• Title/Summary/Keyword: substrate mixture

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Diamond Film Deposition by Microwave Plasma CVD Using a Mixture of $CH_4$, $H_2$, $O_2$, (마이크로웨이브 플라즈마 화학증착법에 의해 메탄, 수소, 산소의 혼합가스로부터 다이아몬드 박막의 합성)

  • 이길용;제정호
    • Journal of the Korean Ceramic Society
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    • v.27 no.4
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    • pp.513-520
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    • 1990
  • Diamond film was deposited on Si wafer substrate from a gas mixture of methane, hydrogen and oxygen by microwave plasma-assisted chemical vapor deposition. The effects of the pre-treatments of the substrate and of the oxygen addition on the diamond film synthesis are described. In order to obtain diamond film, the substrate was pre-treated with 3 kinds of methods. When the substrate was ultrasonically vibrated within the ethyl alcohol dispersed with 25${\mu}{\textrm}{m}$ diamond powder, the denset diamond film was deposited. Addition of oxygen in the gas mixture of methane and hydrogen improved the crystallinity of the deposited diamond film and also increased the deposition rate of the diamond film more than two times.

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Biological Removal of a VOC Mixture in a Two-stage Bioreactor (이단미생물반응조에서 혼합 VOCs의 생분해 특성)

  • Song, Ji-Hyeon
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.6
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    • pp.758-766
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    • 2006
  • A two-stage bioreactor, which consists of a biotrickling filter module and a biofilter module in series, was investigated for the enhanced treatment of a VOC mixture, toluene and methyl ethyl ketone (MEK). Throughout the experiments, the overall inlet loading rate was maintained at approximately $43g/m^3/hr$, but the inlet ratios of the VOCs were modified. The experimental results showed that the different ratios of the VOC mixture resulted in changes of overall removal efficiencies, elimination capacities (ECs) and microbial accumulation on the surface of each packing material. The ratio of inlet toluene to MEK at 50 : 150 was found to be most effective in terms of the overall removal efficiency, because, at this condition, MEK (i.e., the hydrophilic compound) was mostly removed in the biotrickling filter module and the following biofilter module was used to remove toluene. It was also found that when the inlet loading rate of the VOC mixture was serially increased stepwise within short-term periods, the ECs for toluene dropped significantly but the ECs for MEK increased at the ratio of the VOC mixture. These results implied that substrate interaction and/or substrate preferable utilization might have an effect on the biological removal of each compound in the two-stage bioreactor; therefore, the bioreactor should be operated in the condition where the substrate interaction could be minimized in order to maximize overall performance of the two-stage bioreactor.

Deposition and characterization of compositional gradient CrNx coatings prepared by arc ion plating

  • Zhang, Min;Kim, Kwang-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.05a
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    • pp.177-181
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    • 2009
  • Compositional gradient CrNx coatings were fabricated using arc ion plating in Ar/$N_2$ gaseous mixture by gradually increasing $N_2$ flux rate from 0 to 120 SCCM. The effect of negative substrate bias on the film microstructure and mechanical properties were systematically investigated with XRD, GDOES, and SEM. The results show that substrate bias has an important influence on film growth and microstructure of gradient CrNx coatings. The coatings mainly crystallized in the mixture of hexagonal $Cr_{2}N$ and fcc CrN phases. By increasing substrate bias, film microstructure evolved from an apparent columnar structure to an equiaxed one. With increasing substrate bias, deposition rate first increased, and then decreased. The maximum of deposition rate was 15 nm/min obtained at a bias of -50V.

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BIO-BARRIER FORMAT10N BY BACTERlUM/FUNGUS INJECTION INTO SOILS

  • Kim, Geonha
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2001.11a
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    • pp.11-16
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    • 2001
  • If microorganisms are injected into porous medium such as soils along with appropriate substrate and nutrients, soil pore size and shape are changed from the initial condition as a result of biofilm formation, which make hydraulic conductivity reduced. In this research, hydraulic conductivity reduction was measured after specific bacterium or fungus was inoculated into soil pore. Hydraulic conductivity was decreased to 10 % ∼ 1 % and maintained constant while substrate was provided. Under the adverse conditions such as no substrate, chemical solution permeation, and freeze-thaw cycles, hydraulic conductivity was increased 30∼50%. Hydraulic conductivity decrease of fungus-soil mixture was faster than that of bacterium-soil mixture. Fungus-soil mixture, however, was more sensitive to the adverse conditions.

