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Fabrication and Characterization of Nano-sized Fe-50 wt% Co Powder from Fe- and Co-nitrate (Fe- 및 Co-질산염을 이용한 Fe-50 wt% Co 나노분말의 합성 및 특성 평가)

  • Riu, Doh-Hyung;Oh, Sung-Tag
    • Korean Journal of Materials Research
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    • v.20 no.10
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    • pp.508-512
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    • 2010
  • The optimum route to fabricate nano-sized Fe-50 wt% Co and hydrogen-reduction behavior of calcined Fe-/Conitrate was investigated. The powder mixture of metal oxides was prepared by solution mixing and calcination of Fe-/Co-nitrate. A DTA-TG and microstructural analysis revealed that the nitrates mixture by the calcination at $300^{\circ}C$ for 2 h was changed to Fe-oxide/$Co_3O_4$ composite powders with an average particle size of 100 nm. The reduction behavior of the calcined powders was analyzed by DTA-TG in a hydrogen atmosphere. The composite powders of Fe-oxide and Co3O4 changed to a Fe-Co phase with an average particle size of 40 nm in the temperature range of $260-420^{\circ}C$. In the TG analysis, a two-step reduction process relating to the presence of Fe3O4 and a CoO phase as the intermediate phase was observed. The hydrogen-reduction kinetics of the Fe-oxide/Co3O4 composite powders was evaluated by the amount of peak shift with heating rates in TG. The activation energies for the reduction, estimated by the slope of the Kissinger plot, were 96 kJ/mol in the peak temperature range of $231-297^{\circ}C$ and 83 kJ/mol of $290-390^{\circ}C$, respectively. The reported activation energy of 70.4-94.4 kJ/mol for the reduction of Fe- and Co-oxides is in reasonable agreement with the measured value in this study.

Head Pose Estimation Based on Perspective Projection Using PTZ Camera (원근투영법 기반의 PTZ 카메라를 이용한 머리자세 추정)

  • Kim, Jin Suh;Lee, Gyung Ju;Kim, Gye Young
    • KIPS Transactions on Software and Data Engineering
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    • v.7 no.7
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    • pp.267-274
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    • 2018
  • This paper describes a head pose estimation method using PTZ(Pan-Tilt-Zoom) camera. When the external parameters of a camera is changed by rotation and translation, the estimated face pose for the same head also varies. In this paper, we propose a new method to estimate the head pose independently on varying the parameters of PTZ camera. The proposed method consists of 3 steps: face detection, feature extraction, and pose estimation. For each step, we respectively use MCT(Modified Census Transform) feature, the facial regression tree method, and the POSIT(Pose from Orthography and Scaling with ITeration) algorithm. The existing POSIT algorithm does not consider the rotation of a camera, but this paper improves the POSIT based on perspective projection in order to estimate the head pose robustly even when the external parameters of a camera are changed. Through experiments, we confirmed that RMSE(Root Mean Square Error) of the proposed method improve $0.6^{\circ}$ less then the conventional method.

An Investigation of Performance Characteristics of A Biogas-Fueled Motorcycle Engine (바이오 가스 이륜차 기관의 성능 특성 연구)

  • Huynh, Thanh Cong;Chiem, Tran Lam;Vu, Thi Kim Chau
    • Journal of Hydrogen and New Energy
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    • v.23 no.4
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    • pp.373-381
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    • 2012
  • To determine the performance characteristics of motorcycle engine using biogas for practical use, the intake system of a 110 cc motorcycle engine is properly modified to operate with biogas as a fuel. Biogas is a potentially renewable fuel for replacing gasoline in future, but it has high percentage of $CO_2$ that could lead to slow the burning rate of biogas-air mixture and cause instability in combustion. Thus, the performance characteristics of biogas-fueled motorcycle engines could be different from those of gasoline motorcycle engines. In this paper, the important parameters of performance characteristics (such as: power output, thermal efficiency, fuel consumption, exhaust emission,${\cdots}$) of biogas-fueled motorcycle engine are studied and estimated with change of engine speed and load. The obtained results when operating with biogas are used to compare with that of gasoline fuel under the same operating conditions. Engine speed in the experimental is changed from 1500 rpm (idle-mode) up to 3500 rpm by a step of 500 rpm. Engine load is changed from zero to maximum load with the help of an exciting voltage device from generator-type dynamometer. The experimental results show that the tested engine operated with richer biogas-air mixture than that of gasoline-air mixture under the same test conditions. Biogas-fueled engine gives a higher fuel consumption and lower thermal efficiency under the same power output. Brake thermal efficiency of biogas engine is found to be about 3% lower than gasoline-fueled motorcycle engine for whole range of speed. Exhaust emission of biogas-fueled motorcycle engine (such as: CO, HC) is found to be lower than the limitation level of the emission standards of Vietnam for motorcycle engines (CO <4.5% HC <1200 ppm).

