• Journal of the Korean Society of Safety
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• v.26 no.4
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• pp.47-58
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• 2011

Halogen free intumescent flame retardants(IFRS), such as the mixture of melamine phosphate(MP) and char forming agents(pentaerythritol(PER), di-pentaerythritol(DiPER), tris(2-hydroxyethyl) isocyanurate(THEIC)), were prepared and characterized. Polypropylene(PP)/$IFR_S$ composites were also prepared in the presence of ethylene diamine phosphate(EDAP) as a synergist and used into flame retardant PP powder coatings. Thermoplastic PP powder coatings at 20 wt% flame retardant loading were manufactured by extruded and then mechanical cryogenic crushed to bring them in fine powder form. These intumescent flame retardant powder coatings($IFRPC_S$) were applied on mild steel surface for the purpose of protection and decorative. It is a process in which a $IFRPC_S$ particles coming in contact with the preheated mild steel surface melt and form a thin coating layer. The obtained MP flame retardant was analyzed by utilizing FTIR, solid-state $^{31}P$ NMR, ICP, EA and PSA. The mechanical properties as tensile strength, melt flow index(MFI) and the thermal property as TGA/DTA and the fire safety characteristics as limiting oxygen index(LOI), UL94 test, SEM were used to investigate the effect of $IFRPC_S$. The experimental results show that the presence of $IFR_S$ considerably enhanced the fire retardant performances as evidenced by the increase of LOI values 17.3 vol% and 32.6 vol% for original PP and $IFRPC_S$-3(PP/MP-DiPER/EDAP), respectively, and a reduction in total flaming combustion time(under 15 sec) in UL94 test of $IFRPC_S$. The prepared $IFRPC_S$-3 have good comprehensive properties with fire retardancy 3.2 mm UL94 V-0 level, LOI value 32.6%, tensile strength $247.3kg/cm^2$, surface roughness Ra $0.78{\mu}m$, showing a better application prospect. Through $IFRPC_S$-2(PP/MP-PER/EDAP) and $IFRPC_S$-3 a better flame retardancy than that of the $IFRPC_S$-1(PP/MP/EDAP) was investigated which was responsible for the formed more dense and compact char layer, improved synergy effect of MP and PER/DiPER.

• Korean Journal of Materials Research
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• v.24 no.10
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• pp.550-555
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• 2014

The present study deals with the effects of tempering treatment on the microstructure and mechanical properties of Cu-bearing high-strength steels. Three kinds of steel specimens with different levels of Cu content were fabricated by controlled rolling and accelerated cooling, ; some of these steel specimen were tempered at temperatures ranging from $350^{\circ}C$ to $650^{\circ}C$ for 30 min. Hardness, tensile, and Charpy impact tests were conducted in order to investigate the relationship of microstructure and mechanical properties. The hardness of the Cu-added specimens is much higher than that of Cu-free specimen, presumably due to the enhanced solid solution hardening and precipitation hardening, result from the formation of very-fine Cu precipitates. Tensile test results indicated that the yield strength increased and then slightly decreased, while the tensile strength gradually decreased with increasing tempering temperature. On the other hand, the energy absorbed at room and lower temperatures remarkably increased after tempering at $350^{\circ}C$; and after this, the energy absorbed then did not change much. Suitable tempering treatment remarkably improved both the strength and the impact toughness. In the 1.5 Cu steel specimen tempered at $550^{\circ}C$, the yield strength reached 1.2 GPa and the absorbed energy at $-20^{\circ}C$ showed a level above 200 J, which was the best combination of high strength and good toughness.

• Carbon letters
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• v.22
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• pp.48-59
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• 2017

This study synthesized pure anatase carbon doped $TiO_2$ photocatalysts supported on a stainless steel mesh using a sol-gel solution of 8% polyacrylonitrile (PAN)/dimethylformamide (DMF)/$TiCl_4$. The influence of the pyrolysis temperature and holding time on the morphological characteristics, particle sizes and surface area of the prepared catalyst was investigated. The prepared catalysts were characterized by several analytical methods: high resolution scanning electron microscopy (HRSEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), and X-ray photoelectron spectroscopy (XPS). The XRD patterns showed that the supported $TiO_2$ nanocrystals are typically anatase, polycrystalline and body-centered tetragonal in structure. The EDS and XPS results complemented one another and confirmed the presence of carbon species in or on the $TiO_2$ layer, and the XPS data suggested the substitution of titanium in $TiO_2$ by carbon. Instead of using calcination, PAN pyrolysis was used to control the carbon content, and the mesoporosity was tailored by the applied temperature. The supported $TiO_2$ nanocrystals prepared by pyrolysis at 300, 350, and $400^{\circ}C$ for 3 h on a stainless steel mesh were actual supported carbon doped $TiO_2$ nanocrystals. Thus, $PAN/DMF/TiCl_4$ offers a facile, robust sol-gel related route for preparing supported carbon doped $TiO_2$ nanocomposites.

