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Enhancement of Electrical Properties on ZnO: Al Thin Film due to Hydrogen Annealing and SiO2 Coating in Damp-heat Environment

  • Chen, Hao;Jeong, Yun-Hwan;Park, Choon-Bae
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.2
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    • pp.58-61
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    • 2009
  • The electrical stability of ZnO: Al thin films deposited on glass substrate by the RF magnetron sputtering method have been modified by a hydrogen annealing treatment and $SiO_2$ protection layer. AZO thin films were deposited at room temperature and different RF powers of 50, 100, 150, and 200 W to optimize the AZO film growth condition. The lowest value of resistivity of $9.44{\times}10^{-4}{\Omega}cm$ was obtained at 2 mtorr, room temperature, and a power level of 150 W. Then, the AZO thin films were annealed at $250-400^{\circ}C$ for 1 h in hydrogen ambient. The minimum resistivity obtained was $8.32{\times}10^{-4}{\Omega}cm$ as-annealed at $300^{\circ}C$. The electrical properties were enhanced by the hydrogen annealing treatment. After a 72 h damp-heat treatment in harsh conditions of a water steam at $110^{\circ}C$ for four representative samples, a degradation of electrical properties was observed. The sample of hydrogen-annealed AZO thin films with $SiO_2$ protection layer showed a slight degradation ratio(17%) of electrical properties and a preferable transmittance of 90%. The electrical stability of AZO thin films had been modified by hydrogen annealing treatment and $SiO_2$ protection layer.

Impact of thermal and chemical treatment on the mechanical properties of E110 and E110G cladding tubes

  • Kiraly, M.;Hozer, Z.;Horvath, M.;Novotny, T.;Perez-Fero, E.;Ver, N.
    • Nuclear Engineering and Technology
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    • v.51 no.2
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    • pp.518-525
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    • 2019
  • The mechanical and corrosion behavior of the Russian zirconium fuel cladding alloy E110, predominantly used in VVERs, has been investigated for many decades. The recent commercialization of a new, optimized E110 alloy, produced on a sponge zirconium basis, gave the opportunity to compare the mechanical properties of the old and the new E110 fuel claddings. Axial and tangential tensile test experiments were performed with samples from both claddings in the MTA EK. Due to the anisotropy of the cladding tubes, the axial tensile strength was 10-15% higher than the tangential (measured by ring tensile tests). The tensile strength of the new E110G alloy was 11% higher than that of the E110 cladding at room temperature. Some samples underwent chemical treatment - slight oxidation in steam or hydrogenation - or heat treatment - in argon atmosphere at temperatures between 600 and $1000^{\circ}C$. The heat treatment during the oxidation had more significant effect on the tensile strength of the claddings than the oxidation itself, which lowered the tensile strength as the thickness of the metal decreased. The hydrogenation of the cladding samples slightly lowered the tensile strength and the samples but they remained ductile even at room temperature.

Bondline Strength Evaluation of Honeycomb Sandwich Panel For Cure Process and Moisture Absorption (경화공정 및 수분흡수에 따른 복합재료 하니콤 샌드위치 판넬의 접합강도특성 연구)

  • Choe, Heung-Seop;Jeon, Heung-Jae;Nam, Jae-Do
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.1
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    • pp.115-126
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    • 2001
  • In this paper, through a series of comparative experiments, effects of two different cure processing methods, cocure and precure, on the mechanical properties of honeycomb core materials for aircraft applications are considered. Mass of moisture accumulated into the closed cells of the sandwich panel specimen from the measured mass of moisture diffused to the full saturation state into the elements(skin, adhesive layer, Nomex honeycomb), consisting the honeycomb sandwich specimen has been calculated. Water reservoir of 70$\^{C}$ was used to have specimens absorb moisture to see the influence of moisture absorbed into sandwich panel on its mechanical properties. For the repair condition holding for 2 hours at 177$\^{C}$(350℉) temperature, a pressure due to the vapor expansion in each cell of the sandwich panel, which may result in the local separation of the interface between laminated skin and the surface of the honeycomb, has been estimated by vapor pressure-temperature relation from the thermodynamic steam table and compared to the pressure from the ideal gas state equation. The bonding strengths of the laminated skins on the flat surface of the Nomex honeycomb have been compared by the flatwise tension test and climbing drum peel test performed at room temperature for dry, wet and wet-repair specimens, respectively.

