• Title/Summary/Keyword: strength and stability

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Stability Constants of Copper Sulfa-Drug Complexes in Dimethylformamide Aqueous Solution (Dimethylformamide 수용액중에서의 Sulfa제-Cu 착화합물의 안정도정수)

  • 이왕규
    • YAKHAK HOEJI
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    • v.9 no.1_2
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    • pp.4-7
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    • 1965
  • Acid dissociation constants of sulfamethoxypyridazine, sulfadimethoxine, sulfamerazine, sulfathiazole and sulfadiazine, and stability constants for formation of copper chelate were calculated from their titration curves in 80% dimethylformamide with ionic strength 0.1 at $25{\deg}$ It was found that the acid dissociation constants (pKa) of sulfa-drugs were in the range of 9.33 - 10.05, and the stability constants (log $k_{1}$, $k_{2})$ of their copper chelates were in the range of 9.33-9.71.

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Fabrication and Characteristics of Y-TZP/Ce-TZP Structural Ceramics (Y-TZP/Ce-TZP 구조세라믹스의 제조 및 특성연구)

  • 이종현;이윤복;김영우;오기동;박흥채
    • Journal of the Korean Ceramic Society
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    • v.33 no.10
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    • pp.1177-1185
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    • 1996
  • Y-TZP/Ce-TZP ceramics having relative sintered densities of>95% average grain sizes of 0.36$\mu\textrm{m}$ microhar-dness of 1150 kg/mm2 fracture strength of 390-830 MPa and toughness of 6.4-10.2 MPa$.$mm1/2 were prepared by conventional sintering of 3 mol% Y2O3-ZrO2 and 12 mol% CeO2-ZrO2 powders at 1400 and 1500$^{\circ}C$ The average grain sizes of Y-TZP/Ce-TZP ceramics were mainly governed by those of Ce-TZP. White increasing Ce-TZP content toughness increased while microhardness and fracture strength decreased. With comparing microhardness and toughness fracture strength was more sensitive on not only grain size but also other factors such as microstructural and compositional variations. The densification of Y-TZP/Ce-TZP cermaics was not greatly affected by composition and soaking time at temperature over 1400$^{\circ}C$ With increasing CE-TZP content the stability of t-ZrO2 decreased under thermal aging in air whereas increased in hydrothermal atmosphere and aqueous solution.

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Stability Analysis of Unsaturated Soil Slope by Coupled Hydro-mechanical Model Considering Air Flow (공기흐름을 고려한 수리-역학적 연동모델에 의한 불포화 토사사면의 안정해석)

  • Cho, Sung-Eun
    • Journal of the Korean Geotechnical Society
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    • v.32 no.1
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    • pp.19-33
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    • 2016
  • Stability analysis based on the limit equilibrium method combined with the result of infiltration analysis is commonly used to evaluate the effect of rainfall infiltration on the slope stability. Soil is a three-phase mixture composed of solid particle, water and air. Therefore, a fully coupled mixture theories of stress-deformation behavior and the flow of water and air should be used to accurately analyze the process of rainfall infiltration through soil slope. The purpose of this study is to study the effect of interaction of air and water flow on the mechanical stability of slope. In this study, stability analyses based on the coupled hydro-mechanical model of three-phases were conducted for slope of weathered granite soil widespread in Korea. During the process of hydro-mechanical analysis strength reduction technique was applied to evaluate the effect of rainfall infiltration on the slope stability. The results showed an increase of air pressure during infiltration because rain water continuously displaced the air in the unsaturated zone. Such water-air interaction in the pore space of soil affects the stress-deformation behavior of slope. Therefore, the results from the three-phase model showed different behavior from the solid-water model that ignores the transport effect of air in the pores.

