• 제목/요약/키워드: stable Cs

검색결과 117건 처리시간 0.028초

Li, K과 Na-흑연 층간화합물의 stage 전이특성 (Stage transformation characteristice of Li, K and Na-graphite intercalation compounds)

  • 오원춘;임창성;오근호;고영신
    • 한국결정성장학회지
    • /
    • 제8권1호
    • /
    • pp.83-90
    • /
    • 1998
  • Li, K과 Na-흑연 층간화합물의 stage 전이 특성을 탄소층사이에 존재하는 intercalants의 deintercalation 메카니즘을 고려하여 제시하였다. 온도와 압력을 조절하여 합성된 Li-GICs(graphite intercalation compounds)를 분위기하에서 자발적으로 분해시켰다. 이들 화합물을 XRD 분석한 결과 1, 2 stage의 d001-값이 각각 3.71, 7.06 $\AA$으로 나타났다. 분위기하에서 Li-GiCs를 deintercalation 반응을 시킨 6주 후에 잔유화합물이 형성됨을 알 수 있었다. 또한, two-bulb 법으로 K-GICs를 합성하였으며, K-GDICs(graphite deintercalation compounds)의 구조적 안정성과 stage 전이에 대하여 조사하였다. X-선회절 결과로부터 K-GDICs는 10주 동안 안정한 K-흑연 잔유 화합물을 형성하였다. 그리고 고온, 고압법을 이용하여 합성된 1, 2stage의 Na-GICs의 deintercalation 반응과 열적 안정성에 대한 온도 의존성에 대하여 논하였다. 열적 안정성과 관련하여 Na-GICs의 구조변화를 XRD에 의하여 확인하였다. 이들 과정에 따르면 stage 전이는 무질서한 stage를 가진 GDICs의 불규칙적인 deintercalation에 의하여 형성됨을 제시할 수 있었다.

  • PDF

자가미세유화를 이용한 이부프로펜 액상제제의 제조와 특성 (Preparation and Characterization of Liquefied Ibuprofen Using Self-Microemulsion Drug Delivery System (SMEDDS))

  • 안용산;송지희;강복기;김문석;조선행;이종문;이해방;강길선
    • Journal of Pharmaceutical Investigation
    • /
    • 제34권1호
    • /
    • pp.35-42
    • /
    • 2004
  • Ibuprofen (IBU), is a non-steroidal anti-inflammatory drug, used to treat rheumatoid arthritis, removal of fever and mild to moderate pain. Because of small dosage and very low accumulation in the body, IBU has been used to heal children's fever. However, IBU was very low solubility in a low pH and water (in water $0.03{\sim}2.5$ mg/ml). A nanoemulsion containing IBU by means of self-microemulsion drug delver system (SMEDDS) was prepared in order to enhance the solubility of IBU. The SMEDDS was composed of cosurfactant, oil and surfactant The solubility of IBU in various components such as cosurfactant, oil and surfactant was examined. $Carbitol^{\circledR}\;(386.99{\pm}20.5\;mg/ml)$ as a cosurfactant, $Labrafil^{\circledR}$  M1944CS $(90.16{\pm}1.60mg/ml)$ as an oil and $Cremopher^{\circledR}$  RH-40 $(239.01{\pm}2.8\;mg/ml)$ as a surfactant were used in this study for preparing SMEDDS. Optimized formulation of SMEDDS was obtained by phase diagram which express the section of nanoemulsion formation. The SMEDDS containing IBU had higher dissolution rate than conventional IBU sirups. Thus the SMEDDS was a potential candidate of stable conventional and effective oral dosage form for IBU.