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A Study on the Laser Melting Deposition of Mixed Metal Powders to Prevent Interfacial Cracks (레이저 용융 금속 적층 시 결함 방지를 위한 혼합 분말 적층에 관한 연구)

  • Shim, D.S.;Lee, W.J.;Lee, S.B.;Choi, Y.S.;Lee, K.Y.;Park, S.H.
    • Transactions of Materials Processing
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    • v.27 no.1
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    • pp.5-11
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    • 2018
  • Direct energy deposition (DED) technique uses a laser heat source to deposit a metal layer on a substrate. Many researchers have used the DED technique to study the hardfacing of molds and dies. The aim of this study is to obtain high surface hardness and a sound bonding between the AISI M4 deposits and a substrate utilizing a mixed powder that contains M4 and AISI P21 powders. To prevent interfacial cracks between the M4 deposits and the substrate, the mixed powder is pre-deposited onto a JIS S45C substrate, before the deposition of M4 powders. Interfacial defects occurring between the deposits and substrate and changes in the microhardness of the intermediate layer were examined. Observations of the cross-sections of deposited specimens revealed that the interfacial cracks appeared in samples with one and two mixed layers regardless of the mixture ratio. However, the crack was removed by increasing the mixture ratio and the number of intermediate layers. Meanwhile, the microhardness in the mixed layer was found to decrease with increasing ratio of P21 powder in the mixture and that in the upper region of the deposited layers was approximately 800 HV, which was attributed to various alloying elements in the M4 powder.

Characteristics of Diamond Films Deposited on Cemented Tungsten Carbide Substrate (초경합금기판 위에 성장되는 다이아몬드 막의 특성)

  • 김봉준;박상현;박재윤
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.7
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    • pp.387-394
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    • 2004
  • Diamond films were deposited on the cemented tungsten carbide WC-Co cutting insert substrates by using both microwave plasma chemical vapor deposition(MWPCVD) and radio frequency plasma chemical vapor deposition (RFPCVD) from $CH_4$$-H_2$$-O_2$ gas mixture. Scanning electron microscopy and X-ray diffraction techniques were used to investigate the microstructure and phase analysis of the materials and Raman spectrometry was used to characterize the quality of the diamond coating. Diamond films deposited using MWPCVD from $CH_4$$-H_2$$-O_2$ gas mixture show a dense, uniform, well faceted and polycrystalline morphology. The compressive stress in the diamond film was estimated to be (1.0∼3.6)$\pm$0.9 GPa. Diamond films which were deposited on the WC-Co cutting insert substrates by RFPCVD from $CH_4$$-H_2$$-O_2$ gas mixture show relatively good adhesion, very uniform, dense and polycrystalline morphology.

Synthesis of diamond thin film on WC-Co by RF PACVO (고주파 플라즈마 CVD에 의한 초경합금상에 다이아몬드 박막의 합성)

  • 김대일;이상희;박종관;박구범;조기선;박상현;이덕출
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.452-455
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    • 2000
  • Diamond thin films were synthesized on WC-Co substrate at various experimental parameters using 13.56MHz RF PACVD(radio frequency plasma-assisted chemical vapor deposition). In order to increase the nucleation density, the WC-Co substrate was polished with 3$\mu\textrm{m}$ diamond paste. And the WC-Co substrate was pretreated in HNO$_3$: H$_2$O = 1:1 and O$_2$ plasma. In H$_2$-CH$_4$gas mixture, the crystallinity of thin film increased with decreasing CH$_4$concentration at 800W discharge power and 20torr reaction pressure. In H$_2$-CH$_4$-O$_2$gas mixture, the crystallinity of thin film increased with increasing O$_2$concentration at 800W discharge power, 20torr reaction pressure and 4% CH$_4$concentration.

