• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
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• pp.138-138
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• 2006

• 암석학회지
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• 제4권2호
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• pp.134-143
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• 1995

울프리버 저반의 화강암질 심성암체의 황함량과 황동위원소는 각각, 30~150 ppm 및 1.1~6.5 permil의 조성범위를 보이며, 마그마 기원으로 판단된다. 주변 모암인 피노키안 심성암체의 황함량과 동위원소 조성은 각각, 31~381 ppm과 -1.7~7.2의 범위로서 울프리버 저반의 직접적인 근원 암이 될 수 없는 것으로 보인다. 피노키안 심성암체와 울프리버 저반의 화강암체들의 산소와 황동위원소 조성이 상당히 뚜렸한 선형의 경향을 보이는데, 이러한 경향은 심부 지하가 근원인 본원마그마에 의한 피노키안 심성암체의 동화작용, 또는 심부에서 본원 마그마와 좀 더 높은 산소 및 황동위원소 조성을 갖는 또 다른 마그마와의 혼합에 의한 것으로 볼 수 있다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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• pp.90-93
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• 2003

Sampling of waters from each stage of treatment system, SAPS (Successive Alkalinity Producing System), and spring water near the Hanchang coal mine of Kangwon. Province were carried out periodically and analyzed to evaluate the source and possible path of groundwater contamination by acid mine drainage(AMD). Chemical and sulfur isotope compositions showed that spring water was affected by seepage from mine tailings, and seepage of stonewall, a part of treatment system, was affected by both seepage from mine tailings and mine adit drainage. Through the treatment system no appreciable decrease of sulfur content was identified. And almost similar sulfur isotope compositions of water from each stage of the treatment system may suggest incomplete or very poor sulfate reduction by sulfate reducing bacteria.

• 대한자원환경지질학회:학술대회논문집
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• 대한자원환경지질학회 2002년도 춘계 공동학술발표회
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• pp.59-61
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• 2002

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 추계학술발표회
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• pp.501-504
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• 2003

Sulfur isotope composition was used to identify the sources of groundwater contamination near abandonded coal mines. From the analysis of mine adit drainages, tailing seepages, and spring waters near the abandonded Hambaek and Hanchang coal mines in Kangwon Province, it was inferred that it the highly possible source of the contamination of spring water is acid mine drainage(AMD). Sulfur isotope composition showed that seepage from tailings seemed to have more effect on the groundwater contamination than mine adit drainage, which suggests the remediation and anti-contamination methods of tailing seepages not only mine adit drainage are required.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
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• pp.209-212
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• 2006

Using sulfur sotope analysis of dissolved sulfate in surface water, we have investigated the source of sulfate in order to identify the abandoned metallic mines, which have the potential of heavy metal contamination within watershed. The range of the sulfur isotope values for dissolved sulfate in stream waters (DD-1 and 2) are similar to those of sulfides from the Dunjun mine, which suggests that oxidation of sulfides is the principal source of $SO_4^{2-}$ in these stream waters. Also, heavier sulfur isotopes in waters near Baekjun and Hamchang mines imply the possibility of contamination in waters by these metallic mines.

• Journal of Ginseng Research
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• 제41권2호
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• pp.195-200
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• 2017

Background: The natural ratios of carbon (C), nitrogen (N), and sulfur (S) stable isotopes can be varied in some specific living organisms owing to various isotopic fractionation processes in nature. Therefore, the analysis of C, N, and S stable isotope ratios in ginseng can provide a feasible method for determining ginseng authenticity depending on the cultivation land and type of fertilizer. Methods: C, N, and S stable isotope composition in 6-yr-old ginseng roots (Jagyeongjong variety) was measured by isotope ratio mass spectrometry. Results: The type of cultivation land and organic fertilizers affected the C, N, and S stable isotope ratio in ginseng (p < 0.05). The ${\delta}^{15}N_{AIR}$ and ${\delta}^{34}S_{VCDT}$ values in ginseng roots more significantly discriminated the cultivation land and type of organic fertilizers in ginseng cultivation than the ${\delta}^{13}C_{VPDB}$ value. The combination of ${\delta}^{13}C_{VPDB}$, ${\delta}^{15}N_{AIR}$, or ${\delta}^{34}S_{VCDT}$ in ginseng, except the combination ${\delta}^{13}C_{VPDB}-^{34}S_{VCDT}$, showed a better discrimination depending on soil type or fertilizer type. Conclusion: This case study provides preliminary results about the variation of C, N, and S isotope composition in ginseng according to the cultivation soil type and organic fertilizer type. Hence, our findings are potentially applicable to evaluate ginseng authenticity depending on cultivation conditions.

