• Title/Summary/Keyword: surface and interface

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Structural Study of Interface Layers in Tetragonal-NiSi (010)/Si using Density Functional Theory (밀도범함수를 이용한 정방정계-NiSi (010)/Si 계면 층의 구조 연구)

  • Kim, Dae-Hee;Kim, Dae-Hyun;Seo, Hwa-Il;Kim, Yeong-Cheol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.5
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    • pp.377-381
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    • 2009
  • Tetragonal-NiSi (010)/Si superstructures were calculated for studying the interface structure using density functional theory, The orthorhombic-NiSi was changed to the tetragonal-NiSi to be matched with the Si surface for epitaxy interface. The eight interface models were produced by the type of the Si surfaces, The tetragonal-NiSi (010)/Si (020)[00-1] superstructure was energetically the most favorable, and the interface thickness of this superstructure was the shortest among the tetragonal-NiSi (010)/Si superstructures. However, in the case of tetragonal-NiSi (010)/Si (010)[00-1] superstructure, it was energetically the most unfavorable, and the interface thickness was the longest. The energies and interface thicknesses of tetragonal-NiSi (010)/Si superstructures were influenced by the coordination number of Ni atoms and the bond length between atoms located at the interface.

Slippage on which interface in nanopore filtration?

  • Xiaoxu Huang;Wei Li;Yongbin Zhang
    • Membrane and Water Treatment
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    • v.15 no.1
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    • pp.31-39
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    • 2024
  • The flow in a nanopore of filtration membrane is often multiscale and consists of both the adsorbed layer flow and the intermediate continuum fluid flow. There is a controversy on which interface the slippage should occur in the nanopore filtration: On the adsorbed layer-pore wall interface or on the adsorbed layer-continuum fluid interface? What is the difference between these two slippage effects? We address these subjects in the present study by using the multiscale flow equations incorporating the slippage on different interfaces. Based on the limiting shear strength model for the slippage, it was found from the calculation results that for the hydrophobic pore wall the slippage surely occurs on the adsorbed layer-pore wall interface, however for the hydrophilic pore wall, the slippage can occur on either of the two interfaces, dependent on the competition between the interfacial shear strength on the adsorbed layer-pore wall interface and that on the adsorbed layer-continuum fluid interface. Since the slippage on the adsorbed layer-pore wall interface can be designed while that on the adsorbed layer-continuum fluid interface can not, the former slippage can result in the flux through the nanopore much higher than the latter slippage by designing a highly hydrophobic pore wall surface. The obtained results are of significant interest to the design and application of the interfacial slippage in nanoporous filtration membranes for both improving the flux and conserving the energy cost.

Deformation characteristics at the contact boundary in cylinder compression process (원기둥 압축 공정에서 접촉 경계면의 변형 특성)

  • Min, Kyung-Ho;Ko, Byung-Du;Lee, Ha-Seong
    • Design & Manufacturing
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    • v.8 no.2
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    • pp.30-36
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    • 2014
  • In this study, surface deformation patterns have been investigated by the rigid-plastic finite element method for friction factor test in solid cylinder compression process. AA1100 and AA6063 aluminum alloys, which show different work hardening characteristics respectively, have been adopted as model materials used for analysis. The main objective of this study is to provide the deformation mechanics in detail in solid cylinder compression process, especially at the die/workpiece interface that is closely related with the frictional conditions. For this reason, solid cylinder compression process has been numerically analyzed. The surface flow patterns at the contact boundary have been analyzed in terms of surface expansion, surface expansion velocity, pressure distributions exerted on the die surface along the die surface. By defining bulge factor, barreling phenomenon also have been examined with calibration curves to verify their effects on the surface flow pattern that is important for evaluating the frictional condition at the interface.

