• 제목/요약/키워드: structure-property relationships

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천공저항시험에 의한 콘크리트 터널라이닝의 역학적 특성 추정 (Estimation of the Mechanical Properties of the Concrete Tunnel Lining by Drilling Resistance Test)

  • 최순욱;성연창;정호섭;장수호
    • 한국지반공학회논문집
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    • 제23권11호
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    • pp.87-98
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    • 2007
  • 화재 후 터널 구조물의 신속한 복구를 위하여 화재손상 구간을 정확하고 빠르게 파악하는 것이 무엇보다도 중요하다고 할 수 있다. 본 연구에서는 화재로 인한 라이닝 콘크리트의 역학적 특성 변과를 라이닝의 두께방향으로 연속적으로 측정하기 위한 천공저항시험법을 제안하고, 천공시험으로부터 측정된 천공 변수들로부터 모르타르와 콘크리트의 역학적 특성을 추정하고자 하였다. 비교적 균질한 모르타르에 대하여 일련의 천공저항시험을 실시한 결과, 분당회전수가 1,300rpm, 관입속도가 1.40mm/sec, 그리고 비트직경이 10mm인 경우에 측정된 천공 반력값의 편차가 가장 작게 나타나 최적의 시험조건으로 판별할 수 있었다. 최적 시험조건에서 모르타르에 대해 천공저항시험을 실시한 결과, 천공반력과 모르타트의 압축강도 및 탄성계수 사이의 결정계수가 각각 0.91 및 0.93으로 나타나 양호한 상관관계를 도출할 수 있었다. 또한 콘크리트에 존재하는 골재의 영향을 고려하기 위하여 반력 에너지 개념을 제시하였고 실제 압축강도와의 결정계수는 0.94로서 역시 양호한 상관관계를 도출할 수 있었다. 이상과 같이 천공 비트의 관입과 동시에 연속적으로 재료의 역학적 특성을 추정할 수 있는 천공저항시험의 적용 가능성을 파악할 수 있었다.

Structure-Antifungal Activity Relationships of Cecropin A-Magainin 2 and Cecropin A-Melittin Hybrid Peptides on Pathogenic Fungal Cells

  • Lee, Dong-Gun;Jin, Zhe-Zhu;Shin, Song-Yub;Kang, Joo-Hyun;Hahm, Kyung-Soo;Kim, Kil-Lyong
    • Journal of Microbiology and Biotechnology
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    • 제8권6호
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    • pp.595-600
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    • 1998
  • In order to investigate a relationship of the structure-antifungal and hemolytic activities between cecropin A(1-8)-magainin 2(1-12) and cecropin A(1-8)-melittin(1-12) hybrid peptides, several analogues with amino acid substitution at positions 10 (Ile) and 16 (Ser) were designed and synthesized. The increase of the hydrophobicity by substituting with Leu, Phe, and Trp at position 16 in cecropin A(1-8)-magainin 2(1-12) did not have a significant effect on antifungal activity but caused a remarkable increase in hemolytic activity. These results indicate that the hydrophobic property at position 16 of cecropin A(1-8)-magainin 2(1-12) is more correlated to hemolytic activity than to antifungal activity. Replacement with Pro at position 10 of cecropin A(1-8)- magainin 2(1-12) and cecropin A(1-8)-melittin (1-12) caused a remarkable decrease in a-helical contents in the 50% TFE solution and induced a reduction in lytic activity against Aspergillus flavus, and Aspergillus fumigatus. These results demonstrate that flexibility at the central hinge region is essential for lytic activity against fungal cells and $\alpha$-helicity of the peptides.

