• 전기화학회지
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• 제5권3호
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• pp.143-152
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• 2002

Self-assembled monolayer(SAM)로 변형된 금 전극 위로 폴리피롤의 전기화학적 석출 과정을 수용액 상태에서 in-situ EQCM (Electrochemical Quartz Crystal Microbalance)과 ex-situ AFM (Atomic Force Microscopy)을 이용하여 조사하였다. 금 전극에서 cyclic voltammetry로 살펴본 폴리머의 석출은 산화 제한 전위 (anodic limiting potential) 값에 매우 의존적이었으며 주사 횟수에는 의존하지 않았다. 제한 산화 전위가 0.8V (vs Ag | ArCl) 이상일 때 폴리머의 석출은 크게 증가하였다. 그리고 주사 횟수가 증가하면서 질량의 비이상적 변화가 관찰되었는데 이것은 폴리피롤 필름의 rearrangement가 원인이라고 생각된다. 1-dodecanethiol SAM 전극과 thiophene SAM전극에서는 폴리머가 3차원적으로 성장하며 필름의 rearrangement를 수반하였지만 BPUS $(Bis(\omega(N-pyrrolyl)-n-undecyl)disulfide)$ SAM 전극에서는 2차원적인 layer-by-layer 성장을 하고 필름의 rearrangement는 관찰되지 않았다. 폴리머가 급격하게 전극 면으로 석출되면 사슬 모양과 도너츠 모양의 폴리머를 만들며, 정류 상태에 이르면서 주름잡힌 폴리머 필름이 생성되는 것이 원자 힘 현미경 (Atomic Force Microscopy) 이미지로 관찰되었다.

• Journal of Advanced Marine Engineering and Technology
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• 제3권1호
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• pp.19-31
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• 1979

Recently the adaptive control system, which keeps the control system always optimal by adjusting the control parameters automatically according to the variations of the plant parameters, have become very important in the field of control engineering. The adaptive control systems are usally composed of the plant identification, the decision of the optimal control parameters, and the adjustment of the control parameters. This paper deals with a method of the adaptive control system when PI or PID controller is used in the feed back control system. Its controlled object (the plant) is assumed to be described by the transfer function of $\frac{ke^{-LS}}{1+TS}$ where k, T and L are steady state gain, time constant and pure dead time respectively, and their values are variable in accordance with the change of environmental circumstance. It has been known that a pseudo-random binary signal is quite effective for the measurement of an impulse response of a plant. In adaptive control systems, however, the impulse response itself is not appropriate to determine the control parameters. In this paper, the authors propose a method to estimate directly the parameters of the plant k, T and L by means of the correlation technique using 3 level M-sequence signal as a test signal. The authors also propose a method to determine the optimal parameters of the PI or PID controller in the sense of minimizing the square integral of the control error in the feed back control system, and the values of the optimal parameters are computed numerically for various values of T and L, and the results are examined and compared with those of the conventional methods. Finally the above-mentioned two methods are combined and an algorithm to struct an adaptive control system is suggested. The experiments for the indicial responses by means of both the model of the temperature control system using SCR actuater and the analog simulations have shown good results as expected, and the effectiveness of the proposed method is verified. The M-sequence generator and the time delay circuit, which are manufactured for the experiments, are operated in quite a good condition.

• 대한기계학회논문집B
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• 제33권7호
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• pp.486-494
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• 2009

One-dimensional modeling of $CH_4$/air premixed flame was conducted to validate the heat loss model and investigate NOx formation characteristics in the postflame region. The predicted temperature and NO concentration were compared to experimental data and previous heat loss model results using a constant gradient of temperature (100 K/cm). The following conclusions were drawn. In the heat loss model using steady-state heat transfer equation, the numerical results using the effective heat loss coefficient ($h_{eff}$) of $1.0\;W/m^2K$ were in very good agreement with the experiments in terms of temperature and NO concentration. On the other hand, the calculated values using the constant gradient of temperature (100 K/cm) were lower than that in the experiments. Although the effects of heat loss suppress NO production near the flame region, a significant difference in NO concentration was not found compared to that under adiabatic conditions. In the postflame region, however, there were considerable differences in NO emission index as well as the contribution of NO formation mechanisms. In particular, in the range of ${\phi}\;{\geq}\;0.8$, the prompt NO mechanism plays an important role in the NO reduction under the adiabatic condition. On the other hand, the mechanism contributes to the NO production under the heat loss conditions.

