• Korean Journal of Materials Research
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• v.11 no.4
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• pp.290-293
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• 2001

The SrBi$_2$Nb$_2$O$_{9}$ (SBN) thin films were deposited on p-type(100) Si substrates by rf magnetron sputtering to confirm the Possibility of Pt/SBN/Si structure for the application of nondestructive read out ferroelectric random access memory (NDRO- FRAM). The SBN thin films were deposited by co-sputtering method with Sr$_2$Nb$_2$O$_{7}$ (SNO) and Bi$_2$O$_3$ ceramic targets. The SBN thin films deposited at room temperature were annealed at $700^{\circ}C$ for 1hr in $O_2$ ambient. The structural and electrical properties of SBN with different power ratios of targets were measured by x-ray diffraction(XRD), scanning electron microscopy(SEM), capacitance-voltage(C-V), and current-voltage(I-V). The C-V curves of the SBN films showed hysteresis curves of a clockwise rotation showing ferroelectricity. When the Power ratio of the SNO/Bi$_2$O$_3$ targets was 120 W/100 W, the SBN thin films had excellent electrical properties. The memory window of SBN thin film was 1.8 V-6.3 V at applied voltage of 3 V-9 V and the leakage current density was 1.5 $\times$ 10$^{-7}$ A/$\textrm{cm}^2$ at applied voltage of 5 V The composition of SBN thin films was analysed by electron probe X-ray micro analyzer(EPMA) and the atomic ratio of Sr:Bi:Nb with pawer ratio of 120 W/100 W was 1:3:2.

• Journal of the Korean Society for Marine Environment & Energy
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• v.14 no.2
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• pp.114-120
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• 2011

The characteristics of a helical turbine to be used for tidal stream energy conversion have been numerically studied with varying a few design parameters. The helical turbines were proposed aiming at mitgating the well known poor cut-in characteristics and the structural vibration caused by the fluctuating torque, and the basic concept is introducing some twisting angle of the vertical blade along the rotation axis of the turbine. Among many potential controling parameters, we focused, in this paper, on the twisting angle and the height to diameter ratio of the turbine, and, based on the numerical experiment, We tried to propose a configuration of such turbine for which better performance can be expected. The three-dimensional unsteady RANS equations were solved by using the commercial CFD software, FLUENT with k-${\omega}$ SST turbulence model, and the grid was generated by GAMBIT. It is shown that there are a range of the twisting angle producing better efficiency with less vibration and the minimum height to diameter ratio above which the efficiency does not improve considerably.

• Journal of Korean Society of Steel Construction
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• v.22 no.3
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• pp.281-291
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• 2010

In this study, a five-story steel frame was designed in accordance with KBC2005 to evaluate the effects of the beam-column connection on the structural behavior. The connections were designed as fully rigid and semi-rigid. The fiber model was used to describe the moment-curvature relationship of the steel beam and the column, the power model for the moment-rotation angle of the semi-rigid connection and the three-parameter model for the hysteretic behavior of the steel beam, column, and connection. The structure was idealized as separate 2-D frames and as connected 2-D frames. The peak ground accelerations of four earthquake records were modified in a time-history analysis for the levels of the mean return period and for the maximum base-shear force in a pushover analysis. The top story displacement, base-shear force, story drift, demanded ductility ratio for the semi-rigid connection, maximum bending moment of the column, beam, and connection, and distribution of the plastic hinge were examined in the time-history analysis. The frame with the semi-rigid connection yielded a lower base-shear force, less magnitude, and increasing ratio in the bending moment of the column, beam, and connection than the frame with a fully rigid connection. The TSD connection was deemed to have secured the economy and safety of the sample structure that was subjected to seismic excitation for the Korean design level.