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Growth Responses of Eggplant (Solanum melongena) to Hydrophilic Polymer Mixture Ratio in Growing Medium for Lower Maintenance Urban Agriculture via Green Roofs (옥상 내 저관리 도시농업에서 친수성 중합체 배합비에 따른 가지(Solanum melongena)의 생육반응)

  • Ju, Jin-Hee;Kim, Won-Tae;Xu, Hui;Yoon, Young-Han;Choi, Eun-Young
    • Journal of Environmental Science International
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    • v.25 no.5
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    • pp.625-633
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    • 2016
  • This study was conducted to investigate the influence of hydrophilic polymer (HP) mixture ratio (Control, 1.0%, 2.5%, 5.0%, and 10.0%) on growth of eggplant (Solanum melongena) for lower maintenance urban agriculture via green roofs. Although it was not statistically significant (p > 0.05), substrate temperature was decreased as hydrophilic polymer mixture ratio were increased. High substrate water content (95%) was found consistently in growing media under elevated hydrophilic polymer mixture ratio at over 5% during the entire growing period. Substrate electronic conductivity was increased as hydrophilic polymer mixture ratio were increased. Growth index was decreased as hydrophilic polymer mixture ratio was increased. It was reduced about 1/3 and 1/5 compared to that of Control in HP5.0 and HP10.0 treatment plants, respectively. Number of leaves, leaf length, and leaf width were decreased in following order: Control> HP1.0> HP2.5> HP5.0> HP10.0 treatments. There numbers were significantly lower in HP5.0 and HP10.0 treatment plants. Dry weight of shoot and root were decreased as hydrophilic polymer mixture ratio was increased. They were reduced by 1/4 compared to those of Control treatment plants. In addition, visual value was decreased as hydrophilic polymer mixture ratio was increased. Plants grown in HP1.0, HP2.5, and HP5.0 treatments all survived. However, plants grown in the HP10.0 treatment had the lowest survival rate (56%) after 3 months of growing. These results indicate that the advantage of adding hydrophilic polymer to green roof growing media may greater during dry periods. However, the proper mixture proportion of hydrophilic polymer should be determined according to different characteristics of growing media and plant species.

Investigation of Internal Flow Fields of Evaporating of Binary Mixture Droplets (증발하는 이성분혼합물 액적의 유동장 해석)

  • Kim, Hyoungsoo
    • Journal of the Korean Society of Visualization
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    • v.15 no.2
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    • pp.21-25
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    • 2017
  • If a liquid droplet evaporates on a solid substrate, when it completely dries, it leaves a peculiar pattern, which depends on the composition of the liquid. Not only a single component liquid but also complex liquids are studied for a different purpose. In particular, a binary mixture droplet has been widely studied and used for an ink-jet printing technology. In this study, we focus on investigating to visualize the internal flow field of an ethanol-water mixture by varying a concentration ratio between two liquids. We measure the in-plane velocity vector fields and vorticities. We believe that this fundamental study about the internal flow field provides a basic idea to understand the dried pattern of the binary mixture droplet.

Fermentation of Glucose, Xylose and Cellobiose by Pichia stipitis (Pichia stipitis에 의한 Glucose, Xylose 및 Cellobiose의 발효)

  • 이유석;권윤중;변유량
    • Microbiology and Biotechnology Letters
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    • v.20 no.1
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    • pp.91-95
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    • 1992
  • The hydrolyzates of lignocellulosic biomass contain a mixture of glucose, xylose and cellobiose. The yeast which can produce ethanol efficiently from xylose and cellobiose was selected and its growth and ethanol formation behavior on each sugar and their mixture were investigated. Ethanol yields during batch culture of Pichia stipitis CBS 5776 were 0.4. 0.36 and 0.23 g/g substrate on glucose, xylose and cellobiose, respectively. Mixed sugar fermentation data indicate that glucose causes catabolite regulation on xylose and cellobiose utilization. However, xylose and cellobiose were utilized simultaneously. Ethanol yields on mixtures of sugars were generally additive for each of the substrates.

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