• 한국환경과학회지
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• 제4권1호
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• pp.91-103
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• 1995

The reaction rate, equilibrium, and flow injection analysis methods were fundamentally evaluated for the determination of aqueous ammonia. The selected indophenol blue method was based on the formation of indophenol blue in which ammonium ion reacted with hypochlorite and phenol in alkaline solution. In the optimized reaction condition, the reaction followed 1st order reaction kinetics and the final product was stable. The absorbance measurements before and after the equilibrium were utilized for the reaction rate and equilibrium methods. The reaction rate methods, based on the relative analytical signals for the possibility of eliminating interferents, were shown to have good linear calibration curves but the detection limit and the calibration sensitivity were poorer than those in the equilibrium method. The detection limits were 32-49 pub and 24 pub for the reaction rate and equilibrium methods, respectively In the flow injection analysis, the absorbance was measured before the equilibrium reached and thus resulted in 30% reduction of calibration sensitivity. However, the detection limit was 11 ppb, indicating that the peak-to-peak noise for the blank was remarkably improved. Compared to the manual methods, the optimized experimental condition in a closed reaction system reduced the blank absorbance and the inclusion of ammonia from the atmosphere was prevented. In addition, highly reproducible mixing of sample and reagents and analytical data extracted from continuous recording showed excellent reproducibility.

• 조명전기설비학회논문지
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• 제24권10호
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• pp.58-66
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• 2010

This paper shows an implementation and management result of wireless networks based security light control system, which performs a great role in protection of pedestrians and prevention of crime. Conventional security light units have severe limits in confirmation and inspection of security light unit failure, like wilful damage by someone or failure by influence of other equipment or failure by spontaneous heat-increase, and so on. In addition, local government offices are responsible for maintenance of security light units and as a matter of fact, most of civil complaints are about security light units. It is an obvious that the existing security light maintenance system reaches the limit and the security light maintenance problem is a difficulty of local government. Therefore, efficient security light control system is needed, which enables central control and intelligent maintenance. Moreover, the system has to be easy to control and has to be stable. In this study, wireless sensor network based security light control system is implemented, which is independent of programming language and platform, and which is simple to control and extend the system. The proven protocols, HTTP and SOAP, are utilized in order to improve the system reliability. This paper shows the excellence of our proposed system by implementing and operating it in real environment.

• Journal of Power Electronics
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• 제13권6호
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• pp.964-974
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• 2013

A modified direct torque control (DTC) method based on torque angle is proposed for interior permanent-magnet synchronous motor (IPMSM) drivers used in electric vehicles (EVs). Given the close relationship between torque and torque angle, proper voltage vectors are selected by the proposed DTC method to change the torque angle rapidly and regulate the torque quickly. The amplitude and angle of the voltage vectors are determined by the torque loop and stator flux-linkage loop, respectively, with the help of the position of the stator flux linkage. Furthermore, to satisfy the torque performance request of EVs, the nonlinear dead-time of the invertor caused by parasitic capacitances is considered and compensated to improve steady torque performance. The stable operation region of the IPMSM DTC driver for voltage and current limits is investigated for reliability. The experimental results prove that the proposed DTC has good torque performance with a brief control structure.

• Bulletin of the Korean Chemical Society
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• 제14권1호
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• pp.123-127
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• 1993

New lipophilic Crown-4 compounds of 16-membered rings containing furan (neutral carrier,I), tetrahydrofuran (neutral carrier,II) and lithium complex of the latter (neutral carrier,III) have been synthesized and tested as the active sensors for lithium ion in poly(vinyl chloride) (PVC) membrane electrode, in the presence and absence of an anion excluder, tetrakis(4-chloro-phenyl)borate (KTClPB), 2-nitrophenyl phenyl ether (NPPE), tris(2-ethylhexyl)phosphate (TEHP), o-nitrophenyl octyl ether (NPOE), dioctyl adipate (DOA), bis(2-ethylhexyl)adipate (BEHA), di-n-octylphenyl phosphonate (DOPP) were used as plasticizing solvent mediators. The electrode response function had a nearly Nernstian slope of 54-61 mV per decade (25$^{\circ}$C) within the concentration range of $10^{-1}-10^{-4}$ M LiCl and the detection limits for all electrodes were ca. $5{\times}10^{-4}$ M. The response time of the electrode was faster at the higher lithium concentration and the response of the electrode was stable for longer than 6 months. The sensor membranes exhibit improved response times and increased lifetimes as compared to the system described earlier.

