• Journal of the Korean Chemical Society
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• v.23 no.5
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• pp.314-319
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• 1979

The electronic spectrum of marine dinoflagellate antenna pigment, peridinin, has been described in terms of PPP SCF MO CI computations and fluorescence polarization of the peridinin component in photosynthetic pigment complex of Amphidinium carterae. The main absorption band at 470 nm, $^1B{\leftarrow}A$, is polarized nearly along the long molecular axis. There appear to be two ${\pi}{\rightarrow}{\pi}^*$ transitions (C and $D{\leftarrow}A$) in the socalled "cis" peak region, and they are polarized roughly parallel to the main $B{\leftarrow}A$ absorption. In addition, we have found that the carbonyl group undergoes very 1ittle reorganization of the electronic structure in going from the ground to the $^1B$ excited states of peridinin, while the allenic group shows a strong charge transfer tendency in producing an electron-deficient allente allene group in the excited state.

• Journal of IKEEE
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• v.13 no.2
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• pp.159-166
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• 2009

So far, many researches have been done to retrieve music information using static classification descriptors such as genre and mood. Since static classification descriptors are based on diverse content-based musical features, they are effective in retrieving similar music in terms of such features. However, human emotion or mood transition triggered by music enables more effective and sophisticated query in music retrieval. So far, few works have been done to evaluate the effect of human mood transition by music. Using formal representation of such mood transitions, we can provide personalized service more effectively in the new applications such as music recommendation. In this paper, we first propose our Emotion State Transition Model (ESTM) for describing human mood transition by music and then describe a music classification and recommendation scheme based on the ESTM. In the experiment, diverse content-based features were extracted from music clips, dimensionally reduced by NMF (Non-negative Matrix Factorization, and classified by SVM (Support Vector Machine). In the performance analysis, we achieved average accuracy 67.54% and maximum accuracy 87.78%.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.139.2-139.2
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• 2016

Electrons and phonons in chalcogenide-based materials play are important factors in the performance of an optical data storage media and thermoelectric devices. However, the fundamental kinetics of carriers in chalcogenide materials remains controversial, and active debate continues over the mechanism responsible for carrier relaxation. In this study, we investigated ultrafast carrier dynamics in an multilayered $\{Sb(3{\AA})/Te(9{\AA})\}n$ thin film during the transition from the amorphous to the crystalline phase using optical pump terahertz probe spectroscopy (OPTP), which permits the relationship between structural phase transition and optical property transitions to be examined. Using THz-TDS, we demonstrated that optical conductance and carrier concentration change as a function of annealing temperature with a contact-free optical technique. Moreover, we observed that the topological surface state (TSS) affects the degree of enhancement of carrier lifetime, which is closely related to the degree of spin-orbit coupling (SOC). The combination of an optical technique and a proposed carrier relaxation mechanism provides a powerful tool for monitoring TSS and SOC. Consequently, the response of the amorphous phase is dominated by an electron-phonon coupling effect, while that of the crystalline structure is controlled by a Dirac surface state and SOC effects. These results are important for understanding the fundamental physics of phase change materials and for optimizing and designing materials with better performance in optoelectronic devices.

• Journal of KIISE:Software and Applications
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• v.27 no.3
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• pp.210-216
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• 2000

Place/Transition(P/T) nets has been used in protocol verification and concurrent system verification since it is suitable for describing concurrency and provides several well-established verification techniques. And it has been used as a base formalism for such high-level Petri nets as colored Petri nets, object-oriented Petri nets and etc. However, when analyzing complex models using P/T nets and P/T nets-based high-level Petri nets, there may be state explosion in reachability analysis due to improper handling of concurrency. In this paper, we define a structural concurrency in P/T nets, propose a partitioning algorithm based on the detected structural concurrency, and provide analysis techniques for such properties as boundedness of places and liveness of transitions, which are performed on compositional reachability graphs. The analysis techniques based on Petri net slices can be used in efficiently analyzing P/T nets-based high-level Petri net models as well as P/T net models.

• Korean Journal of Materials Research
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• v.22 no.5
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• pp.215-219
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• 2012

Red phosphors $Ca_{1-1.5x}WO_4:{Eu_x}^{3+}$ were synthesized with different concentrations of $Eu^{3+}$ ions by using a solid-state reaction method. The crystal structure of the red phosphors was found to be a tetragonal system. X-ray diffraction (XRD) results showed the (112) main diffraction peak centered at $2{\theta}=28.71^{\circ}$, and the size of crystalline particles exhibited an overall decreasing tendency according to the concentration of $Eu^{3+}$ ions. The excitation spectra of all the phosphors were composed of a broad band centered at 275 nm in the range of 230-310 nm due to $O^{2-}{\rightarrow}W^{6+}$ and a narrow band having a peak at 307 nm caused by $O^{2-}{\rightarrow}Eu^{3+}$. Also, the excitation spectrum presents several strong lines in the range of 305-420 nm, which are assigned to the 4f-4f transitions of the $Eu^{3+}$ ion. In the case of the emission spectrum, all the phosphor powders, irrespective of $Eu^{3+}$ ion concentration, indicated an orange emission peak at 594 nm and a strong red emission spectrum centered at 615 nm, with two weak lines at 648 and 700 nm. The highest red emission intensity occurred at x = 0.10 mol of Eu3+ ion concentration with an asymmetry ratio of 12.5. Especially, the presence of $Eu^{3+}$ in the $Ca_{1-1.5x}WO_4:{Eu_x}^{3+}$ shows very effective use of excitation energy in the range of 305-420 nm, and finally yields a strong emission of red light.