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Evaluation of Bond Performance for AC overlay on PCC Pavement (AC / PCC 복합포장 경계면 재료의 부착 성능 평가)

  • Kim, Dong kyu;Hwang, Hyun sik;Christopher, Jabonero;Ryu, Sung woo;Cho, Yoon ho
    • International Journal of Highway Engineering
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    • v.18 no.5
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    • pp.1-9
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    • 2016
  • PURPOSES : This study focuses on the evaluation of interface performance with varying surface texture and tack coat application in an asphalt overlay. METHODS : The evaluation is carried out in two phases: tracking test and interface bond strength test. Using an image processing tool, tracking test is conducted to evaluate the susceptibility of the tack coat material to produce excessive tracking during application. Using the pull-off test method, the bond strength test is performed to determine the ability of the interface layer to resist failure. RESULTS : Results show that the underseal application yields less tracking compared to other applications. However, the bond strength is barely within the minimum acceptable value. On the other hand, RSC-4 produces higher bond strength for all surface types, but the drying time is long, which produces excessive tracking. CONCLUSIONS : While underseal application may be suitable for a trackless condition, the bond strength is less appealing compared to the rest of the tack applications available. RSC-4 demonstrated a high and consistent bond strength performance, but more time is required for drying to avoid excessive tracking. Tack coat application and surface type combination produce varying results. Therefore, these should be considered when selecting suitable future tack coat application options.

Effects of Alloying Elements on the Corrosion Layer Formation of Pb-Grid/Active Materials Interface (Pb 기판/활물질 계면의 부식층형성에 미치는 합금원소영향)

  • Oh, Se-Woong;Choe, Han-Cheol
    • Journal of the Korean institute of surface engineering
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    • v.40 no.5
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    • pp.225-233
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    • 2007
  • Effects of alloying elements on the corrosion layer formation of Pb-grid/active materials interface has been researched for improvement of corrosion resistance of Pb-Ca alloy. For this research, various amounts of alloying elements such as Sn, Ag and Ba were added to the Pb-Ca alloys and investigated their corrosion behaviors. Batteries fabricated by using these alloys as cathode grids were subjected to life cycle test. Overcharge life cycle test was carried out at $75^{\circ}C$, 4.5 A, for 110 hrs. with KS standard (KSC 8504). And then, after keeping the battery with open circuit state for 48 hr, discharge was carried out at 300A for 30 sec. Corrosion morphology and interface between Pb-grid and active materials were investigated by using ICP, SEM, WDX, and LPM. Corrosion layer of Pb-Ca alloy got thicken with increasing Ca content. For Pb-Ca-Sn alloy, thickness of corrosion layer decreased as Sn and Ag content increased gradually. In case of Pb-Ca-Sn-Ba alloy, thickness of corrosion layer decreased up to 0.02 wt% Ba addition, whereas, it was not changed in case of above 0.02 wt% Ba addition.

Mechanical Properties of Unidirectional Carbon-carbon Composites as a Function of Fiber Volume Content

  • Dhakate, S.R.;Mathur, R.B.;Dham, T.L.
    • Carbon letters
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    • v.3 no.3
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    • pp.127-132
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    • 2002
  • Unidirectional polymer composites were prepared using high-strength carbon fibers as reinforcement and phenolic resin as matrix precursor with keeping fiber volume fraction at 30, 40, 50 and 60% respectively. These composites were carbonized at $1000^{\circ}C$ and graphitised at $2600^{\circ}C$ in the inert atmosphere. The carbonized and graphitised composites were characterized for mechanical properties as well as microstructure. Microscopic studies were carried out of the polished surface of carbonized and graphitised composites after etching by chromic acid, to understand the effect of fiber volume fraction on oxidation at fiber-matrix interface. It is found that the flexural strength in polymer composites increases with fiber volume fraction and so does for the carbonised composites. However, the trend was found to be reversed in graphitised composites. In all the carbonized composites anisotropic region has been observed at fiber-matrix interface which transforms into columnar type microstructure upon graphitisation. The extension of strong and weak columnar type microstructure is function of fiber volume fraction. SEM microscopy of the etched surface of the sample reveal that composites containing 40% fiber volume has minimum oxidation at the interface, revealing a strong interfacial bonding.

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Characterization of Thermal Contact Resistance Doped with Thermal Interface Material (접촉열전도재를 도포한 접촉열저항 특성연구)

  • Bajracharya, Iswor;Ito, Yoshimi;Nakayama, Wataru;Moon, Byeong-Jun;Lee, Sun-Kyu
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.9
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    • pp.943-950
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    • 2013
  • This paper describes the thermal contact resistance and its effect on the performance of thermal interface material. An ASTM D 5470 based apparatus is used to measure the thermal interface resistance. Bulk thermal conductivity of different interface material is measured and compared with manufacturers' data. Also, the effect of grease void in the contact surface is investigated using the same apparatus. The flat type thermal interface tester is proposed and compared with conventional one to consider the effect of lateral heat flow. The results show that bulk thermal conductivity alone is not the basis to select the interface material because high bulk thermal conductivity interface material can have high thermal contact resistance, and that the center voiding affects the thermal interface resistance seriously. On the aspect of heat flow direction, thermal impedance of the lateral heat flow shows higher than that of the longitudinal heat flow by sixteen percent.

