• 제목/요약/키워드: surface and interface

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다양한 유기용매와 물 경계면에서의 양친매성 금나노입자의 흡착 거동 (Adsorption Behaviors of Amphiphilic AuNPs at the Interface between Diverse organic Solvents and Water)

  • 임연수;이영민;구교찬;이희영
    • 접착 및 계면
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    • 제25권1호
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    • pp.157-161
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    • 2024
  • 양친매성 금나노입자는 표면에 친수성 및 소수성 리간드가 동시에 결합된 입자로 에너지, 바이오, 광학, 전자 기술 분야 등 그 응용분야가 다양하다. 특히 이러한 양친매성 금나노입자는 친수성과 소수성 특성을 모두 지니고 있어 서로 섞이지 않는 두 유체의 경계면에서 계면을 활성화하고 정렬된 구조체를 형성할 수 있다. 여기서, 금나노입자의 표면 특성은 두 유체의 경계면에서 금나노입자의 거동에 중요한 영향을 미친다. 따라서 본 연구에서는 양친매성 금나노입자의 표면 특성 및 유기용매의 종류에 따른 금나노입자의 유기용매-물 경계면에서의 흡착 거동을 확인하였다. 소수성 리간드의 탄화수소가 길수록, 유기용매의 탄화수소가 짧을수록 계면에 흡착되는 금나노입자의 양이 증가함을 확인하였다. 또한 Langmuir 흡착등온식을 토대로 양친매성 금나노입자가 단일층을 이루고 있음을 확인함과 동시에 유의미한 열역학적 값(KL, Cmax)들을 얻었다.

플라즈마를 이용한 신발소재의 환경 친화적인 접착 표면 처리(I) (Leather's Environment-friendly Adhesion Surface Treatment of shoe's material by Plasma)

  • 하선희;장유진;설수덕
    • 접착 및 계면
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    • 제6권2호
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    • pp.6-12
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    • 2005
  • 플라즈마는 고체, 액체, 기체와 더불어 제 4의 물질상태로 불리어지고 있는데, 기체의 일부가 전리된 가스상태이며 외부기장에 영향을 받고 전기를 통과시키면 발광하는 에너지가 높은 기체의 영역으로 정의된다. 인위적으로 에너지를 가하여 플라즈마를 발생시켜 많은 부분에서 새로운 첨단 연구가 활발하게 이루어지고 있으며, 많은 부분들이 우리의 생활에 들어와 있다. 플라즈마를 이용하여 고분자물의 표면을 처리하게 되면 몇 가지 장점이 있다. 먼저 플라즈마는 표면의 물성만을 변화시켜 고분자 본 물성을 유지시켜주고, 유기용제를 사용하지 않으며, 공정 운행 중 발생하는 폐기물이 없어 환경친화적이며, 상압 플라즈마의 경우 자동화 연속공정이 가능하다. 본 실험에서는 신발소재 고분자 재료의 상호 접착능력을 향상시키기 위하여 플라즈마를 사용하여 표면 개질을 시도하였고, 처리 시간과 사용한 가스의 유량에 따른 박리강도 시험을 통하여 접착력 향상을 확인하였고, 접촉각 측정과 SEM 측정을 통하여 고분자 표면 변화를 확인하였다.

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INFLUENCE OF CAPILLARITY AND ELASTICITY ON MICRO-CONTACTS

  • Zheng, J.;Streator, J.L.
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.65-66
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    • 2002
  • One aspect of the stiction problem may be explained by the action of capillary forces in conjunction with surface elasticity. In the present work, the interaction between two elastic half-spaces separated by a small liquid bridge is investigated. By minimizing the total free energy stored in the interface (including elastic energy and surface energy), the equilibrium interface geometry is determined analytically in the case where there is no solid-solid contact. A non-dimensional number, $N_c=299\frac{{\gamma}^2_{LA}cos^2{\theta}V_o}{E^{'2}H^5}$ is found to govern the structure stability. When $N_c{\ge}1$, the two surfaces jump into solid-solid contact and, once this occurs, the contact area will continue to expand until the two surfaces are in full contact.

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2-유체 모델의 고유치에 근거한 기포류에서의 계면압력도약항 (Mechanistic Pressure Jump Terms based on the System Eigenvalues of Two-Fluid Model for Bubbly Flow)

  • 정문선;이원재;이성재;송철화;하귀석
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집E
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    • pp.81-86
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    • 2001
  • Interfacial pressure jump terms based on the physics of phasic interface and bubble dynamics are introduced into the momentum equations of the two-fluid model for bubbly flow. The pressure discontinuity across the phasic interface due to the surface tension force is expressed as the function of fluid bulk moduli and bubble radius. The consequence is that we obtain from the system of equations the real eigenvalues representing the void-fraction propagation speed and the pressure wave speed in terms of the bubble diameter. Inversely, we obtain an analytic closure relation for the radius of bubbles in the bubbly flow by using the kinematic wave speed given empirically in the literature. It is remarkable to see that the present mechanistic model using this practical bubble radius can indeed represent both the mathematical well-posedness and the physical wave speeds in the bubbly flow.

