• Title/Summary/Keyword: styrene-butadiene-styrene

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Effects of Blend Composition and Compatibilizer on the Mechanical Properties of Polypropylene/Acrylonitrile-Butadiene-Styrene Blends (블렌드 조성과 상용화제가 폴리프로필렌/ABS 블렌드의 기계적 물성에 미치는 영향)

  • Park, Jung-Hoon;Sung, Yu-Taek;Kim, Woo-Nyon;Hong, John-Hee;Hong, Byeong-Kwon;Yoo, Tae-Wook;Yoon, Ho-Gyu
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.19-24
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    • 2005
  • Polymer blends containing polypropylene (PP) with compatibilizers were prepared using twin screw extruder. Physical properties were investigated using universal test machine (UTM) and Izod impact tester. In the PP/acrylonitrilebutadiene-styrene (ABS) blends, mechanical strength was increased with the addition of PP-g-styrene acryloritrile (PP-g-SAN) compatibilizer, and the ductility was increased with the addition of ethylene-ethyl acrylate-maleic anhydride (E-EAMAH-g-SAN) compatibilizer. For the PP/ABS/ polycarbonate (PC)/Nylon-6,6 blends, impact strength was increased with the addition of ethylene glycidylmethacrylate (E-GMA compatibilizer) up to 0.5 phr. In the case of the PP/ABS/PC/Nylon-6,6/poly(methyl methacrylate) (PMMA)/poly(oxymethylene) (POM)/poly(vinyl acetate) (PVC)/poly(butylene terephthalate) (PBT) blends, mechanical properties were increased by the complex compatibilizing effects of PP-g-SAN, E-EA-MAH-g-SAN and E-GMA, respectively.

Enhancement in the physical properties of inorganic pigment layer in the color block by incorporation of n liquid additive (액상첨가제에 의한 칼라로도 블록 무기 안료층의 특성 향상)

  • Lee, D.M.;Park, D.W.;Lee, J.H.;Kim, S.M.;Kim, D.Y.;Kim, J.J.;Kim, J.K.;Cho, H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.5
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    • pp.222-226
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    • 2006
  • Effects of a carboxylated styrene-butadiene-based liquid additive on the microstructure, mechanical strength and decolorization resistance of inorganic pigment layer in the color block have been examined. More dense inorganic pigment layer characterized by lower apparent porosity, lower water absorption and uniform pigment distribution has been achieved by incorporation of a liquid additive. Also significant enhancements in the mechanical strength and decolorization resistance have been observed.

The Strength and Durability of Polymer-Cement Mortars (폴리머-시멘트 모르타르의 강도와 내구성)

  • Hwang, Eui-Hwan;Hwang, Taek-Bung;Ohama, Yoshihiko
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.786-794
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    • 1994
  • The strength and durability of polymer-cement mortars were investigated. The specimens of polymer-cement mortar were prepared by using styrene-butadiene rubber(SBR) latex, ethylene-vinyl acetate(EVA) emulsion and polyacrylic ester(PAE) emulsion with various polymer-cement ratios(5, 10, 15, 20wt%). For the evaluation of durability of polymer-cement mortars, freezing-thawing, acid resistance and heat resistance tests were conducted. With an increase of polymer-cement ratio, the frost resistance of polymer-cement mortars was greatly improved, but acid and heat resistance were deteriorated. The compressive and flexural strengths of SBR polymer-cement mortars were improved with an increase of polymer-cement ratio, whereas those of EVA and PAE polymer-cement mortars reached maximum value at polymer-cement ratio of 10wt%.

