• 제목/요약/키워드: super-solution

검색결과 233건 처리시간 0.025초

전기방사를 이용한 Al이 첨가된 ZnO 나노섬유의 제조 및 광학 특성평가 (Optical properties of Al doped ZnO Nanofibers Prepared by electrospinning)

  • 송찬근;윤종원
    • 한국결정성장학회지
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    • 제21권5호
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    • pp.205-209
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    • 2011
  • ZnO는 반도전성과 초전도성을 나타내며 광학적으로도 독특한 재료로 가스센서, 태양전지, 광학도파관 등 여러 방면에 널리 활용되고 있다. 본 논문에서는 이러한 ZnO에 Al을 첨가함에 따라 광학적 특성에 어떠한 영향을 미치는지 알아보기 위하여 ZnO에 Al 첨가량 변화에 따른 나노구조체를 제작하여 특성을 비교하였다. ZnO 용액은 PVP, ethanol, zinc acetate를 이용하여 Sol의 형태로 제작하였으며, Al첨가용액을 넣어 Al이 첨가된 ZnO Sol을 제작하였다. 제작된 Sol을 전기 방사법을 이용하여 나노구조체를 제조하였다. 제조된 섬유들을 각각 300, 500, $700^{\circ}C$로 열처리 한 후 나노 구조체를 XRD, XPS, SEM을 이용하여 분석하였다. 또한 TGA, DSC를 이용하여 온도변화에 따른 질량 및 열량의 변화를 측정하였다. UVvis를 이용하여 ZnO와 Al이 첨가된 ZnO의 흡광도를 측정 비교하였다.

Effects of Ethanol Addition on the Efficiency of Subcritical Water Extraction of Proteins and Amino Acids from Porcine Placenta

  • Park, Sung Hee;Kim, Jae-Hyeong;Min, Sang-Gi;Jo, Yeon-Ji;Chun, Ji-Yeon
    • 한국축산식품학회지
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    • 제35권2호
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    • pp.265-271
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    • 2015
  • In a previous study, hydrolysates of porcine placenta were obtained and the extraction efficiency for proteins and amino acids was compared between sub- and super-critical water extraction systems; optimum efficiency was found to be achieved using subcritical water ($170^{\circ}C$, 10 bar). In this study, the effects of adding ethanol to the subcritical water system were investigated. The lowest-molecular-weight extraction product detected weighed 434 Da, and the efficiency of extraction for low-molecular-weight products was increased when either the concentration of ethanol was decreased, or the extraction time was lengthened from 10 min to 30 min. The highest concentration of free amino acids (approximately 8 mM) was observed following 30 min extraction using pure distilled water. The concentration of free amino acids was significantly lower when ethanol was added or a shorter extraction time was used (p<0.05). Color change of the solution following extraction was measured. There were no significant differences in color between lysates produced with different extraction times when using distilled water (p>0.05); however, using different extraction times produced significant differences in color when using 20% or 50% ethanol solution for subcritical extraction (p<0.05). The range of pH for the hydrolysate solutions was 6.4-7.5. In conclusion, the investigated extraction system was successful in the extraction of $\leq$ 500 Da hydrolysates from porcine placenta, but addition of ethanol did not yield higher production of low-molecular-weight hydrolysates than that achieved by DW alone.

지상파 DMB 베트남 진출 사례를 통한 T-DMB 글로벌 확산 연구 (A Study on the Global Diffusion through a Case for the Expansion of the T-DMB into Vietnam)

  • 은종원;박성열;윤동승
    • 산업클러스터
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    • 제4권1호
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    • pp.1-13
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    • 2010
  • 디지털방송 기술과 통신 기술이 융합되어 탄생한 지상파 DMB는 CD 수준의 음질을 제공하고 시속 300Km 이상의 빠른 속도로 달리는 KTX와 같은 초고속 열차에서도 TV 수신이 가능하며, 다양한 방송통신 융합형 서비스를 휴대폰, PDA, 전용단말기 등을 통해 제공이 가능한 기술로 세계 속으로 확산되고 있다. 본 논문은 T-DMB 글로벌 확산에 필요한 비즈니스 모델을 정립하여 이를 베트남 시장 진출에 활용하였다. 본 논문은 베트남에 유료 T-DMB 서비스를 제공하기 위한 T-DMB 시스템 구축에 관한 사례를 기술한다. T-DMB 베트남 진출은 T-DMB 글로벌 확산에 크게 기여할 것으로 예견된다.

