• 제목/요약/키워드: spiroether

검색결과 1건 처리시간 0.014초

Cerium(IV) Ammonium Nitrate를 이용한 Spiroannulated 다이하이드로퓨란 화합물의 합성 (Synthesis of Spiroannulated Dihydrofuran Compounds Utilizing Cerium(IV) Ammonium Nitrate)

  • 김병소
    • 한국산업융합학회 논문집
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    • 제5권4호
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    • pp.385-390
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    • 2002
  • An efficient synthesis of spiroannulated dihydrofurans is achieved from 1,3-dicarbonyl compounds and exocyclic alkenes in the presence of cerium ammonium nitrate(IV) in moderate yields. In the case of entries 3-9, as a single product was seen. Especially, reaction of 15 with methylenecyclohexane afforded the two regioisomeric cyclo adducts 21 and 22. The structures of these adducts were confirmed by IR and NMR-Spectra.

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