• Title/Summary/Keyword: surface and interface

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Surface Characterization of Poly(vinylidene fluoride) and Poly(methyl methacrylate) Blend Coatings Prepared by Dispersion Coating (분산코팅에 의해 형성된 Poly(vinylidene fluoride)와 Poly(methyl methacrylate) 블렌드 코팅층의 표면 특성)

  • Seok, Kwang Hee;Ha, Jong-Wook;Lee, Soo-Bok;Park, In Jun;Kim, Hyung Joong
    • Polymer(Korea)
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    • v.37 no.2
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    • pp.177-183
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    • 2013
  • Surface properties such as morphology, crystalline structure, and chemical composition of poly(vinylidene fluoride) (PVDF)/poly(methyl methacrylate) (PMMA) blend coatings prepared by dispersion coating on poly(ethylene terephthalate) (PET) film have been investigated. It was observed that the surface properties were greatly influenced by the coating temperature and blend composition according to SEM, ATR-FTIR and XPS analysis. The typical surface morphology of ${\alpha}$-crystalline structure of PVDF could be observed when the coating temperature was lower than $120^{\circ}C$ or the amount of PVDF was higher than 80 wt% in the blend. Otherwise, the crystalline structure was changed from ${\alpha}$-crystal to ${\gamma}$-crystal or amorphous state. Based on the XPS analysis, the surface segregation of PVDF chains in the blend coating was confirmed.

Studies on the Air-Liquid Interface Culture as an Experimental Model for Physiology and Pharmacology of Tracheal Epithelial Cells (기관(氣管) 상피세포 생리 및 약리 실험모델로서의 공기-액체 접면 일차배양법 연구)

  • 이충재;이재흔;석정호;허강민
    • Biomolecules & Therapeutics
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    • v.10 no.4
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    • pp.281-286
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    • 2002
  • In this study, we intended to get a preliminary data for establishing rat tracheal surface epithelial(RTSE) cell culture system as an experimental model for physiology and pharmacology of tracheal epithelial cells. Primary culture on the membrane support and application of the air-liquid interface system at the level of cell layer were performed. The cell growth rate and mucin production rate were measured according to the days in culture. The results were as follows: this culture system was found to manifest mucocilliary differentiation of rat tracheal epithelial cells, the cells were confluent and the quantity of produced and released mucin was highest on culture day 9, the mucin was mainly released to the apical side and tbe free $^3{H}$-glucosamine which was not incorporated to process of synthesis of mucin was left on the basolateral side. Taken together, we suggest that air-liquid interface culture system can be used as a substitute for immersion culture system and as an experimental model for in vivo mucus-hypersecretory diseases.

Chemical Vapor Deposition of Tungsten on TiN Surface (TiN 표면위에 텅스텐의 화학증착)

  • Yi, Chung;Rhee, Shi-Woo;Lee, Kun-Hong
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.29A no.4
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    • pp.49-57
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    • 1992
  • Tungsten film was deposited on the TiN surface in a low pressure chemical vapor deposition reactor and chemical reaction mechanism between TiN surface and ($WF_{6}\;and\;SiH_{4}$ was studied. Interaction of ($WF_{6}\;or\;SiH_{4}$ with TiN surface and tungsten was deposited more easily. $WF_6$ reacted with TiN activated the TiN surface to form volatile TiF_4$ and tungsten nuclei were formed. ($SiH_{4}$ was dissociated on the TiN surface to form silicon nuclei. From RBS and AES analysis, we could not detect the impurities(such as Si or TiF$_x$)at the interface between tungsten and TiN. The adhesion at the W/TiN interface became poor when the deposition temperature was below 275$^{\circ}C$.

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Surface Modification of a Mild and Stainless Steel by Alumina Spraying (아루미나 용사에 의한 연강 및 스테인레스강의 표면개질)

  • 배종규;박승옥;정인상
    • Journal of the Korean institute of surface engineering
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    • v.22 no.4
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    • pp.185-196
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    • 1989
  • The surface modification of a mild and stainless steel by alumina sprayed coating were studied. The effects of surface roughness and bond coating layer on the adhesive strengthy and durability of sprayed specimens were also investiated. The adhesive strength of ceramic coating was affected by surface roughness and bond coating layer thinkness. That showed excellent undergrit blast time and bond coating layer; 60 sec and 0.15-0.33mm, respectively. The adhesive strength and densification of sprayed coating with air pressure were superior to those of without and fracture was mainly occured at alumina-bond coating interface. Under ambient atmosphere at $800^{\circ}C$, the oxides existed within bond coating layer promote diffusion of oxygen to lower durability of sprayed specimens. In this case, fracure was occured at sudstrate-bond coating interface.

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An Experimental Study on the Low-Temperature Behavior of Stratified Fluids in the Square Cavity (저온에서 정방형 공간내 성층화된 유체의 열적거동에 관한 실험적 연구)

  • 강한용;이동석;김병철
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.4
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    • pp.381-387
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    • 2000
  • An experimental study on the stratified fluids was carried out to investigate the flow characteristics, heat transfer through the interface of fluids, and the applications of thermal behaviors in the square cavity. The same volume of water and silicon oil was filled in it. The experiments were performed with the variations of initial temperatures and cooling surface temperatures. And the effect of vertical or horizontal cooling surface positions in the square cavity was investigated. When the cooling surface temperatures were $-4^{\circ}C$ , the supercooling phenomena were observed for both cases of cooling surface positions in the full region regardless of the initial temperature of fluid. In the square cavity with horizontal cooling surfaces, the lower the initial temperatures were, the longer the supercooling durations were, and with vertical cooling surface the lower the initial temperatures were, the shorter the supercooling durations were.