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Effect of the Calcium Nitrate Solution Treatment on the Tensile, Bending, and Shear Properties of Silk Fabric

  • Park, Su-Zin;Kang, Ji-Young;Seol, Da-Won;Yang, Hye-Min;Lee, Ji-Min;Ahn, Ye-Ji;Han, Seo-Young;Kim, Jong-Jun
    • 패션비즈니스
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    • 제14권6호
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    • pp.39-52
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    • 2010
  • Interests in creating three-dimensionally designed fabric materials are growing rapidly in the sectors of the fashionable textiles with the creativity, new functions, and aesthetics. A number of finishing methods have been developed and proposed to add or create new functions and designs for silk fabrics. Due to the strong hydrogen bonds between the molecules of silk fibroins, the thermal treatment methods used in thermoplastic fiber processing, which can easily deform the synthetic filament fabrics to endow three-dimensional appearance to the fabrics, are not applicable to the silk fabric treatment. In order to modify the fine structure of silk fiber, neutral salt solution treatment methods have been suggested. In this study, the effect of the calcium nitrate solution on the physical and mechanical properties of silk fabrics was investigated by using the KES(Kawabata Evaluation System) equipment. Based on these findings, relationships between parameters, for example, the thickness and the compressional energy, the thickness and the compressional linearity, and the air permeability and the pore area statistical analysis were investigated. The relationships between the process parameters such as treatment temperature/time and the resulting fabric property parameters were also analyzed by using several SAS procedures.

인실리코 해석을 통한 단일벽 질화붕소 나노튜브의 크기 변화에 따른 압전탄성 거동 예측연구 (An In-silico Simulation Study on Size-dependent Electroelastic Properties of Hexagonal Boron Nitride Nanotubes)

  • 이재원;양승화
    • Composites Research
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    • 제37권2호
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    • pp.132-138
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    • 2024
  • 본 연구에서는 분자동역학 전산모사를 통해 육방정계 단일벽 질화붕소 나노튜브(BNNT)의 반경 변화에 따른 압전탄성 변화를 규명하였다. 질화붕소의 거동을 비교적 잘 모사하는 Tersoff 포텐셜과 기계적 하중인가에 따른 질소 및 붕소원자의 상대변위로 인한 분극의 정량화를 위해 강체 이온 근사를 채택하였다. 선형 압전탄성 구성방정식을 기반으로 각각의 질화붕소에 변형률을 인가하고 이에 따른 전기적 변위와 응력을 산출하여 압전상수와 영률을 각각 예측하였다. 그 결과, BNNT의 압전상수는 반경이 증가함에 따라 점진적으로 감소하는 양상을 보였다. 반면 탄성계수의 경우 불연속적 구조를 가지는 질화붕소를 등가의 연속체 구조로 등가시키는 방법에 따라 증가 또는 감소하는 경향을 보였다. BNNT의 곡률변화에 따른 물성변화를 가상실험에 기반한 경험적 모델로 근사하기 위해 BNNT의 튜브반경-압전탄성물성 간 상관관계식을 제안하였다. 또한 BNNT의 반경변화에 따른 물성을 곡률의 관점에서 설명하기 위해, BNNT와 질화붕소 나노시트(BNNS)의 결합에너지와 탄성변형에 따른 원자간 결합길이 변화가 각각의 구조의 변형에너지 증가에 기여하는 정도를 상호 비교하였다.

Estimation of Physical-Chemical Property and Environmental Fate of Benzoyl peroxide Using (Q)SAR

