• Title/Summary/Keyword: surface and interface

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Electronic Structure and Magnetism of Ni Monolyer Embedded Between Rh Layers (Ni 단층이 삽입된 Rh 박막의 전자구조와 자성)

  • Kim Sun-Hee;Jang Y.R.;Lee J.I.
    • Journal of the Korean Magnetics Society
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    • v.15 no.1
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    • pp.7-11
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    • 2005
  • A single slab in which one Ni(001) atom layer embedded between two of four Rh layers is considered to examine the oscillation of magnetic moment in each layer. The all electron total-energy full-potential linearized augmented plane wave(FLAPW) method was used to calculate the spin densities, magnetic moments, density of states(DOS), and the number of electrons within each muffin-tin(MT) sphere. The magnetic moment of the center layer Ni(C) in the system of 4Rh/Ni/4Rh is calculated to be 0.34${\mu}_B$, which is 40% have magnetic moment at the interface layers by strong band hybridization with Ni(C) when Ni(001) monolayers is inserted, and the magnetic moment shows a damped oscillation as we go from center Ni(C) layer to the surface Rh(S). From the calculated density of states, it is found that the Fermi level shifts inside the energy band of the Ni(C) in affection of Rh(001).

MBE growth of topological insulator $Bi_2Se_3$ films on Si(111) substrate

  • Kim, Yong-Seung;Bansa, Namrata;Edrey, Eliav;Brahlek, Mathew;Horibe, Yoichi;Iida, Keiko;Tanimura, Makoto;Li, Guo-Hong;Feng, Tian;Lee, Hang-Dong;Gustafsson, Torgny;Andrei, Eva;Cheong, Sang-Wook;Oh, Seong-Shik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.59-59
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    • 2011
  • We will report atomically sharp epitaxial growth of $Bi_2Se_3$ three-dimensional topological insulator films on Si(111) substrate with molecular beam epitaxy (MBE). It was achieved by employing two step growth temperatures to prevent any formation of second phase, like as $SiSe_2$ clusters, between $Bi_2Se_3$ and Si substrate at the early stage of growth. The growth rate was determined completely by Bi flux and the Bi:Se flux ratio was kept ~1:15. The second-phase-free atomically sharp interface was verified by RHEED, TEM and XRD. Based on the RHEED analysis, the lattice constant of $Bi_2Se_3$ relaxed to its bulk value during the first quintuple layer implying the absence of strain from the substrate. Single-crystalline XRD peaks of $Bi_2Se_3$ were observed in films as thin as 4 QL. TEM shows full epitaxial structure of $Bi_2Se_3$ film down to the first quintuple layer without any second phases. This growth method was used to grow high quality epitaxial $Bi_2Se_3$ films from 3 QL to 3600 QL. The magneto-transport properties of these thin films show a robust 2D surface state which is thickness independent.

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Performance Characteristics of Lead Acid Battery with the Contents of Sodium Perborate Tetrahydrate (SPT) in Positive Plate Active Material (과붕산나트륨 양극 활물질 첨가에 따른 차량용 납산배터리 성능 특성)

  • Lim, Tae Seop;Kim, Sung Jun;Kim, Sang Dong;Yang, SeungCheol;Jung, Yeon-Gil
    • Korean Journal of Materials Research
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    • v.30 no.8
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    • pp.426-434
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    • 2020
  • The performance characteristics of a lead acid battery are investigated with the content of Sodium Perborate Tetrahydrate (SPT, NaBO3·4H2O) in a positive plate active material. SPT, which reacts with water to form hydrogen peroxide, is applied as an additive in the positive plate active material to increase adhesion between the substrate (positive plate) and the active material; this phenomenon is caused by a chemical reaction on the surface of substrate. A positive plate with the increasing content of SPT is prepared to compare its properties. It is confirmed that the oxide layer increases at the interface between the substrate and the active material with increasing content of SPT; this is proven to be an oxide layer through EDS analysis. Battery performance is confirmed: when SPT content is 2.0 wt%, the charging acceptance and high rate discharge properties are improved. In addition, the lifetime performance according to the Standard of Battery Association of Japan (SBA) S0101 test is improved with increasing content of SPT.

