• Title/Summary/Keyword: structural degradation

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A Study on Laser Weldability of Al-Si Coated 22MnB5 Steel for TWB Hot Stamping (Al-Si 도금된 22MnB5강의 핫스탬핑 TWB 적용을 위한 레이저용접성 고찰)

  • Kim, Yong;Park, Ki-Young;Lee, Bo-Young
    • Journal of Welding and Joining
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    • v.31 no.2
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    • pp.30-36
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    • 2013
  • Recently the use of ultra high strength steels(UHSS) in structural and safety component is rapidly increasing in the automotive industry. Furthermore, it commonly use in tailor welded blank laser welding process before hot stamping to reduce lightweight vehicle. However TWB process is to be a problem about welded strength after hot stamping because it's welded before heat treatment. Therefore, in this study, laser welds of TWB after heat treatment were analyzed for changes in the characteristics, especially the impact on the oxidation and decarburization in order to prevent pre-coated Al-Si layer welds on the properties for intensive investigation. As a result, the degradation of the TWB weldments changes in the heat treatment conditions alone, without any pre-treatment of the coating layer has confirmed that there is a limitation on the improvement. Furthermore Al-Si elements are overall distributed on the weldment and it specially concentrated along the fusion line. Hardness value of Al-Si segregation area is less than 350Hv and tensile strength showed just 78~83% compared with substrate. Accordingly, we proved that both side Al-Si coating should be removed in order to ensure the strength of the substrate.

Hydrogen-Dependent Catalytic Growth of Amorphous-Phase Silicon Thin-Films by Hot-Wire Chemical Vapor Deposition (HWCVD를 이용한 Amorphous Si 박막 증착공정에서 수소량에 따른 박막성장 특성)

  • Park, Seungil;Ji, Hyung Yong;Kim, MyeongJun;Kim, Keunjoo
    • Current Photovoltaic Research
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    • v.1 no.1
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    • pp.27-32
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    • 2013
  • We investigated the growth mechanism of amorphous-phase Si thin films in order to improve the film characteristics and circumvent photo-degradation effects by implementation of hot-wire chemical vapor deposition. Amorphous silicon thin films grown in a silane/hydrogen mixture can be decomposed by a resistive heat filament. The structural properties were observed by Raman spectroscopy, FTIR, SEM, and TEM. The electrical properties of the films were measured by photo-conductivity, dark-conductivity, and photo-sensitivity. The contents of Si-H and $Si-H_n$ bonds were measured to be 19.79 and 9.96% respectively, at a hydrogen flow rate of 5.5 sccm, respectively. The thin film has photo-sensitivity of $2.2{\times}10^5$ without a crystalline volume fraction. The catalyst behavior of the hot-wire to decompose the chemical precursors by an electron tunneling effect depends strongly on the hydrogen mixture rate and an amorphous Si thin film is formed from atomic relaxation.

Ripening Related Changes in Hot Pepper Fruit Cell Walls Structural Alterations of Cell Wall Polysaccharides and Separation of Galactosidase Isozymes (고추의 성숙에 따른 세포벽 다당류의 변화와 ${\beta}-Galactosidase$ Isozymes의 분리)

  • Kim, Soon-Dong;Kang, Meung-Su;Kim, Kwang-Soo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.14 no.2
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    • pp.157-163
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    • 1985
  • Various cell wall polysaccharides and related enzyme activities in hot pepper fruit were determined at different stages of maturity. The uronic acid content of cell walls decreased between immature green and turning stage fruit and then increased by red ripe stage. In contrast, cellulose content of cell walls changed only a little during ripening. Total neutal sugar content of cell wall material decreased 50% and galactose content of the walls decreased about 80% by the turning stage. Polygalacturonase and ${\beta}-galactosidase$ activities, as well as total hemicellulose from isolated cell walls of ripening hot pepper fruit were studied using gel filtration chromatography. Polygalacturonase activity was not detectable but 5 isozymes of ${\beta}-galactosidase$ were resolved. The activities of the enzymes were relatively high and gel filtration showed that they differed in molecular weight. Hemicellulose content decreased during ripening and softening. The molecular weight profiles shifted from high molecular weight to low molecular weight polymers during ripening. The changes in cell walls that may be associated with fruit softening involve the alteration of hemicellulose prior to the degradation of wall-bound uronic acid. It is suggested that the decrease in cell wall galactose involved changes in turnover of new cell wall components.

