• 제목/요약/키워드: supported

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고순도 수소 생산을 위한 CO 선택적 산화 반응용 Pt 촉매 연구 (A Study on Preferential CO Oxidation over Supported Pt Catalysts to Produce High Purity Hydrogen)

  • 전경원;정대운;장원준;나현석;노현석
    • 한국수소및신에너지학회논문집
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    • 제24권5호
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    • pp.353-358
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    • 2013
  • To develop preferential CO oxidation reaction (PROX) catalyst for small scale hydrogen generation system, supported Pt catalysts have been applied for the target reaction. The supports were systematically changed to optimize supported Pt catalysts. $Pt/Al_2O_3$ catalyst showed the highest CO conversion among the catalysts tested in this study. This is due to easier reducibility, the highest dispersion, and smallest particle diameter of $Pt/Al_2O_3$. It has been found that the catalytic performance of supported Pt catalysts for PROX depends strongly on the reduction property and depends partly on the Pt dispersion of supported Pt catalysts. Thus, $Pt/Al_2O_3$ can be a promising catalyst for PROX for small scale hydrogen generation system.

운동프로그램이 피로, 지각된 건강상태, 운동관련 정서, 지각된 유익성 및 자기효능감에 미치는 효과 - 여대생을 대상으로 - (The Effects of Exercise Program on Fatigue, Perceived Health State, Exercise-related Affect, Perceived benefits, and Self-Efficacy - From the samples of female college students -)

  • 최은숙;이미라
    • 대한간호학회지
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    • 제29권6호
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    • pp.1254-1262
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    • 1999
  • The purpose of this study was to examine the effects of 6-wk low intensity exercise program on fatigue, perceived health state, exercise-related affect, perceived benefits, and exercise self-efficacy for female college student's. The subjects of the study consisted of thirty-four female college students. The research subjects were assigned to experimental and control group. The experimental group participated in 13-17 and 30-60 minute sesseions of exercise program over 6 weeks. Data analysis was done by t-test with SAS program. The results of this study are as follows. 1) The first hypothesis, “The fatigue of experimental group will be lower than control group”, was supported. 2) The second hypothesis, “The perceived health state of experimental group will be higher than control group”, was not supported. 3) The third hypothesis, “The exercise-related affect of experimental group will be higher than control group”, was not supported. 4) The fourth hypothesis, “The benefits of exercise of experimental group will be higher than control group”, was not supported. 5) The fifth hypothesis, “The self-efficacy for exercise of experimental group will be higher than control group”, was supported.

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접촉해석이 연계된 스프링 지지보의 진동해석 (Vibration Analysis of Beam Supported by Springs Considering a Contact)

  • 최명환;강홍석;송기남;윤경호;김형규
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2002년도 춘계학술대회논문집
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    • pp.1216-1221
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    • 2002
  • The fuel rods in the pressurized water reactor are continuously supported by a spring system called a spacer grid which is one of the main structural components for the fuel rod cluster (fuel assembly). The fuel rods are vibrating within the reactor due to coolant flow. Since the vibration, what is called flow-induced vibration(FIV), can wear away the surface of the fuel rod, it is important to understand the vibration characteristics of it. In this paper, the vibration analyses and the tests for the dummy rods supported by New Doublet(ND) spacer grids are described. A new FE model which reflects the contact area between the rod and ND spacer grid spring is developed to replace the previous one by which a good agreement could not be obtained with the vibration test. The natural frequency and mode shape calculated by both the previous FE model and the new one are compared with those of experiment fur a single-spanned rod supported by two ND spacer grids. The results by the new model show good agreement to experiment as compared with the ones by previous model. In addition, the new FE model is applied to the vibration analysis fur the dummy rod of 2.19 m tall continuously supported by five ND spacer grids. It is also obtained that the analysis results by the new FE model well agree to experiment ones as the single-spanned rod.