  • Kim, Mi-Kyoung;Kim, Su-Hyon;Heekyung Bae;Sanghwan Song;Hyunju Koo;Jeon, Seong-Hwan;Na, Jin-Gyun;Park, Kwangsik;Lee, Moon-Soon
    • 한국환경독성학회:학술대회논문집
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    • 한국환경독성학회 2002년도 추계국제학술대회
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    • pp.154-154
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    • 2002
  • Benzoyl peroxide is a High Production Volume Chemical, which is produced about 1,375 tons/year in Korea as of 2001 survey. The substance is mainly used as initiators in polymerization, catalysts in the plastics industry, bleaching agents for flour and medication for acne vulgaris. The substance is one of seven chemicals of which human health and environmental risks are being assessed by National Institute of Environmental Research (NIER) under the frame of OECD SIDS Program. In this study, Quantitative Structure-Activity Relationships (QSAR) is used for getting adequate information on the physical-chemical property and the environmental fate of this chemical. For the assessment of benzoyl peroxide, models such as MPBPWIN for vapor pressure, KOWWIN for octanol/water partition coefficient, HENRYWIN for Henry's Law constant, AOPWIN for photolysis and BCFWN for bioconcentration factor (BCF) were used. These (Q)SAR model programmes were worked by using the SHILES (Simplified Molecular Input Line Entry System) notations. The physical-chemical properties and the environmental fate of benzoyl peroxide were estimated as followed : vapor pressure =0.00929 Pa, Log Kow = 3.43, Henry's Law constant = 0.00000354 atm-㎥/mole at 25 $^{\circ}C$, the half-life of photodegradation = 3 days, bioconcentration factor (BCF) = 92

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신경회로망을 이용한 RF 스퍼터링 ZnO 박막 증착 프로세스 모델링 (Modeling of RF Sputtering Process for ZnO Thin film Deposition using Neural Network)

  • 임근영;이상극;박춘배
    • 한국전기전자재료학회논문지
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    • 제19권7호
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    • pp.624-630
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    • 2006
  • ZnO deposition parameters are not independent and have a nonlinear and complex property. To propose a method that could verify and predict the relations of process variables, neural network was used. At first, ZnO thin films were deposited by using RF magnetron sputtering process with various conditions. Si, GaAs, and Glass were used as substrates. The temperature, work pressure, and RF power of the substrate were $50\sim500^{\circ}C$, 15 mTorr, and $180\sim210W$, respectively : the purity of the target was ZnO 4 N. Structural properties of ZnO thin films were estimated by using XRD (0002) peak intensity. The structure of neural network was a form of 4-7-1 that have one hidden layer. In training a network, learning rate and momentum were selected as 0.2, 0.6 respectively. A backpropagation neural network were performed with XRD (0002) peak data. After training a network, the temperature of substrate was evaluated as the most important parameter by sensitivity analysis and response surface. As a result, neural network could capture nonlinear and complex relationships between process parameters and predict structural properties of ZnO thin films with a limited set of experiments.

Mix Design for Pervious Recycled Aggregate Concrete

  • Sriravindrarajah, Rasiah;Wang, Neo Derek Huai;Ervin, Lai Jian Wen
    • International Journal of Concrete Structures and Materials
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    • 제6권4호
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    • pp.239-246
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    • 2012
  • Pervious concrete is a tailored-property concrete with high water permeability which allow the passage of water to flow through easily through the existing interconnected large pore structure. This paper reports the results of an experimental investigation into the development of pervious concrete with reduced cement content and recycled concrete aggregate for sustainable permeable pavement construction. High fineness ground granulated blast furnace slag was used to replace up to 70 % cement by weight. The properties of the pervious concrete were evaluated by determining the compressive strength at 7 and 28 days, void content and water permeability under falling head. The compressive strength of pervious concrete increased with a reduction in the maximum aggregate size from 20 to 13 mm. The relationship between 28-day compressive strength and porosity for pervious concrete was adversely affected by the use of recycled concrete aggregate instead of natural aggregate. However, the binder materials type, age, aggregate size and test specimen shape had marginal effect on the strength-porosity relationship. The results also showed that the water permeability of pervious concrete is primarily influenced by the porosity and not affected by the use of recycled concrete aggregate in place of natural aggregate. The empirical inter-relationships developed among porosity, compressive strength and water permeability could be used in the mix design of pervious concrete with either natural or recycled concrete aggregates to meet the specification requirements of compressive strength and water permeability.