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An Experimental Study on the Mechanical Properties Model of High Strength Concrete at High Temperature (고온시 고강도 콘크리트의 역학적 특성 모델 설정에 관한 실험적 연구)

  • Kim Heung-Yaul;Seo Chee-Ho;Jeon Hyun-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.5-8
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    • 2005
  • This research is to present experimental materials model of high strength concrete for prediction of fire safety of structural members based on mechanical properties of materials during heating up to 800$^{circ}C$. The following conclusions are drawn from this study. First of all, between 100 to 200$^{circ}C$, the high strength concrete show degradation at 100$^{circ}C$ and restoration at 200$^{circ}C$. The high strength concrete show elastic deformation at 20 - 200$^{circ}C$. Second, between 300 to 400$^{circ}C$, the mechanical properties of the high strength concrete which are exposed to fire show $75\~95\%$ as compared to the original properties because the thermally expanded ingredients of concrete, aggregates and cement paste, etc. Finally, beyond 600$^{circ}C$, the high strength concrete shows $75\~80\%$ reduction in thermal properties as compared to the normal concrete in the range of 600 to 800$^{circ}C$ and it shows $10\~30\%$ as compared to the original properties.

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Analysis of Inner Temperature in High Strength Concrete under Standard Temperature-time Curve (표준화재곡선에 의한 고강도 콘크리트 부재의 내부온도 예측)

  • Song, Hun;Lee, Sea-Hyun;Mun, Kyung-Ju;Do, Jeong-Yun;Soh, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.469-472
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    • 2005
  • With all ensuring the fire resistance structure as a method of setting the required cover thickness to fire, the RC is significantly affected from the standpoint of its structural stability that the compressive strength and elastic modulus is reduced by fire. Normally, the degradation of concrete member exposed to fire is largely dependent on the fire scale and fire condition. There is therefore a need to precisely predict the deterioration and fire damage of the exposed member. Thus, this work estimated the temperature distribution inside a member taking into consideration of the thermal properties by means of finite element method(FEM). The estimation results in a little higher prediction value than the experimental value in surface layer and is almost coincident with the experiment as the heating depth increase. From this work it can be known that the simulation application of FEM using the thermal properties of concrete member in high temperature gives rise to the confident prediction in the prediction of temperature distribution.

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A Study on SEM Observations of Low Temperature Degradation in Zirconia Dental Ceramics (저온열화에 따른 치과용 지르코니아의 전자현미경 관찰 연구)

  • Lee, Jung-Hwan;Joo, Kyu-Ji;Ahn, Jae-Seok
    • Journal of Technologic Dentistry
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    • v.33 no.1
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    • pp.15-23
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    • 2011
  • Purpose: Thy yttria tetragonal zirconia polycrystalline(Y-TZP) is a good structural ceramic for dental restoration. But it have a problem that delamination of veneering ceramic from the Y-TZP core materials. The problem generally occur at the interface, thus this study was conducted to evaluate the interface of Y-TZP using scanning electron microscopy(SEM). Methods: To investigate this aspect, high-resolution SEM observations were made of polished and etched (HF content gel) cross-sections of the interface area. Dry and moist veneering porcelain powders were built up on the zirconia base. Results: The extent of this surface faceting is dependent upon the moisture content of the porcelain powder and the firing temperature. More moisture and higher final heating temperature accelerates the observed faceting of the Y-TZP grains at the interface to the veneering ceramic. Conclusion: These changes of the Y-TZP grains indicate that destabilization of the tetragonal phase of zirconia occurs at the interface during veneering with ceramic. It may result in a reduction of the stability of the zirconia and interface.

X-ray Diffraction Patterns of Activated Carbons Prepared under Various Conditions