• Journal of Life Science
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• v.28 no.10
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• pp.1140-1146
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• 2018

Dual-specificity phosphatases (DUSPs) play a role in cell growth and differentiation by modulating mitogen-activated protein kinases. DUSPs are considered targets for drugs against cancers, diabetes, immune diseases, and neuronal diseases. Part of the DUSP family, DUSP19 modulates c-Jun N-terminal kinase activity and is involved in osteoarthritis pathogenesis. Here, we report screening of cavity-creating mutants and the crystal structure of a cavity-creating L75A mutant of DUSP19 which has significantly enhanced enzyme activity in comparison to the wild-type protein. The crystal structure reveals a well-formed cavity due to the absent Leu75 side chain and a rotation of the active site-bound sulfate ion. Despite the cavity creation, residues surrounding the cavity did not rearrange significantly. Instead, a tightened hydrophobic interaction by a remote tryptophan residue was observed, indicating that the protein folding of the L75A mutant is stabilized by global folding energy minimization, not by local rearrangements in the cavity region. Conformation of the rotated active site sulfate ion resembles that of the phosphor-tyrosine substrate, indicating that cavity creation induces an optimal active site conformation. The activity enhancement by an internal cavity and its structural information provide insight on allosteric modulation of DUSP19 activity and development of therapeutics.

• Journal of the Institute of Electronics and Information Engineers
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• v.50 no.11
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• pp.180-187
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• 2013

The dinger in solar generation is the amount of sunlight which the solar cells absorb. Various types of solar trackers, which rotate themselves in order to make the solar cells face the sun as much as possible, have been developed, and especially the method of tracking with two axes has greatly contributed in increasing the generation amount at work sites. Among theses 2-axis solar trackers, the inclination-dependent 2-axis solar tracker are widely utilized for its advantages of requiring less initial investment and easy maintenance due to a solid structure. However, the drawback is that the generation efficiency is relatively low because of the structural restriction that limits the rotation angle, thus making it less efficient when tracking the sun. This paper proposes a method to increase the generation efficiency of the inclination-dependent 2-axis solar tracker. It also contains the derived equations needed for precise controlling along with a method to keep tracking with the other axis even when one has reached its angle limit. To confirm that the proposed method increases the amount of incidence onto the solar cells, formulas needed for operation on the proposed method and tracking the exact position of the sun are derived, and applying this to the quarterly data of Korea Astronomy and Space Science Institute it shows maximum over 11.1% more incidence compared to existing methods.

• Journal of the Korean Academy of Child and Adolescent Psychiatry
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• v.10 no.2
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• pp.236-243
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• 1999

The purpose of this study were to factor analyze the 25-item Personal Resource Question-naire (PRQ)-Part II, a social support measure, and to establish construct validity for the instrument among adolescents by relationship found between perceived social support and the theoretically relevant variables of attachment, parent-child relationships, and coping, The sample was consisted of 451 college students, aged 18 to 24. According to the criteria used in this study a four-factor structure, which consisted of 15-items, resulting from a principal components analysis with an oblique rotation, best represented the multidimensionality of the PRQ-Part II of late adolescents in Korea. Evidence in support of construct validity for both the 15-item and 25-item PRQPart II was provided by statistically significant correlations found between the two scales and the theoretically relevant variable of attachment, parent-child relationships, and coping. With the findings of this study, the 15-item Korean version of the PRQ-Part II can be used in research and practice as a reliable and valid instrument measuring perceived social support for late adolescents in Korea.

• Journal of the Korean Chemical Society
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• v.18 no.4
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• pp.223-238
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• 1974

CNDO/2 MO theoretical studies and kinetic studies of halide exchange reactions for alkylchloroformates have been carried out in order to investigate structure-reactivity relationship of alkylchloroformates. From the result of energetics, it was concluded that the most stable configuration of alkylchloroformate is that in which alkyl group and chlorine are trans to each other, and that the hindered rotation about the bond between the carbonyl carbon and alkoxy-oxygen bond is attributed to the ${\pi}-$electron delocalization. It has been found that the large charge separation is due to -M effect of carbonyl and alkoxy oxygens and-I effect of chlorine. The order of rates in solvents studied was $(CH_3)_2 > CO > CH_3CN{\gg}MeOH.$$I^->Br^->Cl^-$ in protic solvent, and of Cl^->Br^- >I^-$ in dipolar aprotic solvents. Alkyl group contribution has the decreasing order of $CH_3-> C_2H-{\gg}i-C_3H_7-.$ The solvent effect has been interpreted on the basis of initial and final state contribution. A transition state model has been suggested, and it has been proposed that the most favorable mechanism is the addition-elimination. From the results of activation parameters and electronic properties, an energy profile has been proposed. Structural factors determining reactivities of alkylchloroformates have been shown to be charge, energy level of ${\alpha}^*LUMO$ to C-Cl bond and ${\alpha}^{\ast} $antibonding strength with respect to C-Cl bond in this MO. Charge and polarizability of nucleophile, and the interaction of these effects with solvent structures are also found to be important.

