• Title/Summary/Keyword: surface $CO_2$ flux

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Application of Ceramic MF Membrane at the Slow Sand Filtration Process (완속모래여과 공정에서 세라믹 MF 막의 적용)

  • Choi, Kwang-Hun;Park, Jong-Yul;Kim, Su-Han;Kim, Jeong-Sook;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.12
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    • pp.877-882
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    • 2013
  • The application of ultrafiltration (UF) and microfiltration (MF) membranes has been increased for drinking water purification. The advantages of UF/MF membrane process compared to conventional treatment processes are stable operation under varying feed water quality, smaller construction area, and automatic operation. Most membrane treatment plants are designed with polymeric membranes. Recently, some studies suggested that the process of treating surface water with ceramic membranes is competitive to the application of polymeric membranes. Higher water flux, less frequent cleaning, and much longer lifetime are the advantages of ceramic membrane comparing to polymeric membrane. Therefore, this research focused on the application of ceramic MF membrane pilot plant at the slow sand filtration plant. The ceramic membrane pilot plant has three trains that used raw water and sand filtered water as a feed water, respectively. For optimizing the pilot plant process, the coagulation with PACl coagulant was used as a pretreatment of ceramic membrane process. In addition, CEB (Chemical Enhanced Backwash) process using $H_2SO_4$ and NaOCl was used for 1.5 days, respectively. The experimental results showed that applying the optimum coagulant dose before membrane filtration showed enhancing membrane fluxes for both raw water and sand filtered water. Also, when using raw water as a feed of membrane, minimum fouling rate was 2.173 kPa/cycle with 25 mg/L of PACl and when using sand filtered water, the minimum fouling rate was 0.301 kPa/cycle with 5 mg/L of PACl.

Flame Retardant Synergistic Performance between Cyclic Diphosphonate Ester and Melamine in Polyamide 6 (Polymide 6에서 Cyclic Diphosphonate Ester와 Melamine의 난연 효과)

  • Wang, Xueli;Jiang, Jianming;Yang, Shenglin;Jin, Junhong;Li, Guang
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.125-130
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    • 2008
  • A commercial cyclic diphosphonate ester (TPMP) and melamine (MA) was combined and added to polyamide 6 (PA6) to prepare the fire retardant PA6. An increase of the oxygen index to 28.6 as well as an improvement of the UL-94 classification to V-0 rating was observed. Cone measurements explained the rate of heat release (RHR) decreased and TGA showed the early decomposition and high solid residue due to co-addition of TPMP and MA, suggesting the occurrence of synergistic effect of TPMP and MA on fire resistance of PA6. The morphology of the char developed during combust ion showed the appearance of thick, intumescent cells on the surface of retardant PA6, which protects the underlying material from the action of the heat flux or flame and limits the diffusion of combustible volatile products towards the flame and oxygen.

On-orbit test simulation for field angle dependent response measurement of the Amon-Ra energy channel instrument

  • Seong, Sehyun;Kim, Sug-Whan;Ryu, Dongok;Hong, Jinsuk;Lockwood, Mike
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.211.1-211.1
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    • 2012
  • The on-orbit test simulation for predicting the instrument directional responsivity was conducted by the Monte Carlo based integrated ray tracing (IRT) computation technique and analytic flux-to-signal conversion algorithms. For the on-orbit test simulation, the Sun model consists of the Lambertian scattering sphere and emitting spheroid rays, the Amon-Ra instrument is a two-channel including a broadband scanning radiometer (energy channel) and an imager with ${\pm}2^{\circ}$ FOV (visible channel). The solar radiation produced by the Sun model is directed to the instrument viewing port and traced through the dual channel optical train. The instrument model is rotated on its rotation axis and this gives a slow scan of the Sun model over the full field of view. The direction of the incident lights are fed with scanned images obtained from the visible channel instrument. The instrument responsivity was computed by the ratio of the incident radiation input to the instrument output. In the radiometric simulation, especially, measured BRDF of the 3D CPC was used for scattering effects on radiometry. With diamond turned 3D CPC inner surface, the anisotropic surface scattering model from the measured data was applied to ray tracing computation. The technical details of the on-orbit test simulation are presented together with field-of-view calibration plan.

