3 bond stretching of CVD diamond films, were identified as well. Finally, we improved such parameters as depostion rate ($2.3{\mu}m$/h), diamond surface uniformity, and impurities level by applying Plasma Surface Treatments. These experimental results show the importance of Plasma Surface Treatments for diamond deposition by a plasma source.

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튜브의 열전도도와 튜브 외면에서의 대류열전달이 보텍스튜브의 에너지 분리에 미치는 영향 (The Effect of the Thermal Conductivity of a Tube and the Convective Heat Transfer on the Outer Surface of a Tube on the Energy Separation in Vortex Tubes)

  • 유갑중;이병화;최병철
    • 설비공학논문집
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    • 제13권9호
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    • pp.845-852
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    • 2001
  • The phenomena of energy separation in vortex tubes was investigated experimentally to see the effects of the conductivity of a tube and convective heat transfer on the outer surface of a tube. The experiment was carried out with different conductivity (pyrex, stainless steel and copper) of a tube and three kinds of convective heat transfer modes (adiabatic condition, natural convection (air) and forced convection (water) on the outer surface of a tube. the results were obtained that hot exit fluid temperature was highly affected by a change of conductivity of a tube when the outer surface was cooled by the forced convection of water. However, the cold exit temperature was little affected by heat transfer modes on the outer surface in vortex tubes.

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저속충돌조건에서 효과적인 충돌에너지흡수를 위한 알루미늄 크래쉬 박스의 비드형상 효과 (Effect of Bead Shape in Aluminum Crash Box for Effective Impact Energy Absorption Under Low- Velocity Impact Condition)

  • 이찬주;이선봉;고대철;김병민
    • 대한기계학회논문집A
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    • 제36권10호
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    • pp.1155-1162
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    • 2012
  • 알루미늄 크래쉬 박스는 저속충돌조건에서 프론트 사이드 멤버를 변형을 방지하기 위한 부품이다. 본 연구에서는 저속충돌조건에서 비드형상이 알루미늄 크래쉬 박스의 충돌성능에 미치는 영향을 분석하였다. Edge concave, surface convex 와 surface concave 타입의 비드형상들에 대한 충돌해석 및 실험을 수행하여 비드가 없는 normal 타입의 알루미늄 크래쉬 박스의 충돌성능과 비교분석하였다. 충돌성능은 저속충돌조건에서 크래쉬 박스의 초기 최대하중 및 충돌에너지 흡수능으로 평가하였다. 이를 검증하기 위해 알루미늄 크래쉬 박스와 결합된 프론트 사이드 멤버에 대해 저속충돌실험 수행하고, 이를 분석하였다. Surface concave 타입의 비드가 삽입된 알루미늄 크래쉬 박스 경우, 프론트 사이드 멤버의 변형을 방지할 수 있음을 확인하였다.

Activity Coefficients and Coulombic Correction Factor for Surface Complexation Modeling

  • Rhee, In-Hyoung
    • 한국산학기술학회논문지
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    • 제3권2호
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    • pp.146-155
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    • 2002
  • Surface complexation models employ mass law equations to describe the reaction of surface functional groups with ions in the solution and also Gouy-Chapman theory to consider the electrostatic effects in the surface reactions. In current surface complexation models, however, the coulombic factors used are not wholly consistent with the Gouy-Chapman model of the surface. This study was to provide the derivation of the coulombic term usually employed and then a revised coulombic term completely consistent with Gouy-Chapman Theory. The electrical potential energy. zF${\psi}$, in current surface complexation models is not consistent with the Gouy-Chapman theory with the potential gradient close to the charged surface but with the Donnan model with the uniform potential. Even though the new coulombic factor yielded lower surface potential, it provided worse fits for acid-base titration data of the goethite suspensions.

