• Title/Summary/Keyword: subcritical fluid

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Depolymerization of Polyethylene Terephthalate with Supercritical Methanol (초임계메탄올을 이용한 PET의 분해)

  • Ahn, Jae-Myoung;Ihm, Bang-Hyun;Kim, Sun-Wook;Shim, Jae-Jin
    • Clean Technology
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    • v.13 no.1 s.36
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    • pp.46-53
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    • 2007
  • We depolymerized PET in supercritical methanol and observed the yield of DMT at various reaction conditions. At subcritical state below $240^{\circ}C$, the yield of DMT was very low, about only 50%. It increased dramatically to 80% at supercritical state above $260^{\circ}C$, thereafter the increasing rate was reduced significantly. Similarly, at subcritical state of 6.89 MPa, the DMT yield was only 50%, but it increased abruptly to 85% at supercritical state of 10.34 MPa, yielding no further increase above the pressure. Within 10 minutes after the beginning of the reaction, the DMT yield reached 80%, indicating that the significant portion of the reaction has proceeded, and then, the yield increased slowly. The methanol/PET ratio of 8 showed the maximum DMT yield. We found the optimum depolymerization condition fur PET methanolysis is temperature $300^{\circ}C$, pressure 10.34 MPa, reaction time 40 minutes, and methanol/PET ratio of 8.

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The Study on the Spray Characteristics of Supercritical Spray (초임계상태 분무의 분무 특성에 관한 연구)

  • Park, C.J.
    • Journal of ILASS-Korea
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    • v.4 no.3
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    • pp.8-14
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    • 1999
  • The characteristics of the breakup process in supercritical spray is investigated during the injection of supercritical sulfur hexafluoride into dissimilar gases at supercritical pressures and subcritical temperature of the injected fluid. The visualization techniques used are backlighting and shadowgraph methods. The spray angles are measured and the breakup and mixing process are observed at near and supercritical conditions. The results show that spray angles are decreased with the in..ease of the ratio of density $(\frac{\rho_f}{\rho_g})$. At the supercritical temperature, the spray angles in atomization region are kept nearly constant such as the typical spray angle in gas injection. The mixing process is changed radically at the temperature where $\frac{d\rho}{dT}=\frac{1}{2}[\frac{d\rho}{dT}]_{max}$ at given pressure.

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A Thermal hydraulic Investigation on ADSR Liquid Lead Target

  • Kim, Ju Y.;Byung G. Huh;Chang H, Chung;Tae Y. song;Park, Won S.
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05a
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    • pp.666-671
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    • 1998
  • Computational fluid dynamics(CFD) code FLUENT[11 was used to simulate the thermal hydraulic processes occuring in conceptual design of the accelerator-driven subcritical reactor(ADSR) liquid lead target. The purpose of the analysis is to investigate the thermal hydraulic characteristics of liquid lead as ADSR target material with various target geometries and injection locations of proton beam. In the calculation analysis, the local temperature of the liquid lead target rises to the boiling temperature very rapidly When the proton beam is injected from the bottom of the target system, the duration time to reach the boiling temperature is longer and the temperature distribution is flatter than other cases.

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Numerical Comparison of Thermalhydraulic Aspects of Supercritical Carbon Dioxide and Subcritical Water-Based Natural Circulation Loop

  • Sarkar, Milan Krishna Singha;Basu, Dipankar Narayan
    • Nuclear Engineering and Technology
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    • v.49 no.1
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    • pp.103-112
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    • 2017
  • Application of the supercritical condition in reactor core cooling needs to be properly justified based on the extreme level of parameters involved. Therefore, a numerical study is presented to compare the thermalhydraulic performance of supercritical and single-phase natural circulation loops under low-to-intermediate power levels. Carbon dioxide and water are selected as respective working fluids, operating under an identical set of conditions. Accordingly, a three-dimensional computational model was developed, and solved with an appropriate turbulence model and equations of state. Large asymmetry in velocity and temperature profiles was observed in a single cross section due to local buoyancy effect, which is more prominent for supercritical fluids. Mass flow rate in a supercritical loop increases with power until a maximum is reached, which subsequently corresponds to a rapid deterioration in heat transfer coefficient. That can be identified as the limit of operation for such loops to avoid a high temperature, and therefore, the use of a supercritical loop is suggested only until the appearance of such maxima. Flow-induced heat transfer deterioration can be delayed by increasing system pressure or lowering sink temperature. Bulk temperature level throughout the loop with water as working fluid is higher than supercritical carbon dioxide. This is until the heat transfer deterioration, and hence the use of a single-phase loop is prescribed beyond that limit.

