• Title/Summary/Keyword: surface and interface

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Numerical Study of a Droplet Movement for the Ocean $CO_2$ Sequestration ($CO_2$해양처리를 위한 액적 거동 시뮬레이션 기초연구)

  • Jung Rho-Taek;Kang Seong-Gil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.8 no.1
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    • pp.39-45
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    • 2005
  • In the situation which Russia's ratification of the Kyoto protocol at February,2004, ANNEX I nations must reduce GHG(Green House Gas) discharge rate from 2008 by 2012 to the reduction level at 1990. We introduce the CO₂ ocean sequestration that is one of promising method for getting the stable CO₂ concentration in the atmosphere. There are four categories : ocean transportation technique, ocean initial dissolution technique, ocean deep current evaluation technique, and ocean biological evaluation technique. In this paper, we carried out the fundamental numerical study on the ocean initial dissolution technique, when the Liquidized CO₂ is emitted at the deep ocean, It is very important to the dissolution rate of movable CO₂ interface because it Is directly impact to the ocean organism. In order to investigate the relation of the interface movement and rate of the dissolution, we develope CR(Computational Fluid Dynamics) code that was constructed by the finite volume method based on the unstructured mesh, and a droplet's boundary surface can move and one direction dissolution from disperse phase into continuous phase adopted as its physics be. This study clarifies hydrodynamic relation between solubility and movement of the droplet through the verification of the Cm code.

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A Study on the Stabilization of the Papain Enzyme in the Moderately Concentrated Anionic Surfactant System (음이온 계면활성제에서 파파인 효소의 안정도에 관한 연구)

  • Kim, Ji-Yeong;Kim, Jin-Woo;Kim, Yong-Jin;Lee, Jae-Wook;Lee, Hae-Kwang;Kang, Hak-Hee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.33 no.2
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    • pp.93-97
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    • 2007
  • Even in the moderately concentrated anionic surfactant system, some special encapsulation method can shield the papain enzyme from proteolytic attacks. The stabilization of enzyme has been a major issue for successful therapies. In this study, we first stabilized an enzyme, papain in the microcapsules by using polyols, polyethyleneglycol (PEG), poly-propyleneglycol (PPG), and PEG-PPG-PEG block copolymer. In the analysis of EDS and CLSM, it was demonstrated that polyols are effectively located in the interface of papain and polymer. Polyols located in the interface had an ability to buffer the external triggers by hydrophobic partitioning, preventing consequently the catalytic activity of papain in the micro-capsules. Second. we introduced multi-layer capsulation methods containing ion complex. Such a moderately concentrated anionic surfactant system as wash-off cleansers, surfactants and waters can cause instability of entrapped enzymes. Surfactants and water in our final products swell the surface of enzyme capsules and penetrate into the core so easily that we can not achieve the effect of enzyme, papain. In this case, the ion complex multi-layer capsule composed of sodium lauroyl sarcosinate and polyquaternium-6 could effectively prevent water from penetration into the core enzyme, followed by in vivo test, and evaluate the stratum corneum (SC) turn-over speed.

Evaluation of Fiber Arrangement Condition of CF/PP Composites Using Electrical Resistance Measurement and Wettability (전기저항 평가법 및 접촉각을 이용한 CF/PP 복합재료 사출성형품 섬유 배열성 평가)

  • Kwon, Dong-Jun;Shin, Pyeong-Su;Kim, Jong-Hyun;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.17 no.1
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    • pp.15-20
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    • 2016
  • Fiber arrangement was important for fiber reinforced thermoplastic composites using injection fabrication. In this work, fiber arrangement in CF/PP was investigated to use electrical resistance (ER) method during injection times. There were 3 types of injection products of CF/PP with different ER change ratio by fiber arrangement. High ER change ratio case of injection CF/PP products had better increased tensile strength. This reason was due to the fiber arrangement of CF/PP by injection. Fractured surface and contact angle of CF/PP products were used to evaluate for injection product quality. Uniform fiber arrangement of CF/PP by injection type exhibited the uniform heat condition of melted CF/PP. Steady thermal transfer effect occurred from melted CF/PP to steel injection mold. Steady thermal transfer effect of CF/PP was transmitted to high ER change ratio of mold. Ultimately, good condition CF/PP product by injection molding method could be predicted by using ER method.

Redistribution of Dopant by Silicidation Treatment in Co/Metal/Si (Co/metal/Si 이중층 구조의 실리사이드화 열처리에 따른 dopant의 재분포)

  • Lee, Jong-Mu;Gwon, Yeong-Jae;Lee, Su-Cheon;Gang, Ho-Gyu;Bae, Dae-Rok;Sin, Gwang-Su;Lee, Do-Hyeong
    • Korean Journal of Materials Research
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    • v.8 no.3
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    • pp.189-194
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    • 1998
  • The redistribution behavior of boron during Co silicidation annealing in the Co/metal/Si system was investigated using SIMS. Ti, Nb and Hf films were used as epitaxy promoting metal layers. After annealing treatment the boron peak height was about 1 order lowered in Co/Ti/Si and Co/Nb/Si systems but the relative peak position from the surface did not change. The distribution of boron was very similar to those of Ti and Nb, because of the strong affinities of boron with them. Also, the position of the main boron peak in the Co/Hf/Si system was almost the same as that of Hf, but the distribution feature of the Co/Hf/Si system somewhat differed from those of Co/Ti/Si and Co/Nb/Si systems. This implies that the affinity between B and Hf is weaker than those of B-Ti and B-Nb. Boron tends to be depleted at the silicidelsi interface while it tends to be piled-up at the Co-metal/Co silicide interface during silicidation annealing.

