• Title/Summary/Keyword: supported metal

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Development of a Microbe-Zeolite Carrier for the Effective Elimination of Heavy Metals from Seawater

  • Kim, In Hwa;Choi, Jin-Ha;Joo, Jeong Ock;Kim, Young-Kee;Choi, Jeong-Woo;Oh, Byung-Keun
    • Journal of Microbiology and Biotechnology
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    • v.25 no.9
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    • pp.1542-1546
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    • 2015
  • The purpose of this study was to investigate the potential of zeolite-supported sulfatereducing bacteria (SRB) in enhancing the removal of Cu2+, Ni2+, and Cr6+ in contaminated seawater. Our results show that SRB-immobilized zeolite carriers can enhance the removal of heavy metals. In addition, heavy metals were generally better removed at conditions of 37°C. Cu2+, Ni2+, and Cr6+ were effectively removed by 98.2%, 90.1%, and 99.8% at 100 parts per million concentration of the heavy metals, respectively. These results indicate that SRB-zeolite carriers hold great potential for use in the removal of cationic heavy metal species from marine environment.

Vibration and damping behaviors of symmetric layered functional graded sandwich beams

  • Demir, Ersin
    • Structural Engineering and Mechanics
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    • v.62 no.6
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    • pp.771-780
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    • 2017
  • In this study, free vibration and damping behaviors of multilayered symmetric sandwich beams and single layered beams made of Functionally Graded Materials were investigated, experimentally and numerically. The beams were composed of Aluminum and Silicon Carbide powders and they were produced by powder metallurgy. Three beam models were used in the experiments. The first model was isotropic, homogeneous beams produced by using different mixing ratios. In the second model, the pure metal layers were taken in the middle of the beam and the weight fraction of the ceramic powder of each layer was increased towards to the surfaces of the beam in the thickness direction. In the third model, the pure metal layers were taken in the surfaces of the beam and the weight fraction of the ceramic powder of each layer was increased towards to middle of the beam. Then the vibration tests were performed. Consequently, the effects of stacking sequence and mixing ratio on the natural frequencies and damping responses of functionally graded beams were discussed from the results obtained. Furthermore, the results obtained from the tests were supported with a finite-element-based commercial program, and it was found to be in harmony.

Effect of Preparation Conditions on the Hydrogenation Activity and Metal Dispersion of Pt/C and Pd/C Catalysts

  • Jhung, Sung-Hwa;Lee, Jin-Ho;Lee, Jong-Min;Lee, Ji-Hye;Hong, Do-Young;Kim, Myong-Woon;Chang, Jong-San
    • Bulletin of the Korean Chemical Society
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    • v.26 no.4
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    • pp.563-568
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    • 2005
  • The Pt/C and Pd/C catalysts were prepared from conventional chloride precursors by adsorption or precipitation-deposition methods. Their activities for hydrogenation reactions of cyclohexene and acetophenone were compared with those of commercial catalysts. The Pt/C and Pd/C catalysts obtained from the adsorption procedure reveal higher hydrogenation activity than commercial catalysts and the catalysts prepared by the precipitation-deposition method. Their improved performances are attributed to the decreased metal crystallite sizes of Pt or Pd formed on the active carbon support upon the adsorption of the precursors probably due to the same negative charges of the chloride precursor and the carbon support. Under the preparation conditions studied, the reduction of the supported catalysts using borohydrides in liquid phase is superior to a gas phase reduction by using hydrogen in the viewpoint of particle size, hydrogenation activity and convenience.

Decomposition of Toluene by γ-Al2O3 Catalysts Impregnated with Transition Metal (전이금속을 함침한 γ-Al2O3 촉매의 Toluene 분해)

  • Choi, Sung-Woo;Lee, Chul-Kyu
    • Journal of Environmental Science International
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    • v.22 no.8
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    • pp.945-951
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    • 2013
  • Alumina-supported catalysts containing different transition metals such as Cu, Cr, Mn, Zn, Co, W were investigated for their activity in the selective oxidation of toluene. Catalytic oxidation of toluene was investigated at atmospheric pressure in a fixed bed flow reactor system over transition metals with $Al_2O_3$ catalyst. The result showed the order of catalytic activities for the complete oxidation of toluene was Mn > Cu> Cr> Co> W> Zn for 5wt.% transition $metals/Al_2O_3$. $Mn/Al_2O_3$ catalysts containing different amount of Mn were characterized by X-ray diffraction spectroscopy for decision of loading amount of metal to alumina. 5 wt.%$Mn/Al_2O_3$ catalyst exhibits the highest catalytic activity, over which the toluene conversion was up to 90% at a temperature of $289^{\circ}C$.

An Elastic-Plastic Stress Analysis in Silicon Carbide Fiber Reinforced Magnesium Metal Matrix Composite Beam Having Rectangular Cross Section Under Transverse Loading

  • Okumus, Fuat
    • Journal of Mechanical Science and Technology
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    • v.18 no.2
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    • pp.221-229
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    • 2004
  • In this work, an elastic-plastic stress analysis has been conducted for silicon carbide fiber reinforced magnesium metal matrix composite beam. The composite beam has a rectangular cross section. The beam is cantilevered and is loaded by a single force at its free end. In solution, the composite beam is assumed perfectly plastic to simplify the investigation. An analytical solution is presented for the elastic-plastic regions. In order to verify the analytic solution results were compared with the finite element method. An rectangular element with nine nodes has been choosen. Composite plate is meshed into 48 elements and 228 nodes with simply supported and in-plane loading condations. Predictions of the stress distributions of the beam using finite elements were overall in good agreement with analytic values. Stress distributions of the composite beam are calculated with respect to its fiber orientation. Orientation angles of the fiber are chosen as $0^{circ},\;30^{circ},\;45^{circ},\;60^{circ}\;and\;90^{circ}$. The plastic zone expands more at the upper side of the composite beam than at the lower side for $30^{circ},\;45^{circ}\;and\;60^{circ}$ orientation angles. Residual stress components of ${\sigma}_{x}\;and \;{\tau}_{xy}$ are also found in the section of the composite beam.