Neutronic and thermohydraulic blanket analysis for hybrid fusion-fission reactor during operation

  • Sergey V. Bedenko ;Igor O. Lutsik;Vadim V. Prikhodko ;Anton A. Matyushin ;Sergey D. Polozkov ;Vladimir M. Shmakov ;Dmitry G. Modestov ;Hector Rene Vega-Carrillo
    • Nuclear Engineering and Technology
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    • v.55 no.7
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    • pp.2678-2686
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    • 2023
  • This work demonstrates the results of full-scale numerical experiments of a hybrid thorium-containing fuel plant operating in a state close to critical due to a controlled source of D-T neutrons. The proposed facility represented a level of generated power (~10-100 MWt) in a small pilot. In this work, the simulation of the D-T neutron plasma source operation in conjunction with the facility blanket was performed. The fission of fuel nuclei and the formation of spatial-energy release were studied in this simulation, in pulsed and stationary modes of the facility operation. The optimization results of neutronic and fluid dynamics studies to level the emerging offsets of the radial energy formed in the volume of the facility multiplying part due to the pulsed operation of the D-T neutron plasma source were presented. The results will be useful in improving the power control-based subcriticality monitoring method in coupled systems of the "pulsed neutron source-subcritical fuel assembly" type.

The Hydraulic Assessment of Side Weir using 3D Computational Fluid Dynamics Program (3차원 수치모형에 의한 횡월류위어의 수리학적 평가)

  • Nam, Ki-Young;Han, Kun-Yeun;Park, Hong-Sung;Kim, Keuk-Soo;Choi, Seung-Yong
    • Journal of Environmental Impact Assessment
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    • v.19 no.2
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    • pp.153-168
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    • 2010
  • The objectives of this study are to analyze flow characteristics for a side weir, which is an inlet structure for flow discharge reduction in the main channel through 3 dimensional numerical analysis and to understand the efficiency of the overflow effect at the side weir. In this study over 40 simulations using FLOW-3D, a computational fluid dynamics program were conducted, and the results were analyzed to find the influence of the flow hydraulics, geometry, channel and weir shapes on the coefficient. It is especially considered the relatively high stage in downstream that may cause flow within channel to be backed up along the channel. Additionally by setting up the scale of simulations much larger than the existing test equipment designed by other researchers, it is intended to analyze more accurate hydraulic behavior along with the realistic hydraulic features such as structures and volumes of flow. The results show that for design with subcritical flow only if the Froude number of upstream is sustained below 0.5 and the length of weir is 33-100% of the width of channel, it is expected to improve the efficiency of the overflow over a side weir.

Numerical modeling of rapidly varied flow using the SST turbulence model and a hybrid free-surface capturing approach (자유수면 포착기법과 난류모형을 이용한 급변류 수치모델링)

  • Kim, Byung Ju;Paik, Joongcheol
    • Proceedings of the Korea Water Resources Association Conference
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    • 2020.06a
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    • pp.149-149
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    • 2020
  • 하천에서 물 흐름이 보와 댐과 같은 수공구조물을 지날 때 일반적으로 흐름상태에 다양하고 급진적인 변화가 발생한다. 특히 흐름이 구조물을 지나면서 사류(supercritical flow)로 변하고 다시 상류(subcritical flow)로 복원되면서 일어나는 도수(hydraulic jump) 현상은 수위의 급변화, 흐름 에너지 소산, 변동성이 강한 압력 분포 등이 특징이다. 이러한 흐름 특성들은 보나 여수로와 같은 수공구조물 자체의 성능뿐만 아니라 이들 수공구조물의 하류에서 발생하는 국부세굴로 인해 구조물의 안정성에 부정적인 영향을 줄 수 있다. 따라서 수공구조물을 설계할 때는 이들 구조물을 통과하는 흐름의 비정상 난류 흐름 특성을 정확하게 해석하여 반영하여야 한다. 이 연구에서는 k-omega SST 난류 모형과 자유수면의 급격한 변동을 해석하기 위한 하이브리드-VOF(hybrid volume of fluid)기법을 이용하여 도수현상을 수치적으로 재현하고자 한다. 기존 CFD(computational fluid Dynamics) 모델링에서는 자유수면 변동의 영향을 고려하기 위해 VOF 기법을 많이 사용하였다. 하지면 전통적인 VOF 기법은 다상흐름(multiphase flow)을 오직 부피분율(volume fraction)의 함수로만 고려하며 모의함으로써 강한 수면변동뿐만 아니라 공기연행(air entrainment)를 동반하는 난류 흐름을 모의하는데는 한계가 있다. 이 연구에서 이용하는 Eulerian 기법인 하이브리드 VOF 기법은 물과 공기의 각 상에 대하여 흐름 특성들을 개별적으로 계산하기 때문에 공기연행을 포함한 급변류 흐름에서 전통적인 VOF 기법보다 적용성이 우수하다. 이와 같은 난류모형과 자유수면 포착기법을 이용하여 3차원 비정상 난류 흐름 수치모형을 구축하여 수공구조물 주변에서 발생하는 강한 공기연행과 난류 특성를 보이는 급변류를 수치적으로 재현한다. 이 연구는 계산된 수치해석 결과를 기존 수리실험 결과와 비교하여 수치모형의 적용성을 평가하고 도수 현상에서 발생하는 독특한 흐름 특성을 제시한다.

