• 한국수소및신에너지학회논문집
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• 제19권4호
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• pp.283-290
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• 2008

In this paper, experiments with an air-breathing proton exchange membrane fuel cell (PEMFC) for mobile devices were carried out according to cathode conditions. These conditions are defined by the cathode flow field plate type (the channel type, the open type) and the cathode surface direction. Single-cell and 6-cell stack were used in the experiments. The experimental results showed that the open-type cathode flow field plate gave a better performance than the small channel type. In the experiments related to the direction of the slits on the cathode flow field plate, the horizontal slit cell was better than the vertical one. With respect to the cathode surface direction, when the cathode surface is placed in the direction normal to the ground, the PEMFC generated more stable power in the mass transport loss region. Since stable power in the mass transport region is closely related to the air supply, computational fluid dynamics (CFD) analysis for air-breathing PEMFC of different cathode surface directions was performed.

• Current Applied Physics
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• 제18권11호
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• pp.1345-1351
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• 2018

To allow stable cycling of layered nickel-rich cathode material at high voltage, silyl-functionalized dimethoxydimethylsilane is proposed as a multi-functional additive. In contrast to typical functional additive, dimethoxydimethylsilane does not make artificial cathode-electrolyte interfaces by electrochemical oxidation because it is quite stable under anodic polarization. We find that dimethoxydimethylsilane mainly focuses on scavenging nucleophilic fluoride species that can be produced by electrolyte decomposition during cycling, leading to improving interfacial stability of both nickel-rich cathode and graphite anode. As a result, the cell cycled with dimethoxydimethylsilane-controlled electrolyte exhibits 65.7% of retention after 100 cycle, which is identified by systematic spectroscopic analyses for the cycled cell.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.550-553
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• 2008

In this paper, experiments of air-breathing proton exchange membrane fuel cell (PEMFC) for mobile devices were carried out according to the cathode conditions. These conditions are defined by the cathode flow field plate type (the channel type, the open type) and the cathode surface direction. Single cell and 6-cell stack were used in this experiments. The experimental results showed that the open type cathode flow field plate gave better performance for small size PEMFCs because the open type cathode plate allowed better air convection than the channel type cathode plate. In the experiments related to the direction of the slits on the cathode flow field plate, the horizontal slit cell was better than the vertical slit cell. With respect to the cathode surface direction, when the cathode surface is placed in the direction normal to the ground, PEMFC generated more stable power in the mass transport loss region.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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• pp.1199-1202
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• 2007

The improvement of the electron injection is of critical importance for obtaining efficient and stable organic light-emitting diodes(OLEDs). Here, we report some of our recent results on the development of new cathode interlayer materials for OLEDs. Some of our new materials show performance superior to that of LiF.

• Journal of Electrochemical Science and Technology
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• 제14권3호
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• pp.272-282
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• 2023

Ni-rich layered oxides cathode has recently gained attention as an advanced cathode material due to their applicable energy density. However, as the Ni component in the layered site is increased, the high reactivity of Ni⁴⁺ results in parasitic reaction associated with decomposing electrolyte, which leads to a rapid decreasing the lifespan of the cell. The electrolyte additive triallyl borate (TAB) improves interfacial stability, leading to a stable cathode-electrolyte interphase (CEI) layer on the LNCM83 cathode. A multi-functionalized TAB additive can produce a uniformly distributed CEI layer via electrochemical oxidation, which implies an increase in long-term cycling performance. After 100 cycles at elevated temperature, the cell tested by 0.75 TAB retained 88.3% of its retention ratio, whereas the cell performed by TAB-free electrolyte retained 64.1% of its retention. Once the TAB additive formed CEI layers on the LNCM83 cathode, it inhibited the decomposition of carbonate-based solvents species in addition to the dissolution of transition metal components from the cathode. The addition of TAB to LNCM83 cathode material is believed to be a promising way to increase the electrochemical performance.

