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Synthesis and Optical Property of Au/Cu, Au/Ag Alloy Nanocluster (Au/Cu, Au/Ag 합금 나노 미립자의 합성과 광학적 성질)

  • Na Hye Jin Na;Kyoung Chul Lee;Eun Ah Yoo;Kang Sup Chung
    • Journal of the Korean Chemical Society
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    • v.47 no.4
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    • pp.315-324
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    • 2003
  • In this study, a new method is presented to produce stable hydrophobic metal alloy nanocluster in chloroform solution including surfactant NaAOT(sodium bis(2-ethylhexyl)-sulfosuccinate) via the chemical reduction of metal salt $(HAuCl_4,\AgNO_3,\Cu(NO_3)_2)$ by sodium borohydride. For the alloy nanocluster, several samples were prepared by changing the molar ratio of Au/Cu, Au/Ag alloy nanocluster, 3:1, 1:1, 1:3. The alloy nanoclusters were characterized by UV-Visible spectrophotometer, TEM(Transmission Electron Microscope), and XPS(X-ray Photoelectron Spectrometer). With the change of the mole ratio of the alloy component, the wavelengths of the surface plasmon absorption shift linearly from 520 nm of the pure Au nanocluster to 570 nm of the pure Cu nanocluster for Au/Cu alloy nanoclusters and from 405 nm to 520 nm for Au/Ag alloy nanoclusters. The chemical shifts of the Au4f, Ag3d, Cu2p XPS peaks were observed with changing the molar ratio of the alloy element. The alloy nanoclusters in chloroform solution were made uniformly in size and colloidally stable for long periods of time. These results indicate that the method here is a very effective method for synthesizing hydrophobic alloy nanoclusters with uniform or nearly uniform particle size distribution.

Design of the Wideband Notched Compact UWB Antenna (넓은 대역폭이 소거된 소형 UWB 안테나 설계)

  • Kim, Cheol-Bok;Lim, Jung-Sup;Lee, Ho-Sang;Jang, Jae-Sam;Jung, Young-Ho;Jo, Dong-Ki;Lee, Mun-Soo
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.44 no.9
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    • pp.54-62
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    • 2007
  • In this paper, a novel wideband notched compact UWB antenna is designed to satisfy the licensed UWB frequency bandwidth($3.1{\sim}4.8$ GHz, $7.1{\sim}10.2$ GHz) by symmetrically arranging two adjacent sectorial loop antennas. The wideband($4.8{\sim}7.1$ GHz) notch can be obtained by inserting the inverted-L shaped slits on the patch. The designed UWB antenna has return loss lower than -10dB at 3.1 GHz and over, group delay value lower than 1 ns and the linear phase property. The optimized UWB antenna inserted the inverted-L shaped slits has return loss great than -10dB, 5 ns of group delay, nonlinear phase and decreased gain properties over the frequency band, 4.8 GHz to 7.1 GHz.

The Development of Iodine-123 with MC-50 Cyclotron (MC-50 싸이클로트론을 이용한 $^{123}I$ 제법 연구)

  • Suh, Yong-Sup;Yang, Seung-Tae;Chun, Kown-Soo;Lee, Jong-Doo;Han, Hyon-Soo
    • The Korean Journal of Nuclear Medicine
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    • v.25 no.2
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    • pp.286-293
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    • 1991
  • $^{123}I$, which is applied for the thyroid and other in vivo kinetic study, has a special role in life sciences. The 159 KeV $\gamma-ray$ from $^{123}I$ is almost ideally appropriate for the current imaging instrumentation. Its decay mode (electron capture) and short half-life (13.3 hr) reduced the burden of radiation dose to the patients, and its chemical property makes it easy to synthesize the labelling compounds. In this experiment, the production of $^{123}I$ via the nuclear reaction $^{124}Te(p,2n)^{123}I$ with 28 MeV protons was sutdied. $TeO_2$ is used as a target material, because it has good physical properties. The target was prepared with $TeO_2$ powder and was molten into a ellipsoidal cavity (a=14 mm, b=10 mm, $270.8mg/cm^2$ thick) of pure platinum. The irradiation was carried out in the external proton beam with incident energies range from 28 MeV to 22 MeV, and current was $30{\mu}A$. The loss of $TeO_2$ target was significantly reduced by using $4\pi-cooling$ system in irradiation. The dry distillation method was adopted for the separation of $^{123}I$ from irradiated target, and when it was kept 5 minutes at $780^{\circ}C$, its result was quantitative. The loss of the target material $(TeO_2)$ was below 0.2% for each production run and $^{123}I$ from the dry distillation apparatus was captured with 0.01 N NaOH in $Na^{123}I$ form, then the pH of the solution was adjusted to $7.5\sim9.0$ with HC1/NaOH. The $Na^{123}I$ solution was passed through $0.2{\mu}m$ membrane filter, and sterilized under high pressure and temperature for 30 minutes. The production of $^{123}I$ is acceptable for clinical application based on the quality of USP XXI.

