• Title/Summary/Keyword: stability coefficient

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Residual Stress and Elastic Modulus of Y2O3 Coating Deposited by EB-PVD and its Effects on Surface Crack Formation

  • Kim, Dae-Min;Han, Yoon-Soo;Kim, Seongwon;Oh, Yoon-Suk;Lim, Dae-Soon;Kim, Hyung-Tae;Lee, Sung-Min
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.410-416
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    • 2015
  • Recently, a new $Y_2O_3$ coating deposited using the EB-PVD method has been developed for erosion resistant applications in fluorocarbon plasma environments. In this study, surface crack formation in the $Y_2O_3$ coating has been analyzed in terms of residual stress and elastic modulus. The coating, deposited on silicon substrate at temperatures higher than $600^{\circ}C$, showed itself to be sound, without surface cracks. When the residual stress of the coating was measured using the Stoney formula, it was found to be considerably lower than the value calculated using the elastic modulus and thermal expansion coefficient of bulk $Y_2O_3$. In addition, amorphous $SiO_2$ and crystalline $Al_2O_3$ coatings were similarly prepared and their residual stresses were compared to the calculated values. From nano-indentation measurement, the elastic modulus of the $Y_2O_3$ coating in the direction parallel to the coating surface was found to be lower than that in the normal direction. The lower modulus in the parallel direction was confirmed independently using the load-deflection curves of a micro-cantilever made of $Y_2O_3$ coating and from the average residual stress-temperature curve of the coated sample. The elastic modulus in these experiments was around 33 ~ 35 GPa, which is much lower than that of a sintered bulk sample. Thus, this low elastic modulus, which may come from the columnar feather-like structure of the coating, contributed to decreasing the average residual tensile stress. Finally, in terms of toughness and thermal cycling stability, the implications of the lowered elastic modulus are discussed.

Temperature Dependence on Dry Etching of $ZrO_2$ Thin Films in $Cl_2/BCl_3$/Ar Inductively Coupled Plasma ($Cl_2/BCl_3$/Ar 유도 결합 플라즈마에서 온도에 따른 $ZrO_2$ 박막의 식각)

  • Yang, Xue;Kim, Dong-Pyo;Lee, Cheol-In;Um, Doo-Seung;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.145-145
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    • 2008
  • High-k materials have been paid much more attention for their characteristics with high permittivity to reduce the leakage current through the scaled gate oxide. Among the high-k materials, $ZrO_2$ is one of the most attractive ones combing such favorable properties as a high dielectric constant (k= 20 ~ 25), wide band gap (5 ~ 7 eV) as well as a close thermal expansion coefficient with Si that results in good thermal stability of the $ZrO_2$/Si structure. During the etching process, plasma etching has been widely used to define fine-line patterns, selectively remove materials over topography, planarize surfaces, and trip photoresist. About the high-k materials etching, the relation between the etch characteristics of high-k dielectric materials and plasma properties is required to be studied more to match standard processing procedure with low damaged removal process. Among several etching techniques, we chose the inductively coupled plasma (ICP) for high-density plasma, easy control of ion energy and flux, low ownership and simple structure. And the $BCl_3$ was included in the gas due to the effective extraction of oxygen in the form of $BCl_xO_y$ compounds. During the etching process, the wafer surface temperature is an important parameter, until now, there is less study on temperature parameter. In this study, the etch mechanism of $ZrO_2$ thin film was investigated in function of $Cl_2$ addition to $BCl_3$/Ar gas mixture ratio, RF power and DC-bias power based on substrate temperature increased from $10^{\circ}C$ to $80^{\circ}C$. The variations of relative volume densities for the particles were measured with optical emission spectroscopy (OES). The surface imagination was measured by scanning emission spectroscope (SEM). The chemical state of film was investigated using energy dispersive X-ray (EDX).