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금속지지체식 SOFC 제작 및 평가 (Fabrication and Evaluation of Metal-Supported SOFC)

  • 최진혁;이태희;최미화;유영성
    • 한국수소및신에너지학회논문집
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    • 제22권1호
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    • pp.77-82
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    • 2011
  • In this study, a metal-supported SOFC was fabricated using a relatively cheap and simple process. The adhesion process between ceramic cell and metal support was performed in high temperature over $1400^{\circ}C$ and the deformation of large metal-supported cell happened in this process. Using bi-layered metal support fabricated by diffusion bonding, the deformation of the metal-supported cell can be minimized and the sealing efficiency of anode and cathode was improved. The flatness of the cell was improved by over 20% and the maximum power density of over 0.5 $Wcm^{-2}$ was obtained at the operation condition of $800^{\circ}C$.

차세대 고속철도 특수교량의 설계 및 기술사양 조사 (Investigation of Design and Technical Specifications on Cable Supported Bridges for Next-Generation High-Speed Railways)

  • 박만호;문제우;김성일;홍성모;김종태
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2008년도 춘계학술대회 논문집
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    • pp.206-213
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    • 2008
  • Mo-Am arch bridge is only the long-span bridge (with 125m span) in the Kyong-Bu high-speed line in service, while other bridges are PSC box girder bridges and steel composite bridges with span lengths of $25\sim50m$. However, in foreign high-speed lines, special cable-supported bridges like cable-stayed bridges and extradosed bridges are being adopted in earnest with technical specifications. The cable supported bridge is recognized as one of the indices of technology in civil engineering field, and thus it is being adpoted with a sense of rivalry in countries with advanced technology in railway engineering. In this paper, to apply the top-level cable-supported bridge technology to the domestic high-speed line up to 400km/h by establishing the technical specifications on cable-supported bridges including span length, the requirements for securing the dynamic stability and running safety of high speed train are analyzed through case studies for domestic and foreign cases.

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치과 임플랜트 보철 장착자의 구강 감각 기능에 관한 연구 (A STUDY ON ORAL SENSORY FUNCTION IN THE IMPLANT-SUPPORTED PROSTHESES WEARERS)

  • 장경수;김영수
    • 대한치과보철학회지
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    • 제29권1호
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    • pp.215-232
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    • 1991
  • In this study, oral sensory function in the osseointegrated root form implant-supported prostheses wearers was estimated by measuring occlusal tactile perception threshold of thickness and sensibility threshold against lateral static loading, and comparing with normal dentition subjects and complete denture wearers group. Osseointegrated root form implants seemed to be restored in the sensation to some extent, and so, dental implants restored edentulous patients in a wide meaning. Conclusions were summarized as following. 1. Occlusal tactile perception threshold of thickness was highest in complete denture wearers group, following by implant-supported prostheses wearers group, normal dentition subjects group. 2. In the implant-supported prostheses wearers group, occlusal tactile perception threshold of opposing artificial teeth case was higher than of opposing natural or opposing implantsupported teeth case. 3. Sensibility threshold against lateral loading of complete denture wearers and implantsupported prostheses wearers group was higher than that of normal dentition subject group. 4. In the implant-supported prostheses group, sensibility threshold against lateral loading was not significantly different between upper and lower jaws. 5. In occlusal tactile perception threshold of thickness and sensibility threshold against lateral loading test, there was no regularity among values of each tooth, and no significant difference between anterior and posterior teeth as well.

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부벽식 기법을 사용한 자립식 지하연속벽 공법의 싱가폴사례 (Singapore Case Study of Self-Supported Diaphragm Wall Method Using Counterfort Technique)

  • 정경환;박헌국;신민식;한경태;유지영
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2008년도 추계 학술발표회
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    • pp.605-613
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    • 2008
  • Application of anchored or strutted wall system for the earth retention of excavation works in a populated urban area or a poor soil deposit can be limited due to various restrictions. Since the strut becomes longer in a wide excavation site, the stability of an earth retaining wall is decreased, the wall deformation is increased, and the ground settlement is also increased due to an increased buckling or bending deformation of struts. Especially, in a populated urban area, the installation of anchors can be problematic due to the property line of adjacent structures or facilities. Thus, a new concept of earth retaining system like Self-Supported diaphragm Wall can solve several problems expected to occur during excavation in the urban area. Application of self-supported counterfort diaphragm wall was verified in this paper though comparing the design of self-supported counterfort diaphragm wall with the data monitored during excavation in Singapore.