Development and Application of Program Based on Peer Instruction for Science Gifted Students of Start Period (탐색기 과학영재를 위한 동료교수법 기반 교수·학습 프로그램 개발 및 적용)

  • Lee, Ji Won;Kim, Jung Bog
    • Journal of Gifted/Talented Education
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    • v.23 no.2
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    • pp.237-256
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    • 2013
  • The purpose of this study is to develop program that take a genuine interest in science and motivate students to keep up their study for science gifted children of start period. In this study, we develop and apply the program about sinking and floating for elementary science gifted students, and analyse degree of conceptual change. Students' prior knowledge is analysed for developing the program, and each step is settled about concept of density and buoyancy. Conceptests are arranged into step by step, and we apply the program to 26 science gifted students of 6th grade elementary school. We compare a percentage of correct answers of pre-test and post-test and evaluate Hake gain for analysis of degree of conceptual change. As a result, science gifted students' concepts are changed effectively into scientific concepts by program based on peer instruction for gifted students of start period. And they evaluate the program is novel and useful, also they can be motivated by the program.

Proposing the Method for Improving the Forecast Accuracy of Loan Underwriting (대출심사의 예측 정확도 향상을 위한 방법 제안)

  • Yang, Yu-Young;Park, Sang-Sung;Shin, Young-Geun;Jang, Dong-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.4
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    • pp.1419-1429
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    • 2010
  • Industry structure and environment of the domestic bank have been changed by an influx of large foreign-banks and advanced financial products when the currency crisis erupted in Korea. In a competitive environment, accurate forecasts of changes and tendencies are essential for the survival and development. Forecast of whether to approve loan applications for customer or not is an important matter because that is related to profit generation and risk management on the bank. Therefore, this paper proposes the method to improve forecast accuracy of loan underwriting. Processes in experiments are as follows. First, we select the predictor variables which affect significantly to the result of loan underwriting by correlation analysis and feature selection technique, and then cluster the customers by the 2-Step clustering technique based on selected variables. Second, we find the most accurate forecasting model for each clustering by applying LR, NN and SVM. Finally, we compare the forecasting accuracy of the proposed method with the forecasting accuracy of existing application way.

Incremental Regression based on a Sliding Window for Stream Data Prediction (스트림 데이타 예측을 위한 슬라이딩 윈도우 기반 점진적 회귀분석)

  • Kim, Sung-Hyun;Jin, Long;Ryu, Keun-Ho
    • Journal of KIISE:Databases
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    • v.34 no.6
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    • pp.483-492
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    • 2007
  • Time series of conventional prediction techniques uses the model which is generated from the training step. This model is applied to new input data without any change. If this model is applied directly to stream data, the rate of prediction accuracy will be decreased. This paper proposes an stream data prediction technique using sliding window and regression. This technique considers the characteristic of time series which may be changed over time. It is composed of two steps. The first step executes a fractional process for applying input data to the regression model. The second step updates the model by using its information as new data. Additionally, the model is maintained by only recent data in a queue. This approach has the following two advantages. It maintains the minimum information of the model by using a matrix, so space complexity is reduced. Moreover, it prevents the increment of error rate by updating the model over time. Accuracy rate of the proposed method is measured by RME(Relative Mean Error) and RMSE(Root Mean Square Error). The results of stream data prediction experiment are performed by the proposed technique IMQR(Incremental Multiple Quadratic Regression) is more efficient than those of MLR(Multiple Linear Regression) and SVR(Support Vector Regression).

The Development and Application of Practical Problem-based Lesson Plan on Consumer Choice of Genetically Modified Food - Focused on the 'Dietary Life' in High School Home Economics - (유전자변형식품 선택의 실천적문제중심 교수.학습 과정안 개발 및 적용 - 고등학교 식생활 영역 -)

  • Kang, Kyung-Hwa;Kim, Young-Nam
    • Journal of Korean Home Economics Education Association
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    • v.22 no.2
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    • pp.101-113
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    • 2010
  • The purpose of this study is to develop and evaluate the practical problem-based lesson plan for high school home economics class focusing on consumer choice of genetically modified(GM) food. The ADDIE instructional design model was applied. The first analysis step, practical problems were chosen based on the previous studies and the educational goal suggested in the 2007 revised curriculum. The next design and development steps, 4 hours of lesson plans were developed by reconstitution a chapter of Food Safety. Additional learning materials(17 student activity papers, 17 student reading materials, 3 teacher reading materials) were also developed. The implementation step, the lesson plans developed were applied to the S high school students in Bundang, Geyonggi-do. The last evaluation step, the perception change about GM food and the adequacy of teaching method were evaluated. As results, the studens' attitudes and minds towards the GM food were changed. The level of concern on GM food increased, and the ratio of students who would check whether GM food or not was increased. Also students showed high level of satisfaction on teaching method and materials.

