• Title/Summary/Keyword: surface degradation

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Improvement of the Power Generation of Photovoltaic Generation System using Rotating Reflector (회전 반사판을 이용한 태양광발전장치의 발전량 향상)

  • Hong, Kyungjin
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.20 no.5
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    • pp.157-162
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    • 2020
  • In the existing photovoltaic generation system, the system equipped with the reflecting plate is a method in which solar energy (insolation) is concentrated on the surface of the photovoltaic module. However, the solar energy (insolation) lost by being reflected back through the solar module is not considered. Although a method of increasing the amount of power generated by installing a reflector around the solar modules has been proposed, this affects the power generation degradation caused by the shading of other solar modules. Therefore, in order to improve this problem, in this paper, 1) without affecting the development of photovoltaic module according to the shade, 2) photovoltaic module using a reflector rotating the solar energy (insolation) lost by the solar module Study and suggest how to join again. Therefore, the loss of solar energy (insolation) can be minimized through the method of recycling the solar energy according to the countless reflection angle of the lost solar energy (insolation). As a result, it is possible to increase the amount of power generation of the photovoltaic generation system by maximizing the amount of power generation for the same solar radiation.

The Effect of SiO2 Shell on the Suppression of Photocatalytic Activity of TiO2 and ZnO Nanoparticles

  • Lee, Min Hee;Patil, Umakant Mahadev;Kochuveedu, Saji Thomas;Lee, Choon Soo;Kim, Dong Ha
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3767-3771
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    • 2012
  • In this study, we investigate the potential use of $TiO_2@SiO_2$ and $ZnO@SiO_2$ core/shell nanoparticles (NPs) as effective UV shielding agent. In the typical synthesis, $SiO_2$ was coated over different types of $TiO_2$ (anatase and rutile) and ZnO by sol-gel method. The synthesized $TiO_2@SiO_2$ and $ZnO@SiO_2$ NPs were characterized by UV-Vis, XRD, SEM and TEM. The UV-vis absorbance and transmittance spectra of core@shell NPs showed an efficient blocking effect in the UV region and more than 90% transmittance in the visible region. XRD and SAED studies confirmed the formation of amorphous $SiO_2$ coated over the $TiO_2$ and ZnO NPs. The FESEM and TEM images shows that coating of $SiO_2$ over the surface of anatase, rutile $TiO_2$ and ZnO NPs resulted in the increase in particle size by ~30 nm. In order to study the UV light shielding capability of the samples, photocatalytic degradation of methylene blue dye on $TiO_2@SiO_2$ and $ZnO@SiO_2$ NPs was performed. Photocatalytic activity for both types of $TiO_2$ NPs was partially suppressed. In comparison, the photocatalytic activity of ZnO almost vanished after the $SiO_2$ coating.

Application properties of dewatering form system using the Euro-form (유로폼에 대한 투수거푸집의 적용 특성)

  • Lee, Jong-Suk;Ahn, Kee-Hong;Kim, Do-Gyeum;Ahn, Sang-Gu;Min, Jin-Hong;Hong, Hack-Pyo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.601-604
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    • 2008
  • When the concrete is placed, the water, needed for hydration of the cement, is under 30% of W/C including bound and gel water. However, as minimum water content cause bad workability, the W/C have to be higher. Therefore, fresh concrete produce 10${\sim}$20% extra water. As those water remain entrapped air in the concrete, life of the structure is reduced because of the degradation caused by entrapped air. For that reason, if extra water is eliminated, it will be great to improve the durability of the structures. Therefore, this study was performed to verity the fundamental properties through the experiment on the dewatering system using the euro form for eliminating extra water. When the dewatering form was applicated, the compressive strength was increased by 16% than those of normal form. However, the increasing rate of compressive strength got lower as the height is higher. In terms of ultrasonic pulse speed and surface roughness, the dewatering form showed better results than the normal one.

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Characteristics of organic electroluminescent devices having buffer layers (Buffer층을 가진 유기 전기 발광 소자의 특성)