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연일층군 이암에서 산출되는 알루미늄 황산염 광물의 결정화학 및 생성 (I): 배사알루미나팅, 하이드로베사알루미나이트 및 메타배사알루미나이트 (Crystal Chemistry and Paragenesis of Aluminum Sulphates from Mudstones of the Yeonil Group (I): basaluminite, hydrbasaluminite, and metabasaluminite)

  • 노진환
    • 한국광물학회지
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    • 제11권1호
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    • pp.1-12
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    • 1998
  • In Pohang area, basaluminite accompanying a little amounts of hydrobasalumnite, super-genetically occurs as whitish cryptocrystalline (2-4 $\mu\textrm{m}$) clay-like aggregates in the vicinity of altered carbonate concretions embedded within mudstones of the Tertiary Yeonil Group. A hydrobasaluminite changed readily into a basaluminite at room temperature in air, and, in turn, into a metabasaluminite when heating to 150$^{\circ}$~30$0^{\circ}C$. For the basaluminite, a monoclinic unit-cellparameters (a=14.845$\AA$, b=10.006$\AA$, c=11.082$\AA$, $\beta$=122.15$^{\circ}$) were calculated by X-ray powder diffraction data. Its basal reflections (001 and 002) are XRD analyses strongly indicate that the aluminum sulphate mineral has a layer structure and, at least, three types of water, i.e., (1) interlayer water (9.0 wt %), (2) crystal water (8.0 wt %), and (3) structural water (19.0 wt %). may present in its lattice. Based on TG-DTG data combined with EDS and IR analyses, a new chemical formula of Al5SO4(OH)134H2O was given to the basaluminite. Field occurrence and stable isotope data ($\delta$18O, $\delta$D, $\delta$34S) for the basaluminite seem to reflect that it was formed by the leached meteoric solution from surrounding mudstones during or after uplifting. An interaction of the acid solution with carbonate concretion and the resultant local neutralization of the fluid rich in Al3+ and SO42- are major controls on the basaluminite formation.

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용탕단조된 Mg-6Al-xZn (x=1.5, 2.5) 합금(合金)의 미세조직 및 기계적 성질에 미치는 시효의 영향 (Effect of Aging Treatment on the Microstructure and Mechanical Properties of Mg-6Al-xZn (x : 1.5, 2.5) Alloys Fabricated by Squeeze Casting)

  • 김순호
    • 열처리공학회지
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    • 제12권1호
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    • pp.1-8
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    • 1999
  • This study has investigated the effect of aging treatment on the microstructure and mechanical properties of Mg-6Al-xZn(x = 1.5, 2.5) alloys fabricated by the squeeze casting process. The microstructures of as-squeeze cast were composed of pro-eutectic ${\alpha}$, super saturated ${\alpha}$ and ${\beta}(Mg_{17}Al_{12})$ compound. Aged at both $200^{\circ}C$ and $240^{\circ}C$, Mg-6Al-xZn alloys showed the peak hardness due to the formation of ${\beta}(Mg_{17}Al_{12})$ precipitates. The discontinuous precipitates of the lamella type are predominant at $200^{\circ}C$ aging treatment, while the finely dispersed continuous precipitates were dominant at $240^{\circ}C$ aging treatment. Mg-6Al-xZn alloys fabricated by the squeeze casting process had the better combination of tensile strength and elongation compared to the conventionally cast alloys. As zinc contents increased, the tensile strength was increased by the solid solution strengthening effect of zinc.

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HVDC 변환소의 여유요소(Spare)를 고려한 사고확률 분석에 관한 연구 (A Study on Outage Probability Analysis of HVDC Converter Considering Spare Elements)

  • 오웅진;최재석;김찬기;윤용범
    • 전기학회논문지
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    • 제67권11호
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    • pp.1408-1414
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    • 2018
  • Recently, as a solution to the problem of maintaining system reliability, stability, and quality occurring worldwide, such as activation of smart grid and recognition of super grid and rapid grid interconnection of renewable energy sources HVDC(High Voltage Direct Current) will appear on the front of the electric power system. These concepts are also very important concepts in HVDC systems. When the HVDC system is linked to the existing power system, it is composed of AC/DC/AC conversion device, and these conversion devices are composed of many thyristors. These parts(Devices) are connected in a complicated manner, and they belong to the one with a higher failure rate. However, the problem of establishing the concept of failure rate of HVDC parts directly linked to economic efficiency and the understanding accompanying it are still insufficient. Therefore, in this paper, we establish the meaning of reliability in power system and try to develop a model to analyze and verify the failure rate data of HVDC based on this.