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Evaluate the Suitability of MC3T3 Cells to Antibacterial Ag-30CaO·70SiO2 Gel (항균성 Ag-30CaO·70SiO2 Gel의 MC3T3 세포적합성에 관한 연구)

  • Yoon, Geum-Jae;Ryu, Jae-Kyung;An, Eung-Mo;Kim, Yun-Jong;Kim, Taik-Nam;Noh, In-Sup;Cho, Sung-Beck
    • Korean Journal of Materials Research
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    • v.24 no.12
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    • pp.671-676
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    • 2014
  • It is known that bones get damaged by accidents and aging. Since the discovery of Bioglass, various kinds of ceramics have been also found to bond to living bone; some of these ceramics are already being clinically used as bone-repairing materials. In the present study, antibacterial calcium silicate gel ($Ag-30CaO{\cdot}70SiO_2$ gel) was prepared by sol-gel method in order to control the microstructure, which is related to the dissolution rate and induction period of apatite formation in body environment. In addition, biological $Ag-30CaO{\cdot}70SiO_2$ is tested. This was done to impart antimicrobial activity to the $30CaO{\cdot}70SiO_2$. Ag ion was added during sol-gel synthesis to replace the $H_2O$ added during the making of the $30CaO{\cdot}70SiO_2$ gel, which has silver solutions of various concentration. After the sol-gel process, 1N-$HNO_3$ solution was used to wash the gel when synthesizing the gel, in order to maintain the porous structure and remove PEG, water soluble polymers. Then, the apatite forming ability of the sol-gel derived CaO-$SiO_2$ gels was investigated using simulated body fluid (SBF), which had almost the same ion concentration as that of human blood plasma. The gels were analyzed by FT-IR spectroscopy, SEM observation, XRD, and fluorescent microscopy. The apatite was successfully created even after washing the gel; apatite is present in an amorphous state, and was found to affect the concentration of the Ag ion in cells in MC3T3 live & dead assay results. From these results, it is suggested that a good material that can be used to repair defects of nature bone is $Ag-30CaO{\cdot}70SiO_2$ gel.

Strength Properties of Concrete According to Types of High Early Strength Cement and Curing Method (조강형 시멘트의 종류 및 양생방법에 따른 콘크리트의 강도특성)

  • Chang, Chun-Ho;Lee, Wang-Sup;Jung, Yong-Wook;Chung, Youn-In
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.76-84
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    • 2017
  • This study selected a method which uses high early strength cement as a way to reduce the curing time and curing energy source of concrete secondary products and reviewed the improvement in the initial strength of concrete secondary products setting the target strength of the concrete capable of removing the form to 15MPa and the curing time to 6 hours. As a result of the test, the only specimen which achieved the form removal strength of 15 MPa only through atmospheric curing within the target curing time of 6hours was ACC-100, and the specimens of TRC-100 and TRC-50 satisfied the values of 6 hours and 15MPa through steam curing. However, we could see that it was difficult to secure workability in the case of the specimen of ACC-100 due to its high rapid setting property and a retarder such as anhydrous citric acid was required to be used to improve the workability. When we look into the pattern following changes in the water to binder ratio, while, in the case of stream curing, OPC-100, TRC-100, and TRC-50 were all found to satisfy achievement of the form removal strength within 6hours as the water to binder ratio decreased, in the case of atmospheric curing, TRC-100, and TRC-50 achieved 15MPa within 12hours.

