• 한국분말재료학회지
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• 제17권1호
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• pp.36-43
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• 2010

In present work, amorphous TiCuNi powders were fabricated by mechanical alloying process. Amorphization and crystallization behaviors of the TiCuNi powders during high-energy ball milling and subsequent microstructure changes were studied by X-ray diffraction and transmission electron microscope. TEM samples were prepared by the focused ion beam technique. The morphology of powders prepared with different milling times was observed by field-emission scanning electron microscope and optical microscope. The powders developed a fine, layered, homogeneous structure with milling times. The crystallization behavior showed that glass transition, $T_g$, onset crystallization, $T_x$, and super cooled liquid range ${\Delta}T=T_x-T_g$ were 628, 755 and 127K, respectively. The as-prepared amorphous TiCuNi powders were consolidated by spark plasma sintering process. Full densified TiCuNi samples were successfully produced by the spark plasma sintering process. Crystallization of the MA powders happened during sintering at 733K.

• 한국분말재료학회지
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• 제16권1호
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• pp.9-15
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• 2009

Amorphization and crystallization behaviors of $Ti_{50}Cu_{50}Ni_{20}Al_{10}$ powders during high-energy ball milling and subsequent heat treatment were studied. Full amorphization obtained after milling for 30 h was confirmed by X-ray diffraction and transmission electron microscope. The morphology of powders prepared using different milling times was observed by field-emission scanning electron microscope. The powders developed a fine, layered, homogeneous structure with prolonged milling. The crystallization behavior showed that the glass transition, $T_g$, onset crystallization, $T_x$, and super cooled liquid range ${\Delta}T=T_x-T_g$ were 691,771 and 80 K, respectively. The isothermal transformation kinetics was analyzed by the John-Mehn-Avrami equation. The Avrami exponent was close to 2.5, which corresponds to the transformation process with a diffusion-controlled type at nearly constant nucleation rate. The activation energy of crystallization for the alloy in the isothermal annealing process calculated using an Arrhenius plot was 345 kJ/mol.

• 콘크리트학회논문집
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• 제12권2호
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• pp.99-107
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• 2000

This research investigates experimentally an effect on the properties of the high flowing concrete to be poured in the under-ground slurry wall of Inchon LNG receiving terminal(#213,214-TK) according to variations of concrete materials. Variables for sensitivity test were selected items as followings. 1) Concrete temperature (3cases), 2) Unit water (5cases), 3) Fineness modulus of fine aggregate (5cases), 4) Particle size of lime stone powder (3cases), 5) Replacement ratio of blast-furnace slag (4cases) and 6) Addition ratio of high range water reducing agent (5cases). And fresh conditions of the super flowing concrete should be satisfied with required range including slump flow(65$\pm$5cm), 50cm reaching time of flow(4~10sec), V-lot flowing time(10~ 20sec), U-box height(min. 300mm) and air content(4$\pm$1%). As results for sensitivity test, considered flow-ability, self-compaction and segregation resistance of the high flowing concrete, material variations and conditions of fresh concrete should be satisfied with the range as follwings. 1) Concrete temperature are 10~2$0^{\circ}C$(below 3$0^{\circ}C$), 2) Surface moisture of fine aggregate is within $\pm$ 0.6%, 3) Fineness modulus of fine aggregate is 2.6$\pm$0.2, 4)Replacement ratio of blast-furnace slag is 45~50% and 5) Addition ratio of high range water reducing agent is within 1%. Based on the specification for quality control, we successfully finished concrete pouring on the under-ground slurry wall having 75,000㎥(#213,214-TK) and accumulated real date in site.

• 한국재료학회지
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• 제16권2호
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• pp.137-143
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• 2006

The effects of Cu and Fe additions on the thermal stability, microstructure and mechanical properties of $Al_{85}-Ni_{8.5}-Mm_{6.5},\;Al_{84}-Ni_{8.5}-Mm_{6.5}Cu_1,\;Al_{84}-Ni_{8.5}-M_{m6.5}Fe_1$ alloys, manufactured by gas atomization, degassing and hot-extrusion were investigated. Gas atomization, with a wide super-cooled liquid region, allowed the alloy powders to exhibit varying microstructure depending primarily on the powder size and composition. Al hotextruded alloys consisted of homogeneously-distributed fine-grained fcc-Al matrix and intermetallic compounds. A substitution of 1 at.% Al by Cu increased the thermal stability of the amorphous phase and produced alloy microstructure with smaller fcc-Al grains. On the other hand, the same substitution of 1 at.% Al by Fe decreased the stability of the amorphous phase and produced larger fcc-Al grains. The formation of intermetallic compounds such as $Al_3Ni,\;Al_{11}Ce_3\;and\;Al_{11}La_3$ was suppressed by the addition of Cu or Fe. Among the three alloys examined, the highest Vickers hardness and compressive strength were obtained for $Al_{84}-Ni_{8.5}-M_{m6.5}Cu_1$ alloy, and related to the finest fcc-Al grain size attained from increased thermal stability with Cu addition.

