• Title/Summary/Keyword: strong acid

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Effects of Acid Fog and CaCl2 on the Corrosion Fatigue Strength of Structural Steel (구조용 강재의 부식피로 강도에 미치는 산성안개 및 염화칼슘의 영향)

  • Kim, Min-Gun;Kim, Myoung-Sub
    • Journal of Industrial Technology
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    • v.21 no.A
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    • pp.17-26
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    • 2001
  • The fatigue strength of SM55C has significantly decreased by 83% compared with atmosphere where distilled exists due to strong erosive action of acid fog. The reason is inferred in a way that strong acid erosive material such as acid fog act and give rise to multi-site crack on the surface. Several fatigue clacks occurred under the acid fog repeat the process of division and unification on the surface and form a long non-propagating crack throughout the circumference of experimented steel. However, in the depth, many parts do not show much trace of unification, and the depth is not as big as the one of normal crack shape. 10% of $CaCl_2$ causes strong erosive reaction to material. Then eventually make the life of fatigue shooter. On the other hand, 20% of $CaCl_2$ beings about oxidized material organic crack closing due to weak erosive reaction.

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Analysis of Textbook Contents and Chemistry Teachers' Cognition about Species of Strong Acid in Water (강산 수용액에서의 화학종에 대한 교과서 내용 및 화학 교사의 인식 분석)

  • Go, Hyung-Suk;Kim, Kyung-Eun;Paik, Seoung-Hey
    • Journal of the Korean Chemical Society
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    • v.56 no.5
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    • pp.628-637
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    • 2012
  • In this research, the textbook contents related to the ionization degree of strong acid in water were analyzed from 1945 year syllabus to chemistry II textbook in 2009 revised curriculum. Fifty chemistry teachers' cognition related to the species of strong acid in water, and the relationship between the degree of ionization was surveyed by a questionnaire and interviews. As results, most of the teachers thought the species of strong acid in water based on the degree of ionization represented on the chemistry II textbooks. They didn't recognize the conflict of the degree of ionization and definition of strong acid on the textbooks, and then they awakened the conflict, they could not solve the problem.

The Hydrodesulfurization over NiPtMo Catalysts and Acidic Characterization of Supports (NiPtMo계 촉매 담체의 산특성 및 수소첨가 탈황반응)

  • 김문찬;이원묵;김경림
    • Journal of Korean Society for Atmospheric Environment
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    • v.10 no.4
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    • pp.281-288
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    • 1994
  • The hydrodesulfurization (DBT) were Peformed over NiPtMo catalysts supported on HZSM-5, LaY and ${\gamma}$- $Al_2$O$_3$under high H$_2$ pressure. And the acidities of these catalysts were characterized by using TGA and DSC. The result showed that the order of the acid strength for prepared supports was HZSM -5>LaY>${\gamma}$- A1$_2$O$_3$. For the acid amount we obtained the same result for the acid strength The acid strength and the acid amount mainly depended on the kinds of supports whose acid site were strong or not The activity of the hydrodesulfurization decreased for catalysts which had strong acid sites. The origin of acid site was Bronsted in NH50 and NY catalysts And it was Lewis in NA catalyst The order of desorption activation energy for Pyridine was NH50>NY>NA. And the result was the same for thiophene. The activity of the hydrodesulfurization decreased for catalysts which had strong acid sites. The conversion of DBT over NA catalyst was higher than NH and NY catalysts.

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Controlling Size, Shape and Polymorph of TiO2 Nanoparticles by Temperature-Controlled Hydrothermal Treatment

  • Kwon, Do Hun;Jung, Young Hee;Kim, Yeong Il
    • Journal of the Korean Chemical Society
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    • v.59 no.3
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    • pp.238-245
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    • 2015
  • The crystallization and morphology change of amorphous titanias by hydrothermal treatment have been investigated. The amorphous titanias were prepared by pure water hydrolysis of two different precursors, titanium tetraisopropoxide (TTIP) and TTIP modified with acetic acid (HOAc) and characterized prior to hydrothermal treatment. In order to avoid complicate situation, the hydrothermal treatment was performed in a single solvent water with and without strong acids at various temperatures. The effects of strong acid, temperature and time were systematically investigated on the transformation of amorphous titania to crystalline TiO2 under simple hydrothermal condition. Without strong acid the titanias were transformed into only anatase phase nanoparticle regardless of precursor type, temperature and time herein used (up to 250 ℃ and 48 hours). The treatment temperature and time effected only on the crystalline size, not on the crystal phase et al. However, it was clearly revealed that the strong acids such as HNO3 and HCl catalyzed the formation of rutile phase depending on temperature. HCl was slightly better than HNO3 in this catalytic activity. The morphology of rutile TiO2 formed was also a little affected by the type of acid. The precursor modifier, HOAc slightly reduced the catalytic activity of the strong acids in rutile phase formation.