• Restorative Dentistry and Endodontics
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• v.33 no.4
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• pp.323-331
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• 2008

Flexibility and fracture properties determine the performance of NiTi rotary instruments. The purpose of this study was to evaluate how geometrical differences between three NiTi instruments affect the deformation and stress distributions under bending and torsional conditions using finite element analysis. Three NiTi files (ProFile .06 / #30, F3 of ProTaper and ProTaper Universal) were scanned using a Micro-CT. The obtained structural geometries were meshed with linear, eight-noded hexahedral elements. The mechanical behavior (deformation and von Mises equivalent stress) of the three endodontic instruments were analyzed under four bending and rotational conditions using ABAQUS finite element analysis software. The nonlinear mechanical behavior of the NiTi was taken into account. The U-shaped cross sectional geometry of ProFile showed the highest flexibility of the three file models. The ProTaper, which has a convex triangular cross-section, was the most stiff file model. For the same deflection, the ProTaper required more force to reach the same deflection as the other models, and needed more torque than other models for the same amount of rotation. The highest von Mises stress value was found at the groove area in the cross-section of the ProTaper Universal. Under torsion, all files showed highest stresses at their groove area. The ProFile showed highest von Mises stress value under the same torsional moment while the ProTaper Universal showed the highest value under same rotational angle.

• Journal of Korean Society of Steel Construction
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• v.26 no.1
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• pp.55-68
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• 2014

In this study, the beam-to column connections of concrete-encased-and-filled steel tube columns were tested under cyclic loading. Two specimens using steel beams and two specimens using precast concrete beams were tested. The dimension of the column cross section was $670mm{\pm}670mm$. The beam depths were 488mm and 588mm for the steel beams and 700mm for the precast concrete beams. The longitudinal bar ratios of the precast concrete beams were 1.1% and 1.5%. For the connections to the steel beams, continuity plates were used in the tube columns. For the connections to the PC beams, couplers were used for beam re-bar connections. The test results showed that except for a specimen, deformation capacities of the specimens were greater than 4% rotation angle, which is the requirement for the Special Moment Frame. Particularly, specimens using precast concrete beam showed excellent performances in the strength, deformation, and energy dissipation.

• Journal of the Korean Wood Science and Technology
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• v.42 no.3
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• pp.282-289
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• 2014

After being laminated with a combination of glass fiber reinforced plastic and plywood, the GFRP laminated plate was densificated for 1 hour at $150^{\circ}C$ with pressure of $1.96N/mm^2$. A partial reinforced beam was produced by attaching the 5 GFRP laminated plates to the joint of glulam and the column. In addition, the column to beam joint was produced by using reinforced laminated wooden pin which was made of GFRP sheet and plywood, fiber glass reinforced cylindrical-LVL column. The joint was made of round log, glulam and drift pin as the reference specimen, and its moment resistance was evaluated. As a result, the strength performance of specimens with partial reinforced beams were 1.8 times stronger than the reference specimen on average. Furthermore, rupture was neither occurred on partial reinforced beam nor column. Toughness and stiffness of joints were also fine. The GFRP sheet reinforced laminated plate showed better reinforcement effect than GFRP textile reinforced one. GFRP sheet was inserted into each layer of laminate, and it showed good condition in rotation-angle and strength, therefore it is the most appropriate to reinforce the part of the beam.