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Determining of Ground Condition Criteria for Dam Reinforced RIM Grouting (댐체 강화 RIM부 그라우팅을 위한 지반상태 기준 결정)

  • Han, Kiseung;Lee, Donghyuk;Park, Duhee
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.42 no.2
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    • pp.181-186
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    • 2022
  • Dam slope RIM is a highly important contact interface where the main body and the base surface are connected. In general, when the grouting for the slope of the dam structure is designed, it is planned using limited data (drilling, geological map, etc.). This makes it very difficult to accurately consider the original ground characteristics of the slope RIM grouting target, In addition, when the grouting volume planned during the design is drilled and injected into the original ground where the waterstop is secured, there is a possibility that the original ground with the waterstop is disturbed and the effect of the waterstop is rather diminished. In order to overcome such problems, it is more suitable to first consider geological conditions and determine whether to perform optimal grouting on the original ground through on-site repair tests before performing RIM grouting. In this paper, to determine the grouting of the RIM unit, a pilot hole water pressure test was performed on the rock of the slope in the target section. The analysis shows grouting volume of 1 Lugeon or less, and the cement injection amount also shows the injection result of 1 kg/m or less. In this case, performing grouting is rather counterproductive. This result can be evaluated through a rock of which some degree of order of mass is secured, as it is a dam design standard of 1 Lugeon or less when analyzed, using the results of visual observation and geological map creation during slope cutting. Therefore, in conclusion, it is preferable to make the decision for using RIM grouting on the slope of the dam body structure, based on 1 Lugeon in a rock state, and the cement injection amount also at 1 kg/m.

Crustal structure of the Korean peninsula by inverting the travel times of first-arrivals from large explosions (대규모 발파자료 초동주시 역산을 통한 한반도 지각 속도구조 연구)

  • Kim Ki Young;Hong Myung Ho;Lee Jung Mo;Moon Woo Il;Baag Chang Eob;Jung Hee Ok
    • 한국지구물리탐사학회:학술대회논문집
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    • 2005.05a
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    • pp.103-107
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    • 2005
  • In order to investigate the velocity structure of the southern part of the Korean peninsula, exploded seismic signals were recorded for 120 s along a 294-km WNW-ESE line and 150 s along a 335-km NNW-SSE line in 2002 and 2004, respectively. Velocity tomograms were derived from inverting first arrival times. One-dimensional velocity models derived by joint analyses of teleseismic receiver functions and surface wave dispersion at several stations near the profiles were uesd to build initial models. The raypaths indicate several midcrust interfaces including ones at approximate depths of 2.0 and 14.9 km with refraction velocities of approximately 6.0 and 7.1 km/s, respectively. The deepest significant interface varies in depth from 30.8 km to 36.1 km. The critically refracting velocity varies from 7.8 to 8.1 km/s along this interface which may correspond to the Moho discontinuity. The velocity tomograms show (1) existence of a low-velocity zone centered at 6-7 km depth under the Okchon fold belt, (2) extension of the Yeongdon fault down to greater than 10 km, and (3) existence of high-velocity materials under the Gyeongsan basin whose thickness is less than 4.2 km.

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Characteristics of Phosphate Flux at the Sediment-water Interface in Gamak Bay during the Hypoxic Water Mass (가막만 빈산소 발생 시 해수-퇴적물 경계면에서 인산염플럭스 특성)

  • Kim, Sook-Yang;Jun, Sang-Ho;Lee, Young-Sik;Lee, Yong-Hwa;Kim, Byeoung-Man
    • Journal of Environmental Science International
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    • v.20 no.9
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    • pp.1069-1078
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    • 2011
  • The environmental changes related to hypoxic water mass were investigated at Gamak bay in summer times, June, July and August 2006. The hypoxic water mass was found, in first, at the northern area of Gamak bay on 27 June. This water mass has been sustained until the end of August and disappear on 13 September. In Gamak bay, the hypoxic water mass was closely related to geography. During the formation of oxygen deficiency, changes in dissolved nutrients was studied and found that on surface layer and lower layer, DIN were 0.80 ${\mu}M$~19.8 ${\mu}M$(6.03 ${\mu}M$) and 1.13 ${\mu}M$~60.83 ${\mu}M$(10.66 ${\mu}M$), and DIP were 0.01 ${\mu}M$~0.92 ${\mu}M$(0.24 ${\mu}M$), and 0.01 ${\mu}M$~3.57 ${\mu}M$(0.49 ${\mu}M$), respectively, far higher distribution on lower layer of the water where hypoxic water mass was occurred. The configuration of phosphorus was analyzed to figure out the possibility of release of phosphorus from sediments. It was found that the Labile-Phosphorus, which is capable of easy move to water layer by following environmental change was found more than 70%. Therefore, in Gamak bay, it was found that the possibility of large amount of release of soluble P into the water, while hypoxic water mass was occurred in deep layer was higher. It is suggested that DIP in the northern sea of Gamak bay mainly sourced from the soluble P from lower layer of the waters where hypoxic water mass was created more than that from basin. However, existence form of phosphorus in sediments during normal times, not during creation of hypoxic water mass, needs further study.

