• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.16-17
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• 2010

Molecular spintronics has attracted attentions, which combines molecular electronics with the spin degree of freedom in electron transport. Among various molecules as candidates of the molecular spintronics, single molecule magnet (SMM) is one of the most promising material. SMM molecules show a ferromagnetic behavior even as a single molecule and hold the spin information even after the magnetic field is turned off. Here in this report, we show the spin behavior of SMM molecules adsorbed on the Au surface by combining the observation of Kondo peak in the STS and ESR-STM measurement. Kondo resonance state is formed near the Fermi level when degenerated spin state interacts with conduction electrons. ESR-STM detects the Larmor frequency of the spin in the presence of a magnet field. The sample include $MPc_2$ and $M_2Pc_3$ molecules ($M\;=\;Tb^{3+}$, $Dy^{3+}$, and $Y^{3+}$ Pc=phthalocyanine) whose critical temperature as a ferromagnet reaches 40 K. A clear Kondo peak was observed which is originated from an unpaired electron in the ligand of the molecule, which is the first demonstration of the Kondo peak originated from electron observed in the STS measurement. We also observed corresponding peaks in ESR-STM spectra. [1] In addition we found that the Kondo peak intensity shows a clear variation with the conformational change of the molecule; namely the azimuthal rotational angle of the Pc planes. This indicates that the Kondo resonance is correlated with the molecule electronic state. We examined this phenomena by using STM manipulation technique, where pulse bias application can rotate the relative azimuthal angle of the Pc planes. The result indicates that an application of ~1V pulse to the bias voltage can rotate the Pc plane and the Kondo peaks shows a clear variation in intensity by the molecule's conformational change.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.2
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• pp.45.2-45.2
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• 2019

The main-belt asteroid (5247) Krylov is known as a Non-Principal Axis (NPA) rotator. However, the shape model and spin state of this asteroid were not revealed. The physical model of an asteroid including spin state and shape is regarded to be important to understand its physical properties and dynamical evolution. Thus, in order to reconstruct the physical model of Kryolv, we applied the light curve inversion method using not only the optical light curves observed with ground-based telescopes in three apparitions during 2006, 2016, and 2017, but also the infrared light curves obtained with the Wide-field Infrared Survey Explorer (WISE) in 2010. We found that it is rotating in Short Axis Mode (SAM) with the rotation and precession periods of 368.71 hr and 67.277 hr, respectively. The orientation of the angular momentum vector is (298°, -58°) in the ecliptic coordinate system. The ratio of moments of inertia of the longest axis to the shortest axis is I_a/I_c = 0.36; the ratio of moments of inertia of the intermediate axis to the shortest axis is I_b/I_c = 0.96. Finally, the excitation level of this asteroid is found to be rather low with a ratio of the rotational kinetic energy to the basic spin state energy as E/E₀ ≃ 1.024. We will briefly discuss the possible evolutionary process of Krylov in this presentation.

• Advances in materials Research
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• v.2 no.4
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• pp.195-208
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• 2013

A comprehensive theory of the spin coating technique has been reviewed and the basic principles and parameters controlling the process are clearly highlighted, which include spin speed, spin time, acceleration and fume exhaust. The process generally involves four stages: a dispense stage, substrate acceleration stage, a stage of substrate spinning at a constant rate and fluid viscous forces dominate fluid thinning behaviour and a stage of substrate spinning at a constant rate and solvent evaporation dominates the coating thinning behaviour. The study also considered some common thin film defects associated with this technique, which include comet, striation, chucks marks environmental sensitivity and edge effect and possible remedies.