Comparison of Numerical Results for Laminar Wavy Liquid Film Flows down a Vertical Plate for Various Time-Differencing Schemes for the Volume Fraction Equation (수직평판을 타고 흐르는 층류파동액막류에 대한 체적분율식 시간차분법에 따른 해석 결과 비교)

  • Park, Il-Seouk;Kim, Young-Jo;Min, June-Kee
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.11
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    • pp.1169-1176
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    • 2011
  • Liquid film flows are classified into waveless laminar, wavy laminar, and turbulent flows depending on the Reynolds number or the flow stability. Since the wavy motions of the film flows are so intricate and nonlinear, studies on them have largely been experimental. Most numerical approaches have been limited to the waveless flow regime. The various free surface-tracking schemes adopted for this problem were used to more accurately estimate the average film thickness, rather than to capture the unsteady wavy motion. In this study, the wavy motions in laminar wavy liquid film flows with Reynolds numbers of 200-1000 were simulated with various numerical schemes based on the volume of fluid (VOF) method for interface tracking. The results from each numerical scheme were compared with the experimental results in terms of the average film thickness, the wave velocity, and the wave amplitude.

Primary Culture of Human Nasal Epithelial Cell Monolayer for In Vitro Drug Transport Studies (약물의 in vitro 투과 실험을 위한 사람의 비강점막상피세포 단층막의 일차배양)

  • Yoo, Jin-Wook;Kim, Yoo-Sun;Lee, Min-Ki;Roh, Hwan-Jung;Lee, Chi-Ho;Kim, Dae-Duk
    • Journal of Pharmaceutical Investigation
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    • v.32 no.1
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    • pp.21-26
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    • 2002
  • The primary culture of human nasal epithelial cell monolayer was performed on a Transwell. The effect of various factors on the tight junction formation was observed in order to develop an in vitro experimental system for nasal transport studies. Human nasal epithelial cells, collected from human normal inferior turbinates, were plated onto diverse inserts. After 4 days, media of the apical surface was removed for air-liquid interface (ALI) culture. Morphological characteristics was observed by transmission electron microscopy (TEM). A polyester membrane of $0.4\;{\mu}m$ pore size was determined as the most effective insert based on the change in the transepithelial electric resistance (TEER) value as well as the $^{14}C-mannitol$ transport study. The ALI method was effective in developing the tight junction as observed in the further increase in the TEER value and reduction in the permeability coefficient $(P_{app})$ of $^{14}C-mannitol$ transport. Results of the transport study of a model drug, budesonide, showed that the primary culture system developed in this study could be further developed and applied for in vitro nasal transport studies.

Preparation of polymeric composites for surface contamination measurement in order to characterize nuclear facilities decommissioning (원자력시설 해체 시 특성평가를 위한 표면오염 탐지 이중구조 고분자 복합체의 제조)

  • 한명진;서범경;우주희;이근우
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.97-104
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    • 2004
  • Double-layered polysulfone composite films, containing cerium activated yttrium silicate (CAYS) as a flour, were prepared from double casting of two polymeric solutions, and their morphology and physical strength were superior to those of single-layered composites. The prepared polymeric films consist of a dense bottom layer and a CAYS-holding top layer. The former is made of coagulating the polysulfone and methylene chloride binary solution and works as a supporter to improve the composite's physical strength, while the latter holding the inorganic fluor plays a role as an active site to detect the radioactive contamination. The prepared films revealed two distinguished, but tightly attached, double layers, their attachment being identified by morphology of the interface between two layers. As prepared by water immersion coagulation, the films have highly developed macropores, compared with a dense structure in the film prepared by evaporation. In the radionuclide detection test of the CAYS-impregnated composites, the films have reliable detection capacity at a radionuclide spotting test. The double-layered composites with the dense support layer show a better stability in holding the radionuclides spotted on the surface as well as an improvement in physical strength, compared with the single-layer composites having shortcomings such as being too porous or being brittle.

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An Effect of Uplift Pressure Applied to Concrete Gravity Dam on the Stress Intensity Factor (중력식 콘크리트 댐에 작용하는 양압력이 응력확대계수에 미치는 영향)

  • Lee Young-Ho;Jang Hee-Suk;Kim Tae-Wan;Jin Chi-Sub
    • Journal of the Korea Concrete Institute
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    • v.16 no.6 s.84
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    • pp.841-850
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    • 2004
  • The modeling of uplift pressure within dam, on the foundation on which it was constructed, and on the interface between the dam and foundation is a critical aspect in the analysis of concrete gravity dams, i.e. crack stability in concrete dam can correctly be predicted when uplift pressures are accurately modelled. Current models consider a uniform uplift distribution, but recent experimental results show that it varies along the crack faces and the procedures for modeling uplift pressures are well established for the traditional hand-calculation methods, but this is not the case for finite element (FE) analysis. In large structures, such as dams, because of smaller size of the fracture process zone with respect to the structure size, limited errors should occur under the assumptions of linear elastic fracture mechanics (LEFM). In this paper, the fracture behaviour of concrete gravity dams mainly subjected to uplift Pressure at the crack face was studied. Triangular type, trapezoidal type and parabolic type distribution of the uplift pressure including uniform type were considered in case of evaluating stress intensity factor by surface integral method. The effects of body forces, overtopping pressures are also considered and a parametric study of gravity dams under the assumption of LEFM is performed.