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A Study of Recycling Process to Recovery Valuable Resources from Aluminum Black Dross (알루미늄 블랙드로스로부터 유가자원 회수를 위한 재활용 공정 연구)

  • Kang, Yubin;Im, Byoungyong;Kim, Dae-Guen;Lee, Chan Gi;Ahn, Byung-Doo;Kim, Yong Hwan;Lee, Man Seung
    • Resources Recycling
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    • v.27 no.5
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    • pp.61-68
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    • 2018
  • The aluminum dross is oxide generated on the surface of the molten metal during the aluminum melting process and it is divided into white dross and black dross according to presence of the Salt flux. White dross has high metal content and is recycled via the melting process. Black dross is largely berried, because the it has a low metal content and difficulty in separating the components. Black dross contains a salt components such as NaCl and KCl, and inorganic materials such as $Al_2O_3$ and MgO, and it is necessary to study the technology to recover and recycle such valuable resources. In this study, a process for recycling aluminum black dross was proposed. The inorganic and soluble substances present in the black dross were separated through crushing-dissolution-solid/liquid separation-decompression evaporating. By controlling the ratio of water and black dross, the recovery condition of the separated product was optimized and we confirmed the highest Salt flux recovery efficiency 91 wt.% at black dross:water ratio 1:9. Finally, Through the synthesis of zeolite using recovered ceramic material, the materialization possibility of black dross was confirmed.

Behaviors of Metals in the Settling Particles in the Bransfield Strait, Antarctica (남극 브랜스필드 해협에서 침강입자의 금속원소 특성)

  • Kim, Dong-Seon;Kim, Dong-Yup;Kim, Young-June;Kang, Young-Chul;Shim, Jeong-Hee
    • Ocean and Polar Research
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    • v.25 no.1
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    • pp.41-52
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    • 2003
  • Sediment trap samples were collected to find out characteristic behaviors of metals in the settling particles by using time-series sediment traps at 678m and 1678m water depths in the Bransfield Strait from December 27th, 1999 to December 26th, 2000. Total mass fluxes at the intermediate water depth (678m water depth) were high in the austral summer and low in the austral winter, whereas at the deep water depth (1678m water depth) they showed high values in both the summer and winter. Total mass fluxes were generally higher in the deep water depth than in the intermediate water depth, which indicates that a substantial amount of sediments are laterally transported by strong currents into the deep basin from the shallow water depths. Aluminium contents also showed large seasonal variations with high values in the winter and low values in the summer. On the contrary, organic carbon contents were high in the summer and low in the winter. Al contents were negatively correlated with organic carbon contents, which may be ascribed that detrital particles are diluted by organic matter produced by phytoplankton in the surface waters. Metals measured in this study exhibited three characteristic behaviors; 1) a positive correlation with Al-Ti, Fe, Mn, V, Co, and Ba, 2) a negative correlation with Al-Cd and Zn, 3) no relationship with Al-Sr, Cu, Cr, Ni. Terrestrial materials may act as a major source fer metals that are positively correlated with Al, and organic matter may be a major source for metals that are negatively correlated with Al. Enrichment factor (EF) of Fe, Mn, Ba, Vi Co, Sr, Cr, and Ni ranged from 0.5 to 1.5, whereas EF of Zn, Cu, and Cd showed much higher values than 1.