자기상관 비교 범위를 활용한 레이더 신호의 펄스 변조 형태 검출 알고리즘 (A Detection Algorithm for Modulation Types of Radar Signals Using Autocorrelation Comparison Ranges)

  • 김관태;주영관;전중남
    • 융합정보논문지
    • /
    • 제8권5호
    • /
    • pp.137-143
    • /
    • 2018
  • 일반적으로 레이더는 신호 탐지를 회피하기 위해 신호를 변조해 송신한다. 전자전에서는 수신된 레이더 펄스를 분석하여 신호를 방사한 레이더의 제원을 식별한다. 본 논문에서는 자기상관계수를 활용하여 레이더 신호 변조 형태를 식별하는 알고리즘을 제안한다. 레이더 신호의 펄스반복주기 특성에 따라 자기상관을 계산할 때 비교 범위를 다르게 적용한다. 고정 펄스반복주기와 스태거 펄스반복주기에 대하여 좁은 오차 범위를 적용하고, 지터 펄스반복주기에는 넓은 오차 범위를 적용하여 자기상관계수를 계산한다. 실험에 의하여 제안하는 알고리즘은 고정 펄스반복주기, 스태거 펄스반복주기, 지터 펄스반복주기를 정확하게 구분함과 동시에 스태거의 레벨도 정확히 찾을 수 있음을 확인하였다.

In Situ Gamma-ray Spectrometry Using an LaBr3(Ce) Scintillation Detector

  • Ji, Young-Yong;Lim, Taehyung;Lee, Wanno
    • Journal of Radiation Protection and Research
    • /
    • 제43권3호
    • /
    • pp.85-96
    • /
    • 2018
  • Background: A variety of inorganic scintillators have been developed and improved for use in radiation detection and measurement, and in situ gamma-ray spectrometry in the environment remains an important area in nuclear safety. In order to verify the feasibility of promising scintillators in an actual environment, a performance test is necessary to identify gamma-ray peaks and calculate the radioactivity from their net count rates in peaks. Materials and Methods: Among commercially available scintillators, $LaBr_3(Ce)$ scintillators have so far shown the highest energy resolution when detecting and identifying gamma-rays. However, the intrinsic background of this scintillator type affects efficient application to the environment with a relatively low count rate. An algorithm to subtract the intrinsic background was consequently developed, and the in situ calibration factor at 1 m above ground level was calculated from Monte Carlo simulation in order to determine the radioactivity from the measured net count rate. Results and Discussion: The radioactivity of six natural radionuclides in the environment was evaluated from in situ gamma-ray spectrometry using an $LaBr_3(Ce)$ detector. The results were then compared with those of a portable high purity Ge (HPGe) detector with in situ object counting system (ISOCS) software at the same sites. In addition, the radioactive cesium in the ground of Jeju Island, South Korea, was determined with the same assumption of the source distribution between measurements using two detectors. Conclusion: Good agreement between both detectors was achieved in the in situ gamma-ray spectrometry of natural as well as artificial radionuclides in the ground. This means that an $LaBr_3(Ce)$ detector can produce reliable and stable results of radioactivity in the ground from the measured energy spectrum of incident gamma-rays at 1 m above the ground.

Lateral approach for maxillary sinus membrane elevation without bone materials in maxillary mucous retention cyst with immediate or delayed implant rehabilitation: case reports

  • Han, Ji-Deuk;Cho, Seong-Ho;Jang, Kuk-Won;Kim, Seong-Gwang;Kim, Jung-Han;Kim, Bok-Joo;Kim, Chul-Hun
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
    • /
    • 제43권4호
    • /
    • pp.276-281
    • /
    • 2017
  • This case series study demonstrates the possibility of successful implant rehabilitation without bone augmentation in the atrophic posterior maxilla with cystic lesion in the sinus. Sinus lift without bone graft using the lateral approach was performed. In one patient, the cyst was aspirated and simultaneous implantation under local anesthesia was performed, whereas the other cyst was removed under general anesthesia, and the sinus membrane was elevated in a second process, followed by implantation. In both cases, tapered 11.5-mm-long implants were utilized. With all of the implants, good stability and appropriate bone height were achieved. The mean bone level gain was 5.73 mm; adequate bone augmentation around the implants was shown, the sinus floor was moved apically, and the cyst was no longer radiologically detected. Completion of all of the treatments required an average of 12.5 months. The present study showed that sufficient bone formation and stable implantation in a maxilla of insufficient bone volume are possible through sinus lift without bone materials. The results serve to demonstrate, moreover, that surgical treatment of mucous retention cyst can facilitate rehabilitation. These techniques can reduce the risk of complications related to bone grafts, save money, and successfully treat antral cyst.

