• 제목/요약/키워드: supported

검색결과 10,384건 처리시간 0.029초

Ethylene Polymerization Using (n-BuCp)$_{2}ZrCl_{2}$ Catalyst Activated with a Cross-linked MAO-Supported Cocatalyst

  • Yoon, Keun-Byoung
    • Macromolecular Research
    • /
    • 제12권4호
    • /
    • pp.336-341
    • /
    • 2004
  • A new type of cross-linked methylaluminoxane (MAO)-supported cocatalyst has been prepared by the reaction of a soluble MAO and a cross-liking agent such as an aromatic diamine compound. The cross-linked MAO-supported cocatalyst was used for the polymerization of ethylene in the presence of bis(n-butylcyclopentadienyl) zirconium dichloride, (n-BuCp)$_2$ZrCl$_2$. The catalyst activity of (n-BuCp)$_2$ZrCl$_2$ cocatalyzed with the new supported cocatalyst was higher than that of the commercial silica-supported MAO (SMAO) cocatalyst. The molecular weight and the bulk density of the polyethylene produced by using the new supported cocatalyst were slightly higher than those of polyethylene synthesized using commercial SMAO. The resulting polyethylene particles possess spherical morphologies with very few fine particles.

초기 변위를 가지고 연속 이동하는 스프링-질량계가 등분포종동력을 받는 단순지지보의 동특성에 미치는 영향 (Influence of Two Successively-moving Spring-mass Systems with Initial Displacement on Dynamic Behavior of a Simply-supported Beam Subjected to Uniformly Distributed Follower Forces)

  • 윤한익;강혁준;유진석
    • 한국소음진동공학회논문집
    • /
    • 제13권3호
    • /
    • pp.202-209
    • /
    • 2003
  • A simply supported beam subjected to a uniformly distributed tangential follower force and the two successively moving spring-mass systems upon it constitute this vibration system. The influences of the velocities of the moving spring-mass system, the distance between two successively moving spring-mass systems and the uniformly distributed tangential follower force have been studied on the dynamic behavior of a simply supported beam by numerical method. The uniformly distributed tangential follower force is considered within its critical value of a simply supported beam without two successively moving spring-mass systems, and three kinds of constant velocities and constant initial displacement of two successively moving spring-mass systems are also chosen. Their coupling effects on the transverse vibration of the simply supported beam are inspected too. In this study the simply supported beam is deflected with small vibration proportional to natural frequency of the moving spring-mass systems. According to the increasing of initial displacement of the moving spring-mass systems the amplitude of the small vibration of the simply supported beam is increased due to the spring force. The velocity of the moving spring-mass system more affect on the transverse deflection of simply supported beam than other factors of the system and the effect is dominant at high velocity of the moving spring-mass systems.

Attitude and treatment options in implant-supported prosthetics: A survey among a cohort of German dentists

  • Glucker, Carolin;Rauch, Angelika;Hahnel, Sebastian
    • The Journal of Advanced Prosthodontics
    • /
    • 제12권1호
    • /
    • pp.15-21
    • /
    • 2020
  • PURPOSE. The aim of the current study was to analyze treatment concepts of a cohort of German dentists for planning, fabrication, and maintenance of implant-supported fixed and removable restorations. MATERIALS AND METHODS. A questionnaire including queries about experiences with implant-supported restorations as well as prosthetic and maintenance treatment concepts for supplying patients with fixed and removable implant-supported prosthetic restorations was developed and sent to 350 dental offices registered in the municipal area of Leipzig, Germany. RESULTS. An overall total of 62 returned questionnaires were included in the analyses, which relates to a response rate of 17.7%. Participating dentists were more involved in the prosthetic aspects of implant dentistry rather than surgery, while prosthetic concepts such as backward planning, digital processing, and application of all-ceramic materials were not commonly performed. Simple attachments were preferred over complex retention systems in removable implant-supported restorations. Tooth/implant-supported fixed denture prostheses as well as removable denture prostheses with supporting posterior implants were not regarded as a favorable treatment option. CONCLUSION. Within the limitations of the study, the data indicate that dentists favor simple and conventional treatment approaches in implant prosthetics. Prosthetic aspects in the planning of implant-supported restorations are often neglected. Prosthetic treatment guidelines and aspects should commonly be considered in the planning phase of implant-supported prosthetic restorations, and awareness should be increased in postgraduate education.