• 공업화학
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• 제16권5호
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• pp.648-652
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• 2005

대기압하에서 소결이 어렵다고 알려진 초이온 전도체인 $K^+$-beta-aluminas를 attrition mill을 이용하여 약 350 nm의 평균 입도를 가지는 분말로 분쇄한 후, 시편을 일축가압 성형하여 상압 하에서 동일조성의 분위기 분말을 이용하여 소결하였다. 소결온도는 $1400^{\circ}C{\sim}1650^{\circ}C$까지 $50^{\circ}C$ 간격으로 소결하였으며, 각 소결온도에서 시간에 따른 소결특성을 살펴보았다. 또한 고온에서 입자 성장 속도를 조절하기 위하여 $1600^{\circ}C$에서 zone sintering을 실시하였다. $1600^{\circ}C$와 $1650^{\circ}C$에서 소결한 경우와 $1600^{\circ}C$에서 zone sintering한 시편의 경우, 각각 약 93%와 95%의 소결 밀도를 나타내었다. $1600^{\circ}C$ 이상의 온도에서 2 h 이상 장시간 소결할 경우, 입자의 거대성장으로 인하여 소결밀도가 90% 미만으로 감소하였다.

• 한국자동차공학회논문집
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• 제22권5호
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• pp.20-28
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• 2014

The high velocity oxygen fuel spraying (HVOF) is a kind of surface modification process technology to form the sprayed coating layer after spraying the powder to molten or semi-molten state by the ultra-high speed at the high-temperature heat source and conflicting with a substrate. It is desirable to melt completely the thermal spray powder in order to produce the coating layer with an optimal adhesion, however, because a semi-molten powder in a spray process has the low efficiency and become a factor that degrades the mechanical property by the inducement of pore-forming within the coating layer. To improve the wear resistance, corrosion resistance and heat resistance, in this study, the plungers of high-speed and ultra-high pressure reciprocating hydraulic pumps for oil and water used in ironwork are produced with $420J_2$ and the coating layers of plungers are formed by the powders of WC-Co-Cr and WC-Cr-Ni including the high hardness WC. The surface of these plungers is modified by the super-mirror face grinding machine using variable air pressure developed in this laboratory, and then the characteristics of cross-sectional microstructure, and surface roughness and hardness values between no operation and 100 days-operation are examined and made a comparison. The fine tops and bottoms on surface roughness curve of oil-hydraulic pump plunger sprayed by WC-Cr-Ni are molded more and higher than those of water-hydraulic pump sprayed by WC-Co-Cr because the plunger diameter of oil-hydraulic pump is 0.4 times smaller than that of water-hydraulic pump and the pressure of oil-hydraulic pump exerted on the plunger is operated with the 70 bars higher than that of water-hydraulic pump. As a result, it is found that the values of centerline average surface roughness and maximum height for oil-hydraulic pump plunger are bigger than those of water-hydraulic pump plunger.

• 한국건설순환자원학회논문집
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• 제10권1호
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• pp.111-116
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• 2022

최근 들어 건축구조물은 초고층화 및 대규모화 하는 경향에 있으며, 콘크리트 기술의 발달로 인하여 철근콘크리트 구조로 초고층 건축물을 축조하는 것이 일반화 되어 가고 있는 실정이다. 초고층 건축물에 적용되는 철근콘크리트주조는 고유동·고강도 콘크리트가 적용되기 때문에 시공성이 향상되고 단면축소가 가능하게 되었다. 또한 철근콘크리트구조의 초고층 건축물에는 슬라이딩폼, ACS(Auto Climbing Form) 등 시스템 거푸집을 적용하기 때문에 시공의 신속성을 기할 수 있으며, 철골구조보다 저렴한 가격에 내화·내진 등 우수한 품질로 빠른 시일 내에 완성할 수 있게 되었다. 그러나 초고층 건축물을 철근콘크리트 구조로 시공할 경우는 자중이 커지게 된다는 단점을 가지게 된다. 이러한 단점을 보완하고자 개발된 것이 경량골재(LWA, Low Weight Aggregate)이며, 최근까지 다양한 종류의 경량골재가 개발되어지고 있다. 이러한 경량골재를 이용하여 콘크리트를 제조하면 철근콘크리트 구조물의 자중을 줄일 수 있다는 장점을 가지게 되지만, 콘크리트의 강도가 줄어든다는 단점을 가진다. 이는 경량골재가 일반적인 천연골재에 비하여 낮은 강도를 가지고 있기 때문으로 최근에는 이러한 경량골재의 취약점을 보완하기 위한 연구가 진행되고 있다. 본 연구에서는 경량골재 표면코팅 유무에 따른 시멘트 경화체의 강도특성을 알아보기 위한 실험적 연구를 진행하였다. 그 결과, 압축강도는 표면코팅 한 경량골재가 코팅하지 않은 경량골재보다 높은 강도발현을 나타냈으며, 물/시멘트 비 50 %에서 표면코팅 경량골재가 높은 압축강도를 발현하는 것을 알 수 있었다. 이는 표면코팅 경량골재 혼입 시멘트 경화체의 계면 공극이 고로슬래그 미분말 입자로 메워졌기 때문인 것으로 확인되었다.