• Journal of the Korean Chemical Society
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• v.57 no.1
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• pp.25-34
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• 2013

The efficiency of three complex surfactants based on sunflower oil and nitrogen containing compounds as corrosion inhibitors for mild steel in $CO_2$-saturated 1% NaCl solution, has been determined by weight loss and LPR corrosion rate measurements. These compounds inhibit corrosion even at very low concentrations. The inhibition process was attributed to the formation of an adsorbed film on the metal surface that protects the metal against corrosive media. The inhibition efficiency increases with increasing the concentration of the studied inhibitors. Maximum inhibition efficiency of the surfactants is observed at concentrations around its critical micellar concentration (CMC). Adsorption of complex surfactants on the mild steel surface is in agreement with the Langmuir adsorption isotherm model, and the calculated Gibbs free energy values confirm the chemical nature of the adsorption. Energy dispersive X-ray fluorescence microscopy (EDRF) observations of the electrode surface confirmed the existence of such an adsorbed film.

• Corrosion Science and Technology
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• v.16 no.2
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• pp.69-75
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• 2017

Zinc coating on carbon steels give the higher corrosion resistance in chloride containing environments and in carbonated concrete. However, hydrogen evolution accompanies the corrosion of zinc in the initial activity in fresh concrete, which can lead to the formation of a porous structure at the reinforcement -concrete interface, which can potentially reduce the bond-strength of the reinforcement with concrete. The present study examines the mechanism of the corrosion of hot-dip galvanized steel in detail, as in the model pore solutions and real concrete. Calcium ion plays an important role in the corrosion mechanism, as it prevents the formation of passive layers on zinc at an elevated alkalinity. The corrosion rate of galvanized steel decreases in accordance with the exposure time; however, the reason for this is not the zinc transition into passivity, but the consumption of the less corrosion-resistant phases of hot-dip galvanizing in the concrete environment. The results on the electrochemical tests have been confirmed by the bond-strength test for the reinforcement of concrete and by evaluating the porosity of the cement adjacent to the reinforcement.

• International Journal of Naval Architecture and Ocean Engineering
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• v.10 no.6
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• pp.670-682
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• 2018

This paper presents the experimental and numerical investigation results of the response of low-temperature steel (LT-FH32 grade steel) beams under repeated impacts at room temperature and a single impact at a sub-zero temperature. After conducting tensile tests at room and sub-zero, repeated impact tests were conducted on two clamped single-beam models at room temperature, and single-impact tests of two other clamped single-beam models were conducted at $-50^{\circ}C$. The single and repeated impact tests were conducted by releasing a knife-edge striker using a drop testing machine. The permanent deflection of the model measured after each impact gradually increased with increasing number of impacts. Under the reduced temperature, the permanent deflection of the models slightly decreased. The numerical analyses were also performed to predict the damage response of the tested single-beam models. A comparison of the numerical prediction with those of experiments showed quite reasonable agreement.

• Steel and Composite Structures
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• v.25 no.1
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• pp.19-34
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• 2017

The widespread damage to steel Moment Resisting Frames (MRFs) in past major earthquakes have underscored the need to understand the nonlinear inelastic behaviour of such systems. To assess the seismic performance of steel MRF, it is essential to model the nonlinear force-deformation behaviour of beam to column joints. To determine the extent of inelasticity in a beam to column joint, nonlinear finite element analysis is generally carried out, which is computationally involved and demanding. In order to obviate the need of such elaborate analyses, a simplistic method to predict the force-deformation behaviour is required. In this study, a simple, mechanics driven, hand calculation method is proposed to obtain the forcedeformation behaviour of strong axis beam to column moment joints. The force-deformation behaviour for twenty-five interior and exterior beam to column joints, having column to beam strength ratios ranging from 1.2 to 10.99 and 2.4 to 22, respectively, have been obtained. The force-deformation behaviour predicted using the proposed method is compared with the results of finite element analyses. The results show that the proposed method predicts the force-deformation behaviour fairly accurately, with much lesser computational effort. Further the proposed method has been used to conduct Nonlinear Dynamic Time History Analyses of two benchmark frames; close correspondence of results obtained with published results establishes the usefulness and computational accuracy of the method.

• Structural Engineering and Mechanics
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• v.74 no.3
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• pp.325-339
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• 2020

This study presents a practical application of topology optimization (TO) technique to seek the best form of perforated steel plate shear walls (PSPSW) in simple frames. For the numerical investigation, a finite element model is proposed based on the recent particular form of PSPSW that is called the ring-shaped steel plate shear wall. The TO is applied based on the sensitivity analysis to maximize the reaction forces as the objective function considering the fracture tendency. For this purpose, TO is conducted under a monotonic and cyclic loading considering the nonlinear behavior (material and geometry) and buckling. Also, the effect of plate thickness is studied on the TO results. The final material volume of the optimized plate is limited to the material volume of the ring-shaped plate. Finally, an optimized plate is introduced and its nonlinear behavior is investigated under a cyclic and monotonic loading. For a more comprehensive view, the results are compared to the ring-shaped and four usual forms of SPSWs. The material volume of the plate for all the models is the same. The results indicate the strength, load-carrying, and energy dissipation in the optimized plate are increased while the fracture tendency is reduced without changing the material volume.