Specificity of Auxin Action on Ethylene Production in Corn Coleoptile Segments (옥수수(Zea mays L.) 자엽초 절편에서 에틸렌 생성에 대한 오옥신의 작용 특성)

  • 윤인선
    • Journal of Plant Biology
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    • v.34 no.4
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    • pp.325-330
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    • 1991
  • The ability of several auxin analogs to induce ethylene production was tested in the corn coleoptile. The synthetic auxins 1-naphthaleneacetic acid (1-NAA) and 2, 4-dichlorophenoxyacetic acid (2, 4-D) had strong stimulatory effects on ethylene induction surpassing that of IAA. Both 2-naphthalaneacetic acid (2-NAA) and 2, 6-dichlorophenoxy acetic acid (2, 6-D), structural analogs of these auxins, respectively, were found to be inactive. Treatment with NPA, a strong inhibitor of polar auxin transport, led to drastic increase in IAA-induced ethylene production while it has bo effect on ethylene production induced by 1-NAA. A positive correlative existed between intracellular auxin level and ethylene production.

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Studies on co-Operative Effect of Oil-Soluble Antioxidants and Organic Acid. (유용성산화방지제에 대한 유기산의 협력효과에 대한 연구)

  • 유세홍;김선덕;윤오섭
    • Journal of Environmental Health Sciences
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    • v.5 no.1
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    • pp.21-24
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    • 1978
  • This study was conducted to find out the co-operative effect of antioxidants (butyl hydroxy anisol, dibutyl hydroxy toluene, propyl gallate, dl-$\alpha$-tocopherol) and organic acid (citric acid, tartaric acid, succinic acid) on the stability of soybean oil by active oxygen method. The results obtained were summarized as follows: 1. When antioxidants and organic acid were used together, the antioxidants activity was more strong than antioxidants were used only. 2. The co-operative effect of citric acid for antioxydants was the strongest whereas succinic acid was the weakest. 3. The co-operative effect of phenolic antioxydants for organic acid was more strong than dl-$\alpha$-tocopherol.

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Inhibition of Enzymatic Browning of Apple Juices by Benzoic Acid Isolated From Peach (Prunus persica Batsch) Seeds (복숭아씨로부터 분리된 안식향산에 의한 사과주스의 효소적갈변억제)

  • 이준영;홍순갑;최상원
    • Food Science and Preservation
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    • v.7 no.1
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    • pp.103-107
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    • 2000
  • Previously , the methanolic extract of peach sees was found to have a strong tyrosinase inhibitory activity in an in vitro assay. Several phenolic compunds were isolated from the seeds by solvent fractionation , Sephadex LH-20 chromatography, and preparative HPLC , and one of them showing strong tyrosinase inhibition was identified as benzoic acid by UV, IR, $^1$H/$^1$$^3$C-NMR, and EI-MS spectrsopy. Benzoic acid (IC50= 250$\mu\textrm{g}$/ml) and L-ascorbic acid (IC50=28$\mu\textrm{g}$/ml), well-known tyrosinase inhibitors. In particular , benzoic acid inhibited markedly the enzymatic browing (melanosis) of apple juices at low concentration of 0.01% and 0.05, comparable to that of L-ascorbic acid (P<0.05). these results suggest that benzoic acid, one of an effective food preservatives, may be potentially useful as a functional alternative to sulfites for the control of melanosis in fruit juices.

