• Title/Summary/Keyword: structure equation

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Study on the Non-isothermal Crystallization Kinetics of Branched Polypropylene (분지형 폴리프로필렌의 비등온결정화 거동 연구)

  • Yoon, Kyung-Hwa;Shin, Dong-Yup;Kim, Youn-Cheol
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.245-250
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    • 2012
  • Branched polypropylenes (PP) with long chain branch were prepared by solid state reaction with three different branching agent of 0.3 wt% content. The chemical structures, non-isothermal crystallization behavior and complex viscosity of the branched PP were investigated by FTIR, DSC, optical microscope, and dynamic rheological measurement. The chemical structure of the branched PP was confirmed by the existence of =C-H stretching peak of the branching agent at 3100 $cm^{-1}$. There was no distinct change in melting temperature in case of PP-D-0-3 and PP-F-0-3, but PP-H-0-3 indicated a decrease in melting temperature. The decrease in melting temperature was interpreted by the fact that the degradation reaction of PP was more dominant than branched reaction, and confirmed by a decrease in complex viscosity. The non-isothermal crystallization behavior of the branched PP was analyzed using by Avrami equation. The Avrami exponent of PP was 3, and the values of the branched PP with DVB and FS were below 3. The activation energy of PP calculated by Kissinger method was 25 kJ/mol, and there were no big difference in activation energies of the branched PPs compared to PP.

2-Dimensional Equilibrium Analysis and Stability Analysis of Geotextile Tube by Hydraulic Model Test (지오텍스타일 튜브의 2차원 평형해석 및 수리모형시험을 통한 안전성 분석)

  • 신은철;오영인
    • Journal of the Korean Geotechnical Society
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    • v.18 no.5
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    • pp.251-260
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    • 2002
  • Geotextile tribes are made of sewn geotextile sheet and hydraulically or mechanically filled with dredged materials. They have been applied in hydraulic and coastal engineering in recent years(shore protection structure, detached breakwater, groins, and jetty). Therefore, it is composed of geotextile and confined fill material. Recently, new preliminary design criteria supported by model and prototype tests, and some stability analysis calculations have been studied. The stability analysis of geotextile tube is composed of geotechnical and hydrodynamic analysis. The stability check points are sliding failure, overturning, bearing capacity failure against the wave attack. In this paper are presented the stability analysis method by empirical equation and 2-D equilibrium analysis for geotextile tube. Also, the hydraulic model tests were performed to verify the theoretical stability analysis with geotextile tube shape, filling ratio, significant wave height, and so on. The results of this study show that the stability of geotextile tube depends on the tube shape, contact area, projection area. The theoretical analysis and hydraulic model test show almost the same results.

The Effects of work and psychosocial stress on job satisfaction, organizational commitment, and leaving intention in general hospital female office workers (종합병원 사무직 여성의 직무 및 사회심리적 스트레스가 직무만족, 조직몰입, 이직의향에 미치는 영향)

  • Lee, Jeong-Hyun;Cho, Woo-Hyun;Chang, Sei-Jin;Kim, Young-Hoon
    • Korea Journal of Hospital Management
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    • v.17 no.1
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    • pp.1-22
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    • 2012
  • This study tires to examine affects that job and socio-psychological stresses of female office workers influence job satisfaction, organization commitment, and leaving intentions. A complete data are collected by conducting a survey with 240 female office workers from 9 medical institutions regarded as almost general hospital in Seoul. It is analyzed that the relation between socio-psychological stress and job satisfaction, organization commitment, and leaving intentions by using t-test; analysis of variance; correlation analysis; principal component analysis; linear structural equation modeling; etc. The results of this study are summarized as following. First, as it was comprehended by specific characteristics of subjects that the female office workers' level of job and socio-psychological stress, job satisfaction, organizational commitment, and leaving intention, there were statistically significant distinctions from their age, marital status, presence of children, position in the organization, type of employment, and monthly average income. Second, this study regarded relationship between the female office workers' level of job and socio-psychological stresses, job satisfaction, organizational commitment, and leaving intention. Job and socio-psychological stresses were negatively correlated with job satisfaction and organizational commitment, but the stresses were positive with leaving intention. Third, after evaluating effect that 8 features related to the job stress could influence job stress, the most effective valuables were in order to unfairness in organizational structure, workplace culture, inadequate compensation, and relationship conflict. Fourth, when looking at the overall effects of the job and sociopsychological stresses on job satisfaction, organizational commitment, and leaving intention, work autonomy was the most influencing factor of work stress levels. The level of the job stress seemed to be a prevalent impact on the leaving intention and it showed the most negative relationship that path coefficient from leaving intention to organizational commitment and also from organizational commitment to job satisfaction. Based on these findings, it can be defined that the job and socio-psychological stresses strongly influence job satisfaction, organizational commitment, and leaving intention.