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Study on the Effect of Particles Injected Into the Head/Disk Interface (헤드-디스크 인터페이스에 주입되는 입자의 영향에 대한 연구)

  • Han Je-Hee;Lee Rae-Jun;Kim Dae-Eun;Kang Tae-Sik;Cho Keung-Youn
    • 정보저장시스템학회:학술대회논문집
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    • 2005.10a
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    • pp.179-183
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    • 2005
  • Particles in the HDD can cause serious damages such as scratches and thermal asperity(TA) at the head/disk interface(HDI). Accordingly, particles cause data loss including physical and electrical damages. To improve the reliability of head-disk interface, understanding the damage characteristics at the HDI due to particle interactions is required. The materials such as $A1_2O_3$, TiC and aluminum were used in this experiment. The size and hardness of particles injected into the HDI are closely relevant to surface damage caused the data loss on the disk and head. In this paper, a variety of scratches were analyzed using scanning electron microscope(SEM) and atomic force microscope(AFM). In order to analyze defects of very small size on the disk, optical surface analyzer(OSA) was also used.

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Experimental Study on Behavior of Bonding between PSC Girders and Precast Decks (PSC 거더와 프리캐스트 바닥판간 부착 강도 평가를 위한 실험적 연구)

  • Kim In Gyu;Chung Chul Hun;Shim Chang Su;Kim Seong Woon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.770-773
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    • 2004
  • The full-width, full-depth precast panel system is very efficient for the rehabilitation of deteriorated decks as well as for new bridge construction.. The horizontal bond strength at the interface between the two interconnected elements is of primary importance in order to achieve composite action. The strength of the bond between the two precast members should be high enough to prevent any progressive slip from taking place. However, the case when both of the interconnected elements are precast members bonded by means of grout, is not currently addressed by KBDC or AASHTO. This is the main impetus for this study. A total 43 push-off tests were performed to evaluate the horizontal bond strength and to recommend the best practice for the system. Test parameters included different interface surface conditions, different amount and different types of shear connectors. The presence of the shear keys at the top surface of the beam increased the interface bond capacity tremendously compared to the bond capacity with a different surface conditions.

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A Study on Determining Post-machining System for RP parts with Web-based Interface Tool (웹기반 쾌속조형물후가공 선정시스템 개발에 관한 연구)

  • 이상호;안대건;양화준;장태식;이일엽;정해도;이석희
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1257-1260
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    • 2003
  • Rapid Prototyping technology has many advantages such as Rapid Tooling. However, Using the RT technique is limited by the poor surface quality of the RP part. Thus, additional post-machining is required for improving the surface roughness by the sanding, grinding and polishing etc. But, these traditional finishing techniques are time and labor cost consuming. Hence, improving and formulation the finishing technique is inevitably necessary for the RF part. A new post-machining methodology for RP part is presented by the SLS part is used for automobile components in this research. Also, a web based interface tool that user requirements are rapidly ordered for post-machining RP part is developed.

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Influence of the Recombination Parameters at the Si/SiO2 Interface on the Ideality of the Dark Current of High Efficiency Silicon Solar Cells

  • Kamal, Husain;Ghannam, Moustafa
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.15 no.2
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    • pp.232-242
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    • 2015
  • Analytical study of surface recombination at the $Si/SiO_2$ interface is carried out in order to set the optimum surface conditions that result in minimum dark base current and maximum open circuit voltage in silicon solar cells. Recombination centers are assumed to form a continuum rather than to be at a single energy level in the energy gap. It is shown that the presence of a hump in the dark I-V characteristics of high efficiency PERL cells is due to the dark current transition from a high surface recombination regime at low voltage to a low surface recombination regime at high voltage. Successful fitting of reported dark I-V characteristics of a typical PERL cell is obtained with several possible combinations of surface parameters including equal electron and hole capture cross sections.

Effects of Air Void at the Steel-Concrete Interface on the Corrosion Initiation of Reinforcing Steel in Concrete under Chloride Exposure

  • Nam Jin-Gak;Hartt William H.;Kim Kijoon
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.829-834
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    • 2005
  • A series of reinforced G109 type specimens was fabricated and pended with a 15 weight percent NaCl solution. Mix design variables included 1) two cement alkalinities (equivalent alkalinities of 0.32 and 1.08), 2) w/c 0.50 and 3) two rebar surface conditions (as-received and wire-brushed). Potential and macro-cell current between top and bottom bars were monitored to determine corrosion initiation time. Once corrosion was initiated, the specimen was ultimately autopsied to perform visual inspection, and the procedure included determination of the number and size of air voids along the top half of the upper steel surface. This size determination was based upon a diameter measurement assuming the air voids to be half spheres or ellipse. The followings were reached based upon the visual inspection of G109 specimens that were autopsied to date. First, voids at the steel-concrete interface facilitated passive film breakdown and onset of localized corrosion. Based upon this, the initiation mechanism probably involved a concentration cell with contiguous concrete coated and bare steel serving as cathodes and anodes, respectively. Second, the corrosion tended to initiate at relatively large voids. Third, specimens with wire-brushed steel had a lower number of voids at the interface for both cement alkalinities, suggesting that air voids preferentially formed on the rough as-received surface compared to the smooth wire brushed one.