• Title/Summary/Keyword: styrene-butadiene-styrene

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Pinning retrofit technique in masonry with application of polymer-cement pastes as bonding agents

  • Shrestha, Kshitij C.;Pareek, Sanjay;Suzuki, Yusuke;Araki, Yoshikazu
    • Earthquakes and Structures
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    • v.5 no.4
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    • pp.477-497
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    • 2013
  • This paper reports extensive experimental study done to compare workability and bond strength of five different types of polymer-based bonding agents for reinforcing bars in pinning retrofit. In pinning retrofit, steel pins of 6 to 10 mm diameters are inserted into holes drilled diagonally from mortar joints. This technique is superior to other techniques especially in retrofitting historic masonry constructions because it does not change the appearance of constructions. With an ordinary cement paste as bonding agent, it is very difficult to insert reinforcing bars at larger open times due to poor workability and very thin clearance available. Here, open time represents the time interval between the injection of bonding agent and the insertion of reinforcing bars. Use of polymer-cement paste (PCP), as bonding agent, is proposed in this study, with investigation on workability and bond strengths of various PCPs in brick masonry, at open times up to 10 minutes, which is unavoidable in practice. Corresponding nonlinear finite element models are developed to simulate the experimental observations. From the experimental and analytical study, the Styrene-Butadiene Rubber polymer-cement paste (SBR-PCP) with prior pretreatments of drilled holes showed strong bond with minimum strength variation at larger open times.

Evaluation of BR Blending Methods for ESBR/silica Wet Masterbatch Compounds

  • Kim, Woong;Ahn, Byungkyu;Mun, Hyunsung;Yu, Eunho;Hwang, Kiwon;Kim, Wonho
    • Elastomers and Composites
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    • v.52 no.4
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    • pp.242-248
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    • 2017
  • Wet masterbatch (WMB) technology is studied to develop high-content and highly disperse silica-filled compounds. This technology refers to the solidification of surface-modified silica with a rubber solution or latex. Until now, researchs based on styrene butadiene rubber (SBR)/silica WMB has been mainly performed. However, the blending of SBR/silica WMB and BR is not known and is currently under research and development. Therefore, in this study, the BR blending method suitable for emulsion (ESBR)/silica WMB is investigated by measuring their cure characteristics and the mechanical and dynamic viscoelastic properties. As a result, it was confirmed that the blending of ESBR/silica WMB and BR/silica dry masterbatch is most appropriate. However, it showed a disadvantage compared with the conventional mixing method, which was due to the surfactant remained and the sulfuric acid used as the coagulant.

Influence of the Binder Types on the Electrochemical Characteristics of Si-C Composites Electrode in LIBs (Si-C 복합체 전극의 바인더 종류에 따른 전기화학적 특성 변화)

  • Jung, Sung-Hun;Ji, Mijung;Park, Geunyeong;Hong, Jongill;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
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    • v.50 no.2
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    • pp.168-172
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    • 2013
  • This work presents the effects of binders on the electrochemical performance of Si-C composites as the anode of lithium ion batteries. PAI (polyamide-imide) was used as an organic binder, and PAN (polyacrylonitrile), PAA (polyacrylic acid) and CMC + SBR (carboxymethyl cellulose + styrene-butadiene rubber) were used as aqueous binders. As a result, stabilization time for the cell with a Si-C composite anode synthesized using aqueous binders became shorter than an organic binder. Particularly in the case of the cell using PAA binder, better performance was observed in terms of adhesion strength, initial efficiency, the volume expansion ratio, Coulombic efficiency, and capacity retention.

Reliability Estimation of Door Hinge for Rome Appliances (가전제품용 경첩의 신뢰성 추정)

  • Kim Jin Woo;Shin Jae Chul;Kim Myung Soo;Moon Ji Seob
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.29 no.5 s.236
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    • pp.689-697
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    • 2005
  • This paper presents the reliability estimation of door hinge for home appliances, which consists of bushing and shaft. The predominant failure mechanism of bushing made of polyoxymethylene(POM) is brittle fracture due to decrease of strength caused by voids existing, and that of shaft made of acrylonitrile-butadiene-styrene(ABS) is creep due to plastic deformation caused by excessive temperature and lowering of glass transition temperature by absorbed moisture. Since the brittle fracture of bushing is overstress failure mechanism, the load-strength interference model is used to estimate the failure rate of it along with failure analysis. By the way, the creep of shaft is wearout failure mechanism, and an accelerated life test is then planned and implemented to estimate its lifetime. Through the technical review about failure mechanism, temperature and humidity are selected as accelerating variables. Assuming Weibull lifetime distribution and Eyring model, the life-stress relationship and acceleration factor, $B_{10}$ life and its lower bound with $90\%$ confidence at worst case use condition are estimated by analyzing the accelerated life test data.

Studies on the Correlation between Coated Paper and Physical Properties of Latices (라덱스의 물성이 도공지 품질에 미치는 상관성에 대한 연구)

  • 박동국;조교동;고문찬;윤재한;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.1
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    • pp.22-29
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    • 2002
  • The coated paper was greatly affected by the basic physical properties of the binder as well as the amount of the coating formula. High glass transition temperature (Tg) of the styrene-butadiene (SB) latex, selected as the binder in our study, gave the high stiffness to the coated paper, but lowered the binding force and print gloss. The average particle size of the SB latex also greatly affected to the coated paper so that the smaller particle size improved the rheological property of the coating formula and increased the binding force and print gloss. Another property of the SBR latex, gel content, was important because when its value was small, the latex was easily deformed at the high temperature and increased air permeability to the coated paper. Therefore, the lower gel content consequently resulted in the higher blistering resistance, especially in the web paper. The larger portion of the SB latex in the coated formula improved the binding force and print gloss, but decreased the ink set-off and ink-trapping to the coated paper. The heavier coating improved optical properties such as opacity, paper gloss and paper smoothness, to the coated paper.

