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Study on the Synthesis of Graphene Nanowall by Controlling Electric Field in a Radio Frequency Plasma CVD Process (RF 플라즈마 CVD 프로세스의 전계제어에 의한 그래핀 나노월 성장 연구)

  • Han, SangBo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.28 no.9
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    • pp.45-51
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    • 2014
  • This work carried out for the effective synthesis characteristics of graphene nanowall film by controlling the electric field in a RF plasma CVD process. For that, the bipolar bias voltage was applied to the substrate such as Si and glass materials for the best chemical reaction of positive and negative charges existing in the plasma. For supplying the seed formation sites on substrate and removing the oxidation layer on the substrate surface, the electron bombardment into substrates was performed by a positive few voltage in hydrogen plasma. After that, hydrocarbon film, which is not a graphene nanowall, was deposited on substrates under a negative bias voltage with hydrogen and methane gases. At this step, the film on substrates could not easily identify due to its transparent characteristics. However, the transparent film was easily changed into graphene nanowall by the final hydrogen plasma treatment process. The resultant raman spectra shows the existence of significant large 2D peaks corresponding to the graphene.

Analysis of Flow Reversal by Tidal Elevation and Discharge Conditions in a Tidal River (감조하천에서 조위 및 유량조건에 따른 역류 분석)

  • Song, Chang Geun;Kim, Hyung-Jun;Rhee, Dong Sop
    • Journal of the Korean Society of Safety
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    • v.29 no.6
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    • pp.104-110
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    • 2014
  • The Han River is the only waterway in Korea where estuary is not blocked by dykes so that tidal water is flowing in and out through the tidal reach. The extreme tidal range in the Yellow Sea causes an intense flood current, stretching over horizontal extents of tens of kilometers into the rivers. To elucidate the flow reversal by discharge conditions and transient tidal level in the Han river, numerical simulations were conducted under 7 boundary conditions for two days with 10 minute time step. As the flow conditions changed from low discharge and high tidal difference to high discharge and low tidal difference, the flow reversals became weaker and the velocity of forward flow direction became higher due to the increased flow momentums and decreased tidal differences. In the case of normal flow, the maximum reverse velocity was 0.4 m/s, which was equivalent to the maximum forward velocity. In addition, the pattern of the development and decay of forward and reverse flow was presented.

Self Tuning PI Controller of Induction Motor using Fuzzy Control (퍼지제어를 이용한 유도전동기의 자기동조 PI제어기)

  • Nam, Su-Myeong;Lee, Jung-Chul;Lee, Hong-Gyun;Lee, Young-Sil;Chung, Dong-Hwa
    • Proceedings of the KIEE Conference
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    • 2004.10a
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    • pp.173-175
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    • 2004
  • This paper presents a novel design of a self tuning PI controller of induction motor using fuzzy control. In this approach, the fuzzy tuning of a PI controller gains is achieved through fuzzy rules deduced from many robustness simulation tests applied to several induction motors, for a variety of operating conditions such as response to speed command from standstill, step load torque application and speed variations, with nominal parameters and an changed rotor resistance, self inductance and inertia. Simulation results on a speed controller of induction motor are presented to show the effectiveness of the proposed gain tuner. And this controller is better than the fixed gains one in terms of robustness, even under great variations of operating conditions and load disturbance.

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Dielectric Characteristics through 2D-correlation Analysis of SiOCH Thin Film deposited by BTMSM/O2 High Flow Rates (BTMSM/O2 고유량으로 증착된 SiOCH 박막의 2차원 상관관계 분석을 통한 유전특성 연구)

  • Kim, Min-Seok;Hwang, Chang-Su;Kim, Hong-Bae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.6
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    • pp.544-551
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    • 2008
  • We have studied the dielectric characteristics of low-k interlayer dielectric materials fabricated by PECVD for various precursor's flow rates. BTMSM precursor was introduced with the flow rates from 42 sccm to 60 sccm by 2 sccm step in the constant flow rate of 60 sccm $O_2$. The absorption intensities of Si-O-$CH_x$ bonding group and Si-$CH_x$ bonding group changed synchronously for the variation of precursor flow rate, but the intensity of Si-O-Si(C) responded asynchronously with the $CH_x$ combined bonds. The heat treatment reduced the FTIR absorption intensity of Si-O-$CH_x$ bonding group and Si-$CH_x$ bonding group but increased the intensity of Si-O-Si(C). The nanopore and free space formed by the increasement of caged link mode and cross link mode of Si-O-Si(C) group implied the origin of low-k SiOCH films.