Seismic Fragility Evaluation of Cabinet Panel by Nonlinear Time History Analysis (비선형시간이력해석을 이용한 수배전반의 지진취약도 도출)

  • Moon, Jong-Yoon;Kwon, Min-ho;Kim, Jin-Sup;Lim, Jeong-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.2
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    • pp.50-55
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    • 2018
  • Earthquakes are almost impossible to predict and take place in a short time. In addition, there is little time to take aggressive action when an earthquake occurs. Therefore, there are more casualties and property damage than with other natural disasters. Recently, earthquakes have been occurring all over the world. As the number of earthquakes increase, studies on the safety of structures are being carried out. On the other hand, there are few studies on the electric facilities, which are relatively non - structural factors. Currently, electrical equipment in Korea is often not designed for earthquake safety and is quite vulnerable to damage when an earthquake occurs. Therefore, in this study, modeling was conducted through ABAQUS similar to an actual cabinet panel and 3D dynamic nonlinear analysis was performed using a natural seismic. According to seismic zone I and normal ground rock conditions of the power transmission and transmission facility seismic design practical guide, the maximum response acceleration of the performance level was 0.157g. In this study, however, it was not safe to reach the limit state of 30% of the analytical result at 0.1g for the general cabinet panel. From the results, the seismic fragility curve was derived and analyzed. The derived seismic fragility curve is presented as a quantitative basis for determining the limit state of the cabinet panel and can be utilized as basic data in related research.

The Effect of Foliar Application to Improve Putting Green Performance (벤트그래스 그린 관리를 위한 엽면 시비의 효과)

  • Hong, Beom-Seok;Tae, Hyun-Sook;Oh, Sang-Hun;Cho, Yong-Sup
    • Asian Journal of Turfgrass Science
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    • v.25 no.1
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    • pp.94-99
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    • 2011
  • This study was performed to investigate the effect of foliar feeding as the fertilization on creeping benrgrass green. Research results have showed that the visual quality of bentgrass as well as shoot density and chlorophyll index dramatically improved after foliar feeding. Shoot density of bent grass in foliar based fertilization was 2.8 ea/$cm^2$ higher than that of the liquid based fertilization during the experiment period, moreover that the foliar feeding is more effective to alleviate shoot density during the rainy season in summer. Results showed that foliar feeding was key role to achieve the stable visual quality, chlorophyll index and maintained Normalized Difference Vegetation Index (NDVI) throughout the year in addition to get fast recovery after aeration and dry spot. These were consistent with the previous research of foliar feeding which directly provided nutrient to the turfgrass leaf thus increased turfgrass growth within a short time. It is projected to be a especially adequate management program during the hot summer season in which the nutrition feeding is low. However, root growth was no significant difference between foliar based fertilization and liquid based fertilization. Golf Course managers also should consider about the number of frequent fertilizing. Lastly, it was no big change in chemical property by soil foliar based fertilization which is meaning of preventing the soil salinization, meanwhile, it is prone to reach the nutrient deficiency. It hopes to be settled as the general fertilization in golf course of Korea, since there are many advantages of foliar based fertilization program. It is suggested to study more practical process of foliar feeding through the further research.