• Bulletin of the Korean Chemical Society
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• 제22권5호
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• pp.463-466
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• 2001

The determination of Cd2+ and Cu2+ with ammonium pyrrolidinedithiocarbamate (APDC) in Tween 80 micellar media has been studied. The UV-visible spectrum of Cd(PDC)2 complex in Tween 80 media had more sensitivity tha n in chloroform. Although the UV-visible spectrum of the Cu(PDC)2 complex in Tween 80 media had somewhat less sensitivity than that in chloroform, absorbance data of Cu2+ were more reproducible in Tween 80 media. The Cd(PDC)2 and Cu(PDC)2 complexes were very stable at pH 7.0 for up to 100 minutes and could be quantitatively chelated if APDC were added to the sample solution more than 30 times the moles of Cd2+ and Cu2+ . The optimum concentration of Tween 80 was 0.1%. The calibration curves of Cd(PDC)2 and Cu(PDC)2 complexes with good linearity were obtained in 0.1% Tween 80 media. The detection limits of Cd2+ and Cu2+ were 0.0493 ㎍mL-1 and 0.0393 ㎍mL-1 , respectively. Recovery yields of Cd2+ and Cu2+ ions in the spiked real samples were almost 100%. Based on experimental results, this proposed method could be applied to the rapid and simple determination of Cd2+ and Cu2+ in real samples.

• 한국자기학회지
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• 제5권5호
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• pp.819-823
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• 1995

The oil-based magnetic fluids were sysnthesized using ultra-fine $Fe_{3}O_{4}$ powder dispersed in hydrocarbon oil. To synthesize ultra-fine $Fe_{3}O_{4}$, we carried out the experiments varying the pH of reacting medium and the initial concentration of $Fe^{2+}$. We also investigated the amount of oleic acid to obtain a stable dispersion and the proper base oil of MF for loudspeaker application. The limits of adsorbed amount of oleic acid on the $Fe_{3}O_{4}$ surface were approximately 35~40 percents of the total magnetite weight. As the $Fe_{3}O_{4}$ content increased from 0.1g/cc to 0.6g/cc, the viscosity of oil-based magnetic fluid increased from 1,063cP to 1,828cP, and its saturation magnetization at 10kOe increased from 66G to 242G. When we tested the MF sample to a commercial speaker, improvements were noted.

• 한국폐기물자원순환학회지
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• 제34권2호
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• pp.140-147
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• 2017

This study was conducted to evaluate the effects of physical characteristics. Twelve specific odorous compounds and various sources of bacteria were tested via treatment of food waste using an ultra-thermophilic aerobic composting process. Food waste was mixed with seed material and operated for 47 days. During composting, the temperature was maintained at $80-90^{\circ}C$. The variations in $O_2$, $CO_2$ and $NH_3$ production suggested typical microorganism-driven organic decomposition patterns. After composting, the concentrations of 12 specific odorous compounds other than ammonia did not exceed the allowable exhaust limits for odor. After composting, thermophiles represented 50% of all bacteria. After composting, the percentage of thermophile bacterial increased by 15%. Therefore, both stable composting operation and economic benefit can be expected when an ultra-thermophilic composting process is applied to food waste.