• 자원환경지질
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• 제29권2호
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• pp.119-127
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• 1996

Electrum-sulfide minerals of the Namsan Au-Ag mine were deposited in two stages of quartz and calcite veins that fill fault planes in Mesozoic granitic rocks (230~155 Ma). The K/Ar radiometric dating of hydrothermal sericite indicates that mineralization is early Cretaceous age ($127{\pm}3.0Ma$). Mineralogic, fluid inclusion and sulfur isotopic data show that ore minerals were deposited at temperatures between $340^{\circ}C$ and $200^{\circ}C$ from fluid with salinities of 3 to 6 equiv. wt % NaCl. Evidence of fluid boiling (and $CO_2$ effervescence) indicates a maximum pressures of 100 bars. The formation temperature and $fs_2$, of Au-mineralization from the Namsan mines are mainly $280{\sim}230^{\circ}C$ and $10^{-11}{\sim}10^{-13}$ atm, respectively. Au deposition was likely a result of boiling caused to chemical change (pH, $f_{O2}$, ${\Sigma}_{H_2S{\cdot}{\cdot}}$) of ore-fluids. Sulfur isotope composition of sulfide minerals (${\delta}^{34}S=5.1$ to 8.2‰) are consistent with ${\delta}^{34}S_{{\Sigma}{H2S}}$ value of +6 to +7‰, suggesting an igneous source of sulfur partially mixed with wall-rock sulfur.

• 자원환경지질
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• 제18권3호
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• pp.247-251
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• 1985

The sulfide and carbonate mineral samples for sulfur and carbon isotope studies were collected from Sangdong, Geodo, Yeonhwa, Shinyemi and Janggun mines which are distributed in the Metallogenetic Province of the Taebaeg Mt. Region. The ${\delta}S^{34}$ values of molybdenite, pyrite, arsenopyrite, pyrrhotite, chalcopyrite, sphalerite and galena from the above mines are similar and within the range of +1.66 to +6.77‰ with the exception of chalcopyrite from Geodo mine ranging from -1.58 to 1.96‰, while the sulfide minerals are dominated by positive values between +3.05 and +5.08‰. It is suggested that the major sulfur source is genetically related to the Cretaceous granitic activity. The average ${\delta}C^{13}$ values of calcite from limestone, calcite from calcite vein in ore bodies and granite, and rhodochrosite from ore bodies are -0.60‰, -2.69‰ and -6.00‰, respectively. The data on carbon isotope compositions indicate that the calcite from limestone originated in marine environment, the rhodochrosite in hydrothermal solution, and calcite from calcite vein and granite in the mixing condition of marine and hydrothermal waters. The temperatures of mineralization by the sulfur isotopic composition coexisting pyrite-pyrrhotite from Yeonhwa No.1, sphalerite-galena from Weolam and Dong-jeom of Yeonhwa No.1 mine, sphalerite-galena and pyrite-galena from Janggun mine were $273^{\circ}C$, $460{\sim}511^{\circ}C$, $561{\sim}690^{\circ}C$, $341^{\circ}C$ and $375^{\circ}C$, respectively.

• 자원환경지질
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• 제45권2호
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• pp.145-156
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• 2012

해저열수시스템은 중앙해령이나 후열도확장대와 같은 해저화산대를 따라 생성된다. 해저열수시스템은 지각-맨틀과 해양의 에너지와 물질이 교환되는 장으로 이를 통해 지각과 해수의 조성이 변화하며, 해저면에 열수분출구를 침전시켜 열수생태계를 형성하고 금속광상이 만들어진다. 상대적으로 단순한 중앙해령과 달리 지판소멸지역의 해저열수시스템은 섭입되는 물질의 재순환과정에서 다양한 특성이 나타난다. 황동위원소 조성은 이러한 열수시스템의 다양성을 평가하는데 유용하다. 이 논문에서는 서태평양의 지판소멸대에서 발견된 열수분출 지역에서 채취된 열수분출구 시료의 황동위원소 조성변화를 살펴보고 이들 환경에서 열수생성의 다양성을 일으키는 요인을 고찰하였다. 지판소멸대의 열수분출구는 황화광물과 황산염광물 모두 낮은 황동위원소 조성을 갖는 것이 특징이며, 이는 마그마로부터 공급된 $SO_2$ 기체의 유입으로 해석된다. 황동위원소 조성 변화를 포함한 열수시스템의 다양성은 열수시스템 생성과정에서 마그마의 적극적인 역할을 지시한다.