• 공업화학
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• 제8권3호
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• pp.517-523
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• 1997

본 연구는 유동층연소로에서 유,무연탄 혼합연소시 대기오염물질 발생과 연소효율에 관하여 실험하였으며, 실험결과는 다음과 같다. 유동층연소로 높이가 증가할수록 이산화황과 질소산화물의 농도는 증가하는 것으로 나타났으며, 무연탄 혼합비가 증가할수록 이산화황의 농도는 증가하였으나 질소산화물농도는 큰 변화가 없었다. 무연탄 혼합비가 증가할수록 비산유출율도 증가하였고 주입 가연성분에 대한 유출 가연성분비도 증가하였다. 또한, 무연탄 혼합비에 관계없이 비산유출입자의 평균입경에 따른 미연분 함량은 미세입자에서 대체로 높게 나타났다. 한편, 연소효율은 층온도 $850^{\circ}C$, 과잉공기 20% 이상에서 큰 차이를 보이지 않았으므로 유속 0.3m/s, 층온도 $850^{\circ}C$, 과잉공기비 20%의 조건으로 혼합연소시키는 것이 적절한 것으로 나타났다.

• 한국포장학회지
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• 제26권2호
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• pp.53-60
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• 2020

A concept of household container to create and keep the modified atmosphere (MA) beneficial for fresh produce mix was devised and tested under typical chilled storage conditions of 3℃. The container system containing mixed products is initialized by applying weak hypobaric condition (0.9 atm) and subsequently injecting CO₂ gas at an appropriate low level (0.03 atm). The passive atmosphere modification by produce respiration is then induced to reach a target until gas diffusion tube of proper dimension starts to open. The design was made to attain quasi-steady state mass balance of O₂, CO₂ and N₂ to maintain the desired MA through the storage. Interrupted opening for taking out or placing some products was to reinitialize the loop of control logic. The developed concept was tested by the container which held commodities of spinach, pak choi, oyster mushroom, peeled onion, strawberry and cut carrot. The target optimum MA of 11% O₂ and 10% CO₂ (0.11 and 0.10 atm, respectively) was set to avoid injurious range of O₂ and CO₂ concentrations for any commodities. The developed container system could work to reach and maintain beneficial MA of 0.10-0.12 atm O₂ and 0.07-0.10 atm CO₂ close to the target during the storage contributing to quality retention of products measured in weight loss, chlorophyll content of spinach, ascorbic acid content of pak choi, color of onion, texture of oyster mushroom, bacterial count of strawberry and carotenoids of carrot. The container system shows potential to improve current preservation practice of fresh produce mix on consumers' level.

• 대한지하수환경학회지
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• 제5권3호
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• pp.123-128
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• 1998

본 연구에서 고려한 누수대수층 구조는 상부의 자유면대수층과 하부의 피압대수층으로 구성되어있으며 이들 사이에 누수층(leaky layer)이 있다. 상부 지하수 수위의 하강에 따른 피해 방지와 효율적인 지하수 관리를 위해서 상부와 하부의 지하수 수두 변화가 동시에 파악되어야 한다. 누수대수층 구조의 피압대수층(하부)에서 양수를 할때 자유면대수층(상부)은 하부와 상부 대수층을 구분하는 누수층의 영향을 받게 된다. 누수층을 해석하기 위해서 이 층에 대한 수리상수의 결정이 필요하다. 본 논문에서 수리상수를 결정하기 위한 개선된 SM(slope-matching)방법을 제시하였다. 그리고 누수대수층 구조에서 상부와 하부의 지하수 수두를 예측하기 위해 유한차분법을 이용하여 수치모형을 구성하였다. 수치모형의 검증을 위해 1차원 누수대수층 구조에 대한 해석해를 이용하여 정상류 상태에서 수두를 비교하였다. 그 결과는 잘 일치하고 있으며 2차원 누수대수층의 하부층인 피압대수층에서 양수를 할 때 상부 대수층과 하부 대수층에서 지하수 수두의 거동을 고찰하였다.

• 한국터널지하공간학회 논문집
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• 제5권1호
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• pp.3-11
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• 2003

터널 시공 시 막장의 안정은 주요 관심사이다. 그러나, 터널 지보재에 비해 상대적으로 터널 막장의 안정성 문제는 그리 많은 연구가 이루어지지 않은 실정이다. 또한 지하수위 하에서 터널 시공 시 터널 내로 지하수 흐름에 의해 발생된 침투수력은 막장의 안정성에 큰 영향을 미칠 수 있다. 본 논문에서는 두 가지 요소를 고려하여 터널 막장의 안정성을 평가하였다. 하나는 극한이론 중 상한치 이론으로 산출된 유효응력이며, 다른 하나는 정상류 흐름조건에서 수치해석으로부터 산출된 침투수력이다. 열악한 지반조건에서 터널 시공 시 터널의 안정과 인접 구조물의 손상을 방지하기 위해 보조공법이 적용된다. 강관 다단 그라우팅 공법은 근래 국내에서 적용되고 있는 보조공법 중의 하나이다. 본 논문에서는 강관 다단 그라우팅으로 보강된 터널의 막장 안정성도 함께 평가되었다.