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Research on basic mechanical properties and damage mechanism analysis of BFUFARC

  • Yu H. Yang;Sheng J. Jin;Chang C. Shi;Wen P. Ma;Jia K. Zhao
    • Advances in concrete construction
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    • 제16권6호
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    • pp.277-290
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    • 2023
  • In order to study the mechanical properties of basalt fiber reinforced ultra-fine fly ash concrete (BFUFARC), the effects of ultra-fine fly ash (UFA) content, basalt fiber content, basalt fiber length and water reducing agent content on the compressive strength, splitting tensile strength and flexural strength of the composite material were studied through experimental and theoretical analysis. Also, a scanning electron microscope (SEM) was employed to analyze the mesoscopic structure in the fracture surface of composite material specimens at magnifications of 500 and 3500. Besides, the energy release rate (Gc) and surface free energy (γs) of crack tip cracking on BFUFARC in different basalt fiber content were studied from the perspective of fracture mechanics. Further, the cracking resistance, reinforcement, and toughening mechanisms of basalt fibers on concrete substrate were revealed by surface free energy of BFUFARC. The experimental results indicated that basalt fiber content is the main influence factor on the splitting tensile strength of BFUFARC. In case that fiber content increased from 0 to 0.3%, the concrete surface free energy at the tip of single-sided crack showed a trend of increased at first and then decreased. The surface free energy reached at maximum, about 3.59 × 10-5 MN/m. During the process of increasing fiber content from 0 to 0.1%, GC-2γS showed a gradually decreasing trend. As a result, an appropriate amount of basalt fiber can play a preventing cracking role by increasing the concrete surface free energy, further effectively improve the concrete splitting tensile performance.

NUMERICAL ANALYSIS ON THE NATURAL CONVECTION IN A LONG HORIZONTAL PIPE WITH THERMAL STRATIFICATION

  • Ahn, Jang-Sun;Park, Byeong-Ho;Kim, Seoug-Beom;Kim, Eun-Kee;Park, Man-Heung
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1996년도 춘계학술발표회논문집(2)
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    • pp.95-101
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    • 1996
  • In this paper, the steady 2-dimensional model for a long horizontal line with different end temperatures undergoing natural convection at very high Rayleigh number is proposed to numerically investigate the heat transfer and flow characteristics. The dimensionless governing equations are solved by using SIMPLE (Semi-Implicit Method for Pressure Linked Equations) algorithm which is developed using control volumes and staggered grids. The numerical results are verified by comparison with the operating PWR test data. The analysis focuses on the effects of variation of the heat transfer rates at the pipe surface, the thermal conductivities of the pipe material and the thickness of the pipe wall on the thermal stratification. The results show that the heat transfer rate at the pipe surface is the controlling parameter. A significant reduction and disappearance of thermal stratification phenomenon is observed at the Biot number of 5.0$\times$10$^{-2}$. The results also show that the increment of the thermal conductivity and thickness of the wall weakens the thermal stratification and somewhat reduces azimuthal temperature gradient in the pipe wall. Those effects are however minor, when compared with those due to the variation of the heat transfer rates at the surface of the pipe wall.

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Size-dependent analysis of functionally graded ultra-thin films

  • Shaat, M.;Mahmoud, F.F.;Alshorbagy, A.E.;Alieldin, S.S.;Meletis, E.I.
    • Structural Engineering and Mechanics
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    • 제44권4호
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    • pp.431-448
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    • 2012
  • In this paper, the first-order shear deformation theory (FSDT) (Mindlin) for continuum incorporating surface energy is exploited to study the static behavior of ultra-thin functionally graded (FG) plates. The size-dependent mechanical response is very important while the plate thickness reduces to micro/nano scales. Bulk stresses on the surfaces are required to satisfy the surface balance conditions involving surface stresses. Unlike the classical continuum plate models, the bulk transverse normal stress is preserved here. By incorporating the surface energies into the principle of minimum potential energy, a series of continuum governing differential equations which include intrinsic length scales are derived. The modifications over the classical continuum stiffness are also obtained. To illustrate the application of the theory, simply supported micro/nano scaled rectangular films subjected to a transverse mechanical load are investigated. Numerical examples are presented to present the effects of surface energies on the behavior of functionally graded (FG) film, whose effective elastic moduli of its bulk material are represented by the simple power law. The proposed model is then used for a comparison between the continuum analysis of FG ultra-thin plates with and without incorporating surface effects. Also, the transverse shear strain effect is studied by a comparison between the FG plate behavior based on Kirchhoff and Mindlin assumptions. In our analysis the residual surface tension under unstrained conditions and the surface Lame constants are expected to be the same for the upper and lower surfaces of the FG plate. The proposed model is verified by previous work.