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Correlations of Infant Temperament, Mother-Infant Interaction, and Child-rearing Environment (영아 기질과 모아상호작용, 양육환경과의 관계)

  • Han Kyung Ja;Bang Kyung Sook
    • Child Health Nursing Research
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    • v.6 no.2
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    • pp.132-143
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    • 2000
  • The purpose of this correlational study was to find the correlation between the infant temperament, mother-infant interaction, and child-rearing environment. The subjects of this study were 37 dyads of healthy mothers and healthy infants. Data were collected from 15th of March to 3rd of September, 1999. Convenient sampling was done at Obstetric wards of one University hospital, and demographic data were collected before discharge. At one month and three month postpartum, we visited subject's home, and collected the data on the infant temperament, and also video taped the mother-infant interaction during feeding. In addition, child-rearing environment was checked by researcher according to HOME(Home Observation for Measurement of the Environment) at three months postpartum. Mother-infant interactions were rated according to the NCAST Feeding Scale later. Data were analyzed by window SPSS program, and correlations between the infant temperament, mother-infant interaction, and child-rearing environment were analyzed by Pearson's correlational coefficient. The results were as follows: 1. Infant temperament. 1) Among the subscales of infant temperament, mothers perceived cuddliness and amenability most positively at one month, and responsivity and amenability most positively at three months. 2) In subscale analysis of stability, amenability, responsivity, and persistence were stable with the time. 3) Significant relationships were found between the malleability and amenability, between the malleability and responsivity at one month, and also between the malleability and amenability, and between the malleability and cuddliness at three months. 2. Correlations of infant temperament and mother-infant interaction. 1) There was no significant relationship between the infant temperament and mother-infant interaction at one month. 2) There was a significant relationship between the infant temperament and mother-infant interaction at three months(r=.335, p<.05). In subscale analysis, there were significnt relationships between the total score of infant temperament and maternal sensitivity to infant's cues(r=.372, p<.05), and between the total score of infant temperament and maternal response to infant's distress (r=.331, p<.05). 3. Correlations of infant temperament and child-rearing environment. 1) There was no significant relationship between the total score of infant temperament at one month and total score of HOME at three months. In subscal analysis, the total score of infant temperament at one showed significant relationships with the organization of environment(r=.413, p<.05), and the emotional, verbal response at three months(r=.337, p<.05). 2) There was a significant relationship between the total score of infant temperament at three months and the total score of HOME at three months (r=.599, p<.01). In subscal analysis, the total score of infant temperament at three months showed significant relationships with the organization of environment(r=.410, p<.05), maternal involvement(r=.482, p,.01), and the emotional, verbal response(r=.695, p<.01) at three months. 4. Correlations of mother-infant interaction and child-rearing environment. There was a significant relationship between the maternal score of mother-infant interaction at one month and three months and the total score of HOME at three months (r=.474, p<.01; r=.452, p<.01). In conclusion, it was proved that infant temperament had significant relationships with mother-infant interaction and child-rearing environment, especially when the infants were getting older. This showed the possibility for changeability of infant teperament by the maternal factors.

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Operating Conditions Proposal of Bandgap Circuit at Cryogenic Temperature for Signal Processing of Infrared Detector and a Performance Analysis of a Manufactured Chip (적외선 탐색기 신호처리를 위한 극저온 밴드갭 회로 동작 조건 제안 및 제작된 칩의 성능 분석)

  • Kim Yon Kyu;Kang Sang-Gu;Lee Hee-Chul
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.41 no.12
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    • pp.59-65
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    • 2004
  • A stable reference voltage generator is necessary to the infrared image signal readout circuit(ROIC) to improve noise characteristics of signal originated from infrared devices, that is, to gain good images. In this paper, bandgap circuit operating at cryogenic temperature of 77K for Infrared image ROIC(readout integrated circuit) was first made. It demonstrates practical use possibility through taking measurements and estimations. Bandgap circuit is a representative voltage reference circuit. Most of bandgap reference circuits which are presented so far operate at room temperature, and their characteristic are not suitable for infrared image ROIC operating at liquid nitrogen temperature, 77K. To design bandgap circuit operating at cryogenic temperature, suitable circuit is selected and the parameter characteristics of used devices as temperature change are seen by a theoretical study and fitted at liquid temperature with considering such characteristics. This circuit has been fabricated in the Hynix 0.6um standard CMOS process, and the output voltage measured shows that the stability is 1.042±0.0015V over the temperature range of 60K to 110K and is better than bandgap circuits operated at room temperature.