Study of Deepsea Mining Robot "MineRo" Using Table of Orthogonal Arrays (직교 배열표를 이용한 심해저 채광로봇 미내로의 주행 특성 연구)

  • Lee, Chang-Ho;Kim, Hyung-Woo;Choi, Jong-Su;Yeu, Tae-Kyeong;Lee, Min-Uk;Oh, Jae-Won;Hong, Sup
    • Journal of Ocean Engineering and Technology
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    • v.28 no.2
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    • pp.152-159
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    • 2014
  • KRISO(Korea Research Institute of Ships & Ocean Engineering) designed and manufactured a pilot mining robot called "MineRo" in 2012. MineRo is composed of four track modules. In general, much time and money are needed for deep-sea tests. Therefore, a numerical analysis to predict the dynamic behaviors has to be performed before a deep-sea test. In the numerical analysis, the information about the mining robot and soil properties are the most important factors to analyze the driving performance and dynamic response of MineRo. A terra-mechanics model of extremely cohesive soft soil is implemented in the form of the relationships between the normal pressure and sinkage, and between the shear stress and shear displacement. It is possible to acquire information about MineRo from the CAD model in the design phase. The Wong model is applied to the terra-mechanics model. This model is necessary to acquire many soil coefficients for a numerical analysis. However, in soil testing, the amount of soil property data obtained is limited. Moreover, it is difficult to analyze all of the cases for the many soil coefficients. In this paper, the dynamic behaviors of MineRo are analyzed according to the driving velocity, steering ratio, and variable extremely cohesive soft soil properties using a table of orthogonal arrays. The dynamic responses of MineRo are the turning radius, sinkage, and slip ratio. The relationships between the dynamic responses and variable soil properties are derived for MineRo.

A Demodulation Method for DS/CDMA Systems (DS/CDMA 시스템을 위한 새로운 복조 방식)

  • Jung, Bum-Jin;Jin, Ming-Lu;Kwak, Kyung-Sup
    • Journal of IKEEE
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    • v.2 no.2 s.3
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    • pp.212-224
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    • 1998
  • There are two major factors of degrading the performance in the forward link of DS/CDMA systems. One is the multiple access interference (MAI) caused by using the same frequency bands simultaneously and the other is the multipath lading due to multipath propagation. PN codes which have minimum cross correlation properties among spread spectrum codes are necessary to reduce the MAI. In the conventional IS-95A system, the PN sequence has the period of $2^{15}$ and is of the length of 64 chips for spreading each data. In this case, since the length of PN code per bit is very short compared to the period of the PN code, the performance of the conventional system is not satisfied in view of suppressing the multipath interference. However, the correlation property of the PN codes at the demodulation can be improved by increasing the interval of Integration at the demodulation. This paper proposes a demodulation method to reduce the cross correlation among PN codes. The performance of the proposed demodulation method is investigated through computer simulations. We used multipath Ray lading channel and AWGN channel in the simulation. Our simulation results show the improved performance of $0.25{\sim}0.5dB$ SNR in a given BER compared to the conventional demodulation scheme.

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A Study on the Pyroelectric Properties of PZT(30/70) Thick film Prepared by Using 1,3 Propanediol (1,3 Propanediol을 이용해 제작된 PZT(30/70) 후막의 초전특성에 관한 연구)

  • Song, Kum-Suck;Chang, Dong-Hoon;Joung, Yang-Hee;Yoon, Yung-Sup
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.41 no.6
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    • pp.9-15
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    • 2004
  • PZT(30/70) thick film was fabricated by using 1,3 propanediol-based sol-gel method. Prepared film of pyroelectric property was investigated by Dynamic method of modulation frequency dependence. Pyroelectric coefficient was obtained about $5.0{\times}10^{-8}\;C/cm^2{\cdot}K$. The figure of merits for voltage responsively and specific detectivity were $3.4{\times}10^{-11}\;C{\cdot}cm/J$ and $5.9{\times}10^{-9}\;C{\cdot}cm/J$, respectively, because of relative high-dielectric constant and high-pyroelectric coefficient. Voltage responsively was increased at low modulation frequency and it was decreased at high modulation frequency. Voltage responsively was maximum 1.84 V/W at 10Hz. As Johnson noise is dominant, Noise voltage was increased nearly proportional to $f^{-1/2}$. Noise equivalent power and specific detectivity were $2.83{\times}10^{-7}\;W/Hz^{1/2}$ and 3.13{\times}10^5\;cm{\cdot}Hz^{1/2}/W$ the same frequency at 80Hz, respectively.