Changes in Mechanical Properties of Wood Due to 1 Year Outdoor Exposure

  • KIM, Gwang-Chul;KIM, Jun-Ho
    • Journal of the Korean Wood Science and Technology
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    • 제48권1호
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    • pp.12-21
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    • 2020
  • For quantitative evaluation of wooden structures, the mechanical performance of members has undergone outdoor exposure tests. A year-long monitoring was conducted using an SPF species. Test groups were divided into twelve (each month) to measure the moisture content, density and ultimate load. Starting from May when moisture content of the test group was at the lowest, simple failure modes were observed more frequently during the first half of the experiment, whereas complex failure modes took over during the second half. Starting from June when moisture content of the test group was the highest, ultimate load decreased by 30% in the second half compared to the first half. A multiple regression analysis confirmed that moisture content of the test group was the variable with most effect on ultimate load of various outdoor variables, and an estimation equation of a simple regression analysis revealed that moisture content and ultimate load formed an inversely proportionate relationship. It is thought that correlational relationships of variables other than moisture content could be applied with the increase in added data amount by longer periods of outdoor exposure tests.

폴리우레탄 폼의 미세구조와 흡음 관계 밑 Low Monos 폴리올의 응용 (Microstructure-Sound Absorption Relationships of Polyurethane Foam and Application of Low Monos Polyol)

  • 이부연;김소연;이광희;진병석
    • 폴리머
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    • 제31권4호
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    • pp.289-296
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    • 2007
  • 셀 구조는 유사하나 흡음성능에서 차이가 있는 시편을 사용하여 폴리우레탄 폼의 흡음성능을 예측할 수 있는 인자들을 FT-IR, 소각 X-선 산란(SAXS)과 dynamic mechanical thermal analyzer(DMTA)로 조사하였다. 그 결과, 전이영역에서의 damping 특성이 흡음성능과 가장 밀접한 관계가 있음을 알 수 있었다. 최근 개발된 low monol 폴리올(LMP)을 흡음용 폴리우레탄 폼에 적용할 수 있는가를 검토하기 위하여 LMP와 산화프로필렌계 폴리올(PPG)을 기본으로 한 폴리우레탄을 용액중합법으로 제조하고, 이들의 내부구조와 물리적 성질을 상호 비교하였다. Monol 성분을 다량 포함하는 PPG는 LMP에 비하여 분자 유동성이 커서 보다 발달된 상분리 구조를 보여주었다. 그러나 monol 성분에 의해 고분자량으로 성장하지 못한 분자사슬의 비효율적인 damping 거동으로 인하여 LMP의 경우가 PPG에 비하여 전이영역이 넓고, damping 양도 훨씬 더 컸다.

공간구조분석을 위한 시뮬레이션 추적 분석에 관한 연구 (A Study on Simulation tracking analysis for Spatial configuration analysis)

  • 박종현;이종렬
    • 한국디지털건축인테리어학회논문집
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    • 제9권3호
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    • pp.95-102
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    • 2009
  • An architectural space can be considered a life form that interconnects a number of architectural elements such as the humans who live in it. It is difficult to understand and evaluate the complexity of the interrelation between each element, but there have been various attempts to understand and evaluate this architectural space. The Space Syntax that emerged in 1980s has been studied and used more frequently than other methods. Space Syntax is the space analysis tool that analyzes the physical structure of space and represents it as a graph. Space syntax enables its various applications in space analysis by quantifying each spatial property of a whole structure, analyzing it systemically and objectively based on mathematical logic, and representing the results as a quantitative value. Integration of Space Syntax, a widely used index, reflects human behavior in spatial configuration. Meanwhile, there have been various studies in the field of architectural environmental psychology about the relationships between space and human behavior by applying behavioral science to architectural plan. One of the most widely used one is spatial behavior simulation which uses models and simulates the behavioral characteristics to anticipate practical situations and investigate the behavior related spatial problems. In this study, which focuses on the accessibility of the space syntax model, the usefulness of space will be analyzed through the simulation of human behavior that moves through each space. Furthermore, the validity of index will be verified by displaying several examples and compared with integration in space syntax, which represents the usefulness of space.

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