• Current Applied Physics
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• v.18 no.11
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• pp.1447-1450
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• 2018

The electron spin resonance (ESR) detects point defect of the In-Ga-Zn oxide (IGZO) like singly ionized oxygen vacancies and excess oxygen, and get spin density as a parameter of defect state. So, we demonstrated the spin density measurement of the IGZO film with various deposition conditions and it has linear relationship. Moreover, we matched the spin density with the total BTS and the threshold voltage ($V_{th}$) distribution of the IGZO thin film transistors. The total BTS ${\Delta}V_{th}$ and the $V_{th}$ distribution were degraded due to the spin density increases. The spin density is the useful indicator to predict $V_{th}$ instability of IGZO TFTs.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.3
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• pp.771-783
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• 1995

A simplified model for the so-called ACRT(accelerated crucible rotation technique) Bridgman crystal growth was considered in order to investigate the principal effects of the periodic variation of angular velocity. Numerical solutions were obtained for Ro=0.5, Ra=4.236*10$_{6}$ and E=2.176*10$^{-3}$ . The effects of spin-up process combined with natural convection was investigated as a preliminary study. The spin-up time scale for the present problem was a little larger than that observed for homogeneous spin-up problems. Numerical results reveal that over a time scale of (H$^{2}$/.nu..omega.$_{f}$)$^{1}$2/ the forced convection due to the formation of Ekman layer predominates. When the state of rigid body rotation is attained, natural convection due to buoyancy emerges as the main driving force and them the steady-state is approached asymptotically. Based on our preliminary results with simple spin-up, several fundamental features associated with variation of rotation speed are successfully identified. When a periodic variation of angular velocity was imposed, the system response was also periodic. Due to effect of mixing, the heat transfer was enlarged. From the analysis of time-averaged Nusselt number along the bottom surface the effect of a periodic variation of angular velocity on the interface location could be indirectly identified.d.

• Journal of the Korean Society for Precision Engineering
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• v.20 no.2
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• pp.209-217
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• 2003

In this paper, the dynamic system modeling and the state sensitivity analysis of the spin-coater system are proposed for the reduction of the vibration. In the respect of modeling, the spin-coater system is considered to be composed of servomotor, spindle, supporting base and so on. Each component of model is combined and derived to 3 dimensional equations. The combined model is verified by experimental values of actual system in the frequency domain. By direct differentiation of the constraint equations with respect to kinematic design variables, such as eccentricity of spindle, moment of inertia, rotational stiffness and damping of supported base, sensitivity equations are derived to the verified state equations. Sensitivity of design variables could be used for vibration reduction and natural frequency shift in the frequency domain. Finally, dominant design variables are selected from the sensitivity analysis.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.127.1-127.1
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• 2013

Recent experimental evidence that fluorinated graphene creates local magnetic moments around F adatoms has not been supported by semilocal density-functional theory (DFT) calculations where the adsorption of an F adatom induces no magnetic moment in graphene. Here, we show that such an incorrect prediction of the nonmagnetic ground state is due to the self-interaction error inherent in semilocal exchange-correlation functionals. The present hybrid DFT calculation for an F adatom on graphene predicts not only a spin-polarized ground state with a spin moment of ${\sim}1{\mu}_B$, but also a long-range spin polarization caused by the bipartite nature of the graphene lattice as well as the induced spin polarization of the graphene states. The results provide support for the experimental observations of local magnetic moments in fluorinated graphene.

• Journal of the Korean Magnetics Society
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• v.5 no.5
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• pp.762-766
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• 1995

The coercive field $H_{c}$ of amorphous Y-Fe alloys in the spin-glass state has been investigated. Foramorphous $Y_{10}Fe_{90}$ alloy, the thermal variations of $H_{c}$ in the maximum external field $H_{max}=300,\;600$ and 1 k Oe exhibit a maximum. Since spin-glass behavior is strongly affected by external magnetic fields, the maximum point moves to lower temperature with increasing $H_{max}$. The appearance of the maximum in $H_{c}$ has been discussed in terms of the change of the spin-glass state in the external magnetic field. When the value of $H_{max}$ is 55 kOe, the temperature dependence of $H_{c}$ has no maximum and shows an exponential decrease with increasing temperature. Similar trends have been observed over a wide concentration range. The concentration dependence of $H_{c}$ is associated with the magnetic phase diagram.

• Proceedings of the Korean Magnestics Society Conference
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• 2014.05a
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• pp.146-147
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• 2014

• Proceedings of the Korean Magnestics Society Conference
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• 2016.11a
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• pp.124-124
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• 2016