Studies on the Optimal Sterilization Conditions of Red Pepper Paste Packed in Retort Pouch. (레토르트 파우치 고추장의 적정 고온 살균조건에 관한 연구)

  • Lee, Shin-Young;Choi, Kook-Chi;Lee, Sang-Kyu
    • Journal of Industrial Technology
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    • v.3
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    • pp.87-94
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    • 1983
  • Heating characteristics of red pepper paste packed in report pouches of various thicknesses and their storage stability were investigated to determine the adequate processing conditions that good bacteriological safty and minimal quality changes could be obtained, when sterilized by using a steam-air system retort. A heat penetration into pouch-packed red pepper paste was carried out through by a conductive heat transfer, indicating a simple logarithmic heating curve, and the smaller thickness revealed the higher heat penetration rate, suggesting the possibility of high temperature-short time sterilization of red pepper paste. The processing conditions with Fo-value of 4.5 or higher were sufficient for keeping up bacterial safty, but based on C-value, better quality retention was obtained at pouch thickness of 15mm under the processing temperature of $120^{\circ}C$. Subsequent storage study revealed that the red pepper paste packed in 15mm and processed at $120^{\circ}C$ with Fo=4.5 could be held without any spoilage and overall acceptance change, when stored for 6 months at room temperature under the relative humidity of 70%. After 3 months storage in $38^{\circ}C$ under saturation humidity, overall acceptance of red pepper paste were judged not to be maintainable on the acceptable level, but it may be suggested that above the results could be kept up a desirable quality without any remarkable deterioration.

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THERMAL SHOCK FRACTURE OF SILICON CARBIDE AND ITS APPLICATION TO LWR FUEL CLADDING PERFORMANCE DURING REFLOOD

  • Lee, Youho;Mckrell, Thomas J.;Kazimi, Mujid S.
    • Nuclear Engineering and Technology
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    • v.45 no.6
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    • pp.811-820
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    • 2013
  • SiC has been under investigation as a potential cladding for LWR fuel, due to its high melting point and drastically reduced chemical reactivity with liquid water, and steam at high temperatures. As SiC is a brittle material its behavior during the reflood phase of a Loss of Coolant Accident (LOCA) is another important aspect of SiC that must be examined as part of the feasibility assessment for its application to LWR fuel rods. In this study, an experimental assessment of thermal shock performance of a monolithic alpha phase SiC tube was conducted by quenching the material from high temperature (up to $1200^{\circ}C$) into room temperature water. Post-quenching assessment was carried out by a Scanning Electron Microscopy (SEM) image analysis to characterize fractures in the material. This paper assesses the effects of pre-existing pores on SiC cladding brittle fracture and crack development/propagation during the reflood phase. Proper extension of these guidelines to an SiC/SiC ceramic matrix composite (CMC) cladding design is discussed.

Manufacturing 2.25Cr-1Mo Steel In Hot Rolling Strip Mill (2.25% Cr-1%Mo 합금계 열연강판 제조기술)

  • 노태훈
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.08a
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    • pp.390-398
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    • 1999
  • The thermomechanical control process(in hot rolling strip mill) was employed to produce 2.25Cr-1Mo steel, which is to be construction material for the steam generator for power plant. Although the Conventional processes has been the primary means of producing the 2.25Cr-1Mo steel, an alternative method was used to meet the specification of ASTM heat treatment for A387-22-Classl using autotempering after coiling in hot rolling strip mill. The microstructures, tensile properties at various temperatures, and creep-rupture properties have been investigated to compare the properties with those of materials produced by the conventional process and to certify the application of the thermomechanical control process to an actual process of manufacturing 2.25-Cr-1Mo steel, this in turn, will reduce the cost of the process. About 14 to 34% glanular bainite (remainder proetectoid ferrite) formed in a coil, and this variety of volume fraction stems from the different cooling rates, which varies with position of the coil after coiling. Tensile testing from room temperature to 700$^{\circ}C$ indicated that strength increases with test temperature showing peaks at around 600$^{\circ}C$. Creep-rupture properties have been being investigated at the temperature of 500$^{\circ}C$ with 27.5, 32kg/$\textrm{mm}^2$ loads and have showed no rupture for over 1000 hours.

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Evaluation of Degraded Materials by Automated Ball Indentation(ABI) Technique (압입법을 이용한 재료의 열화도 평가)

  • 김석민;석창성;이승석;권재도
    • Journal of the Korean Society of Safety
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    • v.15 no.1
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    • pp.28-35
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    • 2000
  • As huge energy transfer systems like a nuclear power plant, steam power plant and petrochemical plant are operated for a long time, mechanical properties are changed by degradation. The life time of the systems can be affected by the mechanical properties. So determination of the integrity of the metallic structure is required either to en4sure that failure will not occur during the service life of the components or to evaluate the lifetime extension of the structure. An automated ball indentation(ABI) method was developed as a non-destructive technique for evaluating the integrity of such metallic components. In this paper, we would like to present the aging evaluation technique by the ABI method. The five classes of the thermally aged CF8M specimens were prepared using an artificially accelerated aging method. After holding 100, 300, 900, 1800 and 3600 hours at 43$0^{\circ}C$, the specimens were cooled down using water to room temperature respectively. The tensile test, hardness test, charpy impact test, ABI test were performed. The results of the fracture test were compared with those of ABI test and the new evaluation technique of the integrity of metallic structures was developed.

