• 제목/요약/키워드: sulfur oxidation

검색결과 229건 처리시간 0.022초

Application of Sulfur-doping Titanium Dioxide to Trichloroethylene Oxidation

  • 양창희;신명희;장종대;이진우;이준호;조완근
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2008년도 추계학술발표회 발표논문집
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    • pp.127-130
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    • 2008
  • 가시광선에서 활성을 보이는 TiO$_2$광촉매를 이용하여 대표적인 휘발성유기화합물질들 중에 하나인 TCE의 분해을에 대한 실험을 수행하였다. 본 연구에서 여러 가지 변수들 중에 농도와 상대습도에 따른 휘발성유기화합물의 분해율에 대하여 실험하였으며, 농도 및 상대습도의 변화에 따른 분해율의 영향에 대하여 확인 할 수 있었다. 향후 광촉매를 실제 실내대기에 적용하기 위해 더욱 다양한 조건에서 여러 가지 오염물질에 대한 연구들이 진행되어야 할 것이다.

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폐광산 폐석에 의한 환경오염 저감기술 개발 기초 연구

  • 고주인;지상우;이현석;전용원;강희태;김선준
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 추계학술발표회
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    • pp.386-390
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    • 2003
  • To evaluate the potential capacity of mine wastes in the production of heavy metal containing acid water, samples from depths of 0, 30 and 60cm were collected and analyzed. The waste from surface showed the lowest pH which indicates the oxidation of wastes and the capacity of contamination of the area around the waste file. And the lower pH values of leachate of the wastes through the leaching tests with pH controlled water(3, 4, 5) may indicate that minerals producing the acidity still exist. Reduction of sulfur contents in wastes after the leaching test well fit to the increased contents of iron oxide.

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다구찌 방법을 이용한 Inconel 718 소재의 선삭가공에서 표면거칠기 최적화 (Searching Optimal Cutting Condition for Surface Roughness In Turning Operation on Inconel 718 using Taguchi Method)

  • 차진훈;한상보
    • 한국생산제조학회지
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    • 제19권2호
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    • pp.295-300
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    • 2010
  • Inconel 718 alloy, widely used as material of aircraft engine, has a good mechanical property in high temperature, strong anti-oxidation characteristics in oxidated current over $900^{\circ}C$, and also is not easily digested in the air containing sulfur, therefore, its usage as mechanical component is expanding rapidly. Even though Inconel alloy 718 is difficult to machine, it requires highly precise processing/machining to sustain its component quality of high accuracy. In this paper, general turning operation conditions arc tested to select the best cutting process condition by measuring surface roughness through implementing experiments with orthogonal array of cutting speed, feeding speed and cutting depth as processing parameters based on the Taguchi method. Optimal turning operation conditions are extracted from the proposed experimental models.

선삭가공시의 인코넬 718합금의 표면거칠기 최적 절삭조건 (Optimal Cutting Conditions of Surface Roughness for Inconel 718 Alloy in Turning Operation)

  • 박종민;최원식;권순홍;차진훈
    • 한국기계가공학회지
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    • 제8권4호
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    • pp.48-53
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    • 2009
  • Inconel 718 alloy, widely used as material of aircraft engine, has a good mechanical property in high temperature, strong anti-oxidation characteristics in oxidated current over $900^{\circ}C$, and also is not easily digested in the air containing sulfur, therefore, its usage as mechanical component is expanding rapidly. Even though Inconel alloy 718 is difficult to machine, it requires highly precise processing/machining to sustain its component quality of high accuracy. In this paper, general turning operation conditions are tested to select the best cutting process condition by measuring surface roughness through implementing experiments with orthogonal array of cutting speed, feeding speed and cutting depth as processing parameters based on the Taguchi method. Optimal turning operation conditions are extracted from the proposed experimental models.