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Typical Seismic Intensity Calculation for Each Region Using Site Response Analysis (부지응답해석을 이용한 지역별 대표 진도 산출 연구)

  • Ahn, Jae-Kwang;Son, Su-Won
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.1
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    • pp.5-12
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    • 2020
  • Vibration propagated from seismic sources has damping according to distance and amplification and reduction characteristic in different regions according to topography and geological structure. The vibration propagated from the seismic source to the bedrock is largely affected by the damping according to the separation distance, which can be simply estimated through the damping equation. However, it is important to grasp geological information by location because vibration estimation transmitted to the surface are affected by the natural period of the soil located above the bedrock. Geotechnical investigation data are needed to estimate the seismic intensity based on geological information. If there is no Vs profile, the standard penetration tests are mainly used to determine the soil parameters. The Integrated DB Center of National Geotechnical Information manages the geotechnical survey data performed on the domestic ground, and there is the standard penetration test information of 400,000 holes. In this study, the possibility of quantitation the amplification coefficient for each region was examined to calculated the physical interactive seismic intensity based on geotechnical information. At this time, the shear wave column diagram was generated from the SPT-N value and ground response analysis was performed in the target area. The site coefficients for each zone and the seismic intensity distribution for the seismic motion present a significant difference according to the analysis method and the regional setting.

A Study on Viscous Damping System of a Ship with Anti-Rolling Pendulum (안티롤링 진자를 장치한 선박의 점성감쇠계 해석에 대한 연구)

  • Park, Sok-Chu;Jang, Kwang-Ho;Yi, Geum-Joo
    • Journal of Navigation and Port Research
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    • v.41 no.6
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    • pp.365-372
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    • 2017
  • The rolling motion of a floating body makes crews and passengers exhausted and/or applies forces to the structure to cause damage; it might even upset the body. Therefore, almost all ships are equipped with bilge keels for anti-rolling; in special cases, an anti-rolling tank(ART) or fin stabilizer or gyroscope could be installed. But an ART requires a large capacity to install it, and a fin stabilizer and gyroscope need great costs to install and also many expenses to operate. The authors suggest the use of an anti-rolling pendulum(ARP), and they showed that the ARP is effective to reduce rolling by experiments and via a Runge-Kutta analysis. This paper introduces the linearized 2 degrees of freedom with a viscous damping system for a ship equipped with ARP; it also shows the validation of the linearized analysis for the ship's roll motion. The paper proposes an optimum ARP on the basis of the justified model. The case of the 7.7kg model with ship 20g ARP of a mass ratio of 0.26%, is the most effective for reducing roll motion. The paper shows the ARPs with various mass ratios are effective for reducing the roll motion of a ship by free decaying roll experiments.

Differences in Panicle Structure and Spikelet Degeneration in Two Different Types of Rice Cultivars; Milyang 23 and Koshihikari (벼 품종 밀양 23호와 고시히카리의 수형태와 영화 퇴화 차이)

  • 강시용
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.6
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    • pp.833-840
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    • 1997
  • Differentiation and degeneration of spikelets in paddy rice has been studied in high yielding Indica$\times$Japonica hybrid cultivar, Milyang 23 and a Japonica type cultivar, Koshihikari. Germinated seeds planted in 5000$^{-1}$ a pots filled with submerged soil and cultured under natural conditions. The young panicles of main stem were continuously dissected and observered by Cryo-SEM from the panicle initiation stage, and investigated about formation position of the differentiation and degeneration spikelet within a panicle of 7 days after heading. The degeneration of spikelet appeared simultaneously throughout panicle just after closure of spikelet by the palea and lemma. Differentiated and degenerated spikelets per panicle were about 240, 80 for Milyang 23 and 87, 6 for Koshihikari, respectively. The spikelets degeneration in Milyang 23 was mainly on the secondary and tertiary branch which were developed from primary branch of middle-basal panicle node and hardly not the spikelets of primary branch, and degeneration rate of secondary and tertiary rachis branch and spikelets for Milyang 23 were 2.5 times greater than those of Koshihikari. The proper relation equation between total differentiation or normal spikelets number per panicle(Y) and each rachis branch number were different between cultivars, Le., Y=5.5X$_1$+3.0X$_2$ for Koshihikari as previously proposed, but those of Milyang 23, Y=5.7X$_1$+3.5X$_2$+2.8X$_3$ for total differentiation spikelets and Y=5.6X$_1$+3.2X$_2$+2.4X$_3$ for normally developed spikelets, where X$_1$, X$_2$, X$_3$ are number of primary, secondary, tertiary rachis branch, respectively.

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A Study on the effect of Spectrum difference between Cellular and PCS from Mobile Telecommunication Customer's perspective

  • Youn, Young-Seog;Cho, Byung-Sun;Ha, Young-Wook
    • Journal of Korea Technology Innovation Society
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    • v.9 no.4
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    • pp.627-653
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    • 2006
  • The purpose of this study lies in understanding how the spectrum assigned for each mobile operator affects the consumers of mobile service. For this purpose, we have observed the change of path coefficient in the structural equation, using control variables. However, the structure of the mobile service market in Korea has become fixed. Considering this tendency and the conclusion of this study, the 'lock-in effect' occurs seriously in the mobile service market in Korea. It can be explained by the fact that CS(Customer Satisfaction) of the cellular subscribers little affects customer loyalty but the market dominance of the cellular service in the actual market has continued for a long time. In this study, we figured out a strong prejudice about call quality, which is caused by spectrum difference among competitors. Cellular subscribers tends to believe that call quality of their cellular service is better than that of PCS. In addition, we found that PCS operators can catch customer's retention by investment into network in order to increase call quality.

