• Title/Summary/Keyword: structure of charcoal

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An Experimental Study on Indoor Pollutant Reduction of Cementitious Composite Using Charcoal and Phytoncide (숯과 피톤치드를 사용한 시멘트계 복합재의 실내 오염물질 저감에 관한 실험적 연구)

  • Jeong, Hyeon-Woo;Jeong, We-Young;Jung, Yoong-Hoon;Han, Song-Yi;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.1
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    • pp.13-19
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    • 2021
  • In modern society, indoor activities time is increasing due to industrial development. Interest in indoor air quality is increasing as indoor activity time increases. The main causes of indoor air pollution are formaldehyde which a chemical cause, and fungi which a biological cause. Phytoncide effectively reduces Formaldehyde and Fungi. Charcoal which possess porous-structure has a good absorbance of pollutants. In this study, the authors manufactured functional cement matrix using by phytoncide and charcoal to remove formaldehyde and fungi. In this study, Functional cement matrix reduced formaldehyde and Fungi and effectively improve indoor air quality.

A Study on Tree-ring Dating and Speciation of Charcoal found in Pumiceous Deposit of the Quaternary Nari Caldera, Ulleung Island, Korea (신생대 제4기 울릉도 나리칼데라 부석층에서 산출된 탄화목의 연륜연대 및 수종식별 연구)

  • Im, Ji Hyeon;Choo, Chang Oh
    • Economic and Environmental Geology
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    • v.48 no.6
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    • pp.501-508
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    • 2015
  • The purpose of this study is to provide an inquiry into paleovegetation (paleoenvironment), eruption age and inferred emplacement temperature of pyroclastic deposit using charcoal occurred in the Quaternary Nari Caldera, Ulleung Island. In order to obtain the data, we carried out species identification and tree-ring analysis, radiocarbon dating for the charcoal. This sample was collected from pumiceous deposit in lowermost member(Member N-5) of the Nari Tephra Formation, which corresponds to the wood branch that has well preserved the tree-ring structure. Speciation and outermost tree-ring of wood reveal Picea spp. and $263+{\alpha}$ years. The calibrated ages from the center(pith) to the outermost tree-ring are $20,260{\pm}230$, $19,995{\pm}245$, and $19,975{\pm}265cal\;BP$, respectively, which are accordant with the tree-ring position. The youngest age, <19,710 cal BP would have implications for the eruptive age of Member N-5. Our results indicate that Picea spp. is the paleovegetation representing that Nari Caldera was under cold and wet climate conditions during the late Pleistocene. Based on the silky luster, brittleness, color, and streak of charcoal, etc., the lowest emplacement temperatures of pyroclastic flow are interpreted to have been at least as high as $350{\sim}500^{\circ}C$.

Characterization of Pine Bark Charcoal Prepared from Small and Large-Scale Carbonization Kilns (소용량 및 대용량 탄화로에서 제조된 소나무 수피탄의 특성)

  • 문성필;황의도;박상범;권수덕
    • Journal of Korea Foresty Energy
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    • v.21 no.2
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    • pp.1-9
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    • 2002
  • Pine bark was carbonized by using a small-scale experimental kiln and three different types of large-scale kilns (simple (400-$500^{\circ}C$), improved (600-$700^{\circ}C$) and special kiln (800-$1,000^{\circ}C$). The physical properties and pore structures of the bark charcoals prepared were analyzed. When the bark was carbonized at various temperatures ranging from 500 to $900^{\circ}C$in the presence of nitrogen, carbonization yield decreased rapidly with increasing carbonization temperature and it remained constant from 700 to $900^{\circ}C$. The carbonization yield of the bark was 16 - 18% higher than that of pine wood. The BET specific surface areas and iodine values increased with a decrease in carbonization yield. The BET specific surface areas of the bark charcoals reached about 400 -$500m^2/g$ for carbonization yield of 32-40%. The pine wood charcoal prepared at $600^{\circ}C$ for 30 min resulted in a more microporous structure, whereas the bark charcoal prepared at the same condition was more mesoporous. The carbonization yields and physical properties such as iodine values and BET specific surface areas of bark charcoals prepared by using the large-scale kilns were very similar to those of the small-scale kiln. The results indicated that the pine bark could be used as starting material to produce good quality charcoal having a large specific surface area and a high carbonization yield.