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Plasma Oxidation Effect on Ultralow Temperature Polycrystalline Silicon TFT on Plastic Substrate

  • Kim, Yong-Hae;Moon, Jae-Hyun;Chung, Choong-Heui;Yun, Sun-Jin;Park, Dong-Jin;Lim, Jung-Wook;Song, Yoon-Ho;Lee, Jin-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.1122-1125
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    • 2006
  • The TFT performances were enhanced and stabilized by plasma oxidation of the polycrystalline Si surface prior to the plasma enhanced atomic layer deposition of $Al_2O_3$ gate dielectric film. We attribute the improvement to the formation of a high quality oxide interface layer between the gate dielectric film and the poly-Si film. The interface oxide has a predominant effect on the TFT's characteristics, and is regulated by the gap distance between the electrode and the polycrystalline Si surface.

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Alq$_3$-based organic light-emitting devices with Al/fluoride cathode; Performance enhancement and interface electronic structures

  • Park, Y.;Lee, J.;Kim, D.Y.;Chu, H.Y.;Lee, H.;Do, L.M.;Zyung, T.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.105-107
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    • 2002
  • The device characteristics and the interface electronic structures of organic light-emitting devices based on tris-(8-hydroxyquinoline)aluminum were investigated with $Al/CaF_2$, Al/LiF, and Al-only cathodes. Similar to the Al/LiF cathode, the $Al/CaF_2$ cathode greatly improved the performance of the device over Al-only cathode. However, a photoelectron spectroscopy study revealed that despite the performance improvement, the evolution of the new peaks during $Al/CaF_2$ cathode formation closely resembled those of the Al-only cathode rather than the Al/LiF cathode.

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Solid-Electrolyte Interphase in the Spinel Cathode Exposed to Carbonate Electrolyte in Li-Ion Battery Application: An ab-initio Study

  • 최대현;강준희;한병찬
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2017년도 춘계학술대회 논문집
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    • pp.169-169
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    • 2017
  • Due to key roles for the electrochemical stability and charge capacity the solid-electrolyte interphase (SEI) has been extensively studied in anodes of a Li-ion battery cell. There is, however, few of investigation for cathodes. Using first-principles based calculations we describe atomic-level process of the SEI layer formation at the interface of a carbonate electrolyte and $LiMn_2O_4$ spinel cathode. Furthermore, using beyond the conventional density functional theory (DFT+U) calculations we examine the work function of the cathode and frontier orbitals of the electrolyte. Based on the results we propose that proton transfer at the interface is an essential mechanism initiating the SEI layer formation in the $LiMn_2O_4$. Our results can guide a design concept for stable and high capacity Li-ion battery cell through screening an optimum electrolyte fine-tuned energy band alignment for a given cathode.

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Wave Motions in Stratified Fluids by a Translating Plate

  • Joo Sang-Woo;Park Min-Soo
    • Journal of Mechanical Science and Technology
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    • 제20권6호
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    • pp.882-895
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    • 2006
  • Surface and interfacial waves in two superposed horizontal inviscid fluids of finite depths are studied. The flow is induced by translating a vertical rigid plate with a prescribed velocity. Analytical solutions that accurately predict the motion of the free surface and the interface are obtained by using a small-Froude-number approximation. Three different velocities of the plate are considered, while flows induced by any arbitrary motion of the plate can be easily analyzed by a linear superposition of the solutions obtained. It is shown that pinching of the upper layer can occur for a sufficiently thin upper layer, which leads to its rupture into small segments. Other interesting phenomena, such as primary and secondary wiggles generated on the interface near the wavemaker, are discussed.

Tactile Sensation Display with Electrotactile Interface

  • Yarimaga, Oktay;Lee, Jun-Hun;Lee, Beom-Chan;Ryu, Je-Ha
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2005년도 ICCAS
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    • pp.145-150
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    • 2005
  • This paper presents an Electrotactile Display System (ETCS). One of the most important human sensory systems for human computer interaction is the sense of touch, which can be displayed to human through tactile output devices. To realize the sense of touch, electrotactile display produces controlled, localized touch sensation on the skin by passing small electric current. In electrotactile stimulation, the mechanoreceptors in the skin may be stimulated individually in order to display the sense of vibration, touch, itch, tingle, pressure etc. on the finger, palm, arm or any suitable location of the body by using appropriate electrodes and waveforms. We developed an ETCS and investigated effectiveness of the proposed system in terms of the perception of roughness of a surface by stimulating the palmar side of hand with different waveforms and the perception of direction and location information through forearm. Positive and negative pulse trains were tested with different current intensities and electrode switching times on the forearm or finger of the user with an electrode-embedded armband in order to investigate how subjects recognize displayed patterns and directions of stimulation.

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