• Journal of Information Processing Systems
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• 제15권6호
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• pp.1392-1405
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• 2019

The cathode voltage of aluminum electrolytic cell is relatively stable under normal conditions and fluctuates greatly when it has an anomaly. In order to detect the abnormal range of cathode voltage, an anomaly detection algorithm based on sliding window was proposed. The algorithm combines the time series segmentation linear representation method and the k-nearest neighbor local anomaly detection algorithm, which is more efficient than the direct detection of the original sequence. The algorithm first segments the cathode voltage time series, then calculates the length, the slope, and the mean of each line segment pattern, and maps them into a set of spatial objects. And then the local anomaly detection algorithm is used to detect abnormal patterns according to the local anomaly factor and the pattern length. The experimental results showed that the algorithm can effectively detect the abnormal range of cathode voltage.

• Journal of Electrochemical Science and Technology
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• 제13권1호
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• pp.112-119
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• 2022

Molten carbonate fuel cells (MCFCs) are environmentally friendly, large-capacity power generation devices operated at approximately 650℃. If MCFCs are to be commercialized by improving their competitiveness, their cell life should be increased by operating them at lower temperatures. However, a decrease in the operating temperature causes a reduction in the cell performance because of the reduction in the electrochemical reaction rate. The cell performance can be improved by introducing a coating on the cathode of the cell. A coating with a high surface area expands the triple phase boundaries (TPBs) where the gas and electrolyte meet on the electrode surface. And the expansion of TPBs enhances the oxygen reduction reaction of the cathode. Therefore, the cell performance can be improved by increasing the reaction area, which can be achieved by coating nanosized LiCoO₂ particles on the cathode. However, although a coating improves the cell performance, a thick coating makes gas difficult to diffuse into the pore of the coating and thus reduces the cell performance. In addition, LiCoO₂-coated cathode cell exhibits stable cell performance because the coating layer maintains a uniform thickness under MCFC operating conditions. Therefore, the performance and stability of MCFCs can be improved by applying a LiCoO₂ coating with an appropriate thickness on the cathode.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2000년도 제1회 학술대회 논문집
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• pp.105-106
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• 2000

The positive slope of the current-voltage characteristic at pressure up to 850 torr was obtained using the closed microhollow cathode without the individual and/or distributed ballast. This indicates that the stable parallel operation of the discharge was also achieved using the closed microhollow cathode. The parallel operation makes it possible to manufacture de plasma displays with high pressure, small discharge current, and long lifetime.

• 전기학회논문지
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• 제57권1호
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• pp.78-81
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• 2008

A hollow cathode which has extremely stable discharge characteristic has been developed. This is composed of the two separated lanthanum hexaboride(LaB6) of a disk type in the tube as the electron emitters. The way of design is of great advantage to extend the surface discharge area of the LaB6, which is also useful for optimal fixing of the LaB6. The hollow cathode is capable of producing 30 kW(100 V, 300 A) of power continuously. Because the generated plasma beam with the high temperature(above $3000^{\circ}C$) from the hollow cathode passes through the center hole of the two intermediate electrodes, it is designed with the high temperature material of the tungsten and the suitable structure of the water cooling. The combinations of the hollow cathode and the two intermediate electrodes are practically useful for the ion plating plasma beam source.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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• pp.475-476
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• 2005

Efficient electron injection is essential to achieve bright and efficient organic light-emitting diodes (OLEDs). In spite of high work function of Al, it is a common cathode because of its stability. In this paper, to overcome the poor electron injection in OLEDs with Al cathode, OLEDs with various composite cathodes were fabricated and investigated using a conventional OLEDs structure of indium tin oxide ITO/NPB(40 nm)/$Alq_3$(50 nm)/Al. composite cathodes were composed of alkaline materials such as Ca and Li, Al deposition or codeposited with AI. We showed best performance at the device with composite cathode (LiF/Al).