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Analysis of Structure and Physical and Chemical Properties of the Carbonized Powder of Pine Wood (Pinus densiflora Sieb. et Zucc.) (II) - FT-IR, Raman - (가열처리 및 탄화처리 소나무재(Pinus densiflora) 목분의 구조 및 물리·화학적 특성(II) - FT-IR, Raman -)

  • Lee, In-Ja;Lee, Won-Hee
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.4
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    • pp.52-57
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    • 2008
  • In this study, the effects of carbonization temperature on the physico-chemical properties of porous wood charcoal are studied by FT-IR and Raman spectroscopies. IR studies showed that cellulose and hemicellulose are mostly decomposed in the precarbonization stage at $500^{\circ}C$, while the decomposition reaction of relatively more stable lignin lasts up to $700^{\circ}C$. Above $900^{\circ}C$, the peak at $1575cm^{-1}$ disappears and a new peak at $1630cm^{-1}$, which seems to be related to the new carbon deposit phase, is evolved. The results of Raman studies, which show the red-shift of D-band and the increase in the relative intensity of D- to G-band, indicate that the size of the crystalline becomes smaller with increasing the carbonization temperature.

Analysis of Species and Manufacturing Techniques for Wood Coffins of Bae's Family, Excavated in Youngdong, Korea (영동지역 배씨 문중 목관의 수종 및 가공법 분석)

  • Kim, Mun-Sung;Park, Won-Kyu
    • Journal of the Korea Furniture Society
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    • v.20 no.1
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    • pp.95-104
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    • 2009
  • The study was carried out to analyze wood quality of coffin board, the wood species of coffin excavated in Youngdong, Korea. All coffin woods were identified as hard pines, Korean red pine(Pinus densiflora S. & Z.). According to wood quality of coffins, inner coffins of Bae Cheon-Jo and his wife showed similarity and dissimilarity comparing with several literatures. The similarity was in the structure of panels, bottom lining board and charcoal layer, and the dissimilarity was in jointing. From the analysis of fibrous materials attached to coffin woods, the paper mulberry and cotton fibers were identified. In the inner coffin of Bae Cheon-Jo, tool traces by handle planer were observed.

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Analysis of Species and Tree-Ring Dating of Wood Elements Used for the Daewoongjeon Hall of Youngguksa Temple (영국사 대웅전 목부재의 수종 및 연륜연대 분석)

  • Son, Byung-Hwa;Park, Won-Kyu;Yoon, Doo-Hyung
    • Journal of architectural history
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    • v.15 no.2
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    • pp.23-38
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    • 2006
  • During the repair and restoration of the Daewoongjeon Hall of Youngguksa Temple, species identification and tree-ring dating for both present wood elements and charred ones excavated under the Hall, were conducted. The species of 74 wood elements of Daewoongjeon Hall, were identified as Pinus densiflora Sieb. et Zucc. and only 1 was identified as exotic Pinus species. The latter wood, which was used in the laths, seems to have been replaced during past repairs. Many documentary records and various artifacts pertaining to Youngguksa Temple are being excavated, but none described precisely the construction date of the present Daewoongjeon Hall. Also, from beneath the Daewoongjeon Hall, cornerstone and foundation of previous building and several charred wood elements were excavated. In comparing the direction of the stone columns of foundation of the previous structure and the existing Daewoongjeon Hall, the previous structure was rotated in an angle of approximately $15^{\circ}$. Therefore, in order to find the association of the previous structure with the present Daewoongjeon Hall, tree-ring dating was conducted. The dating of 41 original timbers and 14 roof-filling timbers of the present construction elements revealed that the last annual ring was of A. D. 1703 with complete latewood, indicating that those woods was cut some time between the autumn of 1703 and spring of 1704, and the building was erected in 1704 when we assume no period of wood storage. The year of the last annual ring of the charred elements, which were excavated from beneath the Daewoongjeon Hall, was analyzed as 1674. The cutting year of the woods used for the present building began in 1698, therefore, it can be presumed that the Daewoongjeon Hall before the fire was a structure that was elected shortly after 1674 and that a catastrophic fire occurred some time between 1674 and 1698.