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Sonochemical Reaction Mechanism of a Polycyclic Aromatic Sulfur Hydrocarbon in Aqueous Phase

  • Kim, Il-Kyu;Jung, Oh-Jin
    • Bulletin of the Korean Chemical Society
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    • 제23권7호
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    • pp.990-994
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    • 2002
  • Hydroxybenzothiophenes, dihydroxy-benzothiophenes, and benzothiophenedione were identified as inter-mediates of benzothiophene (BT) exposed to ultrasonic irradiation. It is proposed that benzothiophene is oxidized by OH radical to sequentially for m hydroxybenzothiophenes, dihydroxybenzothiophenes, and benzothiophenedione. Benzothiophene is decomposed rapidly following pseudo-first-order kinetics in a first-order manner by ultrasonic irradiation in aqueous solution. The toxicity of sonochemically treated solutions was checked by E. coli and a less inhibition in bacterial respiration was observed from the 120-min treated benzothiophene sample than from the untreated benzothiophene sample. Also evolution of carbon dioxide and sulfite was observed during ultrasonic reaction. A pathway for ultrasonic decomposition of benzothiophene in aqueous solution is proposed.

Genome of Betaproteobacterium Caenimonas sp. Strain SL110 Contains a Coenzyme $F_{420}$ Biosynthesis Gene Cluster

  • Li, Xiuling;Feng, Fuying;Zeng, Yonghui
    • Journal of Microbiology and Biotechnology
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    • 제24권11호
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    • pp.1490-1494
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    • 2014
  • To probe the genomic properties of microbes thriving in desert lakes, we sequenced the full genome of a betaproteobacterial strain (SL110) belonging to the understudied genus Caenimonas of the family Comamonadaceae. This strain was isolated from a freshwater lake in the western Gobi Desert, Northern China. Its genome contains genes encoding carbon monoxide dehydrogenase, nitrate reductase, nitrite reductase, nitric oxide reductase, and sulfur oxidation enzymes, highlighting the potentially important contribution of this group of bacteria to the cycling of inorganic elements in nature. Unexpectedly, a coenzyme $F_{420}$ biosynthesis gene cluster was identified. A further search for $F_{420}$ biosynthesis gene homologs in genomic databases suggests the possible widespread presence of $F_{420}$ biosynthesis gene clusters in proteobacterial genomes.

Marmatite 鑛의 直接酸浸出에 關한 硏究 (第3報) Marmatite 鑛의 酸浸出과 黃化物의 電極電位에 關한 硏究 (Direct Acid Leaching of Zinc from Marmatite Ores 3 Acid Leaching of Marmatite Ores and the Electrode Potential Behavior of Sulfides)

  • 김재원
    • 대한화학회지
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    • 제11권1호
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    • pp.38-43
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    • 1967
  • In order to explain the positive catalytic action of copper compound for the rate of leaching of zinc sulfide minerals, the electrode and redox potentials of both synthetic and natural sulfides were measured at various conditions of temperatures and pressures. The potentials of Chalcopyrite and copper sulfide were considerably higher than that of zinc sulfide, whereas lead sulfide and Galena had slightly lower potentials than that of zinc sulfide. At elevated temperatures and pressures, the same tendency was obtained. By means of comparing the calculated and measured values of potentials for sulfides, it was suggested that the electrode potentials in acid solution were generated by oxidation of sulfur ion. As a result, it was concluded that the catalytic action of copper compound in the leaching of synthetic zinc sulfide should be arised from the galvanic action between sulfides keeping intimate contact one another in which copper sulfide worked as cathodic and zinc sulfide as anodic part analogous to the metal corrosion under galvanic action.