Study of Nano-scale Fullerene (C60) Clusters Formed in Micro-sized Droplet by UV Irradiation

  • Yeo, Seung-Jun;Ahn, Jeung-Sun
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
    • /
    • pp.571-571
    • /
    • 2012
  • We discovered the formation of C60 aggregates in solution by means of photoluminescence spectroscopic study on C60 in solutions. From the in-depth investigation of temperature dependence of the luminescence of C60 in toluene, benzene and CS2 solutions, we reported that the C60 aggregates are formed during cooling at the freezing temperature of these solvents. Furthermore, the C60 aggregates can be changed to stable structures by irradiating with UV pulse-laser (Nd:YAG laser, 355nm). As a consequence, we could obtain nano-scale photo-polymerized C60 clusters, which appear as round-shaped nano- scale particles in high resolution transmission electron-microscopy (HRTEM) images. However, the yield of the nano-scale C60 clusters obtained by this method is too small. So we designed and developed a system to obtain C60 cluster of macroscopic quantity by using ultrasonic nebulizer. In this system, C60 solution was vaporized to several micro-sized droplets in vacuum, resulting in the formation of C60 aggregates by evaporating solvent (toluene). The system was invented to produce nano-scale carbon clusters by the irradiation of UV light upon C60 aggregates in vacuum. We have characterized the products, C60 cluster, obtained from the system by using UV absorption spectra and HPLC spectra. Although the products have a possibility of inclusion various forms of C60 cluster, results support that the product formed from the system by using vaporizer method establishes a new method to obtain C60 cluster in macroscopic quantity. In the presentation, the details of the system and the results of characterization are reported.

  • PDF

Bifidobacterium longum KCTC 3215에 의한 $\beta$-Galactosidase의 생산. 정제 및 특성 (Production, Purification and Characterization of $\beta$-Galactosidase from Bifidobaacterium longurn KCTC 3 2 15)

  • 강국희;민해기;장영효;이호근
    • 한국미생물·생명공학회지
    • /
    • 제19권5호
    • /
    • pp.456-463
    • /
    • 1991
  • Bif. longum KCTC 3215에 의한 Beta-galactosidase의 최적생성조건은 탄소원으로 lactose 1.0, 초기 pH 7.0, 배양온도 $37^{\circ}C$ 및 배양시간 17시간 후였다. 이 효소는 protamine sulfate, ammonium sulfate, DEAE-Sephadex A-50 ion exchange chromatography 및 Sephadex G-150 gel filtration 등 4단계 정제과정을 거쳐 9.25배 정제되었다.

  • PDF

앉은 자세에서 일어날 때 비탄력 테이핑을 이용한 무릎뼈의 아래 안쪽 활주가 안쪽넓은근과 가쪽넓은근의 근활성도에 미치는 영향 (Effect of inferomedial gliding of patella using non-eleastic taping on muscle activity of vastus medialis and vastus lateralis during sit to stand)

