• Title/Summary/Keyword: strong unit

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Copper(II) Coordination Polymers Assembled from 2-[(Pyridin-3-ylmethyl)amino]ethanol: Structure and Magnetism

  • Han, Jeong-Hyeong;Shin, Jong-Won;Min, Kil-Sik
    • Bulletin of the Korean Chemical Society
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    • v.30 no.5
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    • pp.1113-1117
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    • 2009
  • The one-dimensional coordination polymers, $[Cu^{II}(L)(NO_3)_2]_n$ (1) and {$[Cu^{II}(L)(NO_3)]{\cdot}2H_2O}_{2n} (2), were synthesized from $Cu(NO_3)_2{\cdot}3H_2O$ and 2-[(pyridin-3-ylmethyl)amino]ethanol (L, PMAE) in methanol by controlling the molar ratio of copper(II) salt. Copper(II) ion in 1 has one pyridine group of PMAE whose an aminoethanol group coordinates adjacent copper(II) ion. As the pyridine group is bonded to neighboring copper(II) ion, 1 becomes a one-dimensional chain. Contrary to 1, the structure of 2 shows that the oxygen atom of ethoxide group is bridged between two copper(II) ions, which forms a dinuclear complex. Additionally, the pyridine group of PMAE included one dinuclear unit is coordinated to the other dimeric one each other, which leads to a one-dimensional polymer. Due to the structural differences, 1 exhibits weak antiferromagnetic interaction, while 2 shows strong antiferromagnetic interaction. Due to direct spin exchange via oxygen of PMAE 2 has a much strong spin coupling than 1.

The Spatial Pattern and Residential Characteristics of Aging Population in the Seoul Metropolitan Region (수도권 고령인구의 공간 분포와 주거 특성)

  • Choi, Jae-Heon;Yoon, Hyun Wi
    • Journal of the Korean Geographical Society
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    • v.48 no.3
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    • pp.402-416
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    • 2013
  • This paper investigates both the changing spatial patterns of aging population during 1985 to 2010 and their interrelationship with the residential features of elderly households in 2010. The aging level of a region is classified into three different ones such as aging region (7~14%), aged region (14~20%) and super-aged region (over 20%). Residential features of elderly households are examined by such variables as housing type, housing ownership, and house age. Aging process has started from peripheral regions distanced away from Seoul. There are strong tendency that aging households reside in single unit house owned by oneself over 20 years-old aged houses, which shows more strong patterns toward peripheral regions in SMR.

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Exploring the Relationship Between International Classification of Functioning, Disability, and Health Items Linked to Clinical Assessments in Children With Cerebral Palsy

  • Park, Sang-Duk;Yi, Sook-Hee;Kim, Jeong-Soo
    • Physical Therapy Korea
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    • v.28 no.4
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    • pp.245-250
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    • 2021
  • Background: The International Classification of Functioning, Disability, and Health-Child and Youth version (ICF-CY) is designed to record the characteristics of developing children and examine the influence of a child's environment on their health. Objects: This study was designed to determine the relationship between the clinically extracted ICF-CY items and The Pediatric Evaluation of Disability Inventory (PEDI) and Gross Motor Function Measure (GMFM) items. Methods: Thirty patients (17 males and 13 females) who were hospitalized in a pediatric and youth patient unit of a rehabilitation hospital were included in the study. Four health professionals (two physical therapists and two occupational therapists) working independently linked the PEDI and GMFM-66 items to the activity and participation domains of the ICF-CY. Results: There were strong negative correlations between the ICF-CY subdomains and the PEDI subdomains (r = 0.76-0.95; p < 0.05). There were positive strong correlations between the ICF-CY subdomains and the GMFM-66 (r = 0.76-0.95; p < 0.05). Conclusion: The extracted ICF codes were a valid tool for evaluating the mobility and selfcare conditions of cerebral palsy in the pediatric rehabilitation area.