Study of toluene decomposition using nonthermal plasma and catalyst (저온플라즈마와 촉매를 이용한 톨루엔 분해 연구)

  • Lim, Yun Hui;Lee, Ju-Yeol;Shin, Jae-Ran;Choi, Jin-Sik;Park, Byung Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.541-548
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    • 2014
  • This study was performed to obtain high conversion efficiency of $C_7H_8$ using non-thermal plasma and metal-supported catalyst. Adsorption-desorption characteristics of toluene was performed using 4A type (Zeolite) filled in a concentration reactor. Through this test, it was found that the concentration reactor has 0.020 g/g of adsorption capacity (at ambient temperature and pressure) and 3,600 ppm of desorption property at $150^{\circ}C$ (with in 20 min). In case of developed catalyst, toluene decomposition rate of Pd-AO (Pd coated catalyst) was better than Pd/Cu-AO and Pd/Ag-AO (Pd/Ag composite metal catalyst). Developed non-thermal plasma system was obtained flame amplification effect using injection process of desorbed tolune, and 98% of removal efficiency.

A 2-year clinical evaluation of Sculpture crowns

  • Ku, Chul-Whoi;Yang, Hong-So
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.6
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    • pp.806-813
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    • 2000
  • Statement of problems. There are only a few studies available that deal with the clinical behavior of ceromer systems as potential substitutes for metal-ceramic crowns. Purpose. This prospective study was initiated to evaluate the clinical performance of 35 Sculpture crowns after 2 years in service. Material and methods. Thirty five Sculpture crowns were placed for 20 patients (7 men and 13 women). All patients were treated by the same dentist, and all restorations were fabricated by the same dental laboratory. Crown placement involved both the anterior and posterior regions of the dental arches. Patients were evaluated by two examiner at baseline, 12, and 24 months using the CDA quality assessment system in addition to periodontal criteria. Results. Of 34 crowns remaining in the study after 2 years, only one crown had experienced a marginal fracture. The crown was replaced as a result of recurrent caries. All remaining crowns were ranked as either excellent or acceptable for surface and color, anatomic form, and marginal integrity. Conclusion. The 2-year clinical observations and ranking with the CDA quality assessment criteria supported the conclusion that Sculpture crowns may be used in substitutes for metal-ceramic crowns.

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A Study on Machining Distortion of Airfoil Effected by Fixture and Process (에어포일 기계가공 변형 연구 : 지그와 가공단계의 영향)

  • Ra, Kyeong-Woon;Ji, Seong-Bum;Jo, Yeong-Jin;Park, Je-Hong;Seo, Sang-Won;Kim, Su-Jin
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.23 no.5
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    • pp.465-470
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    • 2014
  • Thin and wide airfoils are difficult to be machined precisely because they are deformed during and after machining processes. This paper presents the results of the airfoil deformation measured by three-dimensional (3D) scanning equipment. It also discusses the influences of fixture and the machining process on the distortion of the thin airfoil. The simple fixture bended the thin airfoil to a U-shape at the first process, and the vacuum fixture decreased the distortion of the machined airfoil at the second process. The long and thin airfoil supported by two points was buckled during the machining at its two end-regions at the third process. Results from this study suggest that use of vacuum fixture decreases the machining distortion of thin and wide airfoils.

Release Pattern of Urea from Metal-urea-clay Hybrid with Montmorillonite and Its Impact on Soil Property

  • Kim, Kwang-Seop;Choi, Choong-Lyeal;Lee, Dong-Hoon;Seo, Young-Jin;Park, Man
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.4
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    • pp.545-550
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    • 2011
  • Urea intercalated into montmorillonite (MT) exhibits remarkably enhanced N use efficiency, maintaining its fast effectiveness. This study dealt with the release property of urea from metal-urea-clay hybrid with MT (MUCH) under continuous-flow conditions and the cumulative impacts of its successive application on physicochemical properties of soils. Releases of urea were completed within 4 hrs under continuous-flow condition regardless of the types and the leaching solutions. However, urea release property was significantly affected by both the form of fertilizer and the presence of electrolytes in solution. The fast release property of urea from MUCH in continuous-flow condition was not significantly affected by soil properties such as soil pH and soil texture. In addition, its successive application did not lead to any noticeable change in soil physicochemical properties, water stable aggregate rate, water holding capacity and cation exchange capacity in both sandy loam and clay loam soils. Therefore, this study strongly supported that urea intercalated into MT could be applied as fast-effective N fertilizer, in particular for additional N supply.

The study of detonation of laser-ablated aluminum by high power laser (고 에너지 레이저를 통한 laser-ablated 알루미늄의 detonation 현상 연구)

  • Kim, Chang-Hwan;Yoh, Jack. J
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.04a
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    • pp.425-429
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    • 2011
  • The development of metal plasma generated by high laser irradiance and its effect on the surrounding air using shadowgraph images after laser pulse termination are studied; hence the formation of laser supported detonation and combustion processes has been investigated. The core of the paper is in detecting chemical reaction using X-Ray Diffraction (XRD) between ablated aluminum plasma and oxygen from air by inducing high power laser pulse (>1000 mJ/pulse) and conduct a quantitative comparison of chemically reactive laser initiated waves with the classical detonation of exploding aluminum (dust) cloud in air. This study may suggest a new approach of initiating detonation from metal sample in its bulk form without the need of mixing nano-particles with oxygen for initiation.

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