단순지지 송수관의 동특성에 미치는 이동질량의 영향 (Influence of a Moving Mass on Dynamic Behavior of a Simply Supported Pipe Conveying Fluid)

  • 윤한익
    • 한국해양공학회지
    • /
    • 제15권2호
    • /
    • pp.135-140
    • /
    • 2001
  • A simply supported pipe conveying fluid and a moving mass upon it constitute a vibrational system. The equation of motion is derived by using Lagrange's equation. The influence of the velocity and the inertia force of a moving mass and the velocities of fluid flow in the pipe have been studied on the dynamic behavior of a simply supported pipe by numerical method. The velocities of fluid low are considered within its critical values of the simply supported pipe without a moving mass upon it. Their coupling effects on the transverse vibration of a simply supported pipe are inspected too. as the velocity of a moving mass increases, the deflection of midspan of a simply supported pipe conveying fluid is increased and the frequency of transverse vibration of the pipe is not varied. Increasing of the velocity of fluid flow makes the frequency of transverse vibration of the simply supported pipe conveying fluid decrease and the deflection of midspan of the pipe increase. The deflection of the simply supported pipe conveying fluid is increased by a coupling of the moving mass and the velocities of a moving mass and fluid flow.

  • PDF

평면트러스로 지지된 리프트 게이트의 진동특성 (Dynamic Characteristic of Lift Gate Supported by Plane Truss)

  • 이성행;양동운;함형길;공보성;신동욱
    • 한국농공학회논문집
    • /
    • 제54권3호
    • /
    • pp.133-139
    • /
    • 2012
  • Dynamic characteristic of lift gate supported by plane truss is studied by a model test scaled with the ratio of 1 : 31.25 in the four major rivers project. The vibrations of gate supported by the plane truss is assessed in comparison with those of gate supported by the space truss which was tested formerly. The gate model is made of acryl panel and calibrated by lead. A model test is conducted under the different gate opening and upstream water levels conditions in the concrete test flume dimensioned 1.6 m in width, 0.8 m in height and 24 m in length. In order to verify the model, natural frequencies of the model gate are measured, and compared with the numerical results. The vibrations of gate model supported by the plane truss in opening height of 1.0 cm~2.0 cm shows greater than one supported by the space truss. It is found that the gate model supported by the plane truss is less desirable than one supported by the space truss. thus, the latter type of gate model is requested to design.

조립식 버팀보로 지지된 흙막이 구조물의 거동 특성에 관한 연구 (Characteristics of Walls Supported by Prefabricated Strut)

  • 김낙경;박종식
    • 한국지반공학회:학술대회논문집
    • /
    • 한국지반공학회 2003년도 봄 학술발표회 논문집
    • /
    • pp.553-560
    • /
    • 2003
  • From the analytical standpoint, it is advantageous to consider the behavior of supported walls as plane strain condition. But supported walls constitute geotechnical problems which, in strut terms, are not plane strain cases. These represent differences between the measured and the predicted due to the stiffness and spacing of supported walls and the behavior of discontinuous walls such as solider beams with lagging. This study is to investigate simulations of a system behavior along a horizontal section of walls supported by prefabricated strut. Using a beam column method, relative effects associated with prefabricated strut stiffness and spacing in a systematic behavior were investigated.

  • PDF

Supported Iron Nanoparticles on Activated Carbon, Polyethylene and Silica for Nitrate Reduction

  • Cho, Mi-Sun;Kim, E-Wha;Lee, Kyoung-Hee;Ahn, Sam-Young
    • 한국환경과학회지
    • /
    • 제17권7호
    • /
    • pp.711-717
    • /
    • 2008
  • The use of support materials on the nanoparticle synthesis and applications has advantages in many aspects; resisting the aggregation and gelation of nanoparticles, providing more active sites by dispersing over the supports, and facilitating a filtering process. In order to elucidate the influence of the supports on the nitrate reduction reactivity, the supported iron nanoparticles were prepared by borohydride reduction of an aqueous iron salt in the presence of supports such as activated carbon, silica and polyethylene. The reactivity for nitrate reduction decreased in the order of unsupported Fe(0) > activated carbon(AC) supported Fe(0) > polyethylene(PE) supported Fe(0) ${\ge}$ silica supported Fe(0). Rate constants decrease with increasing initial nitrate concentration implying that the reaction is limited by the surface reaction kinetics.