Nonlinear flexibility-based beam element on Winkler-Pasternak foundation

  • Sae-Long, Worathep;Limkatanyu, Suchart;Hansapinyo, Chayanon;Prachasaree, Woraphot;Rungamornrat, Jaroon;Kwon, Minho
    • Geomechanics and Engineering
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    • v.24 no.4
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    • pp.371-388
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    • 2021
  • A novel flexibility-based beam-foundation model for inelastic analyses of beams resting on foundation is presented in this paper. To model the deformability of supporting foundation media, the Winkler-Pasternak foundation model is adopted. Following the derivation of basic equations of the problem (strong form), the flexibility-based finite beam-foundation element (weak form) is formulated within the framework of the matrix virtual force principle. Through equilibrated force shape functions, the internal force fields are related to the element force degrees of freedom. Tonti's diagrams are adopted to present both strong and weak forms of the problem. Three numerical simulations are employed to assess validity and to show effectiveness of the proposed flexibility-based beam-foundation model. The first two simulations focus on elastic beam-foundation systems while the last simulation emphasizes on an inelastic beam-foundation system. The influences of the adopted foundation model to represent the underlying foundation medium are also discussed.

A Study on the Design Characteristics of Communal Spaces in Vertical Urban Multi-Family Housing Community -Focused on the Territories of a Unit Boundary, Building Interior and Exterior Boundary- (수직적 도시 공동주거 커뮤니티에 적용된 공유공간의 계획특성 연구 -단위세대 경계부와 주거동 내부 및 경계부 영역을 중심으로-)

  • Cho, Min-Jung
    • KIEAE Journal
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    • v.11 no.5
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    • pp.55-67
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    • 2011
  • The purpose of this research is to find applicable design characteristics and methods of communal spaces in vertical urban multi-family housing. With this goal, several overseas' multi-family housing projects are selected and their communal spaces are identified. The design characteristics of the communal spaces are analyzed with a special focus on the territories such as an individual unit boundary, building interior and exterior boundary. In terms of the framework for analysis, territoriality, openness, and unique characteristics are reviewed. As a result, the communal spaces are created using various spatial composition methods such as addition, subtraction, connection, extension, accumulation, and isolation. The communal space programs are integrated in plans and sections throughout the buildings. Visual openness and connection with surrounding urban environments are articulated by void spaces, transparent and translucent building materials, green spaces, and applications of graphical images. Communal identities and aesthetics are emphasized by unique building forms and space arrangements. The uses of finish materials, colors, objects, and images add strong characters to the communal spaces. For a further research, it is necessary to combine a design method study with residents' behaviors and community interactions.

Constitutive Overexpression of the Endoxylanase Gene in Bacillus subtilis

  • Kim, Jong-Hyun;Kim, Jung-Hoe;Kim, Sun-Chang;Nam, Soo-Wan
    • Journal of Microbiology and Biotechnology
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    • v.10 no.4
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    • pp.551-553
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    • 2000
  • A strong constitutive $P_{JH}$ promoter from Bacillus was applied to overexpress the endoxylanase gene in B. subtilis. The expression plasmid, pHJKJ4, was designed to contain the $P_{JH}$ promoter and endoxylanase promoter ($P_B$), and introduced into B. subtilis DB104. Through batch fermentation of the trasformant cell on a maltose medium, endoxylanase was produced in a growth-associated manner as the predominant protein. The total activity reached about 600 unit/ml at the end of the cultivation, which corresponded to 698 mg endoxylanase protein/l with a specific activity of 860 unit/mg protein. It was also found that the segregational plasmid instability was less than 30% and most of the endoxylanase activity was detected in the culture medium. This result suggests that the secretory production of endoxylanase can be significantly enhanced with the use of the $P_{JH}$ promoter and high-cell density culture techniques, quantitatively as well as qualitatively.

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The Influence of Uniform Connectedness in Perceiving Briefly Presented Forms (균질 연결성이 순간 노출된 형태의 지각에 미치는 영향)

  • 박창호
    • Korean Journal of Cognitive Science
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    • v.12 no.4
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    • pp.41-47
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    • 2001
  • Palmer and Rock (1994) proposed that a connected region of uniform visual properties (uniform connectedness) strongly tends to be organized as a single perceptual unit To test this hypothesis using briefly presented forms three experiments were executed. In Experiment 1 and 2 participants were asked to report the identity of a post-cued target. and there was no difference between connected and disconnected displays. In Experiment 3 participants were asked to report the predesignated name of each whole display and the accuracy rate was higher in the connected displays than in the disconnected ones. However negative repetition effects were observed consistently in all the experiments. This indicates uniform connectedness does not have a strong effect in perceiving briefly presented forms.

