• Journal of the Korean Chemical Society
• /
• v.37 no.5
• /
• pp.491-495
• /
• 1993

Synthesis of polymer-supported azacrown ether ion exchanger, {(4,5): (13,14)-dibenzo-6,9,12-trioxa-3,15,21-triazazabicyclo[15.3.1]heneicosa-1(21),17,19-triene-2,16-dione : DBPDA ion exchanger}, and its ion binding ability to alkali metal $(Li^+,\;Na^+,\;K^+)$ picrates were studied. The binding constants $(K_b)$ of DBPDA ion exchanger to the alkali metal picrates in ether type solvents were obtained by spectrophotometry. Binding constants of alkali metal ions were in the order to Li < Na < K, and alkali metal ions were formed 1 : 1 complexes with ligands of DBPDA ion exchanger. Also, $K_b$ was found to depend on the variables such as solvent and temperature. The binding constants for the complexes were obtained in the ranges of $2{\times}10^3{\sim}4{\times}10^4M^{-1}$. In order to obtain the enthalpy (${\Delta}$H) and entropy changes (${\Delta}$S)n the complexation process, Kb were plotted against the temperature in the ranges of 10∼40$^{\circ}C$ according to the van't Hoff theory. Enthalphy and entropy changes were found in the ranges of -2.71∼-3.79 kcal/mol, and -16.52∼-20.57 eu, respectively.

• Journal of the Korean Chemical Society
• /
• v.53 no.3
• /
• pp.233-243
• /
• 2009

We have investigated the infrared spectra for CO adsorbed on silica supported nickel(Ni-Si$O_2$), silica supported copper(Cu-Si$O_2$), silica supported nickel-copper alloys(Ni/Cu-Si$O_2$) of several compositions with varying CO pressures(0.2 $torr{\sim}$50 torr) at room temperature and on pumping to vacumn at room temperature within the frequency range of 1500 $cm^{-1}{\sim}2500\;cm^{-1}$. Four bands(2059.6 $cm^{-1},\;{\sim}$2036.5 $cm^{-1},\;{\sim}$ 1868.7 $cm^{-1},\;{\sim}$ 1697.1 $cm^{-1}$) were observed for Ni-Si$O_2$, two bands($\sim$2115.5 $cm^{-1},\;{\sim}$1743.0 $cm^{-1}$) were observed for Cu-Si$O_2$ and five bands(${\sim}2123.2\;cm^{-1}$, 2059.6 $cm^{-1},\;{\sim}$2036.4 $cm^{-1},\;{\sim}$1899.5 $cm^{-1},\;{\sim}$1697.1 $cm^{-1}$) were observed for Ni/Cu-Si$O_2$. These absorption bands correspond with those of the previous reports approximately. The bands below 1800 $cm^{-1}$ were only observed with Ni metal or Ni/Cu alloy crystal plane containing step at room temperature and the ${\sim}1697.1\;cm^{-1}$ bands observed with Ni-Si$O_2$ and Ni/Cu-Si$O_2$ may be ascribed to CO molecule adsorbed on the adsorption sites near step. The bands below 2000 $cm^{-1}$ were rarely observed with Cu metal crystal plane at room temperature and the 1743.0 $cm^{-1}$ bands may be ascribed to CO molecule adsorbed on the adsorption sites near step. The band shifts of adsorbed CO with varing Cu contents from 0 to 0.5 mole fraction at the same CO pressure or at the same pumping time to vacumn were below 21 $cm^{-1}$. and comparatively small than those with other ⅠB metal addition. It may means ligand effect of Cu d electron is small.

• Journal of Korean Association for Spatial Structures
• /
• v.1 no.2 s.2
• /
• pp.10-22
• /
• 2001

A few characteristics of membrane structures which the author thinks important for design are described on the basis of his experience in research and design of this kind of structures. Different in behaviors of air-supported and air-inflated structures are first explained for a better understanding of these structures. Attention is drawn to unfavorable behaviors of an air-beam when it is reinforced by diagonal members. The shallowest membrane structure which can be made as an airdome is pursued, and its application to a metal membrane dome is shown. Attempts which have been made by the author seeking for the possibility of membrane structures made of metal sheet, plastic film with and without reinforcement are described with realized examples. A 100m long jumbo carp is explained as an example of a flying membrane.

• Carbon letters
• /
• v.10 no.3
• /
• pp.213-216
• /
• 2009

The electrochemical deposition of Pt nanoparticles on carbon nanotubes (CNTs) supports and their catalytic activities for methanol electro-oxidation were investigated. Pt catalysts of 4~12 nm average crystalline size were grown on supports by potential cycling methods. Electro-plating of 12 min time by potential cycling method was sufficient to obtain small crystalline size 4.5 nm particles, showing a good electrochemical activity. The catalysts' loading contents were enhanced by increasing the deposition time. The crystalline sizes and morphology of the Pt/support catalysts were evaluated using X-ray Diffraction (XRD) and Transmission Electron Microscopy (TEM). The electrochemical behaviors of the Pt/support catalysts were investigated according to their characteristic current-potential curves in a methanol solution. In the result, the electrochemical activity increased with increased plating time, reaching the maximum at 12 min, and then decreased. The enhanced electroactivity for catalysts was correlated to the crystalline size and dispersion state of the catalysts.