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저품위 동광석의 세균침출에 관한 연구 2

  • 이강순;민봉희;장정순
    • 미생물학회지
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    • 제10권1호
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    • pp.1-8
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    • 1972
  • This experiment was carried out to investigate the physiological characteristics of isolated bacteria, Ferrobacillus ferooxidans from copper mine water in Korea. The results obtained were as follows ; 1. The optimum pH range for the growth of these bacteria was 2.0-3.0 and optimum temperature was $20^{\circ}C$-$30^{\circ}C$. 2. The oxidation curves of ferrous iron to the ferric iron ran parallel with the growth curves. 3. The optimum nitrogen concentration was 400-800 ppm and the minimal flow rate of air for the maximal growth of the bactria was 70 ml air/min./200ml medium. 4. The growth of these bacteria was inhibited by the absence of ferrous iron and by the addition of sulfur. 5. Ferrous iron at a concentration of 9000 ppm, appeared to be optimum for the most rapid growth of Ferrobacillus ferrooxidans.

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알칼리 환원수 필터의 산화환원전위 안정화 평가 (Evaluation of the Stability of Oxidation-Reduced Potential (ORP) Using the Filter of the Alkaline Water)

  • 남상엽;권윤중
    • 전자공학회논문지
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    • 제53권8호
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    • pp.129-135
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    • 2016
  • 본 연구는 알칼리 환원수기에 3가지 필터(활성카본, 중공사막, 카본블럭)를 이용해서 원수를 통과시켜 통수 양에 따른 산화환원전위(Oxidation Reduction Potential) ORP값이 안정화되는 것을 평가한 것이다. 알칼리 환원수기는 환원의 기능을 가지고 있는 물을 만드는 시스템으로 인체에 유익한 미네랄과 ORP값이 일반 물에 비해 매우 낮은 값을 가지고 있는 기능수이다. 필터를 통과한 물을 전기 분해하면 물속에 있는 음이온과 양이온은 격막을 통해서 -전극 쪽에는 칼슘($Ca^+$), 칼륨($K^+$), 마그네슘($Mg^+$), 나트륨($Na^+$)을 포함한 물로 인체에 유익한 미네랄이 포함된 알칼리 환원수를 얻고 +극에는 염소(Cl),인(P),유황(S)등 - 이온을 띄고 있는 유기물이 만들어 진다. 실험에서 알칼리 환원수(Alkaline Reduced Water)에서 전기분해의 전압의 크기를 조절하여 1단(pH8), 2단(pH8.5), 3단(pH9), 4단(pH9.5)으로 알칼리 환원수에 사용되고 -1단(pH6.0), -2단(pH5.0)의 산성산화수로 사용하고 있다. 이러한 시스템으로 3가지 필터에 통수하면서 ORP값이 어떻게 변화하고 어느 정도에서 안정화되는지를 평가하였고 대략 100L는 통수되어야 ORP값이 안정화하는 것을 측정하고 평가하였다.

고온.산소가압하(高溫.酸素加壓下)에서의 황동광(黃銅鑛)의 황산침출 거동 고찰 (Behavior of the High Temperature Oxygen Pressure Leaching of Chalcopyrite in Sulfuric Acid Solution)

  • 엄형춘;윤호성;유경근;손정수
    • 자원리싸이클링
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    • 제16권3호
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    • pp.44-49
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    • 2007
  • 본 연구는 고온 산소가압 하에서의 황동광(칠레산 에스콘디다광석) 황산침출에 관한 연구로 침출시간, 침출온도, 산소압력에 따른 Cu 침출율 및 침출거동에 대하여 고찰하였다. 침출온도가 Cu의 침출율에 미치는 영향이 가장 켰으며, 산소압력은 큰 영향을 미치지 않았다. 침출온도 $200^{\circ}C$, 산소압력 10 atm인 조건으로 2시간 침출하여 87.1%의 Cu를 침출하였으며, 이 때 함께 침출된 Fe는 대부분 hematite($Fe_2O_3$) 형태로 재침전이 일어났다. 산소가압 하에 고온($150^{\circ}C$ 이상) 침출조건에서 황동광 침출반응은 주로 산소의 산화작용에 의한 분해인 것을 확인하였으며, 황은 대부분 황산염 형태로 산화되어 단체황 생성으로 인한 passivating 현상은 일어나지 않은 것으로 사료된다.