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Measuring of Loss factor and Young's modulus of Plastics with Temperature Variation (온도변화에 따른 플라스틱의 손실계수와 Young 률의 측정)

  • Shin Su Hyun;Jung Sung Soo;Lee Yong Bong;Lee Doo Hee
    • Proceedings of the Acoustical Society of Korea Conference
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    • autumn
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    • pp.321-322
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    • 2004
  • It is well known that the loss factor and Young's modulus are fundamental mechanical properties of materials. In this study. the dynamic characteristics of plastics are evaluated by using two different standard test methods which are ASTM E 756 and ISO 6721. Polycarbonate and acrylonitrile butadiene styrene were used as test specimens. In order to evaluate vibration of damping properties with temperature, we measured loss factor and Young's modulus of the specimens the temperature range between $-10^{\circ}C$ and $60^{\circ}C$. The Young's modulus for polycarbonate decreased significantly as increasing temperature, while the loss factor increased. However, the Young's modulus and loss factor of acrylonitrile butadiene styrene are varied somewhat with temperature.

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Influence of Filler Composition Ratio on Properties of Both Silica and Carbon Black-Filled Styrene-Butadiene Rubber Compounds (실리카와 카본블랙으로 보강된 SBR 고무 배합물의 특성에 보강제 조성비가 미치는 영향)

  • Choi, Sung-Seen
    • Elastomers and Composites
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    • v.36 no.1
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    • pp.37-43
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    • 2001
  • Influence of the filler composition ratio on cure characteristics and bound rubber content of the compounds and on physical properties of the vulcanizates were studied using both silica and carbon black-filled styrene-butadiene rubber (SBR) compounds with the total filler content of 80.0 phr. The bound rubber content increased slightly with increase of the silica content ratio. The viscosity also increased with increasing the silica content ratio, especially increased steeply after the silica content of 60.0 phr. The cure times obtained with a rheometer, t2, t40, and t90, are increased by increasing the silica content ratio and the cure rate decreased. The delta torque increased with the increased silica content ratio. Variation or the modulus with the silica content ratio showed a decreased trend though the delta torque increased. The tan ${\delta}$ at $60^{\circ}C$ decreased with increased of the silica content ratio.

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Electrical Characteristics Assessment for PE Series Insulations (PE 계열 절연재 전기적 특성 평가)

  • Jung, Jong-Wook;Jung, Jin-Soo;Han, Woon-Ki
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.5
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    • pp.430-435
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    • 2007
  • This paper describes the results of electrical characteristics assessment for organic insulations of polyethylene(PE) series insulations and acrylonitrile butadiene styrene copolymer(ABS). In the experiment, 4 kinds of specimens by composition density were tested in relative permittivity, specific resistance and tracking duration. A WinDETA system and a tracking test set manufactured for this assessment were used to measure the dielectric parameters and tracking duration, respectively. In measuring the tracking duration, the time from testing voltage application to testing circuit breaking due to the tracking current was measured. As a result, dielectric dispersion was observed in measuring the relative permittivity of ABS. It was confirmed that the relative permittivity decreased with the density of the PE series insulations and it depends rather on the temperature than frequency. In most specimens, specific resistance exponentially decreased with frequency and the result for each specimen was almost similar. By the way, in the tracking test, all the PE series insulations showed more excellent performance than ABS and especially in the case of HDPE, its tracking withstand performance was the best.

Rheological Studies, Physico-Mechanical Properties, Thermal Properties and Morphology of PVC/Waste-Gypsum Composites

  • Nguyen, Vu-Giang;Kang, Hae-Jun;Kang, Sang-Yong;Jung, Da-Woon;Ko, Jin-Whoan;Thai, Hoang;Do, Quang-Tham;Kim, Myung-Yul
    • Composites Research
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    • v.27 no.3
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    • pp.115-121
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    • 2014
  • The effect of addition of gypsum on the rheology, physico-mechanical properties, thermal properties and morphology development of polymer composites based on polyvinyl chloride (PVC) and waste-gypsum with and without methylene-butadiene-styrene (MBS) has been studied. It was shown that the replacement of gypsum for methylene-butadiene-styrene (MBS) component in PVC/gypsum polymer composites enhanced the tensile strength and stiffness of composites, but gradually decreased its impact strength. The observation of morphology, the results of the physico-mechanical properties and thermal properties proved simultaneously that PVC/gypsum composite with the waste-gypsum content of 22.56 wt% reached the optimum results among five kinds of PVC/gypsum polymer composite materials investigated.