Prediction of Compaction, Strength Characteristics for Reservoir Soil Using Portable Static Cone Penetration Test (휴대용 정적 콘 관입시험을 통한 저수지 제방 토양의 다짐, 강도 특성 및 사면 안정성 예측)

  • Jeon, Jihun;Son, Younghwan;Kim, Taejin;Jo, Sangbeom;Jung, Seungjoo;Heo, Jun;Bong, Taeho;Kim, Donggeun
    • Journal of The Korean Society of Agricultural Engineers
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    • v.65 no.5
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    • pp.1-11
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    • 2023
  • Due to climate change and aging of reservoirs, damage to embankment slopes is increasing. However, the safety diagnosis of the reservoir slope is mainly conducted by visual observation, and the time and economic cost are formidable to apply soil mechanical tests and slope stability analysis. Accordingly, this study presented a predicting method for the compaction and strength characteristics of the reservoir embankment soil using a portable static cone penetration test. The predicted items consisted of dry density, cohesion, and internal friction angle, which are the main factors of slope stability analysis. Portable static cone penetration tests were performed at 19 reservoir sites, and prediction equations were constructed from the correlation between penetration resistance data and test results of soil samples. The predicted dry density and strength parameters showed a correlation with test results between R2 0.40 and 0.93, and it was found to replace the test results well when used as input data for slope stability analysis (R2 0.8134 or more, RMSE 0.0320 or less). In addition, the prediction equations for the minimum safety factor of the slope were presented using the penetration resistance and gradient. As a result of comparing the predicted safety factor with the analysis results, R2 0.5125, RMSE 0.0382 in coarse-grained soil, R2 0.4182 and RMSE 0.0628 in fine-grained soil. The results of this study can be used as a way to improve the existing slope safety diagnosis method, and are expected to be used to predict the characteristics of various soils and inspect slopes.

응력-침투 연계 해석에 의한 필 댐의 최적 설계

  • Park, Chun-Sik;Lee, Jun-Suk;Kim, Jong-Hwan
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.03a
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    • pp.862-870
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    • 2010
  • This thesis has been researched on optimized design method for the total cross section of embankment considering the fact that the size of embankment cross section is directly related with economic efficiency when dam designing. In general, embankment cross section of fill dam is either determined by cohesion and angle of internal friction, a strength parameter of embankment materials or by permeability of embankment. Therefore the size of embankment cross section depending on strength parameter of embankment materials was determined by using MIDAS-GTS program through stress-seepage coupled analysis at the time of fill dam design. As a result, determination of embankment cross section was more affected by the size of central core and permeability rather than by slope stability by shear strength and it was revealed that in case of embankment height being over 20m, stability against infiltration and slope action could be secured only when embankment slope is at least over 1:2.5. In addition, it was also revealed that in case of making the size of central core exceeding specification standard, total cross section of embankment could be reduced considerably and at the time of embankment design, adequate size and appropriateness of embankment cross section could be determined with referring the table suggested by this study.

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Analysis on the effect of strength improvement and water barrier by tunnel grouting reinforcement (터널 그라우팅 보강에 의한 차수 및 강도 증가효과의 분석)

  • You, Kwang-Ho
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.13 no.4
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    • pp.291-304
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    • 2011
  • Recently concern for subsea tunnels is increasing, The effect of high water pressure can not be ignored in the case of a deep subsea tunnel. Reinforcement like grouting is necessary for the stability of such a subsea tunnel. In this study, therefore, it was investigated how the water barrier and shear strength increment resulted from grouting had an effect on the stability of a subsea tunnel. To this end, two-dimensional hydromechanical coupled analyses were performed for a sensitivity analysis in terms of different range, permeability coefficient, and cohesion of grouting reinforcement for the rock classes I, III, and V with respect to RMR system. The mutual relationship between strength increment and water pressure increased by barrier effect due to grouting was investigated by analyzing the numerical results.

Evaluation of Shear Strength at Interface Between Geotextile and Cementitious Binder Materials (시멘트계 결합재가 적용된 지오텍스타일의 접촉면 전단강도 평가)