촉매에 의해 안정화된 희박 예혼합기의 연소 (THE CATALYTICALLY SUPPORTED COMBUSTOR FOR LEAN MIXTURE)

  • 서용석;강성규;신현동
    • 한국연소학회:학술대회논문집
    • /
    • 한국연소학회 1998년도 제17회 KOSCI SYMPOSIUM 논문집
    • /
    • pp.59-67
    • /
    • 1998
  • The aim of this study is to investigate advantages that the catalytically supported combustor can have. For this purpose, the catalytic combustor was prepared which consisted of the catalyst bed and the thermal combustor at the downstream of the catalyst bed. The catalyst bed consisted of two-stage. Pd catalyst was installed in the first stage of the catalyst bed, and Pt catalyst was placed in the second stage. Results showed that the catalytically supported combustion had some advantages. One was that auto-ignition occurred in the thermal combustor. This can give merit that an igniter is not necessary to start flame ignition. Other was that the catalytically supported combustion was stable for lean mixture. When combustion of lean mixture was not supported by surface reaction it became unstable so that big combustion noise was created. Therefore, it is desirable to support flame by catalytic surface reaction to obtain the stable combustion of lean mixture.

  • PDF

담지된 납산화물 촉매상에서 메탄의 전환반응 (Methane Conversion over Supported Lead Oxide Catalysts)

  • 장종산;박상언
    • 대한화학회지
    • /
    • 제36권1호
    • /
    • pp.147-156
    • /
    • 1992
  • ${\alpha}-{\beta}-,{\gamma}$-알루미나 및 MgO를 담체로 사용하여 담지된 납산화물 촉매를 제조하였다. 담지된 납산화물 촉매상에서 메탄의 $C^{2+}$ 탄화수소로의 전환반응은 MgO 담지촉매에서 $C^{2+}$ 선택도가 최대로 얻어졌으며, ${\gamma}$-알루미나 담지 PbO 촉매에서는 $CO_2$ 선택도가 높았다. 그리고 ${\alpha}$-알루미나 담지촉매에서는 중간정도의 활성이 얻어졌으며, ${\beta}$-알루미나 담지촉매에서는 활성이 거의 나타나지 않았다. 이러한 반응특성은 촉매의 격자산소의 활성에 크게 의존하였으며, 또한 격자 산소의 활성은 담체와 산화물간의 상호작용과 담체의 성질에 영향받았다. 특히 MgO 담지 촉매에서는 X-선 회절분석에서 여타의 담체에서보다 PbO 산화물의 (002)면의 피크 세기가 (111)면의 세기에 비해 훨씬 크게 나타난 것으로 볼 때 메탄의 Oxidative Coupling 반응에서의 표면산화물-담체 상호작용(SOSI)의 한 예로 여겨졌다.

  • PDF

A retrospective comparison of clinical outcomes of implant restorations for posterior edentulous area: 3-unit bridge supported by 2 implants vs 3 splinted implant-supported crowns

  • Yi, Yuseung;Heo, Seong-Joo;Koak, Jai-Young;Kim, Seong-Kyun
    • The Journal of Advanced Prosthodontics
    • /
    • 제14권4호
    • /
    • pp.223-235
    • /
    • 2022
  • PURPOSE. To compare the clinical outcomes of two types of implant restoration for posterior edentulous area, 3-unit bridge supported by 2 implants and 3 implant-supported splinted crowns. MATERIALS AND METHODS. The data included 127 implant-supported fixed restorations in 85 patients: 37 restorations of 3-unit bridge supported by 2 implants (2-IB), 37 restorations of 3 implant-supported splinted crowns (3-IC), and 53 single restorations (S) as controls. Peri-implantitis and mechanical complications that occurred for 14 years were analyzed by multivariable Cox regression model. Kaplan-Meier curves and the multivariable Cox regression model were used to analyze the success and survival of implants. RESULTS. Peri-implantitis occurred in 28.4% of 2-IB group, 37.8% of 3-IC group, and 28.3% of S control group with no significant difference. According to the implant position, middle implants (P2) of the 3-IC group had the highest risk of peri-implantitis. The 3-IC group showed a lower mechanical complication rate (7.2%) than the 2-IB (16.2%) and S control group (20.8%). The cumulative success rate was 52.8% in S (control) group, 62.2% in 2-IB group, and 60.4% in 3-IC group. The cumulative survival rate was 98.1% in S (control) group, 98.6% in 2-IB group, and 95.5% in 3-IC group. There was no significant difference in the success and survival rate according to the restoration type. CONCLUSION. The restoration type was not associated with the success and survival of implants. The risk of mechanical complications was reduced in 3 implant-supported splinted crowns. However, the middle implants of the 3 implant-supported splinted crowns had a higher risk of peri-implantitis.