• Title/Summary/Keyword: super p black

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Dispersion and Enrichment of Potentially Toxic Elements in Chubu Area Covered with Black Shales and Slates in Korea (추부지역 흑색셰일 및 점판암 분포지역에서의 잠재적 독성원소들의 분산과 부화)

  • Kim, Jong Shin;Chon, Hyo Taek
    • Economic and Environmental Geology
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    • v.30 no.2
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    • pp.89-103
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    • 1997
  • The purpose of this research is to investigate the enrichment and distribution patterns of naturally occurring potentially toxic elements in soils derived from black shales and slates. Soil samples were collected from the Chubu area covered with uranium-enriched black shales and slates of the Changri Formation of the Okchon Super Group, and analysed for multiple-elements using INAA, ICP-AES and AAS. Soil pH and loss-an-ignition were also measured. Trace element contents in black shale and slate of the Chubu area are relatively lower than those in black shales, and higher than those in black slates reported elsewhere (Chon, Jung, 1991; Chon et al., 1996). Soil pH values range from 3.5 to 6.5, and loss-an-ignition values are in the range from 3 to 10%. Potentially toxic elements including As, Ba, Cr, Cu, Mo and U are highly enriched in residual soils with maximum content of $540{\mu}g/g$, $35,000{\mu}g/g$, $280{\mu}g/g$, $300{\mu}g/g$, $240{\mu}g/g$ and $860{\mu}g/g$, respectively. Significant concentrations of those elements were found in soils taken from the Tojangkol, the Chubu tunnel and the Meokti areas. Soils derived from black shales and slates, calcareous and phyllitic rocks, and intrusions were discriminated in terms of As, Ba, Co, Cr, Cu, Mo, Sc and U contents. Enrichment index was calculated using the concentrations of As, Ba, Cr and Mo, and enrichment index map shows very similar trend with U distribution in soils.

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Enhanced Performance of Li Metal Negative Electrode using Protection Film by Carbon Black and Polymeric Binder (카본블랙과 고분자 바인더로 구성된 보호필름을 통한 리튬금속 음극의 성능개선)

  • Noh, Seong Ho;Ryu, Da Young;Jang, Young Seok;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.25 no.1
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    • pp.42-49
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    • 2022
  • In this study, the surface protection film based on organic-inorganic composite is manufactured for suppressing lithium dendrite growth, and the film is applied on the surface of Li metal negative electrode for lithium metal batteries (LMBs). The film is consist of the polyvinylidene fluoride (PVDF) polymeric binder which has good mechanical strength and high electrochemical stability, and carbon black (Super-P) which has outstanding electrical conductivity as the inorganic compound. First, in order to confirm the suppression of the internal short circuit by the lithium dendrite, the time required for the short circuit is measured while a constant current is continuously applied. As a result, the internal short circuit is delayed in proportion to the carbon black content of the film, and it is significantly delayed than bare Li metal electrode which does not use protection film. The cycle performance of the thick protection film (8 ㎛), is worse than that of the thin film (4 ㎛). However, as the carbon black content of the film increased, the cycle performance is improved. Thus, the surface protection film based on carbon black/PVDF composite can delay the internal short circuit, and has low overvoltage during the cycle. However, more stable cycle performance needs to be built through further improvements.

Electrochemical Performances of Lithium-air Cell with Carbon Materials

  • Park, C.K.;Park, S.B.;Lee, S.Y.;Lee, H.;Jang, H.;Cho, W.I.
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3221-3224
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    • 2010
  • This study investigates the requirements of lithium-air cathodes, which directly influence discharge capacity. The cathodes of Li-air cell are made by using five different carbon materials, such as Ketjen black EC600JD, Super P, Ketjen black EC300JD, Denka black, and Ensaco 250G. The Ketjen black EC600JD provides discharge capacity of 2600 mAh/g per carbon weight, while that of Ensaco 250G shows only 579 mAh/g. To figure out the differences of discharge capacity from carbon materials, their surface area and pore volume are analyzed. These are found out to be the critical factors in determining discharge capacity. Furthermore, carbon loading on Ni foam and amounts of electrolyte are significant factors that affect discharge capacity. In order to investigate catalyst effect, electrolytic manganese dioxide (EMD) is incorporated and delivered 4307 mAh/g per carbon weight. This infers that EMD facilitates to break $O_2$ interactions and leads to enhance discharge capacity.