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Herbicidal Activity and Persistency in Aqueous Solution of Ortho Disubstituted Benzenesulfonyl Urea Derivatives (새로운 Ortho 이치환 Benzenesulfonyl Urea 유도체의 제초활성과 수용액중의 잔류성)

  • Kim, Yong-Jip;Chang, Hae-Sung;Kim, Dae-Whang;Sung, Nack-Do
    • Applied Biological Chemistry
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    • v.38 no.6
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    • pp.570-576
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    • 1995
  • The new sixteen herbicidal N-2-(1-hydroxy-2-fluoroethyl)-6-substituted(X)-benzenesulfonyl-N'-4,6-dimethoxypyrimidinyl-2-yl urea derivatives(S) were synthesized and thier herbicidal activities$(pI_{50})$ in vivo against rice(Orysa Sativa L.), Barnyard grass(Echninochloa orizicola) and Bulrush(Scirpus juncoides) were measured by the pot test under paddy conditions. The structure activity relationship(SAR) were studied using the physicochemical parameters of ortho-substituents(X) and hydrolysis rate constant(logk) and herbicidal activities by the multiple regression technique. The SAR suggested that the herbicidal activities were more dependant on the hydrolysis rate constant(logk>0) than the steric constants $(Es, small width($B_4$) and length($L_1$). Among them, halogens(2 & 5), methyl(15) and non(H) substituent(1) showed higher herbicidal activity for weeds which was not tolerent to rise and weeds. The herbicidal activity was increased and the persistency in aqueous solution was decreased by electron donating(${\sigma}0<0$) groups as ortho-substituent(X). From the relationship equation between herbicidal activity and hydrolysis rate constant, it was assumed that the both reactions would be proceeds with similar process. And the conditions on the ortho substituents to show higher herbicidal activity and the persistency in aqueous solution were also discussed.

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Economies of Scale and Scope In Seoul's Urban Bus Industry (서울 시내버스운송업의 규모 및 범위의 경제성 분석)

  • 김성수;김민정
    • Journal of Korean Society of Transportation
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    • v.19 no.6
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    • pp.89-102
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    • 2001
  • Using a multiproduct translog cost function model, this paper examines the existence or absence of scale and scope economies in Seoul's urban bus industry. The Paper then conceptualizes that the bus firm produces three outputs (city, seat and local bus-kilometers) using low input factors(labor, capital, fuel and maintenance). Using 1996 annual observations for 81 Seoul's bus firms, the equation system consisting of a cost function and three input share equations is estimated with the nonlinear iterative Zellner method. The findings show that the cost function corresponding to a non-homothetic production technology with separability between local bus outputs and inputs adequately represents the structure of cost for Seoul's bus firms, and that the demand lot all input factors is quite inelastic with respect to their own price. On the other hand, nearly all firms experience mild overall economies or scale, but rather marked product-specific economies of scale with respect to all the three outputs. In addition, there appear to be substantial economies or scope associated with the joint production of city and seat bus services, while considerable diseconomies of scope associated with that of city and local bus services. These results indicate that the merger of smaller firms into larger firms with a fleet of approximately 200 buses would result in more cost-efficient bus services.

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Economies of Scale and Scope in the Korean Railway Industry: A Generalized Translog Cost Function Approach (일반초월대수 비용함수모형을 이용한 한국 철도산업의 규모 및 범위의 경제성 분석)

  • Park, Jin-Kyung;Kim, Sung-Soo
    • Journal of Korean Society of Transportation
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    • v.22 no.6
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    • pp.159-173
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    • 2004
  • Using a generalized translog multiproduct cost function model, this paper examines economies of scale and scope in the vertically-integrated Korean railway industry. The paper then conceptualizes that the Korea National Railroad (KNR) produces four outputs (passenger-kilometers, ton-kilometers of freight, average length of passenger trips, and average length of freight haul) using three input factors(labor, fuel and maintenance, and rolling stock and capital). Using time series data collected from the KNR's annual records for the years from 1977 to 2002, the simultaneous equation system consisting of a cost function and two input share equatins is estimated with the Zellner's iterative seemingly unrelated regression. The findings show that the cost function corresponding to a non-Cobb-Douglas, non-homothetic, and non-homogeneous production technology adequately represents the KNR's cost structure. On the other hand, the Korean railway industry experiences sizeable overall scale economies, which result from substantial product-specific scale economies associated with passenger-kilometers and freight ton-kilometers and from scope economies associated with their joint production. In addition, the magnitude of economies of scope is influenced largely by the ratio of passenger trips, and has increased over time as the former has increased while the latter has decreased.