  • 윤상혁;강종호
    • 융합정보논문지
    • /
    • 제7권4호
    • /
    • pp.39-43
    • /
    • 2017
  • 본 연구의 목적은 앉은 자세에서 일어날 때 비탄력 테이핑을 이용한 무릎뼈의 안쪽 활주와 아래 안쪽 활주가 안쪽넓은근과 가쪽넓은근의 근활성도 비율에 미치는 영향에 대해 알아보고자 하는 것이었다. 측정 결과, 안쪽 활주와 비교하여 아래 안쪽 활주를 적용했을 때 안쪽넓은근의 근활성도가 전체 근활성도 대비 비율이 더 높게 나타나는 것을 확인할 수 있었다. 무릎뼈의 안쪽 활주보다 아래 안쪽 활주가 무릎관절의 안정성에 더 큰 기여를 하며, 특히 무릎넙다리 통증증후군의 증상 완화 및 예방에 효과적일 것으로 사료된다. 이와 관련하여 무릎뼈를 아래 안쪽 방향으로 활주 시킬 수 있는 보조기 및 운동복 등의 개발은 무릎관절의 건강을 확보할 수 있는 새로운 방법이 될 것으로 기대한다.

테들러 백 샘플러의 대체 소재로서 폴리에스터 알루미늄 백에 대한 예비연구: 환원황화합물을 중심으로 (A Preliminary Study on Polyester Aluminum Bag as the Possible Substitute for Tedlar Bag Sampler in RSC Analysis)

  • 김기현;조상희
    • 한국대기환경학회지
    • /
    • 제27권4호
    • /
    • pp.454-459
    • /
    • 2011
  • In this study, the recovery rate of Tedlar bag (T) sampler was investigated in comparison to polyester aluminum bag (P) sampler. To derive the comparative data sets for the relative performance between different samplers, a series of calibration experiments were performed by using 1 ppb standard of four offensive reduced sulfur compounds (RSC) odorants ($H_2S$, $CH_3SH$, DMS, and DMDS) along with $SO_2$ and $CS_2$. All the analysis was made by gas chromatography/pulsed flame photometric detector (GC/PFPD) combined with air server/thermal desorber (AS/TD). The measurement data were obtained by loading gaseous standards (1 ppb) at 3 injection volumes (250, 500 and 1,000 mL) at three intervals (0, 24 and 72 hrs). The recovery rates (RR) of P sampler were computed against the slope values of T sampler. According to our analysis, P sampler exhibits slightly enhanced loss relative to T, especially with light RSCs ($H_2S$ and $CH_3SH$). At day 0, RR for the two were 88 and 85%, respectively. Such reduction proceeded rather rapidly in the case of $H_2S$ through time. However, P sampler was more stable to store $SO_2$ unlike others. Despite slightly reduced recovery, P sampler appears as a good replacement of T sampler.

하천제방 붕괴의 불확실성을 고려한 확률론적 홍수위험지도 개발 (Development of Probabilistic Flood Risk Map Considering Uncertainty of Levee Break)

  • 남명준;이재영;이창희
    • 융합정보논문지
    • /
    • 제9권11호
    • /
    • pp.125-133
    • /
    • 2019
  • 본 연구에서는 홍수시나리오에 의해 발생한 제방붕괴에서 불확실성을 포함한 확률홍수위험지도를 산정하였다. 불확실성을 포함한 극치수문시나리오와 그에 따른 홍수위가 산정된 선행연구자료를 활용하였고 이에 따라 제방붕괴 예측지점을 산정하였다. 단순한 조건에 따른 일률적인 파제폭을 제시하는 경험식과 지반공학적 복합요소들에 대한 불확실성을 고려한 물리적 기반의 수치모의 방식을 결합하여 파제폭을 산정하였다. 이에 따라 확률론적 파제유입량을 결정하였고, 신뢰도를 기반으로 100회 모의수행을 통한 2차원 제내지 침수해석을 실시하여 확률침수심도를 작성하였다. 이를 통해 홍수위험지도 작성기법을 기반으로 확률침수심도와 결합하여 확률홍수위험지도를 작성하였다. 본 연구결과는 제내지의 비상대처계획(EAP)의 정량적 근거자료로 보다 경제적, 안정적인 설계지표 제시하는데 효과적일 것으로 기대된다.