• Journal of the Korea Furniture Society
• /
• v.14 no.1
• /
• pp.11-20
• /
• 2003

Wood cell-wall modification with acetic anhydride, lumen filled with styren monomer and methyl methacrylate, and a combination of these two treatments were studied for their effectiveness for dimensional stability. Compared to those of untreated Pinus densiflora Sieb. et Zucc and sole acetylated red pine, The combination of acetylation and impregnation with methy methacrylate greatly reduced water absorption, increased ASE to the best and gave better bending strength and compression strength.

• 제어로봇시스템학회:학술대회논문집
• /
• 1994.10a
• /
• pp.207-212
• /
• 1994

A mathematical model is developed for a batch reactor in which the free radical bulk copolymerization of styrene and acrylonitrile takes place. In this model, we introduce the free volume theory to quantify the diffusion controlled termination and propagation reactions, and develop a model for the chain length dependent termination reaction in the context of the pseudo kinetic rate constant method(PKRCM). The simulation results from this model are found to be in good agreement with experimental data under different copolymerization conditions. The present model can predict both the copolymer composition and the number and weight average molecular weights. These kinetic approaches provide greater insight into the performance of the batch reactor used for the free radical bulk copolymerization of styrene and acrylonitirle.

• The Korean Journal of Rheology
• /
• v.9 no.4
• /
• pp.133-139
• /
• 1997

PC(polycarbonate), SAN(styren-acrylonitrile)공중합체, 그리고 충격 보강제를 근간 으로 하는 다성분계 고분자 블렌드에 대하여 고정된 사출조건에서 블렌드의 조성에 따른 weldline강도의 변화를 조사하였다. 블렌드의 전체적인 함량에 있어서 PC가 그함량이 높아 연속상이 되는 경우가 비교적 높은 weldline강도를 나타내지만 PC함량이 감소함에 따라서 급격한 저하가 발생하여 채-continuity의 성향이 강한 50%부근에서 최소 값을 보였다. PC 함량이 고정되었을 때에는 분산상의 점도가 증가할수록 weldline 강도가 향상되었는데 이는 weldline의 형성 시에 발생하는 분수형 흐름장에 의한 분산상의 배향이 억제되어 외부 응력 에 대하여 균일하게 대응할수 있는 형태학을 유지하는 효과로 설명된다. 충격보강제의 변경 과 상용화제의 적용으로부터 얻은 결과를 종합하여 볼 때 다성분계 고분자 블렌드의 weldline강도는 구성성분간의 상용성 뿐만 아니라 유변학적인 조건이 만족되어야 효과적으 로 향상될수 있다.

• Journal of Environmental Science International
• /
• v.17 no.11
• /
• pp.1255-1263
• /
• 2008

The efficiency of PP-g-AA and PP-g-St nonwoven fabric synthesized by photoinduced polymerization as an adsorbent for removal $NH_3-N$ from waste water was evaluated. The results evidently indicate that the adsorption capacities of $NH_3-N$ onto PP-g-AA nonwoven fabric were extremely superior to those onto sulfonated PP-g-St nonwoven fabric, PK and zeolite. PP-g-AA nonwoven fabric showed the maximum adsorption capacity of $NH_3-N$ at the degree of grafting of 80 wt.%. The adsorption behaviour of $NH_3-N$ onto PP-g-AA and sulfonated PP-g-St nonwoven fabric was controlled by an ion exchange reaction, and tended to be similar to both trends of Langmiur and Freundlish isotherm. Futhermore, PP-g-AA non-woven fabric could be regenerated more than 5 times by a simple washing with 0.1N HCl with no decrease of adsorption capacity and no degradation of physical properties. Also sulfonated PP-g-St nonwoven fabric could be regenerated by washing with 0.1N ${H_2}{O_4}$. However, their regeneration efficiency was significantly low because grafting layer acted as functional radical for adsorption was continuously desquamated in the adsorption or regeneration processes, which resulted in decrease of adsorption capacity and weight of adsorbent. All results obtained from this study indicate that the $NH_3-N$ removal capacity of PP-g-AA non-woven fabric was extremely superior to those of PP-g-St non-woven fabric, PK and zeolite.