• Journal of the Korea Society of Computer and Information
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• v.17 no.3
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• pp.11-25
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• 2012

We present the method to infer Context-Free Grammars by applying genetic algorithm to the Binary Third-order Recurrent Neural Networks(BTRNN). BTRNN is a multiple-layered architecture of recurrent neural networks, each of which is corresponding to an input symbol, and is combined with external stack. All parameters of BTRNN are represented as binary numbers and each state transition is performed with any stack operation simultaneously. We apply Genetic Algorithm to BTRNN chromosomes and obtain the optimal BTRNN inferring context-free grammar of positive and negative input patterns. This proposed method infers BTRNN, which includes the number of its states equal to or less than those of existing methods of Discrete Recurrent Neural Networks, with less examples and less learning trials. Also BTRNN is superior to the recent method of chromosomes representing grammars at recognition time complexity because of performing deterministic state transitions and stack operations at parsing process. If the number of non-terminals is p, the number of terminals q, the length of an input string k, and the max number of BTRNN states m, the parallel processing time is O(k) and the sequential processing time is O(km).

• Journal of the Korean Chemical Society
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• v.22 no.4
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• pp.239-244
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• 1978

Spectroscopic studies of trans-1,2-bispyrazylethylene (BPE), one of the stilbene analogues, were carried out. In normal UV spectra, a distinct $n{\rightarrow}{\pi}^*$ absorption band is missing because of a strong, nearly isoenergetic ${\pi}{\rightarrow}{\pi}^*$ absorption band. The second derivative and low temperature $(77^{\circ}K)$ UV absorption spectra were taken and $n{\rightarrow}{\pi}^*$ absorption band was identified by these methods. The transition energies of ${\pi}{\rightarrow}{\pi}^*$ transitions were calculated by Pariser-Parr-Pople (PPP)-SCF-CI MO method. The calculated values showed good agreement with the observed spectral data. Luminescence studies were also carried out at low temperature. From the fluorescence spectra, fluorescence polarization studies, and PPP-SCF-CI MO calculation, the fluorescent state was determined to be a singlet $({\pi},\;{\pi}^*)$ state. This conclusion is in good agreement with the results obtained from alkaline salt effects on the fluorescence of this compound.

• Resources Recycling
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• v.16 no.5
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• pp.46-50
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• 2007

Blue phosphor calcium aluminate, $CaAl_2O_4:Eu^{2+}$ co-doped with $Nd^{3+}$ was prepared by solid state synthesis method. Phosphor materials with 1 mol% $Eu^{2+}$ and varying compositions of $Nd^{3+}$ show high brightness and long persistent luminescence. The synthesized phosphor materials were investigated by powder x-ray diffraction (XRD), SEM, TEM, photoluminescence excitation and emission studies. Broad band UV excited luminescence of the $CaAl_2O_4:Eu^{2+}:Nd^{3+}$ was observed in the blue region (${\lambda}_{max}=440\;nm$) due to transitions from the $4f^65d^1$ to the $4f^7$ configuration of the $Eu^{2+}$ ion. $Nd^{3+}$ ion doping in the phosphor results in long afterglow phosphorescence when the excitation light is cut off.

• Journal of Digital Convergence
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• v.11 no.11
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• pp.491-498
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• 2013

The purpose of this study was to evaluate the economy and efficiency of two trained athlete groups of different training status. The subjects were 20 elite athletes composed of the cyclists group (n=10) and triathlon group (n=10). All subjects performed steady state testing at 50, 100, and 150 watts, with ample time to reach resting $VO_2$ and ventilation values between stages. The efficiency of two groups appears to be quite different, with triathlon competitors displaying superior efficiency values for the transitions from 0 to 50 and 100 watts. This same principle likely explains the economy of the groups, as triathlon competitor was again more economic at 50 and 100 watts. As though this matching of oxygen consumption and workload they can reduce the amount of oxygen deficit that must be repaid post exercise.

• Journal of the Korean institute of surface engineering
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• v.48 no.3
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• pp.82-86
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• 2015

$Dy^{3+}$- and $Eu^{3+}$-codoped $CaMoO_4$ Phosphors were synthesized by using the solid-state reaction method. The crystal structure, morphology, and optical properties of the resulting phosphor particles were investigated by using the X-ray diffraction, field-emission scanning electron microscopy, and photoluminescence spectroscopy. XRD patterns exhibited that all the synthesized phosphors showed a tetragonal system with a main (112) diffraction peak, irrespective of the content of $Eu^{3+}$ ions. As the content of $Eu^{3+}$ ions increased, the grains showed a tendency to agglomerate. The excitation spectra of the synthesized powders were composed of one strong broad band centered at 305 nm in the range of 220 - 350 nm and several weak peaks in the range of 350 - 500 nm resulting from the 4f transitions of activator ions. Upon ultraviolet excitation at 305 nm, the yellow emission line due to the $^4F_{9/2}{\rightarrow}^6H_{13/2}$ transition of $Dy^{3+}$ ions and the main red emission spectrum resulting from the $^5D_0{\rightarrow}^7F_2$ transition of $Eu^{3+}$ ions were observed. With the increase of the content of $Eu^{3+}$, the intensity of the yellow emission band gradually decreased while that of the red emission increased. These results indicated that the emission intensities of yellow and red emissions could be modulated by changing the content of the $Dy^{3+}$ and $Eu^{3+}$ ions incorporated into the host crystal.