The Automatical Process Map Generation Using Network Representation In Radiopharmaceutical Synthesis (네트워크 모델링을 통한 방사성의약품 합성 프로세스 맵 자동생성 시스템)

  • Lee, Cheol-Soo;Heo, Eun-Young;Kim, Jong-Min;Kim, Dong-Soo
    • IE interfaces
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    • v.24 no.2
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    • pp.156-163
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    • 2011
  • The radiopharmaceutical synthesis for PET (positron emission tomography) is composed of chemical reactions using automated synthetical equipment. Due to the radioactive material, the automated equipment is being frequently developed to replace human operators who conduct dangerous, repetitive and dexterous operations. As to operation, the manipulating program is commonly coded using the spread sheet while the whole actuators are mapped in every step. The process map (program) is changed according to such parameters as temperature of reactor, keeping time, mixture sequence and amount of reagent. In cases of customizing the automated synthetical equipment or developing the new radiopharmaceuticals, lots of experiments should be conducted and the programming mistake is not allowed as it can lead abnormal control of the equipment to leak the radioactive materials. The exact process map has depended on trial and error manner. Thus, this study developed the methodology to tabulate the synthetical process to convert the process map automatically while the synthetical module formation is represented by a network model. The proposed method is validated using the actual radiopharmaceutical synthetical procedure.

A Study on the Bending Collapse at the Open Cross-Section Members with Experiment and Analysis (열린 단면 부재의 굽힘 붕괴 실험 및 해석에 관한 연구)

  • 이승철;강신유
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.4
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    • pp.132-139
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    • 2004
  • The open section members have been used as the members of vehicle such as automotives, airplanes and trains. When vehicles are crashed, these members have absorption of the energy and it is necessary for retainment of the survival space, and as the result, the prediction for the displacement of members in this case of the crash of vehicles is very important. The displacements of members in this case of the crash of automotives show combined aspect of both axial collapse and bending collapse. In the rollover accident when bending collapse happen, the collapse of each members is progressed by the plastic hinge which made from bending moment, and therefore the research for the behavior of members under bending moment after collapse is necessary to determine the internal energy which the members can absorb and the deformed shapes of the members on the step of design. In this paper, the characteristics of bending collapse at the members of the open cross-section were studied with experiment and numerical analysis. We made a comparative studied of the result of the experiment, and changed the axis according to the parallel-axis theorem.

Electrorhelological Properties of Monodispersed Submicron-sized Hollow Polyaniline Adipate Suspension

  • Sung, Bo-Hyun;Choi, Ung-Su
    • KSTLE International Journal
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    • v.6 no.1
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    • pp.28-32
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    • 2005
  • The electrorheoloRical (ER) fluids are composed of a colloidal dispersion of polarizable particles in insulating oil, and it's the rheological property changes by the applied electric field. These changed are reversible and occur fast within a fewmilliseconds. The ER properties of the ER fluid such as increment of viscosity and yield stress come from the particle chain structure induced by electric fleld. When formulating the ER fluid for a speciflc application, some requirement must besatisfled, which are high yield stress under electric field, rapid response, and dispersion stability. While this characteristic makes valuable ER fluids in valious industrial applications, their lung term and quiescent application has been limited because ofproblems with particle sedimentation. In an effort to overcome sedimentation problem of ER fluids, the anhydrous ER materials of monodispersed hollow polyaniline (PANI) and adipate derivative respectively with submicron-sized suspension providing wide operating temperature range and other advantage were synthesized in a four-step procedure. The ER fluidswere characterized by FT-lR, TGA, DLS, SEM, and TEM. Stability of the suspensions was examined by an UV spectroscopy.The rheological and electrical properties of the suspension were investigated Couette-type rheometer with a high voltagegenerator, current density, and conductivity. And the behavior of ER suspensions was observed by a video camera attached toan optical microscope under 3kV/mm. The suspensions showed good ER properties, durability, and particle dispersion.

