• 한국세라믹학회지
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• 제36권7호
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• pp.698-704
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• 1999

Li rich Li1+xMn2-xO4(x=0.07) spinel powders were prepared by an oxalate precipitation of wet chemical methods at temperature lower than $600^{\circ}C$. The FTIR results showed that the powders prepared at $600^{\circ}C$ had high degree of crystal quality comparing with the spinel powders prepared by solid state reaction at 75$0^{\circ}C$ which was the lowest synthesis temperature of the solid state reaction method. The particle size of powders prepared by the oxalate precipitation at $600^{\circ}C$ was smaller than 0.2${\mu}{\textrm}{m}$ and the specific surface area was 11.01 m2/g A heat treatment over 90$0^{\circ}C$ formed second phase in the precipitates. It was shown that there were phase transitions at temperatures. T1,T2 and T2. The transitions involved weight loss and gain during heating and cooling. The low temperature synthesis below $600^{\circ}C$ avoided the second phase formation and the prepared powders showed improved compositional and physical properties for secondary lithium battery applications.

• 한국정보처리학회논문지
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• 제3권6호
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• pp.1365-1374
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• 1996

분산 환경하에서 전역 트랜잭션의 원자성을 보장하기 위해 보편적으로 사용하는 2단계 완료규약(2PC)의 블록킹 현상을 완화하기 위해 낙관적 2PC를 사용할 수 있다. 낙관적 2PC는 보상 트랜잭션을 사용하여 트랜잭션의 원자성을 의미적으로 보장하게 되지만 보상 트랜잭션의 특성으로 인하여 전역 직렬성(global serializability)을 위 배할 수 있다. 본 논문에서는, 전역 트랜잭션의 상태전이 분석을 통하여 전역 직렬성 을 보장하는 올바른 전역 트랜잭션 관리 규약들을 제안한다. 제안된 규약들은 한 전 역 트랜잭션의 실행을 결정하기 전에 동시에 실행되는 다른 전역 트랜잭션들의 상태 를 검사하여 이 결과에 따라 전역 트랜잭션의 실행을 지연시킴으로써 전역직렬성을 보장한다.

• 대한산업공학회지
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• 제21권4호
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• pp.609-628
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• 1995

This paper presents a reliability model and a data-analytic procedure for a repairable unit subject to failures due to multiple non-identifiable causes. We regard a failure cause as a state and assume the life distribution for each cause to be exponential. Then we represent the dependency among the causes by a Markov switching model(MSM) and estimate the transition probabilities and failure rates by maximum likelihood(ML) method. The failure data are incomplete due to masked causes of failures. We propose a specific version of EM(expectation and maximization) algorithm for finding maximum likelihood estimator(MLE) under this situation. We also develop statistical procedures for determining the number of significant states and for testing independency between state transitions. Our model requires only the successive failure times of a unit to perform the statistical analysis. It works well even when the causes of failures are fully masked, which overcomes the major deficiency of competing risk models. It does not require the assumption of stationarity or independency which is essential in mixture models. The stationary probabilities of states can be easily calculated from the transition probabilities estimated in our model, so it covers mixture models in general. The results of simulations show the consistency of estimation and accuracy gradually increasing according to the difference of failure rates and the frequency of transitions among the states.

• Journal of Magnetics
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• 제16권3호
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• pp.197-200
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• 2011

Using the full potential linearized augmented plane wave (FLAPW) method, the influences of uniform and tetragonal strains on the magnetic state have been explored for chemically ordered bulk $L1_2$ $FePt_3$. The ordered state displays antiferromagnetic $Q_1$ (AFM-$Q_1$) state but it transitions into antiferromagnetic $Q_2$ (AFM-$Q_2$) state at about 10% uniform strain. The ferromagnetic (FM) state is observed at 11% uniform strain. For tetragonal strain, it is also seen that the transition from AFM-$Q_1$ to AFM-$Q_2$ depends on the strength and direction of the applied strain. The FM state does not appear in this case. Magnetocrystalline anisotropy (MCA) calculations for tetragonal distortion reveal that the spin reorientation transition occurs. In addition, we find that the direction of magnetization and the magnitude of magnetic anisotropy energy strongly depend on the c/a ratio.