• Journal of Nutrition and Health
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• 제27권1호
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• pp.12-22
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• 1994

Effects of very low level of lead in diet and exposure time on the accumulation and distribution in organs and tissues was investigated with growing rats. 21 days old Sprague-Dawley rats were exposed to lead for 7, 14 and 21 days by feeding of 0.03, 0.42, 0.92 and 1.46mg/kg Pb as Pb-acetate containing diet, respectively. Lead concentrations in blood, liver, kidney and bone exhibit a linear relationship with lead levels in diet. After 7 days of exposure, the greatest dose dependent accumulation of lead was found in kidney and followed in bone. However, after 14 and 21 days, the dose dependent accumlation of lead in bone was about two fold greater than that in kidney. The accumulation of lead in liver and blood was relatively low. As continuous exposure to lead, the concentrations of lead in liver, kidney, blood and intestinal tracts were rather not increased with exposure time. However, bone lead concentration was increased with exposure time by feeding of 0.92 and 1.46mg/kg Pb in diet, but not 0.42mg/kg. The lead concentration in gastrointestinal tracts tends also to increasing with lead levels in diet after 7 and 14 days of exposure. However, by 21 days of exposure the lead concentration revealed relatively constant value regardless of the dietary lead levels. It is concluded that the binding capacity of the lead in blood, liver, kidney and bone seems to be increased with increasing lead levels in diet. The lead concentration in these organs, with the exception of the lead in bone, seems, however, to be standing under steady state regulation by continued exposure with the same dietary lead level. Therefore, by chronic exposure condition with environmental relevant lead level bone might be a principle targe organ for lead and blood lead repesents better the current lead exposure than the lead body burden.

• 한국소음진동공학회논문집
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• 제26권3호
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• pp.340-349
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• 2016

A coupled room system consists of adjacent rooms and apertures where the sound energy is exchanged between the two rooms. Acoustically, a coupled room system shows a non-exponential decay profile. Most of the related researches have been to analyze the acoustic properties of two-room coupled system so far whereas three-room coupled system were seldom studied. In this regard, this paper aims to analyse the distribution of sound pressure level, sound decay curve of three-room coupled system and sound energy flow between them by using the acoustic diffusion model and to further verify them through experiments. Firstly, the sound pressure level distribution and mean sound pressure level in the steady-state condition are analyzed at various frequencies and source locations. Good agreements are observed in both experiments and analysis results. Secondly, two double slope effect quantifiers of sound attenuation, LDT/EDT and LDT/T10 are compared at various frequencies and for different source locations. The result indicates that LDT/T10, less affected by the early reflection patterns than LDT/EDT, is more suitable to the analysis and experiments of a multi-slope sound decay curve. Lastly, the sound energy flow in each room is analyzed based on the acoustic diffusion model. After the early decay stage, the sound energy is observed to flow from the room with a long reverberation time to the room with a short one.

• 수산해양기술연구
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• 제49권1호
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• pp.58-66
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• 2013

Most of steam power plant in Korea are heating the feed water system to prevent freezing water flowing in the pipe in winter time. The heating system is operated whenever the ambient temperature around the power plant area below 5 degree Centigrade. But this kind of heat supplying system cause a lot of energy consuming. If we think about the method that the temperature of the each pipe is controled by attaching the temperature measuring sensor like RTD sensor and heat is supplied only when the outer surface temperature of the pipe is under 5 degree Centigrade, then we can save a plenty of energy. In this study, the computer program package for simulation is used to compare the energy consumption load of both systems. Energy saving rate is calculated for the location of Youngweol area using the data of weather station in winter season, especially the January' severe weather data is analyzed for comparison. Various convection heat transfer coefficients for the ambient air and the flowing water inside the pipe was used for the accurate calculation. And also the various initial flowing water temperature was used for the system. Steady state analysis is done previously to approximate the result before the simulation. The result shows that the temperature control system using RTD sensor represents the high energy saving effect which is more than 90% of energy saving rate. Even in the severe January weather condition, the energy saving rate is almost 60%.