• 제목/요약/키워드: surface and interface

검색결과 2,772건 처리시간 0.031초

Novel Thin Film Composite Forward Osmosis Membranes of Highly Enhanced Water Flux with Interlayer Polysiloxane Between Polysulfone and Polyamide (폴리술폰과 폴리아미드 경계층에 형성된 폴리실록산을 이용한 정삼투 복합 박막의 유량 향상)

  • Jung, Boram;Kim, Nowon
    • Membrane Journal
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    • 제26권5호
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    • pp.391-400
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    • 2016
  • In this work, novel thin film composite (TFC) forward osmosis (FO) membranes are developed via interfacial polymerization on the polysulfone (PS) substrate, using TEOS as the a sol-gel reagent to form hydrophilic interlayer polymer between PS and polyamide (PA). The PS substrate was cast on a very thin polyester nonwoven to reduce membrane resistance. With the incorporation of TEOS (tetraethoxy silane) polymer in the interface between PS and PA, the formed TFC FO membrane exhibits better hydrophilicity and improved water flux, and therefore superior membrane performance. By changing the polymerization sequence of PA interfacial polymerization and TEOS sol-gel condensation, the surface properties and performance of FO membranes are changed significantly. The permeability of FO membranes were estimated using the bench-scale FO test equipment. The distribution of the polysiloxane on composite membrane and morphology are also studied with FE-SEM and EDAX. The PS_PA_TEOS membrane showed highly enhanced water flux (79.2 LMH) but reverse salt flux (RSF) value (7.10 GMH) also increased. However, the flux of PS_TEOS_PA membrane increased moderately (54.1 LMH) without increasing RSF value (1.60 GMH) compare with PS_PA membrane.

In Vitro Study on the Bond Strength Between 3D-Printed Resin and Resin Cement for Pediatric Crown Restoration (소아용 크라운 수복을 위한 3D 프린팅 레진과 레진 시멘트 간의 접착 강도 평가)

  • So Yung Kim;Yoosoek Shin;Ik-Hwan Kim;Je Seon Song
    • Journal of the korean academy of Pediatric Dentistry
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    • 제50권1호
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    • pp.104-112
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    • 2023
  • A 3D-printed resin crown is a novel option for esthetic crown restoration for primary teeth, which are typically bonded with resin cement. The purpose of this study was to evaluate the bonding ability of a 3D printing resin and compare it with other indirect resin materials for crown fabrication. The shear bond strengths of two 3D printing resin materials, Graphy (GP) and NextDent (NXT), and two indirect resin materials, VIPI Block (VIPI) and MAZIC Duro (MZ), were compared in the study. For all materials, the shear bond strength at the interface between the surface of the resin material and resin cement was measured. The mean shear bond strength values of GP, NXT, MZ, and VIPI were 23.29 ± 3.88, 26.14 ± 4.67, 25.41 ± 4.03, and 18.79 ± 4.26 MPa, respectively. There was no significant difference among the SBSs of GP, NXT and MZ except for VIPI. The result of this study indicates that the 3D printing resin meets the essential requirement for clinical use by showing clinically adequate bond strength.

Electrical and Structure Properties of W Ohmic Contacts to $\textrm{In}_{x}\textrm{Ga}_{1-x}\textrm{N}$ (W/InGaN Ohmic 접촉의 전기적 구조적 특성)

  • Kim, Han-Gi;Seong, Tae-Yeon
    • Korean Journal of Materials Research
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    • 제9권10호
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    • pp.1012-1017
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    • 1999
  • Low resistance ohmic contacts to the Si-doped $\textrm{In}_{0.17}\textrm{Ga}_{0.83}\textrm{N}$(~$\times10^{19}\textrm{cm}^{-3}$) were obtained using the W metallization schemes. Specific contact resistance decreased with increasing annealing temperature. The lowest resistance is obtained after a nitrogen ambient annealing at $950^{\circ}C$ for 90 s, which results in a specific contact resistance of $2.75\times10^{-8}\Omega\textrm{cm}^{-3}$. Interfacial reactions and surface are analyzed using x-ray diffraction and scanning electron microscopy (SEM). The X-ray diffraction results show that the reactions between the W film and the $\textrm{In}_{0.17}\textrm{Ga}_{0.83}\textrm{N}$ produce a $\beta$-$W_2N$ phase at the interface. The SEM result shows that the morphology of the contacts is stable up to a temperature as high as $850^{\circ}C$. Possible mechanisms are proposed to describe the annealing temperature dependence of the specific contact resistance.