• Steel and Composite Structures
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• v.27 no.5
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• pp.577-598
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• 2018

The imperfect steel-concrete interface bonding is an important deficiency of the concrete-filled double skin tubular (CFDST) columns that led to separating concrete and steel surfaces under lateral loads and triggering buckling failure of the columns. To improve this issue, it is proposed in this study to use longitudinal and transverse steel stiffeners in CFDST columns. CFDST columns with different patterns of stiffeners embedded in the interior or exterior surfaces of the inner or outer tubes were analyzed under constant axial force and reversed cyclic loading. In the finite element modeling, the confinement effects of both inner and outer tubes on the compressive strength of concrete as well as the effect of discrete crack for concrete fracture were incorporated which give a realistic prediction of the seismic behavior of CFDST columns. Lateral strength, stiffness, ductility and energy absorption are evaluated based on the hysteresis loops. The results indicated that the stiffeners had determinant role on improving pinching behavior resulting from the outer tube's local buckling and opening/closing of the major tensile crack of concrete. The lateral strength, initial stiffness and energy absorption capacity of longitudinally stiffened columns with fixed-free end condition were increased by as much as 17%, 20% and 70%, respectively. The energy dissipation was accentuated up to 107% for fixed-guided end condition. The use of transverse stiffeners at the base of columns increased energy dissipation up to 35%. Axial load ratio, hollow ratio and concrete strength affecting the initial stiffness and lateral strength, had negligible effect of the energy dissipation of the columns. It was also found that the longitudinal stiffeners and transverse stiffeners have, respectively, negative and positive effects on ductility of CFDST columns. The conclusions, drawn from this study, can in turn, lead to the suggestion of some guidelines for the design of CFDST columns.

• Korean Journal of Metals and Materials
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• v.46 no.10
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• pp.609-616
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• 2008

Conventional bake-hardenable(BH) steels should be annealed at higher temperatures because of the addition of Ti or/and Nb which forms carbides and raises recrystallization start temperature. In this study, the development of new BH steels without Ti or Nb addition has been reviewed. The new BH steels have nearly same mechanical properties as the conventional BH steels even though it is annealed at lower temperature. The steels also show smaller deviation of the mechanical properties than that of the conventional BH steels because of the conarol of solute carbon content during steel making processes. The deviation of mechanical properties in conventional BH steels is directly dependent on the deviation of solute carbon which is greatly influenced by the amount of the carbide formers in conventional BH steels. Less alloy addition in the newly developed BH steels gives economical benefits. By taking the advantage of sulfur and/or nitrogen which scarenge in Interstitial-Free or conventional BH steels, fine manganese sulfides or nano size copper sulfides were designed to precipitate, and result in refined ferrite grains. Aluminum nitrides used as a precipitation hardening element in the developed steels were also and resull in fine and well dispersed. As a result, the developed steels with less production cost and reduced deviation of mechanical properties are under commercial production. Note that the developed BH steels are registered as a brand name of MAFE(R) and/or MAF-E(R).

• Journal of Korean Society of Steel Construction
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• v.14 no.6
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• pp.765-772
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• 2002

Many researchers have studied several vibration control devices such as TMD, TLD, and VED to reduce the acceleration level for tall buildings. Advantages of TLD (tuned liquid damper) include easy installation, low cost, and less maintenance. However, the dynamic characteristics of TLD must be verified by experiment and analysis due to the difficulties in evaluating the characteristics of water sloshing. In this study, free vibration and dynamic excitation experiments of structure with TLD were conducted to verify vibration control force of the proposed TLD for high-rise building. The parameters were mass ratio of water to structure, number of damping nets, and aspect ratio. From the test results, the responses of structure with water tank were observed to be smaller than those of structure alone. Furthermore, better damping effect could be achieved with larger mass ratio, more damping nets, and larger aspect ratio. However, in the case of water tank with no damping net, little damping effect was obtained.

