• Title/Summary/Keyword: surface and interface

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Electronic and Structural Properties of Interfaces in Fe∖MgO∖Cu-Phthalocyanine Hybrid Structures (Fe∖MgO∖Cu-Phthalocyanine 복합구조 계면구조와 그 전자기적 특성)

  • Bae, Yu Jeong;Lee, Nyun Jong;Kim, Tae Hee;Pratt, Andrew
    • Journal of the Korean Magnetics Society
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    • v.23 no.6
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    • pp.184-187
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    • 2013
  • The influence of insertion of an ultra-thin Cu-Phthalocyanine (CuPc) between MgO barrier and ferromagnetic layer in magnetic tunnel juctions (MTJs) was investigated. In order to understand the relation between the electronic and structural properties of Fe${\backslash}$MgO${\backslash}$CuPc, the surface (or interface) analysis was carried out systematically by using spin polarized metastable He de-excited spectroscopy for the CuPc films grown on the Si(001)${\backslash}$5 nm MgO(001)${\backslash}$7 nm Fe(001)${\backslash}$1.6 nm MgO(001) multilayer structure as the thickness of CuPc increases from 0 to 5 nm. In particular, for the 1.6 nm CuPc surface, a rather strong spin asymmetry between up- and down-spin band appears while it becomes weaker or disappears for the CuPc films thinner or thicker than ~1.6 nm. Our results emphasize the importance of the interfacial electronic properties of organic layers in the spin transport of the hybrid MTJs.

Effect of De-graphitization Heat Treatment on Interfacial Bonding Properties of Flake Graphite Cast Iron-Aluminum Dissimilar Materials Produced by High Pressure Die Casting (고압 다이캐스팅법으로 제조한 편상흑연주철 -알루미늄 이종소재의 계면접합특성에 미치는 탈흑연 열처리의 영향)

  • Yang, Ji-Ba-Reum;Kim, TaeHyeong;Jeong, JaeHeon;Kim, SangWoo;Kim, YoonJun;Kim, DongEung;Shin, JeSik
    • Journal of Korea Foundry Society
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    • v.41 no.6
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    • pp.535-542
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    • 2021
  • In this study, to improve the interfacial bond strength of cast iron-aluminum dissimilar materials, graphite was removed to a certain depth from the cast iron surface through de-graphitization heat treatment. As the heat treatment time increased, the depth at which graphite was removed increased, showing a linear relationship between the heat treatment time and depth. Aluminum was filled to a certain depth on the de-graphitized cast iron surface through die-casting method, and no intermetallic compounds were formed on the cast iron-aluminum interface. The interfacial bonding strength showed a value of 90 MPa regardless of the heat treatment time, which is very high compared to the 12MPa bonding strength of the material without de-graphitization heat treatment. This result is thought to be due to the mechanical bonding of the undercut structure as the liquid aluminum, penetrated by the high pressure die-casting process, solidified in the de-graphitized region of the cast iron.

An Accelerated IK Solver for Deformation of 3D Models with Triangular Meshes (삼각형 메쉬로 이루어진 3D 모델의 변형을 위한 IK 계산 가속화)

  • Park, Hyunah;Kang, Daeun;Kwon, Taesoo
    • Journal of the Korea Computer Graphics Society
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    • v.27 no.5
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    • pp.1-11
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    • 2021
  • The purpose of our research is to efficiently deform a 3D models which is composed of a triangular mesh and a skeleton. We designed a novel inverse kinematics (IK) solver that calculates the updated positions of mesh vertices with fewer computing operations. Through our user interface, one or more markers are selected on the surface of the model and their target positions are set, then the system updates the positions of surface vertices to construct a deformed model. The IK solving process for updating vertex positions includes many computations for obtaining transformations of the markers, their affecting joints, and their parent joints. Many of these computations are often redundant. We precompute those redundant terms in advance so that the 3-nested loop computation structure was improved to a 2-nested loop structure, and thus the computation time for a deformation is greatly reduced. This novel IK solver can be adopted for efficient performance in various research fields, such as handling 3D models implemented by LBS method, or object tracking without any markers.

Pullout Resistance of Geosynthetic Strip with Rounded Band Anchor (수동저항부가 형성된 띠형 섬유보강재의 인발저항 특성)

  • Lee, Kwang-Wu;Cho, Sam-Deok;Han, Jung-Geun;Hong, Ki-Kwon
    • Journal of the Korean Geosynthetics Society
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    • v.10 no.3
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    • pp.43-51
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    • 2011
  • This paper describes the results of pullout tests in the laboratory, which are conducted to assess the pullout performance of recently developed geosynthetic strip reinforcement with rounded band anchor. The geosynthetic strip can be used as reinforcements in reinforced soil wall with concrete block facing. The pullout resistance of the geosynthetic strip with rounded band anchor is mobilized by the combination of the interface friction between soil-reinforcement surface and the passive soil resistance caused by the rounded band anchor. Therefore, both the friction resistance and the passive resistance have to be considered in design. From the pullout test results, when the rounded band anchor are formed in the end part of the geosynthetic strip, pullout strength increases about from 10% to 65%. The passive resistance can be evaluated based on the pullout test results.