A Study on Friction-induced Surface Fracture Behaviors of Thermoplastic Polyurethane (TPU)/Rubber Blends (열가소성 폴리우레탄 (TPU)/고무 블렌드의 마찰에 의한 표면 파괴 거동)

  • Jeon, Jun-Ha;Park, Sang-Min;Um, Gi-Yong;Bea, Jong-Woo
    • Journal of Adhesion and Interface
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    • v.14 no.3
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    • pp.121-127
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    • 2013
  • In this work, the thermoplastic polyurethane (TPU) was melt-blended with EPDM, NBR and BR to form TPU/Rubber blend films, their composition and friction-induced surface fracture relationship was investigated. TPU/EPDM and TPU/BR blends exhibited the improved friction-induced surface fracture, especially the effect of BR was excellent. With addition of more than 10 wt% BR, TPU/BR blends exhibited the improved friction-induced surface fracture. The increase of the soft segment with increasing BR content, which was confirmed by scanning electron microscopy (SEM) analysis enabled us to estimate the improved friction-induced surface fracture.

Investigation of Electrical Resistance Properties in Surface-Coated Lightweight Aggregate (표면코팅 경량골재의 전기저항 특성)

  • Kim, Ho-Jin;Kim, Chang-Hyun;Choi, Jung-Wook;Park, Sun-Gyu
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.6
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    • pp.727-738
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    • 2023
  • In concrete, the interface between the aggregate and cement paste is often the most critical factor in determining strength, representing the weakest zone. Lightweight aggregate, produced through expansion and firing of raw materials, features numerous surface pores and benefits from low density; however, its overall aggregate strength is compromised. Within concrete, diminished aggregate strength can lead to aggregate fracture. When applying lightweight aggregate to concrete, the interface strength becomes critical due to the potential for aggregate fracture. This study involved coating the surface of the aggregate with blast furnace slag fine powder to enhance the interfacial strength of lightweight aggregate. The impedance of test specimens was measured to analyze interface changes resulting from this surface modification. Experimental results revealed a 4% increase in compressive strength following the coating of the lightweight aggregate surface, accompanied by an increase in resistance values within the impedance measurements corresponding with strength enhancement.

Stability of the Grain Configurations of Thin Films-a Model for Agglomeration (박막내 결정립 배열의 열적 불안정성1)-응집 모델)

  • Na, Jong-Ju;Park, Jung-Geun
    • 연구논문집
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    • s.27
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    • pp.183-200
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    • 1997
  • We have calculated the energy of three distinct grain configurations, namely completely connected, partially connected and unconnected configurations, evolving during a spheroidization of polycrystalline thin film by extending a geometrical model due to Miller et al. to the case of spheroidization at both the surface and film-substrate interface. "Stabilitl" diagram defining a stable region of each grain configuration has been established in terms of the ratio of grain size to film thickness vs. equilibrium wetting or dihedral angles at various interface energy conditions. The occurrence of spheroidization at the film-substrate interface significantly enlarges the stable region of unconnected grain configuration thereby greatly facilitating the occurrence of agglomeration. Complete separation of grain boundary is increasingly difficult with a reduction of equilibrium wetting angle. The condition for the occurrence of agglomeration differs depending on the equilibrium wetting or dihedral angles. The agglomeration occurs, at low equilibrium angles, via partially connected configuration containing stable holes centered at grain boundary vertices, whereas it occurs directly via completely connected configuration at large equilibrium angles except for the case having small surface and/or film-substrate interface energy. The initiation condition of agglomeration is defined by the equilibrium boundary condition between the partially connected and unconnected configurations for the former case, whereas it can, for the latter case, largely deviate from the equilibrium boundary condition between the completely connected and unconnected configurations because of the presence of a finite energy barrier to overcome to reach the unconnected grain configuration.

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