• Steel and Composite Structures
• /
• v.28 no.6
• /
• pp.671-679
• /
• 2018

The paper is devoted to the stability analysis of a simply supported five layer sandwich beam. The beam consists of five layers: two metal faces, the metal foam core and two binding layers between faces and the core. The main goal is to elaborate a mathematical and numerical model of this beam. The beam is subjected to an axial compression. The nonlinear hypothesis of deformation of the cross section of the beam is formulated. Based on the Hamilton's principle the system of four stability equations is obtained. This system is approximately solved. Applying the Bubnov-Galerkin's method gives an ordinary differential equation of motion. The equation is then numerically processed. The equilibrium paths for a static and dynamic load are derived and the influence of the binding layers is considered. The main goal of the paper is an analytical description including the influence of binding layers on stability, especially on critical load, static and dynamic paths. Analytical solutions, in particular mathematical model are verified numerically and the results are compared with those obtained in experiments.

• Advances in materials Research
• /
• v.6 no.2
• /
• pp.129-153
• /
• 2017

Platinum is a transition metal that is very resistant to corrosion. It is used as catalyst for converting methyl alcohol to formaldehyde, as catalytic converter in cars, for hydrocracking of heavy oils, in Fuel Cell devices etc. Moreover, Platinum compounds are important ingredient for cancer chemotherapy drugs. The nano forms of Platinum due to its unique physico-chemical properties that are not found in its bulk counterpart, has been found to be of great importance in electronics, optoelectronics, enzyme immobilization etc. The stability of Platinum nanoparticles has supported its use for the development of efficient and durable proton exchange membrane Fuel Cells. The present review concentrates on the use of Platinum conjugated with various metal or compounds, to fabricate nanocomposites, to enhance the efficiency of Platinum nanoparticles. The recent advances in the synthesis methods of different Platinum-based nanocomposites and their applications in Fuel Cell, sensors, bioimaging, light emitting diode, dye sensitized solar cell, hydrogen generation and in biosystems has also been discussed.

• Advanced Composite Materials
• /
• v.17 no.2
• /
• pp.177-190
• /
• 2008

As the first step in discussing the reliability of composite structures, a fundamental study was performed to obtain the scattering characteristics of glass-fiber reinforced plastics (GFRP) and woven carbon fiber reinforced plastics (WCFRP) as well as a reference metal. The Euler buckling load was obtained experimentally for each material. The experiments were conducted for specified rectangular specimens with simply supported edges. A new attachment to realize the simply support boundary conditions for composite materials have been prepared before these experiments. The scattering data in the results for GFRP and WCFRP composites were compared with those of a typical metal of aluminum alloy. The experimental data were also compared with numerical simulations including the uncertainties.

• Bulletin of the Korean Chemical Society
• /
• v.16 no.3
• /
• pp.205-210
• /
• 1995

Catalytic effects of various Schiff base metal(II) complexes on the reduction of thionyl chloride at glassy carbon electrode are evaluated by determining the kinetic parameters from cyclic voltammetry technique. The charge transfer process is affected strongly by the concentration of catalysts during the reduction of thionyl chloride. The catalytic effects are shown by both a shift of the reduction potential for thionyl chloride toward more positive direction and an increase in peak current. The diffusion coefficient value, Do, of the 8.17 ${\times}$ 10-9 $cm^2/s$ was observed at the bare glassy carbon electrode, whereas larger values (0.9-1.09 ${\times}$ 10-8 $cm^2/s$) were observed at the catalyst supported glassy carbon electrode. Significant improvements in the cell performance have been noted in terms of both exchange rate constants and current densities at glassy carbon electrode.

• 제어로봇시스템학회:학술대회논문집
• /
• 1993.10a
• /
• pp.981-986
• /
• 1993

A fast algorithm based upon geometry to measure the wafer center and the position of a wafer fiducial mark is developed and implemented on a single-axis aligner. Design issues for a controller when a National Semiconductor's LM629 is used as a PID controller of an aligner are discussed. Performance of an aligner with the algorithm and a LM629 was measured in experiments. The result shows that it takes about 4.1 seconds on average to align a hot wafer supported by metal pins on the chuck.

• Journal of the Korean institute of surface engineering
• /
• v.35 no.6
• /
• pp.401-407
• /
• 2002

Most of organic compounds discharged from industrial wastewater are treated by chemical oxidation, adsorption and biodegradable process. This process has been demanded a new advanced environmental wastewater treatment process. From this point of view, an electrochemical oxidation process using electrocatalysts has been developed for the destruction of organic compounds. Through this study, a ruthenium oxide/iridium oxide supported on titanium expanded metal was fabricated by thermal decomposition method and its performance was excellent during this experiment.