Effect of Vinyl Acetate-Ethylene(VAE) Emulsion on Coated Paper Properties (비닐아세테이트 에틸렌 공중합체 바인더가 도공지의 품질에 미치는 영향)

  • Lee, Yong-Kyu;Won, Jong Myoung;Lee, Woo-Jae;Choi, Yong-Hae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.5
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    • pp.37-43
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    • 2013
  • This study was focused on applying a new paper coating binder, vinyl acetate-ethylene(VAE) emulsion, with SB-latex and acrylic emulsion for paper coating application. VAE emulsion has a low monomer cost and is non-toxic chemical than conventional adhesive for paper coating such as styrene-butadiene latex( SB-latex) and acrylic emulsion. We conducted double coating in order to test VAE emulsion, which was applied on top surface only. The results showed that optical properties of the coated paper with VAE were similar with the SB-latex binders. In case of bonding strength, dry-pick of the coated paper with VAE showed almost same with other binders while wet-pick of the coated paper with VAE had a little bit lower strength than that with SB-latex.

Synthesis and Properties of New Polymeric Photostabilizers Containing HALS Groups (HALS 그룹을 가진 새로운 고분자형 자외선 안정제의 합성 및 특성)

  • 김한식;채규호
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.625-634
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    • 2001
  • New polymeric photostabilizers containing hindered amine light stabilizer (HALS) were prepared by the reaction of liquid polyisoprene rubber grafted maleic anhydride (MAH) and 2,2,5,6-tetramethyl-4-piperidinol (TMPO). Their chemical composition and physical properties were characterized by titration, GPC and TGA analysis. The effects of polymeric HALS on the photooxidation of the styrene-butadiene rubber were studied from the UV, IR spectral changes, and photo-crosslinking was examined by the measurement of the insoluble fraction. The photooxidation of SBR upon irradiation was inhibited by addition of the new polymeric HALS. The extraction resistance of new polymeric photostabilizer was much better than that of the low molecular weight compound which is prepared by the reaction of MAH and TMPO. The new polymeric HALS ate fairly compatible with the SBR.

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Environmentally Friendly Paper with Superior Moisture -Proof Properties(II) -Recyclable properties of moisture-proof paper- (방습 효과가 우수한 환경친화적인 방습지(2보) -방습 도공지의 재생 특성-)

  • 이명구;유재국
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.1
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    • pp.13-18
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    • 2003
  • This study was done in an effort to evaluate the possibility of recyclability of moisture-proof paper. Because it is difficult to recycle laminated moisture-proof paper, a mixture of styrene-butadiene latex(SB latex) and wax emulsion was used as moisture-proof paper chemicals. A bar coater was applied to make moisture-proof paper and the coated weight was 17 g/$m^2$. The mixing ratios of SB latex to wax emulsion were 85 : 15, 87 : 13, and 90 : 10, respectively. It was observed that the moisture-proof paper treated with SB latex and wax emulsion at the appropriate ratio could be recycled effectively. The moisture-proof paper was similar to base paper in degree of pulping, and there was no significant difference in dispersion between moisture-proof paper and base paper. Most of wax particle which caused the spots during drying process could be removed by flotation process. Tensile strength and tear strength of handsheets made of both moisture-proof paper and base paper after pulping was measured to examine the fiber bonding and no significant difference in mechanical properties was observed.

Fatigue Test of 3D-printed ABS Parts Fabricated by Fused Deposition Modeling (FDM 방식으로 제작된 ABS 재료의 피로 특성 평가)

  • Seol, Kyoung-Su;Shin, Byoung-Chul;Zhang, Sung-Uk
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.3
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    • pp.93-101
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    • 2018
  • FDM is one of the popular 3D printing technologies because of an inexpensive extrusion machine and multi-material printing. FDM can use thermoplastics such as ABS and PLA. The 3D-printed ABS parts fabricated by FDM are attractive in the automotive industry because of their weight. A 10% reduction in weight can increase the fuel economy by approximately 7%. To use 3D-printed ABS parts as automotive parts, we should evaluate the 3D-printed parts in terms of automotive reliability. In this study, 3D-printed ABS samples were evaluated using Ono's rotary bending fatigue test. We obtained an S-N curve for the 3D-printed ABS specimen from the finite-element analysis. The S-N curve can be useful in early-stage design decisions for 3D-printed ABS parts.

Measurement of Loss Factor and Young's Modulus of ABS and PP Specimens by Using a Speaker (스피커를 이용한 ABS와 PP의 손실계수 및 영률 측정)

  • Jeon, Byeong Su;Jung, Sung Soo;Lee, Jong Kyu
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.24 no.9
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    • pp.724-730
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    • 2014
  • It is essential to control noise and vibration in various industrial fields. In the automobile industry, various plastics have been developed and replaced metallic materials in order to reduce mass and vibration effectively. In this study, we measured and analyzed the Young's moduli and the loss factors of Acrylonitrile butadiene styrene(ABS) and Polypropylene(PP). In order to solve the fundamental error to determine the two quantities, a loudspeaker was used instead of conventional electromagnetic devices to generate bending motion to the specimens and a laser vibrometer was also used in detection of vibration signal of the specimen. The measured Young's moduli and loss factors of the ABS specimen were nearly constant as the temperature($-10{\sim}60^{\circ}C$) was increased. The loss factor of PP specimen showed peak value at $20^{\circ}C$ and it means that there is glass transition for the PP specimen. Young's modulus of PP specimen was linearly decreased as the temperature was increased.