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Relationship between Hospital Case Mix and Costs and Incomes of Tehran Heart Center

  • Langroudi, Hamed Rahimpour;Kakhani, Mohammad Jamil;Hojabri, Roozbeh
    • Asian Journal of Business Environment
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    • v.7 no.3
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    • pp.17-22
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    • 2017
  • Purpose - Clarifying one of the biggest public Hospital Costs and incomes according to patients' case mix. It leads to prepare financial information about pubic medical tariffs and hospital operational costs. Research design, data, and methodology - This study calculates the costs both, with and without taking into account capital costs. This holds for comparison of hoteling based on case mix in all medical procedures. The checklists were reviewed and filled by reviewing accounting documents of the hospital, warehouse exclusion list, and daily books of laundry and CSR. Data was analyzed descriptively by using Excel. Results - In both cases, the hospital is losing in terms of hoteling. Because the buildings and equipment are new, this loss is not tangible. However, this will be revealed when costs of reconstruction and replacement of equipment. The loss rate per day of hospitalization was 569318 Rials for Coronary Care Unit (CCU), 528171 Rials for Post Intensive Care Unit (Post ICU), 474570 Rials for ICU, 233183 Rials for Post CCU and 204803 for Surgical ward. Conclusions - Income of hoteling was lower than its costs. ANOVA showed a strong relationship between case mix and hospital costs as well as case mix and its income. This suggests that optimal case mix can minimize the costs and maximize income.

Conjugated Oligomers Combining Fluorene and Thiophene Units : Towards Supramolecular Electronics

  • Leclere, Ph.;Surin, M.;Sonar, P.;Grimsdale, A.C.;Mllen, K.;Cavallini, M.;Biscarini, F.;Lazzaroni, R.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.228-228
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    • 2006
  • Conjugated oligomers, used as models for fluorene-thiophene copolymers, are compared in terms of the microscopic morphology of thin deposits and the optical properties. The AFM images and the solid-state absorption and emission spectra are interpreted in line with the structural data, in terms of the assembly of the conjugated molecules. The compound with a terthiophene central unit and fluorene end-groups shows well-defined monolayer-by-monolayer assembly into micrometer-long strip-like structures, with a crystalline herringbone-type organization within the monolayers. Polarized confocal microscopy indicates a strong orientation of the crystalline domains within the stripes. In contrast, the compound with a terfluorene central unit and thiophene end groups forms no textured aggregates. The difference in behavior between the two compounds most probably originates from their different capability of forming densely-packed assemblies of ${\pi-pi}$ interacting molecules. These assemblies are used as active elements in organic field effect transistors designed by using soft lithography technique.

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Relationship Between Heat Unit Requirement and Growth and Yield of Mulberry, Morns indica L.

  • Sarkar A.;Rekha M.;Keshavacharyulu K.
    • International Journal of Industrial Entomology and Biomaterials
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    • v.10 no.1
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    • pp.65-68
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    • 2005
  • Growth and development of a plant over a growing season is closely related to the daily accumulation of heat. Heat unit measured by accumulated growing degree days (GDD) is becoming increasingly popular to estimate the growth of a plant or even in insect. GDD or heat accumulation per day is measured by calculating average daily temperature and then subtracting the base temperature below which growth does not occur. Heat accumulation per day is added for the desired period and accumulated GDD is determined. The present study was conducted in five seasons in an established garden with K-2, S-36 and V-1 mulberry varieties belonging to Morus indica L. grown under completely irrigated condition at the farm of CSRTI, Mysore during 2001 - 2002. Plants were pruned in each season and the growth of the plant measured by total shoot length and fresh leaf yield was recorded at an interval of 5 days starting from 30 days of pruning (DAP) to 70 days when all the plants were pruned. The accumulated GDD for the corresponding days were recorded and used for analysis. Accumulated growing degree days (GDD) have been found to be perfectly correlated with both growth and yield in all the seasons in all the varieties studied. The high $R^2$ values indicated a strong relationship between the accumulated GDD and, growth and yield of mulberry.