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NON-ENZYMATIC BROWNING REACTIONS IN DRIED SQUID STORED AT DIFFERENT WATER ACTIVITIES (마른 오징어 저장중의 수분활성과 갈변반응)

  • CHOI Ho-Yeon;KIM Mu-Nam;LEE Kang-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.6 no.3_4
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    • pp.97-100
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    • 1973
  • In the previous work(Kim et al, 1973), the quality of sun-dried Alaska pollack, Theragra chalch-ogramma, was discussed in the aspect of non-enzymatic discoloration as a function of relative humidity during storage at room temperature($20^{\circ}C$). In this paper, sun-dried squid, Ommastrephes steam pacificus was investigated at the same aspect mentioned above. Fresh squid from the whole sale market was dressed, filleted, dried for 48 hours in the open air and finally stored in the humidistat chamber. Lipid oxidation ana development of non-enzymatic browning were tested by the same methods described in the previous paper. The TBA value showed a maximum peak on 30 day storage, hereafter tended to decrease gradually. The rate of browning, however, in water soluble fraction as well as in chloroform-methanol fraction was lower at 0.34 to 0.45 water activity than at any other case, and propagation of lipid oxidation was also diminished at the above level of water activity. From the results, it is recognized that storage at Aw=0.34 to 0.45 provides higher quality stability for sun-dried squid.

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A study on the Computer-Aided automatic Design of marine water ejector (선박용 수이젝터의 자동설계를 위한 전산프로그램의 개발)

  • 김경근;김용모;김주년;남청도
    • Journal of Advanced Marine Engineering and Technology
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    • v.10 no.1
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    • pp.74-84
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    • 1986
  • Ejectors, having no moving, lubricating and leaking parats, are widely used as marine pumps because of its high working confidence. For instance, uses in ships are stripping in crude oil tank, bilge discharge in engine room, ballast water pumping on are carrier, and brine discharge from fresh water generator. And it is also used as cooling water recirculating pump in boiling water type nuclear reactor and deep-well pump. It is not easy to determine the optimal dimension for designing each ejector agreed with its suggested performance condition, because complicated calculations must be repeated to obtain the maximum efficiency affected by flowrate ratio, head ratio, area ratio and so on. Therefore, it is considered that the CAD (Computer-Aided Design) for ejector is a powerful method for design according to the individual design condition. In this paper, a computer program for water ejector design is developed based on the previous paper on theoretical analysis and experimental results for water ejector. And from the theoretical approach, an equation for the working limit and an equation for determing the shape of throat are obtained. The validity of the present computer program is sufficiently confirmed through the comparison of the computed results with the main dimension of the previous manufactured water ejector. This program will be easily developed as the CAD for various kinds of ejectors, including steam ejector.

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Quality Characteristics of Tomato Packaged with Functional Film Applied to Essential Oil of Artemisia Princeps Pampanini (사자발쑥 정유를 첨가한 기능성 필름에 의한 토마토의 품질 특성)

  • You, Hae Lin;Chang, Min-Sun;Kim, Gun-Hee
    • Journal of the Korean Society of Food Culture
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    • v.30 no.6
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    • pp.766-772
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    • 2015
  • This research was conducted to investigate the effect of essential oil (EO) from Artemisia Princeps Pampanini on quality of tomato during storage. EO was extracted by steam distillation and diluted by 1 and 2%. Total phenolic contents and antioxidative activities of EO were analyzed. Tomato was packaged corrugated box covered with polypropylene (PP) film containing EO (1 and 2%) and then stored at room temperature for 10 days. During storage, appearance, weight loss rate, soluble solid contents, pH and a (redness) value were measured for tomato. Total phenolic contents of EO increased in a dose-dependence. The DPPH and ABTS radical scavenging activities also showed a concentration-dependent increase. The weight loss rate was lowest using the film packaged in 1% EO. During the storage period, soluble solid contents and pH increased in all treatments. The a value increased regardless of EO concentration in films. Especially, tomato packaged with EO film showed a lower a value than non EO-packaged ones. This result suggests that application of EO to film is effective for tomato quality preservation.