The Effects of Molding Conditions on the Surface Gloss of ABS Molding (ABS(Acrylonitrile-Butadiene-Styrene) 성형품의 성형조건이 표면 광택에 미치는 영향)

  • Jeong, Yeong-Deug;Hwang, Si-Hyon;Lee, Mi-Hye
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.4 s.97
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    • pp.110-115
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    • 1999
  • The surface gloss of an injection molded part is one of the most significant point for evaluating the quality of products appearance. The effects of process condition on the gloss of ABS(Acrylonitrile-Butadiene-Styrene) molded part were investigated in this work. The measurements of gloss and morphology on the surface of molded part were carried out with different melt temperature, mold temperature, mold surface roughness, injection pressure and holding pressure. Gloss had a maximum value with melt temperature in the range of 210 to 220 ${^\circ}C$ and with mold temperature 40 to 50${^\circ}C$ and with injection pressure 80~90 MPa, respectively. Melt temperature was shown to have the largest effect on gloss in our work. Gloss was not improved in the region of melt temperature 240${^\circ}C$ above and of mold temperature 60${^\circ}C$ above. It was concluded that the variation of gloss was mainly caused by rubber particles migration under shear stress not by their aggregation or necklace.

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Development of Polymer-Concrete Composite(I) - Physical Properties of Polymer-Cement Concrete Composites - (폴리머-콘크리트 복합재료 개발(I) - 폴리머-시멘트 콘크리트의 물성 -)

  • Hwang, Eui-Hwan;Kil, Deog-Soo;Oh, In-Seok
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.979-984
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    • 1997
  • Test specimens of polymer-cement concrete composites were prepared using styrene-butadiene rubber(SBR) latex, ethylenevinyl acetate(EVA) and polyacrylic ester(PAE) emulsions as polymer dispersions in cement modified system at constant slump($10{\pm}0.5cm$), then compressive and flexural strengths water absorption, pore size distribution, and microstructures were investigated. Compressive and flexural strengths of these composites were remarkably improved with an increase of polymer-cement ratio. These composites had a desirable pore size distribution against frost damage due to a small capillary pore volume. Continuous polymer film was able to form in higher than 15% of polymer cement ratio.

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An Environment-Friendly Surface Pretreatment of ABS Plastic for Electroless Plating Using Chemical Foaming Agents

  • Kang, Dong-Ho;Choi, Jin-Chul;Choi, Jin-Moon;Kim, Tae-Wan
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.4
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    • pp.174-177
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    • 2010
  • We have developed an environment-friendly etching process, an alternative to the dichromic acid etching process, as a pretreatment of acrylonitrile-butadiene-styrene (ABS) plastic for electroless plating. In order to plate ABS plastic in an electroless way, there should be fine holes on the surface of the ABS plastic to enhance mechanically the adhesion strength between the plastic surface and the plate. To make these holes, the surface was coated uniformly with dispersed chemical foaming agents in a mixture of environmentally friendly dispersant and solvent by the methods of dipping or direct application. The solvent seeps into just below the surface and distributes the chemical foaming agents uniformly beneath the surface. After drying off the surface, the surface was heated at a temperature well below the glass transition temperature of ABS plastic. By pyrolysis, the chemical foaming agents made fine holes on the surface. In order to discover optimum conditions for the formation of fine holes, the mixing ratio of the solvent, the dispersant and the chemical foaming agent were controlled. After the etching process, the surface was plated with nickel. We tested the adhesion strength between the ABS plastic and nickel plate by the cross-cutting method. The surface morphologies of the ABS plastic before and after the etching process were observed by means of a scanning electron microscope.