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Effects of flow variation in the first stage nozzle on the performance of a partial arc admission in a steam turbine (증기터빈 1단 노즐의 조속현상이 터빈성능에 미치는 영향)

  • Yoon, In-Soo;Lee, Tae-Gu;Moon, Seung-Jae;Lee, Jae-Heon
    • Plant Journal
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    • v.4 no.3
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    • pp.60-65
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    • 2008
  • Power plant industry has been developed at high-capacity, high-technology, and innovation. Steam turbine became the most useful equipment that dominate more than 50% of all the world electricity production. And developed new materials of the turbine blade and extended length of the turbine last blade brought reform in steam turbine performance upgrade. In this paper, when do partial load driving in high-capacity steam turbine, optimum driving method found whether there is something. In operating steam turbine, there is a lot of loss from secondary wake and throttle of the 1st stage nozzle by the biggest leading factor that load fluctuation affects in high-pressure steam turbine performance. Effect of internal efficiency by 1 stage nozzle is the biggest here, but here fluid flow and flow analysis were not yet examined closely definitely. So, Analyzed design data and acceptance performance test result to applying subcritical pressure drum type 560 MW, supercritical-pressure once through type 500 MW, and 800 MW steam turbines actually. In conclusion, at partial load driving, partial arc admission(PAA) is more efficient than full arc admission(FAA) efficiency. This is judged by because increase being proportional with gross energy of stream that is pressure - available energy if pressure of stream that is flowed in to the turbine increases, available energy becomes maximum and turbine efficiency improves. Therefore, turbine performance is that preview that first stage performance fell if decline is serious in partial load because first stage performance changes according to load.

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Influence of Critical Point of Jet Injected into Near-Critical Environment on Phase Change (근임계 환경으로 분사되는 제트의 임계점이 상변화에 미치는 영향)

  • Yoon, Taekyung;Shin, Dongsoo;Son, Min;Shin, Bongchul;Koo, Jaye
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.475-481
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    • 2017
  • In this paper, high speed camera images were used to analyze the supercritical injection behavior of liquid hydrocarbon compounds used as main components of propellant fuel. Decane and Methylcyclohexane (MCH), which have different critical points among kerosene constituents, were selected as experimental fluid and Shadowgraphy technique was used for the analysis. The difference in the temperature variation from the initial injector state of the subcritical condition until the vaporization occurs was represented by the different behaviors of Decane and MCH. However, under the Supercritical conditions, the enthalpy of vaporization near the critical point approaches zero and the phase change to the Supercritical phase occurs instead of vaporization process. In the phase change of the Supercritical system, there was no rapid density change, so the liquid state image was observed in both the Decane and MCH.

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Circulation Dynamics of Keum River Estuary II. Fluid Dynamic Characteristics (錦江 河口의 海水循環力學 弟2報 流體力學的 諸特性)

  • Chung, Jong Yul;Bhang, In Kweon
    • 한국해양학회지
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    • v.19 no.2
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    • pp.141-152
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    • 1984
  • In order to investigate the circulation dynamics of the Keum River estuary, 300velocity fields obtained at six sites over two tidal cycles by using instantaneous profiling technique were analyzed in detail. In this investigation, the variability of shear velocity, bottom shear stress, drag coefficient, and roughness length scale were confirmed. The measured values of the bottom boundary drag coefficient show wide range of variations, i.e., C$\_$100/=6.78${\times}$10$\^$-5/∼1.15${\times}$10$\^$-1/, and the mean of 300 measurements is 1.6${\times}$10$\^$-2/. The relationship between U* and C$\_$100/ also show the scatter in values. However, overall mean values over two tidal cycles at 6 stations show that if U* 1cm/s, C$\_$100/ is unpredictable, if U* 1cm/s, C$\_$100/ increase with U*. The values of Re$\_$100/ and C$\_$100/ have scatter. But the overall mean values over two tidal cycles show that if Re$\_$100/ 3.6${\times}$10$\^$5/, C$\_$100/ is unpredictable, if Re$\_$100/ 3.6${\times}$10$\^$5/, C$\_$100/=1.4${\times}$10$\^$-2/. Finally the flow regime of the Keum River estuary was classified as "subcritical fully turbulent" flow.

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