Design of Stable Evaporative Micro-channel Systems Using Expanding Area (확장 면적을 이용한 안정된 증발 마이크로채널 시스템의 설계)

  • Lee, Hee-Joon;Yao, Shi-Chune
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.8
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    • pp.831-838
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    • 2011
  • A growing bubble can be squeezed for water, and it will then encounter flow instability, which reverses toward upstream in straight micro-channels. To reduce the flow instability, a micro-channel that expands at the downstream end has been found to be effective. In the expanding area, a growing bubble will tend to move downstream because the net surface tension force of a vapor-liquid interface is inversely proportional to the local radius of curvature. We propose a static flow instability model and validate it experimentally. Moreover, we apply the local-instability parameter concept to the real design of a stable evaporative micro-channel with an expanding area. Based on the localinstability model, we establish a static design for stable expanding evaporative micro-channels.

Transport behavior of a surfactant tracer(CPC) with Langmuir type adsorption isotherm on NAPL-water interface in a homogeneous porous medium (NAPL-물 계면에서 Langmuir형 흡착특성을 보이는 계면추적자(CPC)의 다공성 균질매질내 유동특성)

  • 김헌기;문희수;이상훈
    • Journal of Soil and Groundwater Environment
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    • v.6 no.2
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    • pp.3-13
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    • 2001
  • It has been known that nonlinear characteristics of sorption affect the transport behavior of water soluble pollutants in soils. However detailed experimental studies have not been performed to verify the effect of non-linearity of adsorption isotherm on transport of chemicals in porous media. In this research, the distortion of breakthrough curves of a cationic surfactant (cetylpyridinium chloride, CPC) in a engineered stainless steel column packed with glass beads were investigated. Glass beads with about 110 $\mu\textrm{m}$diameter coated with a thin n-decane film were used as the media providing the sorption surface for CPC. The CPC adsorption isotherm on the surface of n-decane from aqueous solution was a typical Langmuir type. The breakthrough curve of CPC using step Input showed a late breakthrough on the front side and early breakthrough on the back side accordance to the shape of the isotherm. The retardation factor of CPC was found to be a strong function of the input concentration, which also a manifestation of the non-linearity of the isotherm. The retardation factors for the CPC with step input agreed with those of pulse input that the maximum concentrations are controlled to be the same as the step input concentrations. This results support the validity of the unproven field practices of using hydrogeotracers with non-linear adsorption isotherms to determine the hydrogeological parameters, e.g., NAPL saturation, air-water or NAPL-water interfacial areas.

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Controlling the Location of Thermally Stable Au Nanoparticles with Tailored Surface Property within Block Copolymer Templates (열적으로 안정한 금나노입자를 이용한 블록공중합체 내에서의 입자위치 조절)

  • Kim, Se-Yong;Yoo, Mi-Sang;Jung, Se-Ra;Paek, Kwan-Yeul;Kim, Bum-Joon J.;Bang, Joona
    • Polymer(Korea)
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    • v.35 no.3
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    • pp.238-243
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    • 2011
  • Organic/inorganic hybrid materials have a lot of interest in various areas due to their fascinating properties. To control the location and dispersion of inorganic nanoparticles within polymer matrix. thiol-terminated polymeric ligands have been widely used to tune the surface property of nanoparticles. However, the specific binding between the thiol functional group and metal is unstable with increasing temperature. To archive the thermally-stable Au nanoparticles, we previously synthesized various UV-crosslinkable polymeric ligands, which have different compositions of polar, UV-crosslinkable azide unit comparing to non-polar 스티렌 units. After crosslinking the Au nanoparticles, it was found that the nanoparticles had superb stability at high temperature (above $180^{\circ}C$). In this work, we used thermally-stable Au nanoparticles to control the location within the polymer matrix. By changing the amount of polar azide units in the polymeric ligands, we could precisely control the location of nanoparticles from one domain to the interface of block copolymer templates.