• Korean Journal of Metals and Materials
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• v.46 no.10
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• pp.662-671
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• 2008

The behavior of hydrogen in the steel making process was investigated. The relation between the composition of ladle slag and hydrogen concentration in molten steel was considered. The hydrogen distribution ratio between ladle slag and molten steel was increased with increasing basicity of the slag; it was about 20 when the basicity of slag was 15. Hydroxyl capacity measured from the hydrogen distribution ratio between slag and the molten steel was comparatively corresponding to the value of hydroxyl capacity measured by the equilibrium reaction of slag and $H_2O$ gas. However, it is considerably different from the value calculated by regular solution model. The influence of hydrogen on a sticking type breakout is considered. The effect of hydrogen and $H_2O$ gas on the crystallization behavior of mold powder was investigated by DHTT (Dual hot thermocouple technique). As a result, it was proved that mold powder could be crystallized by $H_2O$ gas in the atmosphere. Therefore, it is concluded that $H_2O$ gas in the atmosphere can be a possible cause of the sticking type breakout that occasionally occurs in the continuous casting process.

• Steel and Composite Structures
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• v.33 no.1
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• pp.1-18
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• 2019

In the present study, the behavior of steel plate shear walls (SPSW) with variable column flexural stiffness is experimentally and numerically investigated. Altogether six one-bay one-story specimens, three moment resisting frames (MRFs) and three SPSWs, were designed, fabricated and tested. Column flexural stiffness of the first specimen pair (one MRF and one SPSW) corresponded to the value required by the design codes, while for the second and third pair it was reduced by 18% and 36%, respectively. The quasi-static cyclic test result indicate that SPSW with reduced column flexural stiffness have satisfactory performance up to 4% story drift ratio, allow development of the tension field over the entire infill panel, and cause negligible column "pull-in" deformation which indicates that prescribed minimal column flexural stiffness value, according to AISC 341-10, might be conservative. In addition, finite element (FE) pushover simulations using shell elements were developed. Such FE models can predict SPSW cyclic behavior reasonably well and can be used to conduct numerical parametric analyses. It should be mentioned that these FE models were not able to reproduce column "pull-in" deformation indicating the need for further development of FE simulations with cyclic load introduction which will be part of another paper.

• Steel and Composite Structures
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• v.31 no.4
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• pp.341-359
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• 2019

Non-monolithic concrete structural connections are commonly used both in new constructions and retrofitted structures where anchors are used for connections. Often, flaws are present in anchor system due to poor workmanship and deterioration; and methods available to check the quality of the composite system afterward are very limited. In case of presence of flaw, load transfer mechanism inside the anchor system is severely disturbed, and the load carrying capacity drops drastically. This raises the question of safety of the entire structural system. The present study proposes a wave propagation technique to assess the integrity of the anchor system. A chemical anchor (embedded in concrete) composite system comprising of three materials viz., steel (anchor), polymer (adhesive) and concrete (base) is considered for carrying out the wave propagation studies. Piezoelectric transducers (PZTs) affixed to the anchor head is used for actuation and the PZTs affixed to the surrounding concrete surface of the concrete-anchor system are used for sensing the propagated wave through the anchor interface to concrete. Experimentally validated finite element model is used to investigate three types of composite chemical anchor systems. Studies on the influence of geometry, material properties of the medium and their distribution, and the flaw types on the wave signals are carried out. Temporal energy of through time domain differentiation is found as a promising technique for identifying the flaws in the multi-layered composite system. The present study shows a unique procedure for monitoring of inaccessible but crucial locations of structures by using wave signals without baseline information.

• Steel and Composite Structures
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• v.39 no.4
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• pp.353-366
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• 2021

Cored moment resisting stub column (CMSC) was previously developed by the features of adopting a core segment which remains mostly elastic and reduced column section (RCS) details around the ends to from a stable hysteretic behavior with large post-yield stiffness and considerable ductility. Several full-scale CMSC components with various length proportions of the RCSs with respect to overall lengths have been experimentally investigated through both far-field and near-fault cyclic loadings followed by fatigue tests. Test results verified that the proposed CMSC provided very ductile hysteretic responses with no strength degradation even beyond the occurrence of the local buckling at the side-segments. The effect of RCS lengths on the seismic performance of the CMSC was verified to relate with the levels of the deformation concentration at the member ends, the local buckling behavior and overall ductility. Estimation equations were established to notionally calculate the first-yield and ultimate strengths of the CMSC and validated by the measured responses. A numerical model of the CMSC was developed to accurately capture the hysteretic performance of the specimens, and was adopted to clarify the effect of the surrounding frame and to perform a parametric study to develop the estimation of the elastic stiffness.

• Korean Journal of Metals and Materials
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• v.49 no.7
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• pp.515-521
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• 2011

Small punch creep testing has received attention due to the convenience of using smaller specimens than those of conventional uniaxial creep tests, which enables creep testing on developing or currently operational components. However, precedent studies have shown that it is necessary to consider friction between the punch and specimen when computing uniaxial equivalent stress from a finite element model. In this study, small punch creep behaviors of AISI 316L stainless steel, which is widely used in high temperature-high pressure machineries, have been compared for the two different ceramic balls such as $Si_3N_4$ and $Al_2O_3$. The optimal range of the friction coefficient is 0.4~0.5 at $650^{\circ}C$ for the best fit between experimental and simulation data of AISI 316 L stainless steel. The higher the friction coefficient, the longer the creep rupture time is. Therefore, the type of ceramic ball used must be specified for standardization of small punch creep testing.