Effect of Aging Time of AlO(OH) Gel Precipitated by Hydrolysis of Aluminum Sulfate on Crystal Growth of the Flaky α-Al2O3 (황산알루미늄의 가수분해에 의해 석출된 AlO(OH) 겔의 숙성시간이 판상 α-Al2O3의 결정성장에 미치는 영향)

  • Choe, Dong-Uk;Park, Byung-Ki;Suh, Jeong-Kwon;Lee, Jung-Min
    • Journal of the Korean Ceramic Society
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    • v.43 no.9 s.292
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    • pp.575-581
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    • 2006
  • To precipitate the complex gel of flux and aluminum hydroxides gel, aqueous solution of the mixture of $Na_2CO_3\;and\;Na_2PO_4{\cdot}12H_2O$ was added with stirring in aqueous solution of the mixture of $Al_2(SO_4)_3{\cdot}14{\sim}18H_2O,\;Na_2SO_4$, and then the complex gel was aged in $0{\sim}30h\;at\;90^{\circ}C$. As aging time passed, the aluminum hydroxides was grown into the acicular AlO(OH) gel. Also, aging time had an effect on physical properties of the AlO(OH) gel and on crystal growth of the flaky ${\alpha}-Al_2O_3$ prepared by molten-salt precipitation. In this study, the complex gel was crystallized in temperature range of $400{\sim}1,200^{\circ}C$ after drying at $110^{\circ}C$, and then it was investigated to effect of aging time on precipitation temperature, size, thickness, morphology and particle size distribution of the flaky ${\alpha}-Al_2O_3$ crystal. As aging time passed, the flaky a${\alpha}-Al_2O_3$ crystal showed a tendency toward an increase in size and thickness as result from an increase in BET surface area and pore volume of the acicular AlO(OH) gel.

Evaluation of Thermal Conductivity of Porous TiO2-SiO2-Base Thermal Insulation (다공성 TiO2-SiO2 복합 단열재의 열전도율 평가)

  • Choi, Byugchul;Kim, Jon-Ho;Kim, Jon Beom;Jung, Woonam;Lee, Sang-Hyun
    • Journal of Institute of Convergence Technology
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    • v.8 no.1
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    • pp.21-25
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    • 2018
  • We developed nano-porous $TiO_2-SiO_2$ composites (commercial name : PTI, porous titania insulator) with low thermal conductivity as thermal insulating material as well as function of photocatalyst. The objectives of this paper are, firstly, to evaluate of the thermal conductivity of the PTI powder in the temperature range from -160 to $250^{\circ}C$, secondly to evaluate of thermal conductivities of insulation materials that is applied PTI powder. The structure of the PTI powder that has the pores size of 20-30 nm and the particle diameter of 2-10 nm. The PTI had a high surface area of $400m^2/g$ and a mean pore size of $45{\AA}$, which was fairly uniform. The thermal conductivity was measured by GHP(guarded hot plate) method and HFM(heat flux method). The PTI structure is a three-dimensional network nano-structures composed by a pearl-necklace that involved a precious stone in the center of the necklace. The thermal conductivities of PTI-PX powder by the GHP and HFM were 0.0366 W/m.K, 0.0314 W/m.K at $20^{\circ}C$, respectively. This is similar to values that are proportional to the square of the absolute temperature of the thermal conductivity of static air. The thermal conductivities of insulating sheets coated with PTI powder were similar results with that of the PTI powder.

Design simulation of magnetic separator for purification of silica sand (자력선별방식을 이용한 고순도 실리카 정제 최적화를 위한 전산모사)

  • Choi, Hyun-Jin;Jo, Young Min;Lee, Jun Yub;Kim, Sang Bum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.1
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    • pp.181-187
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    • 2016
  • Silica is an essential material in the electronics industries of LCDs and OLEDs, which particularly require high purity. This study attempted to find the optimal design of a magnetic separator for silica sand containing iron compounds using CFD simulation. Three designs of magnetic separation were prepared and their efficiency was examined. As a result of the evaluation, the sufficient contact of particulate silica with the surface of magnetic emitters improved the magnetic separation effects. In addition, the loss of $SiO_2$ and the removal rate of $Fe_2O_3$ depended strongly on the particle size, flow rate and magnetic flux density. In addition, magnetic separation is quite effective for a particle size of $10{\mu}m$ with a 0.2 m/s flow rate.