  • 이호식;고삼일;정택균;이원재;김태완;강도열
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.399-402
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    • 1998
  • Electroluminescent(EL) devices based on organic thin films have attracted lots of interests in large-area light-emitting display. One of the problems of such device is a lifetime, where a degradation of the cell is possibly due to an organic layers thickness, morphology and interface with electrode. In this study, light-omitting organic electroluminescent devices were fabricated using Alq$_3$(8-hydroxyquinolinate aluminum) and TPD(N,N'-diphenyl-N,N'-bis(3-methylphenyl(1-1\`-biphenyl]-4,4'-diamine). Where Alq$_3$ is an electron-transport and emissive layer, TPD is a hole-transport layer. The cell structure is ITO/TPD/Alq$_3$/Al and the cell is fabricated by vacuum evaporation method. In a measurement of current-voltage characteristics, we obtained a turn-on voltage at about 9 V. We also investigated stability of the devices using buffer layer with blend of PEI (Poly ether imide) and TPD by varying mot ratios between ITO and Alq$_3$. In current-voltage characteristics measurement, we obtained the turn-on voltage at about 6 V and observed an anomalous behavior at 3∼4 V. And we used other buffer layer of PEDT(3,4-pyrazino-3',4'-ethylenedithio-2,2',5,5'-tetrathiafulvalenium) with ITO/PEDT/TPD/Alq$_3$Al structure. We observed a surface morphology by AFM(Atomic Force Microscopy), UV/visible absorption spectrum, and PL(Photoluminescence) spectrum. We obtained the UV/visible absorption peak at 358nm in TPD and at 359nm in Alq$_3$, and the PL peaks at 410nm in TPD and at 510nm in Alq$_3$. We also studied EL spectrum in the cell structure of ITO/(TPD+PEI)/Alq$_3$/Al.

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Gamma Irradiation Up-regulates Expression of B Cell Differentiation Molecule CD23 by NF-κB Activation

  • Rho, Hyun-Sook;Park, Soon-Suk;Lee, Choong-Eun
    • BMB Reports
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    • v.37 no.4
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    • pp.507-514
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    • 2004
  • Gamma irradiation ($\gamma$-IR) is reported to have diverse effects on immune cell apoptosis, survival and differentiation. In the present study, the immunomodulatory effect of a low dose $\gamma$-IR (5~10 Gy) was investigated, focusing on the role of NF-${\kappa}B$ in the induction of the B cell differentiation molecule, CD23/FceRII. In the human B cell line Ramos, $\gamma$-IR not only induced CD23 expression, but also augmented the IL-4-induced surface CD23 levels. While $\gamma$-IR did not cause STAT6 activation in these cells, it did induce both DNA binding and the transcriptional activity of NF-${\kappa}B$ in the $I{\kappa}B$ degradation-dependent manner. It was subsequently found that different NF-${\kappa}B$ regulating signals modulated the $\gamma$-IR-or IL-4-induced CD23 expression. Inhibitors of NF-${\kappa}B$ activation, such as PDTC and MG132, suppressed the $\gamma$-IR-mediated CD23 expression. In contrast, Ras, which potentiates $\gamma$-IR-induced NF-${\kappa}B$ activity in these cells, further augmented the $\gamma$-IR- or IL-4-induced CD23 levels, The induction of NF-${\kappa}B$ activation and the subsequent up-regulation of CD23 expression by $\gamma$-IR were also observed in monocytic cells. These results suggest that $\gamma$-IR, at specific dosages, can modulate immune cell differentiation through the activation of NF-${\kappa}B$, and this potentially affects the immune inflammatory response that is mediated by cytokines.

Effect of Thickener and Mordants on the Printing Properties of Cotton and Silk Fabrics Printed with Phellodendron Amurense Extract (호료와 매염제가 황벽추출물로 날염한 면/견직물의 날염성질에 미치는 영향)

  • Song, Yu Sun;Song, Wha Soon
    • Fashion & Textile Research Journal
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    • v.15 no.5
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    • pp.825-833
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    • 2013
  • In this study, the dyeing properties of Phellodendron amurense on cotton and silk fabrics were evaluated to establish a scientific database of dyeing methods using natural dyes with the ultimate aim of facilitating the practical use of these dyes. The optimal thickener and dyeing concentrations depending on the thickener type were identified when dyeing with P. amurense, and the fabric color, color fastness, and antibiosis were examined for various thickeners, fabrics, and mordants. The results were as follows.: The optimal concentrations of thickeners when dyeing on cotton and silk fabrics were CMC 3% (w/w), Mayprogum 7% (w/w), and Indalka 9% (w/w). The optimal concentration of P. amurense was 25% (w/w), irrespective of the type of thickener. To maintain the hue unique to P. amurense, thickening with Mayprogum or Indalka and mordanting with Al was effective for cotton, while thickening with Mayprogum or Indalka and mordanting with Al or thickening with CMC and mordanting with gallnut was effective for silk. The dry-cleaning fastness and abrasion resistance of cotton fabrics dyed with P. amurense were excellent at the 4-5 level. Gallnut was effective for washing fastness and perspiration fastness against color degradation, and FFC was effective for light fastness. The washing fastness, dry-cleaning fastness, abrasion resistance, and perspiration fastness of silk fabrics dyed with P. amurense were excellent at level 4, except for washing and perspiration fastness, and FFC was effective for the improvement of light fastness. Dyeing cotton and silk fabrics with P. amurense thus yielded antibiosis and excellent washing fastness.