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Schottky barrier overlapping in short channel SB-MOSFETs (Short Channel SB-FETs의 Schottky 장벽 Overlapping)

  • Choi, Chang-Yong;Cho, Won-Ju;Chung, Hong-Bay;Koo, Sang-Mo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.133-133
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    • 2008
  • Recently, as the down-scailing of field-effect transistor devices continues, Schottky-barrier field-effect transistors (SB-FETs) have attracted much attention as an alternative to conventional MOSFETs. SB-FETs have advantages over conventional devices, such as low parasitic source/drain resistance due to their metallic characteristics, low temperature processing for source/drain formation and physical scalability to the sub-10nm regime. The good scalability of SB-FETs is due to their metallic characteristics of source/drain, which leads to the low resistance and the atomically abrupt junctions at metal (silicide)-silicon interface. Nevertheless, some reports show that SB-FETs suffer from short channel effect (SCE) that would cause severe problems in the sub 20nm regime.[Ouyang et al. IEEE Trans. Electron Devices 53, 8, 1732 (2007)] Because source/drain barriers induce a depletion region, it is possible that the barriers are overlapped in short channel SB-FETs. In order to analyze the SCE of SB-FETs, we carried out systematic studies on the Schottky barrier overlapping in short channel SB-FETs using a SILVACO ATLAS numerical simulator. We have investigated the variation of surface channel band profiles depending on the doping, barrier height and the effective channel length using 2D simulation. Because the source/drain depletion regions start to be overlapped each other in the condition of the $L_{ch}$~80nm with $N_D{\sim}1\times10^{18}cm^{-3}$ and $\phi_{Bn}$ $\approx$ 0.6eV, the band profile varies as the decrease of effective channel length $L_{ch}$. With the $L_{ch}$~80nm as a starting point, the built-in potential of source/drain schottky contacts gradually decreases as the decrease of $L_{ch}$, then the conduction and valence band edges are consequently flattened at $L_{ch}$~5nm. These results may allow us to understand the performance related interdependent parameters in nanoscale SB-FETs such as channel length, the barrier height and channel doping.

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A Study on Thermal Properties of Epoxy Composites with Hybrid Fillers (하이브리드 필러를 함유한 에폭시 복합체의 열적 특성 연구)

  • Lee, Seungmin;Rho, Hokyun;Lee, Sang Hyun
    • Journal of the Microelectronics and Packaging Society
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    • 제26권4호
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    • pp.33-37
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    • 2019
  • In this study, the graded thermal properties of composites are obtained by difference in specific gravity of fillers including Cu, h-BN and GO powders in epoxy. Relatively heavy powders such as Cu and h-BN compared to GO mostly at the bottom layer, while light GO powders were dispersed in the top layer in the composites. The thermal conductivity of composites was gradually increased from 0.55 (0.52) W/mK to 2.82 (1.37) W/mK for GO/h-BN (GO/Cu) epoxy composites from surface to bottom. On the contrary, the coefficient of thermal expansion was decreased from 51 ppm/℃ to 23 ppm/℃ and from 57 ppm/℃ to 32 ppm/℃ for GO/Cu and GO/h-BN, respectively. The variation of thermal properties in composites is attributed due to intrinsic material properties of filler including thermal conductivity, morphology and the distribution by the specific weight of fillers. This simple strategy for realizing graded thermal composites by introducing different filler materials would be effective heat transfer at interface of heterostructure with large thermal properties such as inorganic semiconductor/plastic, metal/plastic, and semiconductor/metal.

Three-Dimensional Numerical Simulations of Open-Channel Flows with Alternate Vegetated Zones (교행식생 영역을 갖는 개수로 흐름에서의 3차원 수치모의)

  • Kang, Hyeongsik;Kim, Kyu-Ho;Im, Dongkyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • 제29권3B호
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    • pp.247-257
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    • 2009
  • In the present paper, turbulent open-channel flows with alternate vegetated zones are numerically simulated using threedimensional model. The Reynolds-averaged Navier-Stokes Equations are solved with the ${\kappa}-{\varepsilon}$ model. The CFD code developed by Olsen(2004) is used for the present study. For model validation, the partly vegetated channel flows are simulated, and the computed depth-averaged mean velocity and Reynolds stress are compared with measured data in the literature. Comparisons reveal that the present model successfully predicts the mean flow and turbulent structures in vegetated open-channel. However, it is found that the ${\kappa}-{\varepsilon}$ model cannot accurately predict the momentum transfer at the interface between the vegetated zone and the non-vegetated zone. It is because the ${\kappa}-{\varepsilon}$ model is the isotropic turbulence model. Next, the open channel flows with alternate vegetated zones are simulated. The computed mean velocities are compared well with the previously reported measured data. Good agreement between the simulated results and the experimental data was found. Also, the turbulent flows are computed for different densities of vegetation. It is found that the vegetation curves the flow and the meandering flow pattern becomes more obvious with increasing vegetation density. When the vegetation density is 9.97%, the recirculation flows occur at the locations opposite to the vegetation zones. The impacts of vegetation on the flow velocity and the water surface elevation are also investigated.