A Comparison of shear Bonding Strength with Polyacrylic acid and Phosphoric acid Enamel Surface Conditioning (폴리아크릴산과 인산으로 법랑질표면 처리후 전단결합강도의 비교)

  • Roh, Joung-Sub;Kim, Sang-Cheol
    • The korean journal of orthodontics
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    • v.32 no.1 s.90
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    • pp.51-57
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    • 2002
  • The purpose of this study was to compare in vitro shear bonding strength with three different enamel surface preparations (1) 30% sulfated polyacrylic acid with 0.3M lithium sulfate (2) 40% sulfated polyacrylic acid with 0.3M lithium sulfate (3) 37% phosphoric acid. 105 extracted human premolar teeth were divided into each three groups of 35. Metal brackets were bonded to teeth in the three groups. The same self curing resin was used for all groups. A shearing force was applied to the teeth. After debonding, bases of bracket and enamel surfaces were examined under steroscopic microscope to determine the failure modes. Statistical analysis of the data was carried out with one way ANOVA and Student t- test. The results were as follows. 1. Shear bond strength values for the 30% polyacrylic acid and 40% polyacrylic acid group were approximately two thirds of the phosphoric acid group. It maintains clinically acceptable but not enough bond strength. 2. There was no statistically significant difference in shear bond strengths between 30% and 40% polyacrylic acid group. 3. The failure modes of brackets had some differences. In polyacrylic acid groups, the percentage of adhesive/enamel failure was higher than that of adhesive/ bracket interface failure. On the contrary in phosphoric acid groups, the results were reversed. Further study of bond strength could be required. If polyacrylic acid enamel conditioning is used clinically.

FINITE ELEMENT STRESS ANALYSIS OF MAXILLARY TWO IMPLANTS-RETAINED OVERDENTURE ACCORDING TO POSITION OF IMPLANT FIXTURES (상악피개의치를 위한 임플랜트의 위치에 따른 응력분포에 대한 유한요소분석)

  • Ha, Heon-Seok;Kim, Chang-Whe;Lim, Young-Jun;Kim, Myung-Joo
    • The Journal of Korean Academy of Prosthodontics
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    • v.46 no.2
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    • pp.193-200
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    • 2008
  • Statement of problem: There have been a few studies about unsplinted implant retainted maxillary overdenture. Purpose: The purpose of this study was to examine the effect of different position of implant for 2 implants-retained maxillary overdenture. Materials and methods: Three-dimensional finite element models were used to reproduce an edentulous human maxilla with an implant-retained overdenture. Two implants in the canine tooth positions on both side and in the second premolar tooth positions on both side models were examined. Axial loads of 100 N were applied to the occlusal surface at the right first molar tooth positions. Maximum stress at the implant-bone interface and stress at the cortical bone surface just under the loading point were observed. Results and conclusion: Within the limits of this study, maximum stresses were concentrated around implant of canine position at loading side. The second premolar area was thought to be more favorable to distribution of stress on mucosa, alveolar bone and implants than canine area for maxillary overdenture.

A Study on the Release Characteristics During Wafer-Level Lens Molding Using Thermosetting Materials (열경화성 소재를 사용한 웨이퍼 레벨 렌즈 성형 중 이형 특성에 관한 연구)

  • Park, Si-Hwan;Hwang, Yeon;Kim, Dai-Geun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.1
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    • pp.461-467
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    • 2021
  • Among the defect factors that can occur when a wafer-level lens is molded using a thermosetting material, the mold sticking problem of a molded lens during the release process can damage the molded substrate and deform the substrate at the wafer level. An experiment was conducted to examine the factors affecting the demolding force in the lens forming process. The demolding force was examined according to the coating material of the molds. The mold was surface-treated with ITO and Ti, followed by plasma treatment in an O2 atmosphere. A DLC coating was then performed, and the curing and releasability were examined. A coating method for the pull-off experiment was selected based on the results. To measure the demolding force according to the curing process conditions, a method of curing at a constant pressure and a method of curing at a constant position were applied. As a result, the TiO2 surface treatment reduced the release force. When cured by controlling the location, curing shrinkage can reduce the adhesion energy of the interface during curing, resulting in better demolding.