Comparison of Coordination and Kinematic Variability of Trunk, Pelvis and Hip Joint in Subjects With and Without Chronic Low Back Pain During an Anterior Load Carriage Task (건강한 성인과 만성요통환자의 전방 짐 나르기 동안 몸통, 골반, 엉덩관절의 협응과 운동형상학적 가변성 비교)

  • Chai, Eun-Su;Kim, Tack-Hoon;Rho, Jung-Suk;Choi, Houng-Sik
    • Physical Therapy Korea
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    • v.22 no.2
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    • pp.21-29
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    • 2015
  • This study investigated the effect of a load of 15% body weight on trunk, pelvis and hip joint coordination and angle variability in subjects with and without chronic low back pain (CLBP) during an anterior load carriage task. Thirty volunteers participated in the study (15 without CLBP, 15 with CLBP). All participants were asked to perform an anterior carriage task with a load of 15% body weight. The outcome measures included the means and standard deviations for measurements of three-dimensional coordination and angle variability of the trunk, pelvis and hip joint. As CLBP patient group .06, control group .70, the correlation coefficient between the groups showed a significant difference only in trunk-pelvic in the sagittal plane (p<.05). Angle variability of CLBP patient group increased significantly in the trunk in frontal plane, the pelvis in all sagittal plane, frontal plane, transverse plane, and the hip in sagittal plane, the hip in frontal plane than angle variability of control group (p<.05). This results mean that the CLBP patient group showed a disconnected coordination pattern in the trunk-pelvis in the sagittal plane, an increased pelvic angle variability in all three planes, and hip angle variability in the sagittal, and frontal planes. The CLBP patient group may have developed a compensatory movement of the pelvis and hip joint arising from the changed stability due to the abnormal coordination patterns of the trunk-pelvic in the sagittal plane. Therefore, CLBP symptoms can potentially worsen in the pelvis and adjacent hip joint in CLBP patients who perform weight-related behaviors in their daily lives. Further research is needed to determine the three-dimensional characteristics of the electromyography and neuromuscular aspects of subjects with CLBP.

Synthesis, Dispersion, and Tribological Characteristics of Alkyl Functionalized Graphene Oxide Nanosheets for Oil-based Lubricant Additives (액체 윤활제 첨가제용 알킬 기능화된 산화 그래핀의 합성/분산 및 트라이볼로지적 특성)

  • Choe, Jin-Yeong;Kim, Yong-Jae;Lee, Chang-Seop
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.533-540
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    • 2018
  • Graphene has been reported to be an excellent lubricant additive that reduces friction and wear when coated on the surface of various materials or when dispersed in lubricants as an atomic thin material with the low surface energy. In this study, alkyl functionalized graphene oxide (FGO) nanosheets for oil-based lubricant additives were prepared by using three types of alkyl chloride chemicals (butyl chloride, octyl chloride, and tetradecyl chloride). The chemical and structural properties of the synthesized FGOs were analyzed by Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscope (SEM), and transmission electron microscope (TEM). The synthesized FGOs were dispersed at 0.02 wt% in PAO-0W40 oil and its tribological characteristics were investigated using a high frequency friction/wear tester. The friction coefficient and the wear track width of poly alpha olefin (PAO) oil added with FGO-14 were tested by a ball-on-disk method, and the measured results were reduced by ~5.88 and ~3.8%, respectively compared with those of the conventional PAO oil. Thus, it was found that the wear resistance of PAO oil was improved. In this study, we demonstrated the successful functionalization of GO as well as the improvement of dispersion stability and tribological characteristics of FGOs based on various alkyl chain lengths.

A temperature stable bandpass filter using dieletric-filled stepped impedance resonators (접합된 Stepped impedance resonator를 이용한 온도보상형 유전체 대역통과 필터)

  • Lim, Sang-Kyu;Kim, Jun-Chul;Kim, Duck-Hwan;Ha, Jong-Su;Oh, Chang-Heon;Sim, Hwa-Sup;An, Chul
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.2
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    • pp.78-85
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    • 1998
  • The design method of a temperature stable bandpass filter using dielectric coaxial resonators of with two dielectric ceramics with opposite signs of temperature coefficient of dielectric constant (${\tau}_{\epsilon}$) to compensate for each other in this method. $MgTiO_3$(${\tau}_{\epsilon}$=+99 ppm/${\circ}C$) as a positive ${\tau}_{\epsilon}$ material and Ba($Zn_{1/3}Nb_{2/3}$)$O_3$(${\tau}_{\epsilon}$=-77ppm/${\circ}C$) as a negative material were selected. The length of a SIR for the temperature stability was calculated according to the design method and the susceptance slope parameter of the SIR was obtained. A temperature stable bandpass filter using dielectric SIR's was designed, simulated and fabricated. The center frequency of this filter was 915 MHz and the pass bandwidth was 20 MHz. Temperature properties of this bandpass filter by simulations were compared with the measured results of the bandpass filter fabricated.