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Investigation of Carbonization Mechanism of Wood (II) (목재의 탄화기구 해석(II))

  • Kwon, Sung-Min;Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.3
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    • pp.45-52
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    • 2007
  • The anatomical characteristics of Quercus variabilis woods carbonized at 310 to $350^{\circ}C$ were examined with an optical and scanning electron microscopy, and an X-ray diffraction analysis. Dimensional change and weight loss were also investigated. Volume of wood samples decreased with increasing the carbonization temperature, and checks were developed along with radial direction. Vessel diameter in tangential direction showed higher shrinkage than that in radial direction. Weight loss of samples increased with increasing carbonization temperature. Especially, the weight loss rapidly increased at the temperature ranging from 330 to $340^{\circ}C$. SEM study presented that the cell walls of samples carbonized at below $320^{\circ}C$ showed the layering structure. However, it was revealed that the layering structure was disappeared at $330^{\circ}C$ and over and showed an amorphous-like structure without cell wall layering. Interestingly, the existence of cellulose crystalline substance at $340^{\circ}C$ was confirmed by X-ray diffraction analysis and it was not detected at $350^{\circ}C$. Consequently, it is considered that the critical temperature for carbonization of wood was around $350^{\circ}C$.

Electrochemical characteristics of active carbon prepared by chemical activation for anode of lithium ion battery (이차전지 음극용 화학적 활성화법으로 제조된 활성탄의 전기화학적 특성)

  • Lee, Ho-Yong;Kim, Tae-Yeong;Lee, Jong-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.480-487
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    • 2015
  • In this study, several kinds of active carbons with high specific surface area and micro pore structure were prepared from the coconut shell charcoal using chemical activation method. The physical property of prepared active carbon was investigated by experimental variables such as activating chemical agents to char coal ratio, flow rate of inert gas and temperature. It was shown that chemical activation with KOH and NaOH was successfully able to make active carbons with high surface area of $1900{\sim}2500m^2/g$ and mean pore size of 1.85~2.32 nm. The coin cell using water-based binder in the electrolyte of LiPF6 dissolved in mixed organic solvents (EC:DMC:EMC=1:1:1 vol%) showed better capacity than that of oil-based binder. Also, it was found that the coin cell of water-based binder shows an improved cycling performance and coulombic efficiency.

Properties of Porous SiC Ceramics Prepared by Wood Template Method

  • Ha, Jung-Soo;Lim, Byong-Gu;Doh, Geum-Hyun;Kang, In-Aeh;Kim, Chang-Sam
    • Journal of the Korean Ceramic Society
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    • v.47 no.4
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    • pp.308-311
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    • 2010
  • Porous SiC samples were prepared with three types of wood (poplar, pine, big cone pine) by simply embedding the wood charcoal in a powder mixture of Si and $SiO_2$ at 1600 and $1700^{\circ}C$. The basic engineering properties such as density, porosity, pore size and distribution, and strength were characterized. The samples showed full conversion to mostly $\beta$-SiC with good retention of the cellular structure of the original wood. More rigid SiC struts were developed for $1700^{\circ}C$. They showed similar bulk density ($0.5{\sim}0.6\;g/cm^3$) and porosity (81~84%) irrespective of the type of wood. The poplar sample showed three pore sizes (1, 8, $60\;{\mu}m$) with a main size of $60\;{\mu}m$. The pine sample showed a single pore size ($20\;{\mu}m$). The big cone pine sample showed two pore sizes (10, $80\;{\mu}m$) with a main size of $10\;{\mu}m$. The bend strength was 2.5 MPa for poplar, 5.7 MPa for pine, 2.8 MPa for big cone pine, indicating higher strength with pine.

Metallugical Study on the Iron Artifaets Ecavated from Buso Sangong (부소산성 출토 고대 철기유물에 대한 금속학적 연구)

  • Im, Seon-Gi;Gang, Dae-Il;Mun, Hwan-Seok;Park, Dong-Gyu;Gang, Seong-Gun
    • 보존과학연구
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    • s.13
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    • pp.37-58
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    • 1992
  • Iron artifacts from Busǒ Sansǒng inffered to late Baikjae periodwere studied on the aspects of metallugy. These materials were the largest size ever since excavated. From the analytical results these artifacts were found to be pureiron system without impurities or hypo-eutectoid steel system in below 0.3% in carbon contents. From the content of phosphorus in the range of 0.03∼0.05% as aim purity it was shown that charcoal were used for making these iron artifacts from sponge iron not fusion method. By observing metallugical structure it was found that iron artifacts was manufactured by repetitive folding and hammering forging method and some by heating method for adding carbon with cool water. This method were to improve the quality of the soften steel to harden one. In addition to those above repetitive hammering method eliminated the nonferrous materials such as slag inclusion and remained relatively pure ferrite.

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