Mixed Carbon/Polypyrrole Electrodes Doped with 2-Naphthalenesulfonic Acid for Supercapacitor (2-Naphthalenesulfonic Acid로 도핑된 혼합카본/폴리피롤을 이용한 Supercapacitor용 전극)

  • Jang, In-Young;Kang, An-Soo
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.425-431
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    • 2005
  • New type of supercapacitor using high surface area activated carbons mixed with high conductivity polypyrrole (Ppy) has been prepared in order to achieve low impedance and high energy density. Mixed carbons of BP-20 and MSP-20 were used as the active electrode material, and polypyrrole doped with 2-naphthalenesulfonic acid (2-NSA) and carbon black (Super P) as conducting agents were added to activated carbons in order to enhance good electric conductivity. Electrodes prepared with the activated electrode materials and the conducting agents were added to a solution of organic binder [P(VdF-co-HFP) / NMP]. The ratio of optimum electrode composition was 78 : 17 : 5 wt.% of (MSP20 : BP-20=1 : 1), (Super P : Ppy=10 : 7) and P(VdF-co-HFP) respectively. The performance of unit cell with addition of 7 wt% Ppy have shown specific capacitance of 28.02 F/g, DC-ESR of $1.34{\Omega}$, AC-ESR of $0.36{\Omega}$, specific energy of 19.87 Wh/kg and specific power of 9.77 kW/kg. With addition of Ppy, quick charge-discharge of unit cell was possible because of low ESR, low charge transfer resistance and quick reaction rate. And good stability up to 500 chargedischarge cycles were retained about 80% of their original capacity. It was concluded that the specific capacitance originated highly from compound phenomena of the pseudocapacitance by oxidation-reduction of polypyrrole and the nonfaradaic capacitance by adsorption-desorption of activated carbons.

A Study on the Synthesis of polyaniline and Characteristics of Polyaniline Battery (Polyaniline의 합성 및 Polyaniline전지의 특성연구)

  • Moon, S.I.;Kim, I.S.;Ahn, M.S.;Kang, D.P.;Hyung, Y.E.;Park, H.Y.;Son, M.W.;Yun, M.S.
    • Proceedings of the KIEE Conference
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    • 1989.07a
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    • pp.284-286
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    • 1989
  • This paper describes the synthesis method of polyaniline and the characteristics of polyaniline/Zn and polyaniline/Li secondary batteries. Polyaniline was synthesized chemical or electrochemical method and then used as cathod active materials to investigate the characteristics of polyaniline/Zn and polyaniline/Li secondary batteries. Characteristics of polyaniline/Zn battery was affected by additives such as graphite powder and carbon black. Internal resistance, energy density and energy efficiency of polyaniline/Li secondary battery were $167{\Omega}$, 140.7 Wh/kg and 95.6%, respectively.

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Study on Biochemical Constituents of Caprine Ovarian Follicular Fluid after Superovulation

  • Mishra, O.P.;Pandey, J.N.;Gawande, P.G.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.12
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    • pp.1711-1715
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    • 2003
  • The experiment was designed on 42 non pregnant Black Bengal goat. Out of which 18 were subjected to a superovulatory treatment comprising of eCG and hCG for embryo transfer study. The remaining 24 goats received no treatment and served as control for parameter studied as well as recipient for embryo transfer studies. Important biochemical constituents such as acid and alkaline phosphatase, total protein and cholesterol and inorganic phosphorus were estimated in the follicular fluid of control and treated group and the values were separately recorded for small medium and large size follicle. The results indicated a significant effect on acid phosphotase activity due to size of follicle. The value increased progressively from small to medium and from medium to large follicles. Alkaline phosphotase activity showed reverse trend. Alkaline phosphotase decreased progressively as size increased. The concentration of inorganic phosphorus did not reveal any significant difference between the control and treatment groups and also between the different size follicles. The concentration of protein decreased significantly from small to medium and from medium to large, although no difference was observed between the control and treatment groups. The concentration of Cholesterol in the follicular fluid indicated a significant increase from small to medium and to large follicle. Here also no difference was observed due to treatment. Similar in the composition of follicular fluid in the respect of above mentioned constituents indicated no of super ovulatory treatment on follicular fluid composition.