• 인터넷정보학회논문지
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• 제10권4호
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• pp.55-70
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• 2009

비전기반 인간컴퓨터 상호작용은 컴퓨터와 인간의 상호소통을 자연스럽게 제공하는 측면에서 과학과 산업분야에서 주목받는 연구 분야이다. 그러한 측면에서 얼굴표정인식에 의한 인간의 심리적 상태를 추론하는 기술은 중요한 이슈이다. 본 연구에서는 감성인식 HMM 모델과 광류에 기반한 얼굴 움직임 추적 방법을 이용하여 동영상으로부터 얼굴표정을 인식하는 새로운 방법을 제시하였다. 특히, 기존의 감성상태 변환을 설명하는 HMM 모델은 특정 표정상태 간의 전환 시 항상 중립 상태를 거치도록 설계되어 있다. 그러나 본 연구에서는 기존의 표정상태 전환 모델에 중간상태를 거치는 과정 없이 특정 표정 상태간의 변환이 가능한 확장된 HMM 모델을 제시한다. 동영상으로부터 얼굴의 특성정보를 추출하기 위하여 탬플릿 매칭과 광류방법을 적용하였다. 광류에 의해 추적된 얼굴의 표정특성 정보는 얼굴표정인식을 위한 HMM의 매개변수 정보로 사용된다. 실험을 통하여 제안된 얼굴표정인식 방법이 실시간 얼굴 표정인식에 효과적임을 입증하였다.

• 한국전자통신학회논문지
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• 제17권3호
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• pp.399-408
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• 2022

본 논문에서는 기본 모드 원리를 침해하는 과도 고장이 존재하는 입력/출력 비동기 순차 회로의 내고장성 교정 제어 시스템을 제안한다. 비동기 순차 회로의 과도 천이 과정에서 발생하는 비-기본 모드 고장을 극복하기 위해서는 고장에 의한 상태 천이가 종료되는 시점을 알아야 하며, 회로를 고장 상태로부터 원래 도달해야 하는 상태와 출력 등가적인 상태로 보내기 위한 교정 동작을 구현해야 한다. 본 논문에서는 이러한 고장 탐지 및 극복을 구현할 수 있는 출력 피드백 교정 제어기의 존재 조건을 규명한다. FPGA 실험을 통해 제안된 제어 시스템의 설계 과정을 제시하고 응용 가능성을 검증한다.

• Journal of Photoscience
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• 제7권1호
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• pp.21-26
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• 2000

The photoemission and excitation spectra of cis-[Cr(cyclam)F$_2$]ClO$_4$ (cyclam = 1,4,8,11-tetraazacy-clotetradecane) taken at 77 K are reported. The 298 K mid- and far-infrared spectra are also measured. The vibrational intervals of the electronic ground state are extracted from the far-infrared and emission spectra. The ten electronic bands due to spin-allowed and spin-forbidden transitions are assigned. The zero-phonon line In the excitation spectrum splits into two components by 169 cm$^{1}$, and the large $^2$E$_{g}$ splitting can be reproduced by the ligand field theory. According to the ligand field analysis, we can confirm that nitrogen atoms of the cyclam ligand have a strong c-donor character, and fluoride ligand also has strong $\sigma$- and $\pi$-donor properties toward chromium(III) ion.n.

• Rapid Communication in Photoscience
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• 제2권1호
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• pp.34-37
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• 2013

Two novel antenna complexes of $Eu^{III}$ with 1-naphthoic acid (NA) as primary ligand and two aromatic N-donor ligands namely N-hexyl-N-(pyridin-2-yl) pyridin-2-amine (1) and 4-((dipyridin-2-ylamino)methyl)benzoic acid (2) have been synthesized and characterized by various spectroscopic techniques. The room-temperature (298 K) photoluminescence spectrum of $Eu^{III}$ complexes composed of typical line like emissions, assigned to transitions between the first excited state $^5D_0$ to the $^7F_J$ (J = 0-4), resulting in red emission along with the residual emission from the 1-naphthoic acid moiety in the blue region. The determined CIE color coordinate value for the complex 2 is (x = 0.36, y = 0.34), which is in white region.

• Bulletin of the Korean Chemical Society
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• 제20권1호
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• pp.81-84
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• 1999

The emission and excitation spectra of [Cr(NH3)5(imH)](ClO4)3·H2O (imH=imidazole) taken at 77 K are reported. The 298 K visible and far-infrared spectra are also measured. The vibrational intervals of the electronic ground state are extracted from the far-infrared and emission spectra. The ten electronic bands due to spin-allowed and spin-forbidden transitions are assigned. Using the observed transitions, a ligand field analysis has been performed to determine the bonding properties of coordinated imidazole in the title chromium(Ⅲ) complex. It is confirmed that nitrogen atom of the imidazole ligand has a medium it-acceptor property toward chromium(Ⅲ) ion. The zero-phonon line in the excitation spectrum splits into two components by 181 cm-1, and the large 2Eg splitting can be reproduced by the ligand field theory.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.657-660
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• 2009

Optically compensated bend (OCB) mode has intrinsic characteristics such as wide viewing angle and fast response time. However, in order to operate the OCB mode in bend state, this device needs quick transitions from the initial splay state to bend state. In this paper, we proposed OCB mode with initially bend state using reactive mesogen (RM) monomer for surface polymer stabilization. The device shows continuous reorientation of the LC with applied field and a very fast response time.