  • Girgis, Badie S.;Temerk, Yassin M.;Gadelrab, Mostafa M.;Abdullah, Ibrahim D.
    • Carbon letters
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    • v.8 no.2
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    • pp.95-100
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    • 2007
  • A series of activated carbons (ACs) were derived from sugarcane bagasse under two activation schemes: steam-pyrolysis at $600-800^{\circ}C$ and chemical activation with $H_3PO_4$ at $500^{\circ}C$. Some carbons were treated at 400, $600^{\circ}C$, or for 1-3 h, and/or in flowing air during pyrolysis of acid-impregnated mass. XRD profiles displayed two broad diffuse bands centered around $2{\theta}=23$ and $43^{\circ}$, currently associated with diffraction from the 002 and 100/101 set of planes in graphite, respectively. These correspond to the interlayer spacing, Lc, and microcrystallite lateral dimensions, La, of the turbostratic (fully disordered) graphene layers. Steam pyrolysis-activated carbons exhibit only the two mentioned broad bands with enhancement in number of layers, with temperature, and small decrease in microcrystallite diameter, La. XRD patterns of $H_3PO_4$-ACs display more developed and separated peaks in the early region with maxima at $2{\theta}=23$, 26 and $29^{\circ}$, possibly ascribed to fragmented microcrystallites (or partially organized structures). Diffraction within the $2{\theta}=43^{\circ}$ is still broad although depressed and diffuse, suggesting that the intragraphitic layers are less developed. Varying the conditions of chemical activation inflicts insignificant structural alterations. Circulating air during pyrolysis leads to enhancement of the basic graphitic structure with destruction and degradation in the lateral dimensions.

Oxidation Behaviors of SiCf/SiC Composites Tested at High Temperature in Air by an Ablation Method

  • Park, Ji Yeon;Kim, Daejong;Lee, Hyeon-Geun;Kim, Weon-Ju;Pouchon, Manuel
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.498-503
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    • 2018
  • Using the thermal ablation method, the oxidation behavior of $SiC_f/SiC$ composites was investigated in air and in the temperature range of $1,300^{\circ}C$ to $2,000^{\circ}C$. At the relatively low temperature of $1,300^{\circ}C$, passive oxidation, which formed amorphous phase, predominantly occurred in the thermal ablation test. When the oxidation temperature increased, SiO (g) and CO (g) were formed by active oxidation and the dense oxide layer changed to a porous one by vaporization of gas phases. In the higher temperature oxidation test, both active oxidation due to $SiO_2$ decomposition on the surface of the oxide layer and active/passive oxidation transition due to interfacial reaction between oxide and base materials such as SiC fiber and matrix phase simultaneously occurred. This was another cause of high temperature degradation of $SiC_f/SiC$ composites.

Maintenance Management System for Long-range Planning of Apartment Buildings (공동주택의 장기수선계획을 위한 유지관리시스템)

  • Lee, Jong-Kyoon
    • KIEAE Journal
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    • v.3 no.3
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    • pp.67-74
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    • 2003
  • The repair and maintenance planning is the principal transaction to prevent from the degradation of apartment buildings to prolong their lives. Various building components as part of living area should be maintained properly and timely before critical defects are realized, then the building life might be extended until the limit of its usability. In other words, various building components such as utilities, finishes and structural members are needed to be repaired and replaced in different time interval after completion. To do this systematically, a maintenance management system for Long-Range Planning (LRP) needs developing. The LRP should be figured out based on the forecast of repairing and replacing cycle of building components according to work trades. And the precise forecast of repairing and replacing time of the components helps to enhance the usability of the developed system. The purpose of this paper is to suggest a system with which apartment building managers carry out the tasks of periodical check, diagnosis and replacement of building components based on the maintenance calendar. By using the system, they can easily forecast repairing and replacing time of the components with the consideration of life cycle of building materials and build the LRP.

Electrical and Structural Properties of Ferroelectric $LiNbO_3$ Thin films for Nonvolatile Memory applications (비휘발 메모리소자응용을 위한 강유전체 $LiNbO_3$ 박막의 전기적 구조적 특성에 관한 연구)

  • 최유신;정세민;김도영;이준신
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.235-238
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    • 1998
  • Ferroelectric $LiNbO_3$ thin films were grown directly on Si(100) substrates by 13.55MHz RF magnetron sputtering system using a ceramic target ($Nb_2O_5/Li_2C0_3$ = 51.4/48.6). Because high temperature process have to avoided to prevent degradation of the interface (insulator/Si), $LiNbO_3$ thin films were deposited below $300^{\circ}C$. After as-deposited films were performed RTA treatments in an oxygen ambient at $600^{\circ}C$ for 60s, electrical measurements performed films before and after anneal treatment. In high field region, the leakage current density of the films after annealing was deceased about 4order and the resistivity of these was increased to about 5\times 10^{11} \Omega \cdot cm$ at 500kV/cm. In accumulation region of C-V curve, we calculated dielectric constant of thin film $LiNbO_3$ as 27.9 which is close to that of bulk value.

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