Slope Stability Analysis by Slice Method and Finite Difference Method- A Comparative Study - (절편법과 유한차분법에 의한 사면안정해석 비교연구)

  • 박연준;채영수;유광호;백영식
    • Journal of the Korean Geotechnical Society
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    • 제15권6호
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    • pp.263-272
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    • 1999
  • Slice method is commonly used in solving slope stability problems since it is easy to use and its computation time is rather short. But depending upon the assumptions on the inter-slice forces, different methods are available. Quite often the difference between methods are so big that it is very difficult to make engineering decisions. This paper describes a method to calculate the factor of safety of a slope using FLAC, a finite difference based program. A FISH routine is developed to calculate the factor of safety, and verified by comparing with Chen's limit equilibrium solution. An example problem was selected from Fredlund and Krhan's paper, and results were compared for different soil and water conditions. The difference was less than 0.01 when the soil is homogeneous, and less than 5 % when a weak layer is embedded. Since most geotechnical application programs are capable of considering complicated ground conditions as well as the effect of ground supports, numerical methods are believed to be very useful in making engineering decisions. The developed routine can be applied to the calculation of the factor of safety of jointed rock slopes or weathered rock slopes where the use of slice method is limited.

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Evaluation of Dispersant Application to Stranded Oil as a Clean-up Technique at Sandy Tidal Flat (사질 조간대 표착유의 방제를 위한 유화분산제의 적용 평가)

  • Cheong, Cheong-Jo
    • Journal of the Korean Society for Marine Environment & Energy
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    • 제11권4호
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    • pp.227-231
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    • 2008
  • The purpose of this study is to clarify the behavior of stranded crude oil and to estimate the restoration of seawater infiltration by application of dispersant as one of cleaning techniques. We made visualization of infiltration process of seawater and stranded crude oil on the sandy beach sediments by using of a model sandy beach. Major conclusions derived from this study are as follows. The seawater infiltration volume was reduced by the stranded crude oil. However, thirty percentage of the sweater infiltration into the sediments was restored by dispersant application to the penetrated oil in sandy beach. The penetration depth of stranded oil were dropped at first falling tide, but were not significantly fluctuated after that. Moreover, oil concentration was most high within the upper 2 cm. The stranded crude oil was broken into small size droplets and dispersed into the sediments by the dispersant application. Therefore, dispersant applications play an important roles in the large increase of surface area of given volume of oil, and it resulted in promoting to biological degradation process at the oil/water interface, dispersing the stranded oil into the water column and restoration of the supplement of the dissolved oxygen and nutrients to the benthic organisms.

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Investigation of Regraphitization during Cam Shaft Remelting (캠 샤프트 재용융 처리시 재흑연화 현상에 관한 연구)

  • Oh, Young-Kun;Kim, Gwang-Soo;Koh, Jin-Hyun
    • Korean Journal of Materials Research
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    • 제8권7호
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    • pp.648-652
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    • 1998
  • TIG remelting was performed to harden the surface of automobile earn shaft. Multipass remelting was conducted in longitudinal direction under argon gas atmosphere. The microstructure of as-east earn shaft was gray iron which consisted of flake graphite and pearlitic matrix. The remelted area had microstructue of both fine pearlite and ledeburite structure that consisted of globular austenite and $Fe_3C$. Hardness for as-cast earn shaft had HRc 25~28, however it increased at remelted area to HRc 53~55. Black line was found at heat affected zone next to the fusion line, that is remelt area of previous pass, during multipass remelting. Black line was identified as graphite, which was transformed from $Fe_3C$. in the ledeburite structure. It is observed that all graphites were nucleated at $Fe_3C$. and matrix interface. High density energy laser remelting process was also applied to verify whether black line could be eliminated. However, black line was still existed as observed in TIG remelting process. Regraphitization was simulated on the ledeburitic structure specimen using Gleeble 1500 with conditions of 1100 and 100$0^{\circ}C$ for 0.5, I, 3, 5 and 1Osee. From the fact that graphite was formed even at the simulation condition of 100$0^{\circ}C$ for 0.5sec, it is seen that regraphitization is an inevitable phenomenon generated whatever processes used during multipass overlap remelting.

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Analysis on the Change in the Pan Evaporation Rate in the Coastal Zone (우리나라 연안의 팬증발량 변화 양상 분석)

  • Lee, Khil-Ha;Oh, Nam-Sun;Jeong, Shin-Taek
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • 제19권3호
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    • pp.244-252
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    • 2007
  • A long-term change in the evaporation rate have an influence on the hydrologic processes at the interface between the land surface-air and crop yield. Several previous studies have reported declines in pan evaporation rate, while actual evaporation rate is expected to increase due to anthropogenic global change in the future. The decreasing trend of pan evaporation rate might be involved with global warming and accordingly the trend of annual pan evaporation rate also needs to be checked here in Korea. In this study, 14 points of pan evaporation observation are intensively studied to investigate the trend of pan evaporation for the time period of 1970-2000. Annual pan evaporation is decreasing at the rate of 1.6mm/yr, which corresponds to approximately 50mm for 30 years. Annual pan evaporation rate is larger by $\sim10%$ at the coastal area and decreasing rate is faster as -2.46 mm/yr per year, while that is -0.82 mm/yr per year at the in-land area. The results of the Mann-Kendall trend test shows 4 points are decreasing and 10 points are unchanged with 95% confidence interval. But national annual average values show the decreasing trend of pan evaporation rate as a whole, which corresponds to general trend all over the world. This study will contribute to a variety of studies on water resources, hydrology, agricultural engineering, meteorology, and coastal engineering in association with future global climate change.