• Title/Summary/Keyword: superhydrophobicity

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Superhydrophobic nanostructured non-woven fabric using plasma modification

  • Shin, Bong-Su;Lee, Kwang-Reoul;Kim, Ho-Young;Moon, Myoung-Woon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.320-320
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    • 2011

  • We describe fabrication of superhydrophobic surface on non-woven fabric (NWF) having nano-hairy structures and a hydrophobic surface coating. Oxygen plasma was irradiated on NWF for nano-texuring and a precursor of HMDSO (Hexamethydisiloxane) was introduced as a surface chemical modification for obtaining superhydrophobicity using 13.56 MHz radio frequency-Plasma Enhanced Chemical Vapor Deposition (rf-PECVD). O2 plasma treatment time was varied from 1 min to 60 min at a bias voltage of 400V, which fabricated pillar-like structures with diameter of 30 nm and height of 150 nm on NWF. Subsequently, hydrophobic coating using hexamethyldisiloxane vapor was deposited with 10 nm thickness on NWF substrate at a bias voltage of 400 V. We evaluate superhydrophobicity of the modified NWF with sessile drop using goniometer and high speed camera, in which aspect ratio of nanohairy structures, contact angle and contact angle hysteresis of the surfaces were measured. With the increase of aspect ratio, the wetting angle increased from $103^{\circ}$ to $163^{\circ}$, and the contact angle hysteresis decreased dramatically below $5^{\circ}$. In addition, we had conducted experiment for nucleation and condensation of water via E-SEM. During increasing vapor pressure inside E-SEM from 3.7 Torr to over 6 Torr which is beyond saturation point at $2^{\circ}C$, we observed condensation of water droplet on the superhydropobic NWF. While the condensation of water on oxygen plasma treated NWF (superhydrophilic) occurred easily and rapidly, superhydrophobic NWF which was fabricated by oxygen and HMDSO was hardly wet even under supersaturation condition. From the result of wetting experiment and water condensation via E-SEM, it is confirmed that superhydrophobic NWF shows the grate water repellent abilities.

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Development of Laser Processing Technology and Life Evaluation Method for Lifespan Improvement of Titanium Superhydrophobic Surface (티타늄 초소수성 표면의 수명 향상을 위한 레이저 처리 기법 개발 및 내수명성 평가법 개발)

  • Kyungeun Jeong;Kyeongryeol Park;Yong Seok Choi;Seongmin Kang;Unseong Kim;Song Yi Jung;Kyungjun Lee
    • Tribology and Lubricants
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    • v.40 no.3
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    • pp.91-96
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    • 2024

  • Recently, extensive studies have been carried out to enhance various performance aspects such as the durability, lifespan, and hardness by combining diverse materials or developing novel materials. The utilization of superhydrophobic surfaces, particularly in the automotive, textile, and medical device industries, has gained momentum to achieve improved performance and efficiency. Superhydrophobicity refers to a surface state where the contact angle when water droplets fall is above 150°, while the contact angle during sliding motion is smaller than 10°. Superhydrophobic surfaces offer the advantage of water droplets not easily sliding off, maintaining a cleaner state as the droplets leave the surface. Surface modification involves two fundamental steps to achieve superhydrophobicity: surface roughness increase and surface energy reduction. However, existing methods, such as time-consuming processes and toxic organic precursors, still face challenges. In this study, we propose a method for superhydrophobic surface modification using lasers, aiming to create roughness in micro/nanostructures, ensuring durability while improving the production time and ease of fabrication. The mechanical durability of superhydrophobic samples treated with lasers is comparatively evaluated against chemical etching samples. The experimental results demonstrate superior mechanical durability through the laser treatment. Therefore, this research provides an effective and practical approach to superhydrophobic surface modification, highlighting the utility of laser treatment.

  • https://doi.org/10.9725/kts.2024.40.3.91 인용 PDF HTML

Underwater Stability of Surface Chemically Modified Superhydrophobic W18O49 Nanowire Arrays

  • Lee, Junghan;Yong, Kijung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.601-601
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    • 2013

  • Superhydrophobic W18O49 nanowire (NW) arrays were synthesizedusing a thermal evaporation and surface chemistry modification methods by self-assembled monolayer (SAM). As-prepared non-wetting W18O49 NWs surface shows water contact angle of $163.2^{\circ}$ and has reliable stability in underwater conditions. Hence the superhydrophobic W18O49 NWs surface exhibits silvery surface by total reflection of water layer and air interlayer. The stability analysus of underwater superhydrophobicity of W18O49 NWs arrays was conducted by changing hydrostatic pressure and surface energy of W18O49 NWs arrays. The stability of superhydrophobicity in underwater conditions decreased exponentially as hydrostatic pressure applied to the substrates increased3. In addition, as surface energy decreased, the underwater stability of superhydrophobic surface increased sharply. Specifically, sueprhydrophobic stability increased exponentially as surface energy of W18O49 NWs arrays was decreased. Based on these results, the models for explaining tendencies of superhydrophobic stability underwater resulting from hydrostatic pressure and surface energy were designed. The combination of fugacity and Laplace pressure explained this exponential decay of stability according to hydrostatic pressure and surface energy. This study on fabrication and modeling of underwater stability of superhydrophobic W18O49 NW arrays will help in designing highly stable superhydrophobic surfaces and broadening fields of superhydrophobic applications even submerged underwater.

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