Analysis of Non-point Source Pollution using GIS Technique (GIS를 이용한 충주호주변의 비점원 오염 분석 연구)

  • 김윤종;유일현;김원영;류주영;이영훈;민경덕
    • Spatial Information Research
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    • v.3 no.1
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    • pp.1-18
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    • 1995
  • Despite the widespread use of GIS over the past ten years, it has been limited application for regional modeling of pollutant loadings such as sediment, nitrogen, and phosphorus(non-point source pollution), The goals of this study were to: select important processes and parameters of watersheds that contribute to non-point source pollution degradation, develop a ranking model to use the environmental geologic data and verify the model by comparing results with existing water quality data(Chung-ju Lake) for specific watersheds, The GIS database consisted of topography, geology, soils, precipitation, rainfall erosivity, land use, and watershed boundaries. The index(NPSP) for assessing non-point source pollution was comprised in the following three seperate components: soil loss index(SLI) assesses the potential soil erosion and sedim-ent delivery from field to stream; run-off potential ratio(R.P.R) predicts the potential production of surface runoff; chloropgyll-a index ranks the potential manure(animal or human) production within a watershed. The GIS model was a valuable tool to assess the impact of environmental pollation in watersheds.

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A Novel Acid-Base Catalyzed Sol-Gel Synthesis of Highly Active Mesoporous TiO2 Photocatalysts

  • Khan, Romana;Kim, Sun-Woo;Kim, Tae-Jeong;Lee, Hyo-Sun
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.1951-1957
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    • 2007
  • A new synthetic strategy based on the acid-base catalyzed sol-gel method was developed for the preparation of a series of mesoporous TiO2 nanoparticles. A key feature of the method involves a gradual change in pH (0.8- 9) during the sol-gel transition, which guarantees easy introduction of mesoporosity without relying on the well-established sonochemical or template approach. In addition, this method leads to the exclusive formation of the anatase phase stable enough to the calcination temperature up to 600 oC. The physicochemical properties of the particles in the series were characterized by various spectroscopic and analytical techniques such as wide-angle XRD, SAXRD, BET surface area, FE-SEM, TEM, FT-IR, TGA, and XPS. The photocatalytic efficiency of these materials was investigated for the oxidation of toluene under UV-irradiation. All but T-ad in the series exhibited high photocatalytic activity pushing the reaction into completion within 3 h. The reaction followed the first order kinetics, and the rate reaches as high as 3.9 × 10?2/min which exceeds the one with the commercially available Degussa P-25 by a factor of 3.2. When comparison is made among the catalysts, the reactivity increases with increase in the calcination temperature which in turn increases the crystallinity of the anatase phase, thus revealing the following rate orders: T-3 < T-4 < T-5 < T-6.

Analysis of Non-point Pollution Source Reduction by Permeable Pavement (투수성 포장에 의한 비점오염원 저감 효과 분석)

  • Koo, Young Min;Kim, Young Do;Park, Jae Hyeon
    • Journal of Korea Water Resources Association
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    • v.47 no.1
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    • pp.49-62
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    • 2014
  • As the Urban area grows and more land is developed both within the city and in surrounding areas, hydrologic functions of the natural water cycle are altered. Urbanization creates impervious areas that negatively impact stormwater runoff characteristics. these changes to the natural hydrologic cycle result in the increased flooding, decreased groundwater recharge, increased urban heat island effects. Finally, the land use and other activities result in accumulation and washoff of pollutants from surface, resulting in water quality degradation. Therefore, in this study, evaluating and quantitative analysis of the percolation effect through infiltration experiment of permeable pavement, which is one of the ways that can reduce the problem of the dry stream. Also the SWMM model is used to study the effect of the hydrologic cycle for permeable pavement block contribution.

Muscle Ultrastructural Changes by Lysosomal Enzymes -2. Scanning Electron Microscopic Studies- (Lysosomal Enzyme에 의(依)한 근육조직(筋肉組織)의 변화(變化) -제(第)2보(報) Scanning Electron Microscopy에 의(依)한 고찰(考察)-)

  • Cho, Moo-Je;Yoon, Tae-Gyu;Bailey, Milton E.
    • Korean Journal of Food Science and Technology
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    • v.10 no.1
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    • pp.36-45
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    • 1978
  • Surface ultrastructural changes in endomysial connective tissue, sarcolemma and transverse ridges of bovine psoas muscle produced by leukocyte lysosomal enzymes in vitro at different pH (pH 7.0 and 4.0), temperature (37 and $4^{\circ}C$) and time interval (12, 24 hours at $37^{\circ}C$ and 36, 168 hours at $4^{\circ}C$ were studied by scanning electron microscope. Muscle incubated with leukocyte lysosomal enzymes at pH 7.0 produced severe degradation of endomysial and sarcolemmal connective tissue and transverse ridges but at pH 4.0 endomysial and sarcolemmal structures remain moderately stable and tranverse ridges are very stable even after 24 hours incubation at $37^{\circ}C$ and 7 days incubation at $4^{\circ}C$.

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