• 한국기후변화학회지
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• 제7권1호
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• pp.1-8
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• 2016

In this study, we investigated the applicability of a short-term carbon dioxide ($CO_2$) passive sampler using turbidity change in a solution containing barium hydroxide ($Ba(OH)_2$). The mass of $CO_2$ introduced into the $Ba(OH)_2$ aqueous solution was strongly correlated ($r^2=0.9565$) to the change in turbidity caused by its reaction with the solution. The sampling rates calculated for 1 h and 24 h were $42.4{\pm}5.4mL\;min^{-1}$ and $2.3{\pm}0.3mL\;min^{-1}$, respectively. Both unexposed (blank) and exposed samplers remained stable during the storage period of at least two weeks. The detection limits of the passive sampler for $CO_2$ were 81.5 ppm for 1 h and 61.5 ppm for 24 h. Based on the results, the passive sampler using the change of turbidity in the $Ba(OH)_2$ aqueous solution appears to be a suitable tool for measuring short-term atmospheric concentrations of $CO_2$.

• 청정기술
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• 제13권4호
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• pp.300-307
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• 2007

본 연구에서는 연료분출각의 변화에 따라 보염기(cylindrical stabilizer) 후류에 형성되는 확산화염의 화염 안정성, 재순환영역의 길이 및 온도, 보염기 후류의 난류강도 분포, 재순환영역의 연소가스 농도 등을 측정하고, 화염의 직접사진 및 슐리렌사진을 촬영하여 확산화염의 연소특성을 고찰하였다. 화염안정성은 연료분출각과 주류공기 유속의 영향을 받으며, 재순환영역의 길이와 온도는 연료분출각의 영향을 받았다. 재순환영역의 길이가 짧고 온도가 낮을수록 화염안정성이 양호하지만, 연료분출각의 변화에 따른 난류강도 분포에는 별로 차이가 없었다. 재순환영역 내 미연가스 농도가 높고 이산화탄소 농도가 낮은 경우, 화염안정성은 양호하지만 연소상태는 불량한 것으로 나타났다. 연소효율, 고부하 출력, 대기환경, 연료의 청정연소조건 등을 고려하여 적절한 연료분출각을 선정함으로써 양호한 연소조건을 유지할 수 있다.

• 한국토양비료학회지
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• 제16권1호
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• pp.1-6
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• 1983

우리 나라에 분포(分布)된 수종(数種) 답토양(畓土壤)에 대(対)한 선형팽진지수(線型膨賑指수)(COLE)를 측정(測定)하여 본 결과(結果)는 다음과 같다. 1. 본(本) 연구(硏究)에서 공시(供試)된 답토양(畓土壤)의 COLE값은 표토(表土)에서 0.024~0.094이었고 심토(心土)에서는 0.022~0.115로 그 범위(範囲)가 넓었으며 배수(排水)가 상대적(相対的)으로 불량(不良)할수록 또 토성(土性)이 점질(粘質) 일수록 COLE값은 높게 나타났다. 2. 하해혼성평탄지(河海混成平坦地)의 식질(埴質) 성숙답(成熟畓)과 제삼기층(第三紀層)이 모재(母材)인 곡간충적답(谷間沖積畓)에서는 COLE값이 0.09 이상(以上)으로서 높았으므로 이들 토양(土壤)의 전단면(全断面)에 대(対)한 조사(調査)를 계속실시(継続実施)하여야 할 것이다. 3. COLE값은 점토함량(粘土含量)과 가장 높은 정상관(正相関)(r=0.8177~0.7623)을 가졌으며 유기물함량(有機物含量), $\frac{1}{3}$ 기압함수량(気圧含水量), Atterberg limits, 내수성(耐水性) 입단량(粒団量) 등(等)과도 유의(有意)한 정상관(正相関)을 나타내었으나 사함량(砂含量)과 미사함량(微砂含量) 등(等)과는 부(負)의 상관(相関)을 나타내었다. 4. 수평면(垂平面)에 대(対)해 측정(測定)한 COLE값은 용적변화량(容積変化量)을 선형(線型)으로 환산(換算)한 COLE값 보다 약간(若干) 큰 값을 보였으나 실용성(実用性)이 인정(認定)되었으며 보다 정확(正確)한 값은 수평면(垂平面) 및 수직면(垂直面)에 대(対)해 얻은 COLE값을 평균(平均)하는 것으로 추정(推定)되었다.