Effects of surface-roughness and -oxidation of REBCO conductor on turn-to-turn contact resistance

  • Y.S., Chae;H.M., Kim;Y.S., Yoon;T.W., Kim;J.H., Kim;S.H., Lee
    • 한국초전도ㆍ저온공학회논문지
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    • 제24권4호
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    • pp.40-45
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    • 2022
  • The electrical/thermal stabilities and magnetic field controllability of a no-insulation (NI) high-temperature superconducting magnet are characterized by contact resistance between turn-to-turn layers, and the contact resistance characteristics are determined by properties of conductor surface and winding tension. In order to accurately predict the electromagnetic characteristics of the NI coil in a design stage, it is necessary to control the contact resistance characteristics within the design target parameters. In this paper, the contact resistance and critical current characteristics of a rare-earth barium copper oxide (REBCO) conductor were measured to analyze the effects of surface treatment conditions (roughness and oxidation level) of the copper stabilizer layer in REBCO conductor. The test samples with different surface roughness and oxidation levels were fabricated and conductor surface analysis was performed using scanning electron microscope, alpha step surface profiler and energy dispersive X-ray spectroscopy. Moreover, the contact resistance and critical current characteristics of the samples were measured using the four-terminal method in a liquid nitrogen impregnated cooling environment. Compared with as-received REBCO conductor sample, the contact resistance values of the REBCO conductors, which were post-treated by the scratch and oxidation of the surface of the copper stabilizer layer, tended to increase, and the critical current values were decreased under certain roughness and oxidation conditions.

Artificial intelligence design for dependence of size surface effects on advanced nanoplates through theoretical framework

  • Na Tang;Canlin Zhang;Zh. Yuan;A. Yvaz
    • Steel and Composite Structures
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    • 제52권6호
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    • pp.621-626
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    • 2024
  • The work researched the application of artificial intelligence to the design and analysis of advanced nanoplates, with a particular emphasis on size and surface effects. Employing an integrated theoretical framework, this study developed a more accurate model of complex nanoplate behavior. The following analysis considers nanoplates embedded in a Pasternak viscoelastic fractional foundation and represents the important step in understanding how nanoscale structures may respond under dynamic loads. Surface effects, significant for nanoscale, are included through the Gurtin-Murdoch theory in order to better describe the influence of surface stresses on the overall behavior of nanoplates. In the present analysis, the modified couple stress theory is utilized to capture the size-dependent behavior of nanoplates, while the Kelvin-Voigt model has been incorporated to realistically simulate the structural damping and energy dissipation. This paper will take a holistic approach in using sinusoidal shear deformation theory for the accurate replication of complex interactions within the nano-structure system. Addressing different aspectsof the dynamic behavior by considering the length scale parameter of the material, this work aims at establishing which one of the factors imposes the most influence on the nanostructure response. Besides, the surface stresses that become increasingly critical in nanoscale dimensions are considered in depth. AI algorithms subsequently improve the prediction of the mechanical response by incorporating other phenomena, including surface energy, material inhomogeneity, and size-dependent properties. In these AI- enhanced solutions, the improvement of precision becomes considerable compared to the classical solution methods and hence offers new insights into the mechanical performance of nanoplates when applied in nanotechnology and materials science.