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SBA-15 실리카에 고정화된 ruthenium 촉매를 사용한 Microwave하에서의 비대칭 수소 전달반응 (Microwave-mediated Asymmetric Hydrogen Transfer by SBA-15-supported Ruthenium Catalyst)

  • 진명종;전인철
    • Korean Chemical Engineering Research
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    • 제46권4호
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    • pp.752-755
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    • 2008
  • 메조포러스 SBA-15 silica와 (1R,2R)-N-(trimethoxysilylpropyl-N-sulfonyl)-1,2-cyclohaxanediamine 또는 (1R,2R)-N-(trimethoxysilylpropyl-N-sulfonyl)-1,2-diphenylethylenediamine과의반응을통하여 메조포러스 silica SBA-15-supported TsCHDA와 TsDPEN가 각각 제조되어졌다. SBA-15-supported TsCHDA로부터 얻어진 ruthenium complex들은 microwave하에서의 케톤의 비대칭 수소 전달반응에서 우수한 촉매능과 만족할 만한 거울상 입체선택도를 주었다. 이불균일상 SBA-15-supported ruthenium 촉매는 사용이 용이하게 안정할 뿐 만 아니라, 재사용 할 수 있었다. 비대칭 수소전달반응을 위한 microwave를 사용한 효율적인 공정이 개발되었다.

Semi-analytical solutions for optimal distributions of sensors and actuators in smart structure vibration control

  • Jin, Zhanli;Yang, Yaowen;Soh, Chee Kiong
    • Smart Structures and Systems
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    • 제6권7호
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    • pp.767-792
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    • 2010
  • In this paper, the optimal design of vibration control system for smart structures has been investigated semi-analytically via the optimization of geometric parameters like the placements and sizes of piezoelectric sensors and actuators (S/As) bonded on the structures. The criterion based on the maximization of energy dissipation was adopted for the optimization of the control system. Based on the sensing and actuating equations, the total energy stored in the system which is used as the objective function was analytically derived with design variables explicitly presented. Two cases of single and combined vibration modes were addressed for a simply supported beam and a simply supported cylindrical shell. For single vibration mode, the optimal distributions of the piezoelectric S/As could be obtained analytically. However, the Sequential Quadratic Programming (SQP) method has to be employed to solve those which violated the prescribed constraints and to solve the case of combined vibration modes. The results of three examples, which include a simply supported beam, a simply supported cylindrical shell and a simply supported plate, showed good agreement with those obtained by the Genetic Algorithm (GA) method. Moreover, in comparison with the GA method, the proposed method is more effective in obtaining better optimization results and is much more efficient in terms of computation time.

Polymer-supported Zinc Tetrahalide Catalysts for the Coupling Reactions of CO2 and Epoxides

  • Lee, Bo-Ra;Ko, Nan-Hee;Ahn, Byoung-Sung;Cheong, Min-Serk;Kim, Hoon-Sik;Lee, Je-Seung
    • Bulletin of the Korean Chemical Society
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    • 제28권11호
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    • pp.2025-2028
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    • 2007
  • Homogeneous zinc tetrahalide complexes, highly active catalysts for the coupling reactions of alkylene oxide and CO2 produce alkylene carbonates, were heterogenized due to their tendency to decompose produced alkylene carbonates during the distillation process. Heterogenization of homogeneous zinc tetrahalide complexes was achieved by polymerizing 1-alkyl-3-vinylimidazolium zinc tetrahalides. These polymerized zinc tetrahalide catalysts displayed similar activities to their corresponding monomeric analogues for the coupling reactions of carbon dioxide with ethylene oxide (EO) or propylene oxide (PO) to produce ethylene carbonate (EC) or propylene carbonate (PC). TGA studies showed that the polymer-supported zinc tetrahalide catalysts are thermally stable up to 320 oC. The catalyst recycle test showed that the supported catalysts could be reused over six times. After removal of the polymer-supported catalyst through a simple filtration, EC was able to be isolated without decomposition.