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A Study on the Applicability of Modified Cam-clay Model in Low Plastic Clays (저소성 점토의 수정 Cam-clay 모델 적용성에 관한 연구)

  • Lee, Song;Kim, Tae-Hwoon
    • Journal of the Korean Geotechnical Society
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    • v.19 no.4
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    • pp.247-256
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    • 2003
  • FEM analyses which are based on modified Cam-clay theory have been generally used in such cases as analyses of stability and displacement fur embankment construction on soft clays. However, the Modified Cam Clay Model can generate some problems in anisotropic stress conditions of field because the critical state theory has been developed through many laboratory tests in isotropic conditions. Thus, the applicability on the prediction of undrained shear strength and pore water pressure which was based on the critical state theory was evaluated by triaxial tests and numerical analyses in isotropic and anisotropic conditions. Used samples often come out in domestic area, together with general low plastic clays which are showing dilatant behavior in shearing process. They were evaluated by laboratory tests and FEM based on MCCM. From the results of test and numerical analysis, the predictions of undrained strength in low plastic clays well coincided with each other in both isotropic and anisotropic conditions. However, the generation of porewater pressure was often overestimated during undrained shearing in anisotropic conditions. The results can generate the errors in the prediction of stress path of field sites during loading such as construction of embankment on soft clays because the field is subjected to anisotropic conditions during loading.

Estimation of Suspended Sediment Concentration in Small Stream with Acoustic Backscatter from Horizontal ADCP based on Real-Scale Field Experiment (실규모 현장 실험 기반 H-ADCP 초음파 산란도 활용 소하천용 하천 부유사 농도 측정 기법 개발)

  • Seo, Kanghyeon;Kim, Dongsu;Son, Geunsoo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.36 no.6
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    • pp.1023-1035
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    • 2016
  • Suspended sediment concentration (SSC) is a crucial riverine parameter in terms that it can be utilized for analyzing sediment transport, stability assessment of river and structure and so on. However, in case of domestic, sediment discharge data are not enough because of using conventional sediment samplers. This study aimed at developing a practical technique for estimating suspended sediment concentration in high spatial and temporal resolution by building relationship between acoustic backscatter (or SNR) from H-ADCP with actually observed data using LISST-100X. In this regard, a dedicated correction algorithm was proposed particularly for the adapted H-ADCP (SonTek SL-3000). Then, a SNR-SSC relation was built based upon a real-scale field experiment, where both H-ADCP and LISST-100X were concurrently operated to observe SNR and SSC, respectively. The coefficient of determination for the developed regression equation of SNR-SSC relation was around 0.85~0.88, thereby the relation could be evaluated to be highly correlated. The result of this study might be potentially applied for real-time and simultaneous observation of SSC when H-ADCP could be applied.

Setting of the range for shear strength of fault cores in Gyeongju and Ulsan using regression analysis (회귀분석을 이용한 경주·울산 지역에 분포하는 단층 핵의 전단강도 범위 설정)

  • Yun, Hyun-Seok;Moon, Seong-Woo;Seo, Yong-Seok
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.17 no.2
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    • pp.127-140
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    • 2015
  • A fault is one of the critical factors that may lead to a possible ground collapse occurring in construction site. A fault core, however, possibly acting as a failure plane in whole fault zone, is composed of fractured rock and gouge nonuniformly distributed and thus can be characterized by its wide range of shear strength which is generally acquired by experimental method for stability analysis. In this study, we performed direct shear test and grain size distribution analysis for 62 fault core samples cropped from 12 different spots located in the vicinity of Kyongju and Ulsan, Korea. As a result, the range of shear strength representing the characteristics of fault cores in the study regions is determined with regard to vertical stress using a regression analysis for experiment data. The weight ratio of gravels in the samples is proportional to the shear strength and that of silt and clay is in inverse proportion to the shear strength. For most samples, the coefficient of determination is over 0.7 despite of inhomogeneity of them and consequently we determined the lower limit and upper limit of the shear strength with regard to the weight ratio by setting the confidence interval of 95%.