Industry safety characteristic of Prismatic EDLCs (각형 전기이중층 커패시터의 산업 안전성)

  • 김경민;장인영;강안수
    • Proceedings of the Safety Management and Science Conference
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    • 2004.05a
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    • pp.247-257
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    • 2004
  • Electrodes were fabricated based on activated carbon powder BP-20, conducting agent such as Super P, vapor grown carbon fiber (VGCF) and acetylene black (AB), and the mixed binders of flexible poly(vinylidenefluoridehexafluoropropylene) [P(VdF-co-HFP)] and cross linking dispersion agent of polyvinylpyrrolidone (PVP) to increase mechanical strength. According to impedance measurement of the electrode with the addition of conducting agent, we found that it was possible to charge rapidly by the fast steady-state current convergence due to low equivalent series resistance (AC-ESR, fast charge transfer rate at interface between electrode and electrolyte and low RC time constant. The self-discharge of unit cell showed that diffusion process was controlled by the ion concentration difference of initial electrolyte due to the characteristics of Electric Double Layer Capacitor (EDLC) charged by ion adsorption in the beginning, but this by current leakage through the double-layer at the electrode/electrolyte interface had a minor effect and voltages of curves were remained constant regardless of electrode material. We found that the 2.3V/230F grade EDLC would be applied to industrial safety usage such as uninterrupted power supply (UPS) because of the constant DC-ESR by IR drop regardless of discharge current.

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Optimum Plant Populations of a Super Sweet Corn Hybrid at Different Planting Dates (초당옥수수의 파종기별 적정 재식밀도)

  • Lee, Suk-Soon;Yang, Seung-Kyu;Hong, Seung-Beom
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.52 no.3
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    • pp.334-340
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    • 2007
  • A super sweet corn hybrid, "Cambella 90", was grown at 5 plant populations (35,000, 45,000, 55,000, 65,000, 75,000 plants/ha) on 1 April, 1 May, and 1 June in 2004 under black polyethylene (P. E.) film mulch to find out the optimum plant populations at different planting dates. Emergence rate and percent stand increased as planting dates delayed. Culm length and ear height were highest at the planting on 1 May and increased with increased plant population. Soluble solids content was highest at the planting on 1 May and decreased as plant population increased. Ear length, seed set ear length, ear diameter, and ear weight decreased as plant population increased. Seed set ear length could not substitute for ear weight to evaluate marketable ears. The optimum plant population of "Cambella 90" was $65,000{\sim}75,000$ plants/ha at the planting on 1 April when emergence rate was low due to low temperature, $55,000{\sim}65,000$ plants/ha at the planting on 1 May, and 65,000 plants/ ha after the planting on 1 June.

Study on the Magnetic Shield Effect of Carbon-based Materials at Extremely Low Frequency (탄소계 소재를 이용한 극저주파 영역에서의 자기 차폐효과 연구)

  • Oh, Seong Moon;Kang, Dong Su;Lee, Sang Min;Baek, Un Gyeong;Roh, Jae Seung
    • KEPCO Journal on Electric Power and Energy
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    • v.1 no.1
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    • pp.15-20
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    • 2015
  • To examine the magnetic shielding effect for carbon-based materials at extremely low frequencies (60 Hz), two types of carbon black (Super-P and Denka Black) and a natural graphite (HC-198) were mixed into organic binder at 10 wt.% to produce a coating solution, and a powder coating with varying thickness was applied on an aluminum disk measuring 88 mm in radius. A device was developed to measure the sheielding effect at extremely low frequencies. A closed circuit was achieved by connecting a transformer and a resistor. The applied voltage was fixed at 65 V, and the magnetic field was measured to being the range of 4.95~5.10 mG. Depending on the thickness of the coating layer, the magnetic field showed a decreasing trend. The maximum decrease in the magnetic field of 38.3% was measured when natural graphite was coated with specimens averaging $455{\mu}m$. This study confirmed that carbon-based materials enable magnetic shielding at extremely low frequencies, and that the magnetic shielding effect can be enhanced by varying the coating thickness.

Development of OCB mode with impulsive driving scheme for improving moving picture quality

  • Kim, J.L.;Lee, C.H.;Park, S.Y.;Yoo, S.W.;Oh, J.H.;Lee, S.H.;Chai, C.C.;Park, C.W.;Ban, B.S.;Ahn, S.H.;Hong, M.P.;Chung, K.H.;Lim, S.K.;Kim, K.H.;Souk, J.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1049-1052
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    • 2004
  • In general, contrary to the CRTs with impulsive emission, liquid crystal displays have motion artifacts such as blurring. ghost image, decrease of dynamic CR(contrast ratio), and stroboscopic motion due to hold type driving method. In this paper, to improve motion picture quality of LCDs. impulsive driving method of black data insertion was applied to the OCB mode which is well known for its fast LC response time and wide viewing angle properties. Subject evaluation was carried out with CRT, TN, SIPS(Super IPS). and impulsive driving OCB. Moving picture image quality near CRT was obtained in impulsive OCB driving mode

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