Improving Charge Injection Characteristics and Electrical Performances of Polymer Field-Effect Transistors by Selective Surface Energy Control of Electrode-Contacted Substrate (에폭시 개질 한 다관능 아크릴레이트를 포함하는 충격 저항성이 향상된 불포화폴리에스터 SMC (Sheet Molding Compound) 소재제조 및 그의 물성연구)

  • Jang, Jeong Beom;Kim, Taehee;Kim, Hye Jin;Lee, Wonjoo;Seo, Bongkuk;Kim, Yongsung;Kim, Changyoon;Lim, Choong-Sun
    • Journal of Adhesion and Interface
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    • v.21 no.3
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    • pp.101-106
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    • 2020
  • In this study, epoxy-modified acrylate was synthesized. The synthesized acrylate was added to the composition for sheet molding compound (SMC) in the range of 5 phr to 15 phr. The prepared SMC prepreg was molded at high temperature and pressure to produce a glass fiber reinforced composite. Physical properties such as tensile and impact strength of the composite were measured, respectively. Experimental data show that the composite with 5 phr of synthesized acrylate has 20% improved tensile strength and 12% improved impact strength than that of the reference sample.

Polymerization Shrinkage Behavior Measured by Digital Image Correlation for Methacrylate-based and Silorane-based Composites During Dental Restoration (디지털 이미지 상관법을 이용한 Methacrylate기질과 Silorane기질 복합레진의 치아 수복 시 중합수축거동)

  • Park, Jung-Hoon;Choi, Nak-Sam
    • Composites Research
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    • v.33 no.3
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    • pp.125-132
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    • 2020
  • The polymerization shrinkage behavior of dimethacrylate-based composite (Clearfil AP-X, Kuraray) and silorane-based composite (Filtek P90, 3M ESPE) used for dental composite restorations was measured using digital image correlation method. The stress distribution on the surface of specimen was calculated by finite element analysis with equivalent elastic modulus and was compared with the measured shrinkage distribution. Camera images were monitored by a CCD camera during and after the irradiation of light. As a result of the DIC analysis, a non-uniform shrinkage distribution was observed in both composite resins, and the resin core inside the ring specimen had free flowability, leading to in greater shrinkage strain than the resin/ring interfacial region. It was observed that as the distance from the center of the resin increased, the radial average shrinkage strain decreased. The radial average shrinkage strain during light irradiation occurred to be 33% for P90 and 57% for AP-X of the entire strain at the end of the test. The shrinkage behavior of P90 and AP-X was measured to be significantly different from each other during light irradiation. In the resin near the resin/ring interface, it was confirmed that the tensile strain rapidly formed to increase after light irradiation, causing a tensile stressed, interface weak.

Crustal Structure of the Korean Peninsula by Inverting the Rravel Times of First-arrivals from Large Explosions (대규모 발파자료 초동주시 역산을 통한 한반도 지각 속도구조 연구)

  • Kim, Ki-Young;Hong, Myong-Ho;Lee, Jung-Mo;Moon, Woo-Il;Baag, Chang-Eob;Jung, Hee-Ok
    • Journal of the Korean Geophysical Society
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    • v.8 no.1
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    • pp.45-48
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    • 2005
  • In order to investigate the velocity structure of the southern part of the Korean peninsula, exploded seismic signals were recorded for 120 s along a 294-km WNW-ESE line and 150 s along a 335-km NNW-SSE line in 2002 and 2004, respectively. Velocity tomograms were derived from inverting first arrival times. One-dimensional velocity models derived by joint analyses of teleseismic receiver functions and surface wave dispersion at several stations near the profiles were uesd to build initial models. The raypaths indicate several midcrust interfaces including ones at approximate depths of 2.0 and 14.9 km with refraction velocities of approximately 6.0 and 7.1 km/s, respectively. The deepest significant interface varies in depth from 30.8 km to 36.1 km. The critically refracting velocity varies from 7.8 to 8.1 km/s along this interface which may correspond to the Moho discontinuity. The velocity tomograms show (1) existence of a low-velocity zone centered at 6-7 km depth under the Okchon fold belt, (2) extension of the Yeongdon fault down to greater than 10 km, and (3) existence of high-velocity materials under the Gyeongsan basin whose thickness is less than 4.2 km.

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