Nucleation and Growth of Vacancy Agglomeration in CZ Silicon Crystals

  • Ogawa, Tomoya;Ma, Minya
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1999년도 PROCEEDINGS OF 99 INTERNATIONAL CONFERENCE OF THE KACG AND 6TH KOREA·JAPAN EMG SYMPOSIUM (ELECTRONIC MATERIALS GROWTH SYMPOSIUM), HANYANG UNIVERSITY, SEOUL, 06월 09일 JUNE 1999
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    • pp.45-49
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    • 1999
  • When concentration of vacancies in a CZ silicon crystal is defined by molar fraction XB, the degree of super-saturation $\sigma$ is given by [XB-XBS]/XBS=XB/XBS-1=ln (XB/XBS) because XB/XBS is nearly equal to unity. Here, XBS is the saturated concentration of vacancies in a silicon crystal and XB is a little larger than XBS. According to Bragg-Williams approximation, the chemical potential of the vacancies in the crystal is given by ${\mu}$B=${\mu}$0+RT ln XB+RT ln ${\gamma}$, where R is the gas constant, T is temperature, ${\mu}$0 is an ideal chemical potential of the vacancies and ${\gamma}$ is an adjustable parameter similar to the activity of solute in a solution. Thus, $\sigma$(T) is equal to (${\mu}$B-${\mu}$BS)/RT. Driving force of nucleation of the vacancy agglomeration will be proportional to the chemical potential difference (${\mu}$B-${\mu}$BS) or $\sigma$(T), while growth of the vacancy agglomeration is proportional to diffusion of the vacancies and grad ${\mu}$B.

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STELLAR POPULATIONS IN EXTERNAL GALAXIES

  • Whang, Yun-Oh;Lee, Sang-Gak
    • 천문학회지
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    • 제22권1호
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    • pp.1-24
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    • 1989
  • By applying population synthesis method, stellar populations in the nuclei of M31 and M32 are studied. We obtained five and four models for M31 and M32 respectively, for different main sequence turn-offs and keeping the astrophysical constraints as loose as possible. The best models for M31 and M32 are thought to have G0-5 and F5-8 main sequence trun-offs respectively. These models show that the main sequence stars outnumber the giants, which indicates the dwarf-dominance in external galactic nuclei. Even though there are some computational difficulties because of non-uniqueness in solution, two major points can be pointed out when compared to the previous papers. First, the ultraviolet deficiency expected from the conventional metal rich population models is not detected in our models, Instead ultraviolet radiation turns out to be somewhat higher than that of observation. Second one is the minor contribution from the Super Metal Rich (SMR) K giants to the integrated light of the program galaxies. That is, in our models, the SMR contribution is at best the same level as normal giants contrary to the SMR dominance of previous models. Since the loose astrophysical constraints are the major difference of our study from the previous ones, one should re-examine carefully for their validity further.

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ON THE ORIGIN OF THE HII REGIONS ASSOCIATED WITH MASSIVE AND COMPACT SUPERSTAR CLUSTERS

  • Silich, Sergiy;Tenorio-Tagle, Guillermo;Munoz-Tunon, Casiana
    • 천문학회지
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    • 제40권4호
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    • pp.187-188
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    • 2007
  • This contribution to the IV Korea-Mexico meeting deals with the hydrodynamics of the matter reinserted within super star clusters (SSCs) by both stellar winds and supernova explosions, results recently printed in The Astrophysical Journal (Silich et al. 2007). The motivation of such a project arose from the persistent presence of the small mass and compact HII regions that sit right on top of many massive and compact SSCs, from which one expects a large mechanical energy power. The data used for our calculations appear only recently (see Smith et al. 2006) for the massive and compact SSC M82-A1. We presented in our paper the calculated flow, derived through analytical and semi-analytical methods, which led to almost identical results. We have found out that the only way of accommodating a compact HII region (4.5 pc in radius, in the case of M82-A1) on top of a 6.3 Myr old and massive (> $10^6M_{\bigodot}$) SSC with a half light radius of 3 pc, requires of two assumptions: a very low heating efficiency (< 10%) within the cluster, what leads to a bimodal solution (see Tenorio-Tagle et al. 2007) and a high pressure in the surrounding medium.

Preliminary Study on the Visualization and Quantification of Elemental Compositions in Individual Microdroplets using Solidification and Synchrotron Radiation Techniques

  • Ma, Chang-Jin;Tohno, Susumu;Kasahara, Mikio
    • Asian Journal of Atmospheric Environment
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    • 제5권1호
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    • pp.56-63
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    • 2011
  • Quantifying the solute composition of a cloud droplet (or a whole droplet) is an important task for understanding formation processes and heating/cooling rates. In this study, a combination of droplet fixation and SR-XRF microprobe analysis was used to visualize and quantify elements in a micro-scale droplet. In this study, we report the preliminary outcome of this experiment. A spherical micro-scale droplet was successfully solidified through exposure to ${\alpha}$-cyano-acrylate vapor without affecting its size or shape. An X-ray microprobe system equipped at the beam line 37XU of Super Photon ring 8 GeV (SPring-8) was applied to visualize and quantify the elemental composition in an individual micro-scale droplet. It was possible to reconstruct 2D elemental maps for the K and Cl contained in a microdroplet that was dispensed from the 10-ppm KCl standard solution. Multi-elemental peaks corresponding to X-ray energy were also successfully resolved. Further experiments to determine quantitative measures of elemental mass in individual droplets and high-resolution X-ray microtomography (i.e., 3D elemental distribution) are planned for the future.