Fouling Mitigation for Pressurized Membrane of Side-Stream MBR Process at Abnormal Operation Condition (가압식 분리막을 이용한 Side-Stream MBR 공정의 비정상 운전조건에서 막 오염 저감)

  • Ko, Byeong-Gon;Na, Ji-Hun;Nam, Duck-Hyun;Kang, Ki-Hoon;Lee, Chae-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.6
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    • pp.323-328
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    • 2016
  • Pressurized membrane used for side-stream MBR process requires fouling control strategy both for normal and abnormal operation conditions for stable operation of the facilities. In this study, $85m^3/day$ of pilot-scale side-stream MBR process was constructed for the evaluation of fouling mitigation by air bubble injection into the membrane module. In addition, fouling phenomena at abnormal operation conditions of low influent and/or loading rate were also investigated. Injection of air bubble was found to be effective in delaying transmembrane pressure (TMP) increase mainly due to scouring effect on the membrane surface, resulting in expanded filtration cycle at a high flux of $40L/m^2{\cdot}h$ (LMH). At abnormal operation condition, injection of PACl (53 mg/L as Al) into the bioreactor showed 19% reduction of TMP increase. However, inhibition of nitrifying bacteria by continuous PACl injection was observed from batch experiments. In contrast, injection of powdered activated carbon (PAC, 0.6 g/L) was able to maintain the initial TMP of $0.2kg/cm^2$ for 5 days at the abnormal conditions. It may have been caused from the adsorption of extracellular polymeric substances (EPS), which was known to be excessively released during growth inhibition condition and act as the major foulants in MBR operations.

DESIGN OPTIMIZATION OF RADIATION SHIELDING STRUCTURE FOR LEAD SLOWING-DOWN SPECTROMETER SYSTEM

  • KIM, JEONG DONG;AHN, SANGJOON;LEE, YONG DEOK;PARK, CHANG JE
    • Nuclear Engineering and Technology
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    • v.47 no.3
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    • pp.380-387
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    • 2015
  • A lead slowing-down spectrometer (LSDS) system is a promising nondestructive assay technique that enables a quantitative measurement of the isotopic contents of major fissile isotopes in spent nuclear fuel and its pyroprocessing counterparts, such as $^{235}U$, $^{239}Pu$, $^{241}Pu$, and, potentially, minor actinides. The LSDS system currently under development at the Korea Atomic Energy Research Institute (Daejeon, Korea) is planned to utilize a high-flux ($>10^{12}n/cm^2{\cdot}s$) neutron source comprised of a high-energy (30 MeV)/high-current (~2 A) electron beam and a heavy metal target, which results in a very intense and complex radiation field for the facility, thus demanding structural shielding to guarantee the safety. Optimization of the structural shielding design was conducted using MCNPX for neutron dose rate evaluation of several representative hypothetical designs. In order to satisfy the construction cost and neutron attenuation capability of the facility, while simultaneously achieving the aimed dose rate limit (< $0.06{\mu}Sv/h$), a few shielding materials [high-density polyethylene (HDPE)eBorax, $B_4C$, and $Li_2CO_3$] were considered for the main neutron absorber layer, which is encapsulated within the double-sided concrete wall. The MCNP simulation indicated that HDPE-Borax is the most efficient among the aforementioned candidate materials, and the combined thickness of the shielding layers should exceed 100 cm to satisfy the dose limit on the outside surface of the shielding wall of the facility when limiting the thickness of the HDPE-Borax intermediate layer to below 5 cm. However, the shielding wall must include the instrumentation and installation holes for the LSDS system. The radiation leakage through the holes was substantially mitigated by adopting a zigzag-shape with concrete covers on both sides. The suggested optimized design of the shielding structure satisfies the dose rate limit and can be used for the construction of a facility in the near future.