Enhancement of Fluorescent Properties and Electrochemical Reduction of Coumarin Derivatives (Coumarin 유도체들의 전기화학적 환원과 형광성의 증강)

  • Chun, Hyun Ja;Kim, Sung Hyun;Jung, Eun Joo;Lee, Hye Suk;Kim, Il Kwang
    • Analytical Science and Technology
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    • v.18 no.1
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    • pp.89-95
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    • 2005
  • Studies on the electrochemical reduction of 7-acetoxy-4-bromomethyl-coumarin (ABMC), 7-acetoxymethyl coumarin (AMC), and coumarin in 0.1 M tetraethyl ammonium perchlorate acetonitrile solution were carried out with direct current, differential pulse polarography, cyclic voltammetry, and controlled potential coulometry. The electrochemical reduction of ABMC was proceeded through three irreversible steps coupled with the chemical reactions. The solution color was changed to yellow when the carbonyl group was reduced during second step and the color change was independent with bromo group of ABMC. Fluorescent intensity was highest when the electrochemical reduction was controlled at near the overpotential of supporting electrolyte (-2.3 volts).

PSYCHO-PHYSICS

  • Oh, Hung-Kuk
    • Proceedings of the Korean Society for Emotion and Sensibility Conference
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    • 2000.04a
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    • pp.35-38
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    • 2000
  • Conventional atom model must be criticized on the following four points.(1) natural motions between positive and negative entities are not circular motions but linear going and returning ones, for examples sexual motion, tidal motion, day and night etc.(2) Potential energy generation was neglected when electron changes its orbit from outer one to inner one. The hv is the kinetic energy of the photo-electron. The total energy difference between orbits comprises kinetic and potential energies. (3) The structure of the space must be taken into consideration because the properties of the electron do not changed during the transition from outer orbit to inner one even though it produces photon. (4) Total energy conservation law applies to the energy flow between mind and matter because we daily experiences a interconnection between mind and body.New atomic model 9the crystallizing $\pi$-bonding) was proposed in the journal of material processing technology since 1997 for the explanation of the mechanical behaviors in terms of physics. $\prod$-ray physics proved that the electrons can come out from in the nucleus and modern chemistry corresponds to the $\pi$-bonding by the nuclear electrons. The $\pi$-bonding structure of the protons outside the nucleus is that electrons move between protons of the different atoms. The perception step and the characteristic frequency in signal transduction is due to the accumulation of the $\pi$-rays outside of the proton before their absorption to the nucleus.

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A new hybrid optimization algorithm based on path projection

  • Gharebaghi, Saeed Asil;Ardalan Asl, Mohammad
    • Structural Engineering and Mechanics
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    • v.65 no.6
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    • pp.707-719
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    • 2018
  • In this article, a new method is introduced to improve the local search capability of meta-heuristic algorithms using the projection of the path on the border of constraints. In a mathematical point of view, the Gradient Projection Method is applied through a new approach, while the imposed limitations are removed. Accordingly, the gradient vector is replaced with a new meta-heuristic based vector. Besides, the active constraint identification algorithm, and the projection method are changed into less complex approaches. As a result, if a constraint is violated by an agent, a new path will be suggested to correct the direction of the agent's movement. The presented procedure includes three main steps: (1) the identification of the active constraint, (2) the neighboring point determination, and (3) the new direction and step length. Moreover, this method can be applied to some meta-heuristic algorithms. It increases the chance of convergence in the final phase of the search process, especially when the number of the violations of the constraints increases. The method is applied jointly with the authors' newly developed meta-heuristic algorithm, entitled Star Graph. The capability of the resulted hybrid method is examined using the optimal design of truss and frame structures. Eventually, the comparison of the results with other meta-heuristics of the literature shows that the hybrid method is successful in the global as well as local search.