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Studies on the Acid stable Protease from Penicillium sp. Part II. Effect of inhibitor on the proteolytic activity of acid Protease and the Milk clotting activity. (내산성 Protease에 관한 연구 제2보 조해제에 의한 영향 및 각종기질에 대한 작용성에 대하여)

  • 김상열
    • Microbiology and Biotechnology Letters
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    • v.1 no.2
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    • pp.99-104
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    • 1973
  • A study on the active center of the acid protease from Penicillium sp. was conducted, and also the milk clotting activity of acid prorease was measured. 1. PCMB failed to influence the proteolytic activity of acid protease, indicating that a reactive sulfhydryl group is not required for the enzymatic activity. 2. $\varepsilon$-amino caproic acid did not show any inhibitory effect on tile proteolytic activity of acid protease. 3. Also 2, 4-dinitro phenol did not show any inhibitory effect on the enzyme activity. 4. Acid protease from Penicillium sp. showed a strong milk clotting activity in the presence of Ca ion. 5. This enzyme had a strong proteolytic activity on various substrate, such as casein, denatured hemoglobin, ovalbumin, denatured bovine muscle protein, denatured percine muscle protein and denatured chicken muscle protein.

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Cinnamic Acid Derivatives I, The Kinetics and Mechanism of the Hydrolysis and Synthesis of Cinnamanilide Derivatives (신남산 유도체 I, Cinnamanilide 유도체의 가수분해 메카니즘과 반응속도론적 연구)

  • Lee, Ki-Chang;Hwang, Yong-Hyun;Lee, Kwang-Il;Jung, Taek-Suh;Park, Kwang-Ha
    • Journal of the Korean Applied Science and Technology
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    • v.6 no.2
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    • pp.59-65
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    • 1989
  • The rate constants of the hydrolysis of cinnamanilide derivatives were determined UV spectrometry in $H_2SO_4\;(5{\sim}20N)$, NaOH($5{\sim}11N)\;at\;50{\sim}110^{\circ}C$ and rate equation could be applied over a strong acid and strong base were obtained. Final product of the hydrolysis was a cinnamic acid. The ${\rho}$ values obtained from the slope of linear plots of log $k_{abs}$ vs. Hammet $t{\sigma}$ constants were slightly negatives, Substituents on cinnamanilide showed a relatively small effect, with hydrolysis facilitated be electron donating group. Activation energy(Ea)was also calculated for the hydrolysis of the cinnamanilide. From this reaction rate equation, substituent effect and experimental of rate constants, that the hydrolysis of cinnamanillde was Initiated by the netural molecule of $H_2O$ which do not dissociate at strong acid, and proceeded by hydroxide ion at strong base.

The Nutritional Composition and Antioxidant Activity from Undariopsis peterseniana (넓미역의 영양성분 및 항산화 활성)

  • Cho, MyoungLae;Yoon, Sung Jin;Kim, Yun-Bae
    • Ocean and Polar Research
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    • v.35 no.4
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    • pp.273-280
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    • 2013
  • The proximate composition, free amino acid composition and mineral contents from Undariopsis peterseniana were determined, and the antioxidant activities of ethanol (EtOH) and hot water extracts of U. peterseniana were investigated using DPPH (1,1-diphenyl-1-picrylhydrazyl), ABTS (2,2'- azino-bis(3-ethylbenzothiazoline-6-sulphonic acid)) radical scavenging effects and reducing power. The contents of moisture, ash, protein, lipid and carbohydrate were 12.5%, 23.1%, 9.7%, 0.2% and 54.5%, respectively, and alginic acid content was 12.3%. The major free amino acid contents were alanine, phenylalanine, aminoethanol, valine, glutamic acid and phosphoserine. Ca (1589.1 mg) was the largest mineral followed by Na (344.6 mg), Mg (74.3 mg), Zn (10.2 mg) and Fe (1.5 mg). The total phenolic contents of EtOH and hot water extracts were exhibited at 15.7 and 4.3 mg GAE/g sample, respectively. The antioxidant activity of EtOH extract exhibited strong ABTS and DPPH radical scavenging activities with reducing power, and hot water extract also demonstrated strong ABTS radical scavenging effects. Therefore, the results of this study suggest that U. peterseniana contained an abundance of naturally occurring nutrients (free amino acids and minerals), and the strong antioxidant activities of EtOH and hot water extracts from U. peterseniana could be good sources of natural antioxidants for healthcare products.