  • Son, Dong-Geon;Byun, Yong-Hoon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.64 no.1
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    • pp.91-98
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    • 2022
  • Multi-layered geotextile tubes may have problems on its stability when used as cofferdam. This study presents the shear strength characteristics at the interface between geotextiles and a cementitious binder material to improve the stability of the multi-layered geotextile tubes. In this study, two different types of geotextiles are used. After mixing with a rapid setting cement, fly ash, sand, accelerator, and water, the cementitious binder material is prepared at the interface between two geotextile samples and cured under water for a desired period. The specimen is placed on upper and lower direct shear boxes by using clamping systems. A series of direct shear tests for two different geotextiles are performed along the curing time under three vertical stresses. Experimental results show that the shear strength at the interface between the cementitious binder material and geotextiles is greater than that at the interface between two geotextiles. For two types of geotextiles, apparent cohesion occurs at the interface between the cementitious binder material and geotextiles. In addition, the friction angles for any curing time are improved, compared to the interface between two geotextiles. The cementitious binder material suggested for the interface between two geotextiles may be useful for the reinforcement of multi-layered geotextile tubes.

Evaluation of Dewaxing and Strengthening Treatments for Stabilization of Aged Beeswax-treated Hanji (열화 밀랍지의 탈랍 및 강도보강 처리 안정성 평가)

  • Jeong, Hye Young;Go, In Hee;Nam, Hyun Ju;Choi, Kyoung Hwa
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.6
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    • pp.10-16
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    • 2013
  • This study aims to carry out the final evaluation on the deterioration stability of dewaxing and strengthening treatments devised to conserve and restore the beeswax-treated volumes of the Annals of the Joseon Dynasty. Thus, this study artificially deteriorated dewaxed Hanji, strengthened Hanji and beeswax-treated Hanji with optimized processing conditions applied, and comparatively analyzed the deterioration characteristics of each kind of Hanji. As a result of this study, it turned out that there was the loss of physical strength and the value of $L^*$ was increased and the values of $a^*$ and $b^*$ were decreased from removing beeswax after dewaxing by supercritical fluid extraction (SFE). Also deteriorated strength during dewaxing was reinforced by strengthening treatment with methylcellulose and it showed higher strength than beeswax-treated Hanji. From the evaluation on deterioration stability after dewaxing and strengthening, it turned out that deterioration stability of strengthened Hanji is the superior. Therefore, it is presumed that conservation of aged beeswax-treated Hanji can be improved and extended when dewaxing and strengthening are applied under optimum conditions.

Strength Properties of CLC According to Additional Ratio of Polymer (폴리머 첨가율에 따른 CLC의 강도 특성)

  • Lee, Jeong-Taek;Lee, Chang- Woo;Hwang, Woo-Jun;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.83-84
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    • 2022
  • Zero-energy construction is being emphasized due to environmental pollution. However, in the case of external insulation using organic insulation with good insulation performance, there are many studies on inorganic insulation as it shows limitations on fire stability. In addition, as the demand for stone for exterior walls increases, Cellular Light -weight Concrete(CLC) with polymer is used to supplement fire stability and insulation performance, and the construction of stone is complemented by combining organic insulation, inorganic insulation, and stone. In this study, the compressive strength and adhesion in tension of CLC are studied. As a result of the experiment, the compressive strength of 28 days according to the polymer addition rate did not change. The adhesion in tension according to the polymer addition rate tends to increase as the addition rate increases. The target adhesion in tension is 0.8 MPa, but the maximum value of the experiment did not reach the target value, and further research was needed to combine to maintain the density and improve the adhesion in tension.

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The Effect of the Area Ratio and Change of Location on the Buckling Stress of Two Rectangular Plates Spot-welded (면적비와 위치변화가 점용접된 두 사각평판의 좌굴응력에 미치는 영향)

  • Han, Geun-Jo;An, Seong-Chan;Sim, Jae-Jun;Lee, Hyeon-Cheol;Jang, Hwal-Su
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.12
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    • pp.54-59
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    • 2001
  • The stability of a thin plate structure is very crucial problem which results buckling. Because the buckling strength of thin plates is lower than the yield strength of the material, reinforcement plate must be used to increase the buckling strength. And, in this case, spot welding is commonly used, however, the spot welded joints are practically designed by experimental decisions, so it is Inefficient and has the risks of buckling demolition. In this study, two parameters, such as the area ratio and the distance ratio of spot welding which have influence on the buckling strength, should be chosen. Under compressive and shearing load, the effect of two parameters on the critical stress is discussed.

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