• Proceedings of the KWS Conference
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• 2002.10a
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• pp.551-554
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• 2002

As a general rule, the brazing process between cemented carbides and steel used by Silver (Ag) type brazing filler. The composition of Ag type filler were used Ag-Cu-Zn-Cd type filler mainly. But, the demand of Cadmium (Cd)-free in Ag type filler was raised recently. The reason why Cd-free in Ag brazing filler were occupied to vaporize as a CdO$_2$ when brazing process, because of Cd element was almost low boiling point of all Ag type filler elements. And, CdO$_2$ was a very harmful element for the human body. This experiment was developed Cd-freeing on Ag type filler that was used Indium (In) instead of Cd element. In this experiment, there were changed from 0 to 5% In addition in Ag brazing filler and investigated to most effective percentage of Indium. As a result, the change of In addition instead of Cd, there was a very useful element and obtained same property only 3% In added specimens compared to Cd 19% added specimens. These specimens were obtained same or more deflective strength. In this case, there were obtained 70 MPa over strength and wide brazing temperature range 650-800 C. A factor of deflective strength were influenced by composition and the shape of $\beta$ phase and between $\beta$ phase and cemented carbides interface. Indium element presented as $\alpha$ phase and non-effective factor directly, but it's occupied to solid solution hardening as a phase. $\beta$ phase were composed 84-94% Cu-Ni-Zn elements mainly. Especially, the presence of Ni element in interface was a very important factor. Influence of condensed Ni element in interface layer was increased the ductility and strength of brazing layer. Therefore, these 3% In added Ag type filler were caused to obtain a high brazing strength.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.11a
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• pp.196-197
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• 2005

Cathodic protection is one of the successful ways to prevent corrosion of steel structures in marine environments. The unique feature of cathodic protection in seawater is the formation of calcareous deposits on cathodic metal surface. The formation principles of calcareous deposit seawater had been known for a long time. That is, cathodic reduction reactions associated with cathodic protection in seawater generate $OH^-$ at the metal surface in accordance with the formular ; 1/2 $O_2$ + $H_2O$ + $2e^-$ $2OH^-$ and $2H_2O$ + $2e^-$ ${\rightarrow}$ $H_2$ + $2OH^-$. These reactions increase the pH at the metal / seawater interface. The high pH causes precipitation of $Mg(OH)_2$ and $CaCO_3$ in accordance with the formular ; $Mg^{2+}$ + $2(OH)^-$ ${\rightarrow}$ $Mg(OH)_2$ and $Ca^{2+}$ + $HCO_3^-$ + $OH^-$ ${\rightarrow}$ $H_2O$ + $CaCO_3$. These are typically the main compounds in calcareous deposits. It obviously has several advantages compared to the conventional coatings, since the environment-friendly calcareous deposit coating is formed by the elements($Mg^{2+}$, $Ca^{2+}$) naturally present in seawater. In this study, environmental friendly calcareous deposit films were prepared on steel plates by electro plating technic in natural seawater. The influence of current density on composition ratio, structure and morphology of the coated films were investigated by scanning electron microscopy formation process of calcareous deposits films in natural seawater. And we confirmed the properties of all the films can be improved greatly by controlling the material structure and morphology with effective use of the electroplating method in natural seawater.

• Journal of Korean Society of Steel Construction
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• v.18 no.2
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• pp.161-171
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• 2006

paper presents the results of a three-dimensional study of the natural vibration of laminated composite rectangular plates with various combinations of clamped and free boundaries. The Ritz method was used to obtain the stationary values of the associated Lagrangian, with displacements approximated using mathematicaly complete, characteristic orthogonal polynomials. The correctness of the three-dimensional model was established through a convergence study of the non-dimensional frequencies, followed by a comparison of the analytical findings in the existing literature. The wide scope of additional three-dimensional frequency results explains the influence of a number of geometrical and material parameters for angle-ply and cross-ply laminated plates, namely aspect ratio (${\mathcal{a/b}}$), thickness ratio (${\mathcal{a/h}}$), orthotropy of material, number of plies (${\mathcal{N}}$), fiber orientation angle (${\theta}$), and stacking sequence.

• Journal of the Korea Concrete Institute
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• v.14 no.6
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• pp.851-863
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• 2002

Corrosion products of reinforcement in concrete induce pressure to the adjacent concrete due to the expansion of steel. This expansion causes tensile stresses around the reinforcing bar and eventually induces cracking through the concrete cover The cracking of concrete cover will adversely affect the safety as well as the service life of concrete structures. The purpose of the this study is to examine the critical corrosion amount which causes the cracking of concrete cover. To this end, a comprehensive experimental and theoretical study has been conducted. Major test variables include concrete strength and cover thickness. The strains at the surface of concrete cover have been measured according to the amount of steel corrosion. The corrosion products which penetrate into the pores and cracks around the steel bar have been considered in the calculation of expansive pressure due to steel corrosion. The present study indicates that the critical amount of corrosion, which causes the initiation of cracking, increases with an increase of compressive strength. A realistic relation between the expansive pressure and average strain of corrosion product layer in the corrosion region has been derived and the representative stiffness of corrosion layer was determined. A concept of pressure-free strain of corrosion product layer was introduced to explain the relation between the expansive pressure and corrosion strain. The proposed theory agrees well with experimental data and may be a good base for the realistic durability design of concrete structures.