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The application and development of the Evaluation Indicators in accordance with the Planning Stages of Low-Carbon City -in relevance with the stage of urban planning establishment, design and operation of urban structure, management and maintenance- (저탄소 도시계획의 단계별 평가지표 설정 및 적용 연구 -도시계획 수립, 설계 및 운영, 유지·관리 단계를 중심으로-)

  • Oh, Deog-Seong;Sung, Jae-Wook;Lee, Seo-Jeong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.9
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    • pp.4560-4571
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    • 2013
  • Current global issue of climate change is growing and greenhouse gases occur in most cities. To solve the problem of climate change, the city should be changed to low-carbon structure. Low-carbon city planning is a step-by-step plan from the initial establishment, from design and operation of urban structure, to maintenance and management should be considered as an integrated whole process. Under this background, this study evaluated the whole process of low-carbon urban planning ways. For this step, divided into three steps and eight divisions, 30 sub-indicators are derived. Through domestic and foreign cases analysis studies and survey of the relevant experts, results were derived. In order to improve these points, in the intial planning establishment stage, planning of urban policy and institutional steps should be made and the plan should be appropriate to the local characteristics. In the design and operation of urban structure stage, detailed and feasible approach is needed and maintenance and management stage, participation of various stakeholders, including establishing governance and management practices could see the need.

Microstructure and Properties of Organic-Inorganic Hybrids(PDMS/SiO$_2$) Through Variations in Sol-Gel Processing (졸-겔공정의 변수조절을 통해 제조된 유기-무기복합체 (PDMS/SiO$_2$)의 미세구조와 특성)

  • Eun, Hui-Tae;Hwang, Jin-Myeong
    • Korean Journal of Materials Research
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    • v.11 no.2
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    • pp.94-103
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    • 2001
  • SiO$_2$ and PDMS/SiO$_2$ xerogels which are derived PDMS into TEOS have been synthesized by sol-gel process and controlled pore size and distribution through 2 step acid/base catalyzed processes using HCI and NH$_4$OH as a catalyst. In HCl catalyzed SiO$_2$ and PDMS/SiO$_2$ xerogels, pH and gellation time of xerogel were 2.3~2.5 and 12~13 days, respectively, and the shape of xerogel was identified to pellet type and column type. Under acidic condition of final reaction solution, the hydrolysis rate is accelerating, resulting in long gel times. The shape of xerogel is pellet type. In contrast, under less acidic condition, the condensation rate is accelerating, resulting in shorter gel times and the shape of xerogel is column type. The surface area and average Pore size were changed 400$\rightarrow$600($\m^2$/g) and 15$\rightarrow$28$\AA$, respectively, depending to the increase of the mole ratio of HCl/NH$_4$OH, and represented uniform pore size distribution. It is that all the alkoxide groups are hydrolyzed by HCl after the first step and the condensation rate is enhanced by NH$_4$OH. The regular backbone structures of silica are formed at low temperature and the uniform pores are produced by heat treatment.

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Exploring Elementary Students' Positioning in a Context of Socio-scientific Issues (SSI) Education: Focus on an Action-oriented Climate Change Club Activity (과학 관련 사회적 문제 (SSI) 교육 맥락에서 초등학생의 위치짓기 양상 -실천 지향 기후변화 동아리 활동을 중심으로-)

  • Kim, Jong-Uk;Kim, Chan-Jong
    • Journal of The Korean Association For Science Education
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    • v.41 no.6
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    • pp.501-517
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    • 2021
  • In the present age, when the development of science and technology is leading the changes, this study supports the view that students should possess the literacy to participate democratically and critically in socio-scientific issues, and should be positioned as agentic and participatory citizens. Accordingly, we implemented a club activity that emphasize climate social action for elementary students, and explored how students were positioned in relation to climate change. In this study, position is defined as a complex cluster of rights and duties that students have in relation to climate change. The club activity was implemented throughout 46 sessions from March to July, 2019 for 11 sixth graders of 'H elementary School' in Seoul, and transcripts of video and interviews were analyzed by means of a constant comparison method. In the course of the activity consisting of three steps, the students exhibited different positioning and they are as follows: In the global warming modeling activity for Step 1, students were positioned as 'active learners', but at the same time, they showed a contradiction in being positioned as 'apprentice'. In the student-led research activities inherent to Step 2, they were positioned as 'scientists who design and conduct research' and 'bystanders' due to the controversial nature of SSI knowledge. As students participate in the social actions involved in Step 3, the position changed from 'elementary school students facing difficulty in making a change' to 'participatory citizens creating changes.' This study is significant because it shows students' potential to promote participatory and democratic citizenship through action-oriented SSI activities. In addition, pedagogical approaches were discussed dealing with the contradictions and limitations of positioning.