A New Method to Determine the Characteristic Lengths for the Failure Analysis of Composite Joint (복합재 체결부의 파손해석을 위한 새로운 특성길이 결정 방법)

  • 안현수;권진희;최진호
    • Composites Research
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    • v.16 no.4
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    • pp.10-21
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    • 2003
  • Proposed is a new method to determine the characteristic lengths for the failure analysis of composite joint without experiments. New method uses the result that the stress distribution in the characteristic length specimens is linearly proportional to the applied load. The compressive characteristic lengths calculated by the present method are exactly same as the lengths obtained by the conventional method based on experiment. The new tensile characteristic length is defined using the strength of the notched laminate, while previous methods use the strength of the sound laminate. That change allows calculating the tensile characteristic length numerically without experiment like the compressive characteristic length. Finite element analyses are conducted by MSC/NASTRAN. The interface between the fastener and laminate is modeled by the contact surface element. The finite element results based on the new characteristic lengths show the excellent agreement with experimental results for the Graphite/Epoxy composite .joints.

Biogeochemical Study of Dissolved Organic and Inorganic Compounds under Oxic/Anoxic Environment in Lake Shihwa (시화호 산화-환원 환경하의 용존 유, 무기 화합물의 생지화학적 연구)

  • Park, Yong-Chul;Park, Jun-Kun;Han, Myong-Woo;Son, Seung-Kyu;Kim, Moon-Koo;Huh, Seong-Hoi
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.2 no.2
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    • pp.53-68
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    • 1997
  • Lake Shihwa, artificially constructed since 1988, shows a typical two-layered system depending on strong haline density stratification. Sill of the water gate at 6 m depth greatly restricts physical mixing with outer seawater and circulation in the lake, and contributes to the enhancement of anoxic environment in the deeper layer. With this enclosed physical environment, Lake Shihwa receives enormous amounts of organics, ammonia, and other pollutants from the neighboring municipal and industrial complexes through six major streams, thus developing biogeochemical differentiation of anoxic to suboxic environment in the high saline bottom water and highly eutrophicated brackish surface water. This study investigated vertical structures, biogeochemical behaviors and processes of various organic and inorganic compounds around oxic-anoxic interface. Nitrite and nitrate rapidly decreased below the pycnocline where about $1{\times}10^8$ tons of hypoxic bottom water exist. In this bottom layer, ammonium ranged from 75 to 360 ${\mu}M$ mainly resulting from deamination of dissolved organic nitrogen and ammonification of precipitated organic particles. Despite large amounts of surface water discharge and dilution by outer seawater inflow about $3{\times}10^8$ tons from April to August, 1996, bottom layer did not show any improvement of water quality and maintained highly reduced environment. The main reason seems to be imbalance between ineffectiveness of dilution due to shallow depth and large surface area, overloaded POC influx from the eutrophicated surface biological activity, and poor replenishment of oxygen in this artificial lake system. Therefore, as long as current salinity dependent two-layered system maintains with its physical limitations, any improvement of water quality cannot be foreseen in Lake Shihwa.

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Polychaete Feeding Guilds from the Continental Shelf Off the Southeastern Coast of Korea (한국(韓國) 동남해역(東南海域)에 분포(分布)하는 다모류(多毛類)의 식이조합(食餌組合))

  • Choi, Jin Woo;Koh, Chul Hwan
    • 한국해양학회지
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    • v.24 no.2
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    • pp.84-95
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    • 1989
  • The feeding guild classification proposed by Fauchald and Jumars (1979) and the relationship between this guild structure and the habitat environment were examined based on the quantitative polycheate samples collected on the continental shelf off the southeastern coast of Korea. Total 12 feeding guilds were found and the major feeding guilds of polychaetes were BSX (burrowing, sessile, non-jawed), SDT (surface deposit feeding, discretely motile, tentaculate), SST (surface deposit feeding, sessile, tentaculate), BMX (burrowing, motile, non-jawed), BMJ (burrowing, motile, jawed), SDJ (surface deposit feeding, discretely motile, jawed). There were more significant associations between feeding guilds and mean grain size (${\phi}$); SST and BMJ showed a positive correlation with mean phi, whereas CDJ (carnivore, discretely motile, jawed) and FDT (filter feeding, discretely motile, tentaculate), a negative value. The CDJ and CMX (carnivore, motile, non-jawed) guilds showed positive correlations with sand content, but only SST guild showed a positive correlation with clay. The heterogeneity of sediment or sorting value (${\phi}$) was highly associated with various feeding strategies of polychaetes. Surface deposit feeders and filter feeders, sessile, and tentaculate strategies were associated with poorly sorted or heterogeneous sediments. Some preliminary polychaete feeding surfaces were posed. Southern and northern coastal region composed of muddy sediment were characterized by SDJ; northern slope of mud by SST; central coast of mud by SDT, BSX; and BMX; southern offshore of sandy sediment by SDJ and IDT (interface feeding, discretely motile, tentaculate).

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